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Answer Key & Solution Explanation, JEE Advanced Test Series, Paper-2 (21 April 2024)

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0% found this document useful (0 votes)
81 views30 pages

Answer Key & Solution Explanation, JEE Advanced Test Series, Paper-2 (21 April 2024)

Uploaded by

mrinalthakur214
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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JEE ADVANCED PAPER – 2

APNI KAKSHA RANKERS PROGRAM

Time : 3 Hours Maximum Marks : 180

PART – 1 : MATHEMATICS
SECTION 1 (Maximum marks: 24)
• This section contains EIGHT (08) questions.
• The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 TO 9, BOTH
INCLUSIVE.
• For each question, enter the correct integer corresponding to the answer using the mouse
and the onscreen virtual numeric keypad in the place designated to enter the answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : ⁡+𝟑 If ONLY the correct integer is entered;
Zero Marks : 0 If the question is unanswered;
Negative Marks : −𝟏 In all other cases.

0 x4 ln⁡ x+2 e2 +a
1. If ∫1 dx = −ln⁡(e2 + 1) where a & b are positive integers. Then value of a + b is
x3 ln⁡ x+x b

2. Number of principal solution(s) of the equation

3. The sum of the coefficients of all the even powers of x in the expansion of (2x 2 − 3x + 1)11 is
P1m P2n where &P2 are prime numbers, P1 < P2 and m&n are positive integers.
P1 +P2
The value of is
n−m

1 1
4. If α + and 2 − β − (α, β > 0) are the roots of the quadratic equation
α β

x 2 − 2(a + 1)x + a − 3 = 0, then the sum of integral value of ' a '.

5. If line ax + by −1 = 0 intercepted between lines ax + y + 1 = 0⁡&⁡x + by = 0 subtends 90∘ at


origin (a, b ∈ R), then maximum possible value of 24a, is

10x −1
6. Number of values of x for which fog(x) = gof f(x) where f(x) = & g(x) = x + 1, is
10x +1

7. A pair of students is selected at random from a probability class. The probability that the pair
10
selected will consist of one male and one female student is . Find the sum of the digits of the
19
maximum number of students the class can contain.

APNI KAKSHA 1
JEE ADVANCED PAPER – 2
APNI KAKSHA RANKERS PROGRAM
π
8. Let ABC be the triangle with AB = 1, AC = 3 and ∠BAC = . If a circle of radius r > 0 touches the
2
sides AB, AC and also touches internally the circumcircle of the triangle ABC, then the value of
r + √10 is

SECTION 2 (Maximum marks: 24)

• This section contains SIX (06) questions.


• Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four
option(s) is (are) correct answer(s).
• For each question, choose the option(s) corresponding to (all) the correct answer(s).
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +𝟒 ONLY if (all) the correct option(s) is (are) chosen:
Partial Marks : +𝟑 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +𝟐 If three or more options are correct but ONLY two options are chosen,
both of which are correct;
Partial Marks : +𝟏 If two or more options are correct but ONLY one option is chosen
and it is a correct option;
Zero Marks : 0 If unanswered;
Negative Marks : −𝟐 In all other cases.

x2 y2 x
9. If P is any point on the ellipse 2
+ = 1 and S is the focus of the elliase and (where x & y arc
a b2 y

coprime natural mumbers) is ratio of the area of the ellipse and the area enclosed by the locus
of mid-point of PS, then which of the following is/are true
(A) x + y = 5 (B) |y − x| = 3

(C) x + y = 10 (D) x 2 + y 2 = 17

10. A line kx − y = 0 intersects the curve y = 1 − √x − 1 at


1−√2 1−√2
(A) no point for k ∈ ( , 1) (B) no point for k ∈ (−∞, ) ∪ (1, ∞)
2 2

1−√2
(C) two points for k ∈ ( , 0) (D) one point for k ∈ [0, ∞)
2

√2sin⁡ x
11. If the maximum and minimum value of the expression y = are m and n respectively,
3−cos⁡ x
then
m
(A) = −1
n

APNI KAKSHA 2
JEE ADVANCED PAPER – 2
APNI KAKSHA RANKERS PROGRAM
(B) 3 m + n = 1
1
(C) m2 + n2 =
4
(D) m − n = 1
x2 y2
12. On an ellipse + = 1, tangents drawn at P1 , P2 , … P8 intersects the major axis at T1 , T2 , … T8
64 9
(area of △Pi Ti F1 )( area of ΔPi Ti F2 )
respectively. If the value of ∑8i=1 = N, where F1 and F2 are the
(Pi Ti )2

foci of ellipse, then


(A) N is perfect square
(B) N is even number
(C) N is prime number
(D) N is composite number

π/2
13. If un = ∫0 cosn x cosnx⁡dx,
π
(A) u1 = 4
π
(B) u2 = 8
π
(C) u3 = 32
π
(D) u4 = 32

14. Let S be the reflection of a point Q with respect to the plane given by
r⃗ = −(t + p)ı̂ + tȷ̂ + (1 + p)k̂
where t, p are real parameters and ı̂, k̂, k̂ are the unit vectors along the three positive coordinate
axes. If the position vectors of Q and S are 10ı̂ + 15ȷ̂ + 20k̂ and αı̂ + βȷ̂ + γk̂ respectively, then
which of the following is/are TRUE ?
(A) 3(α + β) = −101
(B) 3(β + γ) = −71
(C) 3(γ + α) = −86
(D) 3(α + β + γ) = −121

APNI KAKSHA 3
JEE ADVANCED PAPER – 2
APNI KAKSHA RANKERS PROGRAM

SECTION 3 (Maximum Marks: 12)


• This section contains FOUR (04) questions.
• Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the
correct answer.
• For each question, choose the option corresponding to the correct answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks ⁡ :⁡⁡⁡⁡ + 3 If ONLY the correct option is chosen;
Zero Marks ⁡ :⁡⁡⁡⁡ + 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks ⁡ :⁡⁡⁡⁡ − 1 In all other cases.

⃗⃗ = ı̂ + k̂ and c⃗ = ı̂ + 2ȷ̂ − 3k̂ be three given vectors. If r⃗ is a vector such that


15. Let a⃗⃗ = 2ı̂ − 7ȷ̂ + 5k̂, b
⃗⃗ = 0, then |r⃗| is equal to:
r⃗ × a⃗⃗ = c⃗ × a⃗⃗ and r⃗ ⋅ b
11 11 11 √914
(A) √2 (B) √2 (C) (D)
7 5 7 7

π
16. If α, β ∈ ( 2 ; π) and α < β, then which one of the following is true
α β
(A) ecos α−cosβ < (B)ecos β−cosα <
β α
β α
(C) ecos α−cosβ < (D) ecos β−cosα <
α β

−1 ⁡ y dy
17. The solution of the differential equation (1 + y 2 ) + (x − etan ) = 0 is
dx
−1 ⁡ y −1 ⁡ y −1 ⁡ y −1 ⁡ y
(A) 2xetan = e2tan +c (B) xe2tan = e2tan +c
tan−1 ⁡ y tan−1 ⁡ y
(C) xe = tan−1 ⁡ y + c (D) x − 2 = ce
(where c is an arbitrary constant)

18. Lee α and β be the roots of x 2 − x − 1 = 0, with α > β. For all positive integers n, define
αn −βn
an = , n ≥ 1, b1 = 1 and bn = an−1 + an+1 , n ≥ 2.
α−β

Then which of the following options is/are correct?


an 9
(A) ∑∞
n=1 =
10n 89
(B) bn = αn + βn for all n ≥ 1
(C) a1 + a2 + ⋯ + an = an+2 for all n ≥ 1
bn 8
(D) ∑∞
n=1 =
10n 89

APNI KAKSHA 4
JEE ADVANCED PAPER – 2
APNI KAKSHA RANKERS PROGRAM

PART – 2 : PHYSICS
SECTION - 1 (Maximum marks : 24)
• This section contains EIGHT (08) questions.
• The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 TO 9, BOTH INCLUSIVE.
• For each question, enter the correct integer corresponding to the answer using the mouse and the
on-screen virtual numeric keypad in the place designated to enter the answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks ⁡: ⁡ + 𝟑 If ONLY the correct integer is entered;
Zero Marks : 0 If the question is unanswered;
Negative Marks : ⁡ ⁡ − 𝟏⁡ In all other cases.

19. Two long wires with negligible resistance are shunted at their end by a large resistor R and at
the other ends are connected to a source of constant voltage. The radius of the cross section of
each wire is smaller than the distance between the axes of the two wires by a factor of 20. If the
value of the resistance R, at which resultant force of interaction of the wires vanishes, is
(N × 90)Ω, then find the value of N. (given ln20 = 3)

20. An infinite long straight wire that carries a current l1 = 50 A is partially surrounded by a loop
as shown in the diagram. The loop has a length ℓ = 50 cm and a radius R = 25 cm and it carries
current I2 = 20 A. The axis of loop coincides with the infinite wire. The force that acts on the
loop is 4k × 10−4 N. Find the value of k.

APNI KAKSHA 5
JEE ADVANCED PAPER – 2
APNI KAKSHA RANKERS PROGRAM
21. A uniform chain of mass per unit length λ is sliding down the hill with constant speed u.
Dimension of the hill are h and d as shown. Find the momentum of the chain at the instant
shown. (given λ = 1 kg/m, d = 3 m, h = 4 m, and u = 1 m/s)

22. A current I is flowing through a thin cylinder of radius R. The pressure exerted on the cylinder
μ0 I2
due to the flow of current is . Find the value of k.
kπ2 R2

23. A capacitor in an LC oscillator has a maximum potential difference of 15 V and a maximum


energy of 360μJ. At a certain instant the energy in the inductor is 320μJ. At that instant, what is
the potential difference across the capacitor in Volts?

24. A particle moves along a parabolic path y = 9x 2 in such a way that the x component of velocity
remains constant and has a value 1/3 m/s. The acceleration of the particle is kȷ̂ m/s2 . Find the
value of k.

25. Between two isotherms, a cyclic process ABCDA is performed with one mole of ideal mono-
atomic gas. The work done in 1 cycle is 25 K Joule. Find K.

26. In the figure shown, a block B of mass 10 kg rests on a bracket A


(shaded) of 30 kg, All the surfaces are smooth. Find the
magnitude of relative acceleration (in m/s 2 ) of bracket A
(shaded) with respect to block B. (Pulley and string are ideal)

APNI KAKSHA 6
JEE ADVANCED PAPER – 2
APNI KAKSHA RANKERS PROGRAM
SECTION - 2 (Maximum marks : 24)
• This section contains 𝐒𝐈𝐗(𝟎𝟔) questions.
• Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four
option(s) is (are) correct answer(s).
• For each question, choose the option(s) corresponding to (all) the correct answer(s).
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks ⁡: ⁡ ⁡ + 𝟒 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks ⁡: ⁡ ⁡ + 𝟑 If all the four options are correct but ONLY three options are chosen;
Partial Marks ⁡⁡⁡:⁡⁡⁡ + 𝟐 If three or more options are correct but ONLY two options are chosen,
both of which are correct;
Partial Marks :⁡+𝟏 If two or more options are correct but ONLY one option is chosen and it is
a correct option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : ⁡ − 𝟐 In all other cases.

27. A disc of radius a and mass m rests between two light rods, which are smoothly hinged
together at point O with their ends A and B resting on a smooth table and are maintained in
equilibrium by string AB as shown in the figure. Choose the correct option (s).

mg
(A) The magnitude of normal force acting on the rod at point A is .
2
mg
(B) The magnitude of normal force acting on the rod at point A is .
2cos⁡ α
mg a
(C) The tension in the string AB is [cot⁡ α + c sec 2 ⁡ α]
2
mg a
(D) The tension in the string AB is [tan⁡ α + c cosec 2 ⁡ α]
2

APNI KAKSHA 7
JEE ADVANCED PAPER – 2
APNI KAKSHA RANKERS PROGRAM

28. A uniform rod of length 4 m and mass 2√2 kg revolves with constant angular velocity ω about a
vertical axis through a smooth joint A at one extremity of the rod so that it describes a cone of
semi vertical angle 53∘ as shown in the figure. Choose the correct statement(s). (g = 10 m/s 2 )

(A) The value of angular velocity ω is 2.5rad/s


(B) The angle between hinge reaction at point A and vertical axis AC is 45∘
(C) The magnitude of hinge reaction at point A is 40 N
(D) The angular momentum of the rod is constant.

29. A uniform cube of mass 4 kg and side 30 cm is placed on a frictionless horizontal surface. A
vertical force F is applied to the edge as shown in the figure. Choose the most appropriate
option(s). (take g = 10 m/s 2 )

(A) Cube will move in the upward direction if F > 40 N


(B) Cube will not perform any type of translation or rotation motion if 10 N < F < 20 N
(C) Cube will begin to perform rotational motion if 20 N < F < 40 N
(D) Normal reaction applied by the surface shifts to a distance 5 cm from centre C of the cube if
F = 10 N

30. In the given figure, a wire loop has been bent so that it has three segments. Portion OABO is a
quarter circle in xy plane, portion OBC is a right angle triangle in xz plane and portion OCDAO is
a square in yz plane. Here are three choices for a magnetic field through the loop.
(1) ⃗B⃗1 = 3ı̂ + 7ȷ̂ − 5tk̂
(2) ⃗B⃗2 = 5tı̂ − 4ȷ̂ − 15k̂
(3) ⃗B⃗3 = 2ı̂ − 5tȷ̂ − 12k̂

APNI KAKSHA 8
JEE ADVANCED PAPER – 2
APNI KAKSHA RANKERS PROGRAM

⃗⃗1 , B
If the induced current in the loop due to B ⃗⃗2 and B
⃗⃗3 are ı̇1 , ı̇2 and i3 respectively then:
(A) i1 < i2 (B) i1 > i3 (C) i3 > i2 > i1 (D) i1 = i2 = i3

31. Four identical conducting rods are connected by pins. The velocity of point R is v. A uniform
magnetic field B acts out of the paper. Choose the correct statement(S).
(PQ = PS = 4ℓ and QR = SR = 3ℓ)

6Bℓv
(A) The motional emf across PQ is
5
3Bℓv
(B) The motional emf across PQ is
5
3Bℓv
(C) The motional emf across QR is
5
6Bℓv
(D) The motional emf across QR is
5

k
32. Magnetic field in a cylindrical region is varying as B = t, where k is a positive constant. ' t ' is
r
time and r ' is distance from the centre. At the origin where r is zero magnetic field is negligibly
small. A charge q of mass m is released from rest at a distance r0 from the centre. Then choose
the correct option(s).

(A) Force on the charge particle just after the release is qk/2
(B) Force on the charge just after the release is qk.
(C) Magnetic flux in a cylindrical region of radius ' r ' as a function of time 4 ' is 2πktr.
(D) Magnetic flux in a cylindrical region of radius ' r ' as a function of time 4 ' is πktr.
APNI KAKSHA 9
JEE ADVANCED PAPER – 2
APNI KAKSHA RANKERS PROGRAM

SECTION - 3 (Maximum marks : 12)


• This section contains FOUR (04) questions.
• Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the
correct answer.
• For each question, choose the option corresponding to the correct answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks ⁡ :⁡⁡⁡⁡ + 3 If ONLY the correct option is chosen;
Zero Marks ⁡:⁡⁡⁡⁡⁡⁡⁡⁡⁡0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks ⁡: ⁡ ⁡⁡ − 1⁡ In all other cases.

33. In the circuit shown in the figure, the ideal ammeter reading for current is taken
(a) with both switches open (b) with both switches closed

The readings are same in the cases. The value of resistance R is


(A) 2Ω (B) 3Ω (C) 4.5Ω (D) 7.5Ω

34. An equilateral triangular plate of uniform mass density is moving on


a horizontal smooth surface. The acceleration of the vertices A and B
at a particular time t 0 . are 4 m/s 2 and directed along the sides of the
triangle ABC as shown in the figure.
The mass of the triangular plate is 10 kg its and its side is 2 m. O is
the centre of mass of triangular plate. Choose the correct statement.
(A) The acceleration of the third vertex of rectangular plate is 2 m/s 2 and directed along CB
from C to B.
(B) The acceleration of the third vertex of rectangular plate is 2 m/s2 and directed along CO
from C to O
(C) The acceleration of the third vertex of rectangular plate is 4 m/s 2 and directed along CB
from C to B.
(D) The acceleration of the third vertex of rectangular plate is 4 m/s2 and directed along CO
from C to 0.

APNI KAKSHA 10
JEE ADVANCED PAPER – 2
APNI KAKSHA RANKERS PROGRAM
35. A conducting movable rod AB lies across the frictionless parallel conducting rails in a uniform
magnetic field ⃗B⃗ whose magnitude at t = 0 is B0 . The rod AB is given velocity v right ward and
it continues to move with same velocity through out the motion.

[The acceleration due to gravity is along negative z-axis, i.e. ⃗g⃗ = 10 m/s 2 (−k̂),mass of rod = m.]
Which of the following graphs will be the best representation of magnitude of magnetic field
versus time.

(A) (B)

(C) (D)

36. A square plate of mass 10 kg and side 20 m is moving along the groove with the help of two
ideal roller (massless), connected at the corners A and B of the square as shown in the figure.
At the given instant of time during motion (as shown in the figure), the corner A is moving with
velocity 16 m/s downward. Find the speed of corner D (approximately).

APNI KAKSHA 11
JEE ADVANCED PAPER – 2
APNI KAKSHA RANKERS PROGRAM

PART – 3 : CHEMISTRY

SECTION 1 (Maximum Marks: 24)


• This section contains EIGHT (08) questions.
• The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 TO 9, BOTH INCLUSIVE.
• For each question, enter the correct integer corresponding to the answer using the mouse and the
onscreen virtual numeric keypad in the place designated to enter the answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : ⁡ + 𝟑 ONLY if the correct numerical value is entered;
Zero Marks : 0 In all other cases.
Negative Marks : −𝟏 In all other cases.

37. 3 ( aq. ) ⇌ [Ag(S2 O3 )2 ]


AgBr(s) + 2 S2 O2− 3−
+ Br − (aq.)
Given: K sp (AgBr) = 5 × 10−13 ; K f [Ag⁡(S2 O3 )2 ]3− = 5 × 1013
If the molar solubility of AgBr in 0.1MNa2 S2 O3 is ' x ', find the value of x (up to one decimal
places) give answer by multiplying 1000.

38. The oxidation number of Mn in the product of alkaline oxidative fusion of MnO2 is

39. The number of sp2 carbon atoms in the product formed from the following reaction sequence
is______.

40. 100ml0.05MCuSO4 solution is electrolysed using a current of 0.965amp for 100 minutes. Find
out pH of the solution at the end of electrolysis.
warm
41. For given reaction: (excess) LiH + Al2 Cl6 → ′
X ′ + LiCl.
Find out coordination number of aluminum atom in compound ' X '.
42. The number of products from the following, which cannot be formed on nitration of 1,3-
dichlorobenzene with a mixture of concentrated nitric acid and sulfuric acid is

APNI KAKSHA 12
JEE ADVANCED PAPER – 2
APNI KAKSHA RANKERS PROGRAM
43. How many molecular species will produce O2 on reaction with water at room temperature (
note: H2 O2 undergoes slow decompositions at room temp).

CrO5 , XeOF4 , I2 , XeF4 , Br2 , XeF2 , Cl2 , Na2 O2 , F2

44. The total number of chiral molecules formed from one molecules of Q on complete ozonolysis
(O3 , H2 O2 ) is_______.

SECTION 2 (Maximum Marks: 24)


• This section contains 𝐒𝐈𝐗⁡(𝟎𝟔) questions.
• Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four
option(s) is(are) correct answer(s).
• For each question, choose the option(s) corresponding to (all) the correct answer(s).
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks ⁡ :⁡⁡ + 𝟒 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks : +⁡𝟑 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +⁡𝟐 If three or more options are correct but ONLY two options are chosen,
both of which are correct;
Partial Marks : ⁡ + 𝟏 If two or more options are correct but ONLY one option is chosen and it is
a correct option;
Zero Marks : 0 If unanswered;
Negative Marks : −𝟐 In all other cases.

45. In FCC crystal, identify the correct statements(s) {a = edge length of unit cell }
(A) Size of octahedral void is more than that of tetrahedral void
√3 a
(B) Shortest distance between two tetrahedral voids is 2

√2a
(C) Shortest distance between two octahedral voids is 2

(D) Tetrahedral void is surrounded by 6 sphere.

APNI KAKSHA 13
JEE ADVANCED PAPER – 2
APNI KAKSHA RANKERS PROGRAM
46. For the given compound, % s character of phosphorous hybrid orbitals which contribute to
various bonds are given in the table below.

This difference in % ‘s’ character of various phosphorous bonds could be due to


(A) The large size of bromine atom
(B) The large electronegative difference between P and O
(C) Increased overlap of σ-orbitals of terminal P-O bond
(D) Stroger covalent character of P-O in cyclic oxygen atoms

47. In which of the following, a new C − C bond formed in the product?

(A) I (B) II (C) III (D) IV

48. Select correct statement(s) :


(A) Colloid is not a substance but it's a state of substance.
(B) Clouds are aerosols having small droplets of water suspended in air.
(C) The droplets in emulsions are often positively charged and can be precipitated by
electrolytes.
(D) Charge and solvation of the colloidal particles are responsible for the stability of lyophilic
sols.

49. Lowest unoccupied molecular orbital (LUMO) of which of the following molecular species has
centre of symmetry
(A) N2 (B) C2 (C) O2 (D) Li2

APNI KAKSHA 14
JEE ADVANCED PAPER – 2
APNI KAKSHA RANKERS PROGRAM
50. The compound /s which form /s stable hydrate/s is/are

(A) a (B) b (C) c (D) d

SECTION 3 (Maximum Marks: 12)


• This section contains FOUR (04) questions.
• Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the
correct answer.
• For each question, choose the option corresponding to the correct answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks :⁡⁡⁡⁡+𝟑 ONLY if the option corresponding to the correct combination is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −𝟏 In all other cases.

51. Based on below graph plotted between boiling point and mole fraction in liquid phase for the
liquid binary mixture. Comment on the liquid mixture.

(A) Ideal solution


(B) Showing negative deviation from Raoult’s law
(C) Showing positive deviation from Raoult’s law
(D) Mixture of two immiscible volatile liquids
52. Identify the compound which differ in its colour from rest of the three:
(A) Potassium hexanitritocobaltate (III)
(B) Tetraamminecopper (II) sulphate
(C) Ferric ferrocyanide
(D) Hexaamminenickel (II) chloride

APNI KAKSHA 15
JEE ADVANCED PAPER – 2
APNI KAKSHA RANKERS PROGRAM
53. Among the following sets of compounds, the one in which a reaction between them followed by
hydrolysis that does not lead to the formation of 1-phenyl-2- butanol is
(A) phenylacetaldehyde and ethylmagnesium bromide
(B) butanal and phenylmagnesium bromide
(C) propanal and benzylmagnesium bromide
(D) 1-phenyl-2-butanone and NaBH4

54.

Calculate the number of moles (up to two decimal places) in the glass bulb shown in figure at
300 K (assume gas is ideal).

Given: density of glycerine = 2.72 g/mL; ⁡ density of mercury = 13.6 g/mL


(A) 0.63
(B) 0.94
(C) 0.85
(D) 0.92

APNI KAKSHA 16
JEE ADVANCED PAPER – 2
APNI KAKSHA RANKERS PROGRAM

ANSWER KEY

SECTION – 1
Q. 1 2 3 4 5 6 7 8
A. 5.00 6.00 5.00 5.00 3 2 2 4
SECTION – 2
Q. 9 10 11 12 13 14
MATHS
A. ABD BC ABD BD ABD ABC
SECTION – 3
Q. 15 16 17 18
A. A B A B

SECTION – 1
Q. 19 20 21 22 23 24 25 26
A. 4 2 5 8 5 2 3 8
SECTION – 2
Q. 27 28 29 30 31 32
PHYSICS
A. AC ABC ABCD AB AD BC
SECTION – 3
Q. 33 34 35 36
A. C C B B

SECTION – 1
Q. 37 38 39 40 41 42 43 44
A. 45 6 6 1 4 2 5 1
SECTION – 2
Q. 45 46 47 48 49 50
CHEMISTRY
A. AC AC ACD ABD AB AC
SECTION – 3
Q. 51 52 53 54
A. A A B B

APNI KAKSHA 17
JEE ADVANCED PAPER – 2
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Solutions

PART – 1 : MATHEMATICS

0 x4 ln⁡ x+x2 −x2 +2 0 0 x2 −2


1. ∫1 dx = ∫1 xdx − ∫1 dx
x3 ln⁡ x+x x3 ln⁡ x+x
1 2
0 0 −
x x3
∫1 xdx − ∫1 1 dx
ln⁡ x+ 2
x

2. cos⁡ x + sin⁡ x + sin⁡ 2x + cos⁡ 2x + sin⁡ 3x = −1


⇒ (sin⁡ x + sin⁡ 3x) + (cos⁡ x + sin⁡ 2x) = −(1 + cos⁡ 2x)
⇒ 4sin⁡ x − 4sin3 ⁡ x + cos⁡ x(1 + 2sin⁡ x) = −2cos2 ⁡ x
⇒ 4sin⁡ x(1 − sin2 ⁡ x) + 2cos2 ⁡ x + cos⁡ x(1 + 2sin⁡ x) = 0
⇒ (2 cos2 x + cos x)(1 + 2 sin x) = 0
1 1
So, cos⁡ x = 0, − 2 , sin⁡ x = − 2

11 11
(2×12 −3×1+1) +(2(−1)2 −3(−1)+1)
3. Sum = = 3 × 610 = 210 ⋅ 311
2

4. f(x) = x 2 − 2(a + 1)x + (a − 3)


f(0) ≤ 0 and f(2) ≤ 0.

5. Combined equation of lines is


(ax + y + 1)(x + by) = 0
homogenize - ax 2 + b2 + (ab + 1)xy + (x + by)(ax + by) =
perpendicular lines ⇒ a + a + b + b2 = 0
1 1 2 1
⇒ 2a = −b − b2 = − (b + ) ≤ ⇒ 24a ≤ 3
4 2 4

6. fog(x) = gof(x)
10x+1 − 1 10x − 1 2.10x
⇒ = + 1 =
10x+1 + 1 10x + 1 10x + 1
3.10x + 1
use C & D ⇒ 10 x+1
= ⁡ Let 10x = t
1 − 10x
1 1
⇒ 10t 2 − 7t + 1 = 0 ⇒ t = or
2 5

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7. Let total students = n and No. of Boys = x
⁡x C1 ⋅ ⁡n−x C1 10 2 ⋅ x ⋅ (n − x) 10
Probability = n
= ⇒⁡ = ⇒ ⁡19x 2 − 19nx + 5x(n − 1) = 0
⁡ C2 19 n(n − 1) 19
D ≥ 0 ⇒ 0 ≤ n ≤ 20

8.

Now for circle S is


S: (x − r)2 + (y − r)2 = r 2

⁡S: x 2 + y 2 − 2xr − 2yr + r 2 = 0


⁡⇒ CG = |r − r1 |
2
1 2 3 2 √10
⇒ (r − ) + (r − ) = (r − )
2 2 2
1 9
⇒ r2 + − r + r 2 + − 3r
4 4
10 5 5
= r2 + − r√10 = r 2 − 4r + = − r√10
4 2 2
= r = 4 − √10
⇒ r + √10 = 4

x2 y2
9. Let a2 + b2 = 1 be an ellipse

Area = A1 = πab
Let (h, k) be the midpoint of PS
⇒ 2 h = acos⁡ θ + ae&2k = bsin⁡ θ
Eliminating θ we get
ae 2
(x − ) 2
2 + y =1
a 2 b 2
(2) (2)
ab πab
A2 = π 2 2 = 4
x
⇒ A1 : A2 = 4: 1 = =4
y
APNI KAKSHA 19
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10. Given curve is lower branch of parabola
(y − 1)2 = x − 1
and line is y = kx where k is slope of line

√2sin⁡ 𝑥
11. 𝑦 = 3−cos⁡ 𝑥
𝑥
2tan⁡
2
√2 𝑥
1+tan2 ⁡ 2√2𝑡
2
= 𝑥 𝑥
3(1+tan2 ⁡ )−(1−tan2 ⁡ )
= 2+4𝑡 2
2 2
𝑥
1+tan2 ⁡
2

√2𝑡
𝑦 = 1+2𝑡 2 ⁡ ⇒ 2𝑦𝑡 2 − √2𝑡 + 𝑦 = 0 = t ∈ R ⇒ ⁡D > 0
1 1
2 − 8𝑦 2 ≥ 0 ⇒ 4𝑦 2 − 1 ≤ 0⁡𝑦 ∈ [− 2 , 2]
1 1
n = −2, m = 2

12. (Area of △ PTF1 ). (Area of △ PTF2 )


1 1 PT 2 ⋅ b2
= ( PT ⋅ F1 N1 ) ( P𝑇 ⋅ F2 N2 ) =
2 2 4
8
( area of ΔP𝑖 T1 𝐹1 )( area of ΔPi Ti F2 ) 1
∑ = × 9 × 8 = 18 square units
(Pi Ti )2 4
𝑖=1

13. We have,
2/2 cos𝑛 𝑥 𝑠𝑖𝑛 𝑛𝑥 𝜋/2 𝜋/2 sin𝑛𝑥
𝑢𝑛 = ∫0 cos𝑛 𝑥𝑐𝑜𝑠𝑛𝑥 𝑑𝑥 ⇒ 𝑢𝑛 = [ ] + 𝑛 ∫0 cos 𝑛−1 ⁡ 𝑥sin⁡ 𝑥 𝑑𝑥
𝑛 0 𝑛
𝜋
𝜋/2
⇒ 𝑢𝑛 = ∫0 cos𝑛−1 ⁡ 𝑥sin𝑥sin𝑛𝑥𝑑𝑥 ⇒ 𝑢𝑛 = ∫02 cos𝑛−1 𝑥{cos(𝑛 − 1) 𝑥 − cos xcos 𝑛𝑥} 𝑑𝑥⁡
[∵ cos⁡(𝑛 − 1)𝑥 = cos⁡ 𝑛𝑥cos⁡ 𝑥 + sin⁡ 𝑛𝑥sin⁡ 𝑥]
𝜋/2 𝜋/2
⇒ 𝑢𝑛 = ∫0 cos𝑛−1 ⁡ 𝑥cos⁡(𝑛 − 1)𝑥𝑑𝑥 − ∫0 cos𝑛 𝑥cos𝑛𝑥𝑑𝑥
⇒ 𝑢𝑛 = 𝑢𝑛−1 − 𝑢𝑛 ⇒ 2𝑢𝑛 = 𝑢𝑛−1
𝑢𝑛 1 1
⇒𝑢 = 2 for all 𝑛 = 2,3, … … . ⁡ ⇒ 𝑢1 , 𝑢2 , 𝑢3 … … . form a G.P. with common ratio 2 .
𝑛−1
𝜋
1 𝑛−1 𝜋 1 𝑛−1 𝜋 𝜋
Now, ⁡𝑢𝑛 = 𝑢1 (2) = 4 (2) ⇒ 𝑢𝑛 = 2𝑛+1 ⁡⁡⁡⁡⁡⁡⁡⁡⁡⁡ [∵ 𝑢1 = ∫02 cos 2 𝑥𝑑𝑥 = 4 ]

APNI KAKSHA 20
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14. r⃗ = −(t + p)ı̂ + tȷ̂ + (1 + p)k̂


x = −t − p⁡y = t⁡z = 1 + p
∵x+y+z= 1
So, equation of the plane is x + y + z − 1 = 0
α − 10 β − 15 γ − 20 −2(10 + 15 + 20 − 1) −2(44)
= = = =
1 1 1 12 + 12 + 12 3
88 −58
α = 10 − =
3 3
88 −43
β = 15 − =
3 3
88 −28
γ = 20 − =
3 3

3(α + β) = −101
3(β + γ) = −71
3(α + γ) = −86
3(α + β + γ) = −129

⃗⃗ = (c⃗ × a⃗⃗) × ⃗⃗
15. (r⃗ × a⃗⃗)xb b
−(a⃗⃗ ⋅ ⃗⃗
b)r⃗ = (c⃗. ⃗⃗
b)a⃗⃗ − (a⃗⃗. ⃗⃗
b)c⃗ − 7r⃗ = −2(2ı̂ − 7ȷ̂ + 5k̂) − 7(ı̂ + 2ȷ̂ − 3k̂) = 7|r⃗| = 11√2
18. Since α and β are roots of x 2 − x − 1 = 0.
∴ ⁡α + β = 1, αβ = −1
∞ ∞
an 1 α n β n
⁡⁡⁡⁡⁡∑ = ⋅ ∑ {( ) − ( ) }
10n α − β 10 10
n=1 n=1

α β α β
1 1 − 10 1 10(α − β) 10
= { 10 − 10 }= [ 10 ]= [ ]=
α−β 1− α β α−β α+β αβ α − β 100 − 10(α + β) + αβ 89
10 1 − 10 1 − ( 10 ) + 100

Again, bn = an+1 + an−1 , n ≥ 2


(αn+1 − βn+1 ) + (αn−1 − βn−1 )
=
α−β
(αn+1 − βn+1 ) + (−αn β + αβn ) n n−1 n−
(α − β)(αn + βn )
= ⁡(∵ αβ = αβ ⋅ β = −β ) = = αn + βn
α−β α−β
Also, for n = 1, b1 = 1 = α + β
∴ bn = αn + βn , n > 1
∞ ∞ α β α β 2αβ
bn (αn + βn ) α n β n 10 10 10 + 10 − 100
∑⁡ n = ∑ = ∑ {( ) + ( ) } = α + =
10 10n 10 10 1 − β 100 − 10(α + β) + αβ
n=1 n=1 10 1 − 10 100
10(α + β) − 2αβ 12
⁡⁡⁡⁡⁡= =
100 − 10(α + β) + αβ 89
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Clearly, ak+2 − ak+1 − ak = 0
αk+2 −βk+2 αk (α+1)−βk (β+1)
∵ ak+2 = = = ak+1 + ak ]
[ α−β α−β
⇒ ak = ak+2 − ak+1
Now, a1 = a3 − a2
a2 = a4 − a3
an = an+2 − an+1
Adding all above equations, we get
a1 + a2 + ⋯ + an = an+2 − a2
α2 − β2
⁡= an+2 − = an+2 − (α + β)
α−β
⁡= an+2 − 1

APNI KAKSHA 22
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PART – 2 : PHYSICS
19. For unit length of wire,
Fe = λE ⇒ electric force
2λ λ2
=λ =
4πε0 ℓ 2πε0 ℓ
λ ⇒ excess charge per unit length of wire
μ0 |2
Fm ⇒ ⇒ magnetic force
2πℓ

According to given question


Fe = Fm
λ2 μ0 |2
=
2πε0 ℓ 2πℓ

1 2 1 ℓn20 V 2 1 μ0 ℓn20
⇒ ⁡( ) = ⇒ ⁡( × ) = ⇒ ⁡R = √ ( ) = 360Ω
λ ε0 μ0 πε0 V R μ0 ε0 ε0 π

μ0 h1 2×2×10−7 ×50×20×0.50
20. F=2× × μ2 ℓ = = 8 × 10−4 N
2πR 0.25

21. Momentum of segment of mass dm and length dℓ


dp
⃗⃗ = dmu(cos⁡ θı̂ + sin⁡ θȷ̂)
= uλ[dℓcos⁡ θı̂ + dℓsin⁡ θȷ̂]
⃗⃗ = μλ[∫ ⁡ dxı̂ + ∫ ⁡ dyȷ̂]
𝐏
⃗⃗ = uλ[dı̂ + hȷ̂]
p

P = uλ√d2 + h2

= 1 × 1√32 + 42 = 5 kg − m/s

1
23. CV02 = 360 × 10−6
2

360 × 10−6 × 2
⇒C= F
225
When energy stored in capacitor is 40μJ, then let potential difference across the capacito volt,
so
1 2 1 360 × 10−6 × 2
CV = 40 × 10−6 ⇒ × × V 2 = 40 × 10−6
2 2 225
40 × 10−6 × 225
⇒ V2 = ⇒ V = 5 volt
360 × 10−6

APNI KAKSHA 23
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dy dx
24. = 18x dt = 6x
dt

d2 y dx
ay = = 6
dt 2 dt
= 2 m/s2
ax = 0
Concept Involved: (i) Equation of motion
Air: 1 - 5000

P V
25. From diagram, P2 = V2 (since AC passes through origin)
1 1

P P P T
Process AB ⇒ Isochoric ⇒ so WAB = 0 ⇒ T 2 = T 1 ⇒ P2 = TB
B A 1 A

Process BC ⇒ Isobaric ⇒ WBC = P2 V2 − P2 V1 ⇒ WBC = nR(TC − TB )


Process CO ⇒ Isochoric ⇒ WCD = 0
Process CD ⇒ Isobaric ⇒ WDA = P1 V1 − P1 V2 = nR(TA − TD )
W = nR[(TA + TC ) − (TB + TD )] = nR[T1 + T2 ] − (P2 V1 + P1 V2 )

26. F − 2T = ma1
T = ma
T = 3ma′
a + a′
a1 =
2
on solving
F
a − a1 = = 5 m/s 2
4m
mg
27. N2 + F2 = Ncos⁡ θ = 2
mg
N=
2cos⁡ α
mg
T + Nsin⁡ α = F1 ⇒ T + tan⁡ α = F1
2

Taking torque about O

Tc sin⁡ α − N2 ccos⁡ α = Nx

mg mg
⇒ Tcsin⁡ α − cos⁡ α = atan⁡ α
2 2cos⁡ α
mg mg mg atan⁡ α mg a
⇒ Tcsin⁡ α = cos⁡ α + atan⁡ α = [cos⁡ α + ]⇒T= [cot⁡ α + ]
2 2cos⁡ α 2 cos⁡ α 2 cos2 ⁡ α

APNI KAKSHA 24
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28. According to translational equilibrium of rod
L
Rsin = m)2 2 sin⁡ θ

Rcos⁡ ϕ = mg
ω2 Lsin⁡ θ
tan⁡ θ = 2g

1Consider the rotational equilibrium


L
L m
mg sin⁡ θ = ∫ ( ) ω2 xsin⁡ θxcos⁡ θ(dx)
2 0 L
L
mgL m 2
= sin⁡ θ = () sin⁡ θcos⁡ θ ∫ x 2 dx
2 L 0

mgL mω2 cos⁡ θL2 3g 30 × 5


⇒ = = ω2 = =
2 3 2Lcos⁡ θ 2 × 4 × 3
(θ) = 2.5rad/s
5 5 4 1
tan⁡ ϕ = 2 × 2 × 4 × 5 × 20 = 1 ⇒ ϕ = 45∘
3mg
Rsin⁡ ϕ = tan⁡ θ = mg
4
⇒ R = √2mg = 40 N

29. Mg = N + F
Mg − F = N ≥ 0 → body will not move upward
40N ≥ F
Not to perform any motion
a
Mg = N + F, Nx = F
2
Fa
N=
2x
a Mg a
Mg = F [ + 1] ⇒ −1=
2x F 2x
aF a Mg
x= ≤ ⇒ F ≤ Mg − F ⇒ F ≤ = 20N
2(Mg − F) 2 2
30. When ⃗B⃗1 is present
5πa2 t 5πa2 5πa2 3.927a2
ϕ1 = ⇒ e1 = ⇒ i1 = =
4 4 4R R
When ⃗B⃗2 is present
5a2
ϕ2 = 5a2 t ⇒ e1 = 5a2 ⇒ i4 =
R
5a2 t 5a2 5a2
When ⃗B⃗3 is present ϕ2 = ⇒ e1 = ⇒ i1 =
2 2 2R

APNI KAKSHA 25
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31. Velocity of R along QR = vcos⁡ 53∘ = 3v/5
⇒ Net velocity of Q = 3v/5 (along QR)
3v
ωPQ =
5(4ℓ)
1 3v 6Bℓv
ePQ = B( ) (4ℓ)2 =
2 20ℓ 5

vsin⁡ 53 4v
Also, ωQR = =
3ℓ 15ℓ
1 4v 6 BℓV
⇒ eQR = B ( ) (9/)2 =
2 15/ 5
24
33. When both switches are open, then reading of ammeter is = 3 A When both switches are
8

closed. VAB = 9V
⇒ VHG = 15
⇒ So current through R is 2A.
Hence R = 9/2 = 4.5Ω

34. Since speed is constant, it means there is no induced emf ϕ = ℓ(b +


vt)B
dB
e = ℓBv + ℓ(b + vt) dt = 0
dB
⇒ (b + vt) dt = −Bv
B dB t dt
⇒ ∫B = −v ∫0
0 B b+vt
1 b+vt b
⇒ ℓnB/B0 = −v [v ℓln⁡ ( )] = ℓn (b+vt)
b
0 B b
⇒ B = b+vt

Second Method:
So flux does not change with time, so
ϕ(t) = ϕ(t + dt)
⇒ Bℓ(b + vt) = B + dB)ℓ[b + v(t + dt)]

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⇒ (b + vt)dB + Bvdt = 0
dB dt B0 b
⇒ = −v ⇒B=
B b + vt b + vt
Range < 2000
Concept involved: Faraday's law of electromagnetic induction

35. cos⁡ 37∘ = x/a ⇒ x = 4a/5 = 16 m. ⇒ ω = 1rad/s.


a2 + x 2 − y 2
os ⁡ 53∘ =
2ax
⇒ a2 + x 2 − y 2 = 384
⇒ y 2 = 400 + 256 − 384 = 272
⇒ y = 16.5 m( approximately)
vD = yω = 16.5 m/s

36. T = m2 gsin⁡ 30∘


ηAv
T = m1 gsin⁡ 30∘ +

From equation (i) and (ii) we can write

ηAv
= (m2 − m1 )gsin⁡ 30∘ = mgsin⁡ 30∘

mgℓsin⁡ 30∘ 0.02 × 10 × 0.3 × 10−3
η= = 3.46 × 10−3 PaS
vA 2 × 0.085 × 0.1

APNI KAKSHA 27
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PART – 3 : CHEMISTRY

37. AgBr(s) ⇌ Ag + (aq) + Br − (aq)K sp

3−
Ag + (aq) + 2 S2 O2−
3 (aq) ⇌ Ag(S2 O3 )2 (aq)K f
3−
AgBr(s) + 2 S2 O2− −
3 (aq) ⇌ Ag(S2 O3 )2 (aq) + Br (aq)K = K sp × K f = 25

x2
K=
(0.1 − 2x)2
x = 0.045M

38. MnO−2
4

39.

40. Cathode reaction: Cu+2 + 2e− ⟶ Cu


Anode reaction: 2H2 O ⟶ O2 + 4H + + 4e−
Net reaction: 2Cu+2 + 2H2 O ⟶ 2Cu + O2 + 4H +
5 × 10−3 mole⁡0

0⁡5 × 10−3 mole10−2 mole

Volume = 100ml = 0.1 litre

10−2
(H + ) = ⇒ 10−1
0.1

PH = 1

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41. LiAlH4

43. CrO5 , XeOF4 , XeF2 , Na2 O2 , F2

44.

46. The most possible approach to answer the question is by Bent rule. Bromine being large, poor
overlapping results in weak sigma bonding, and lower s character in the hybrid orbital of P. The
oxygen of Exo or terminal P = O uses hybrid orbitals of more s-character as it overlaps to a
greater extent. The oxygen of the cyclic ring therefore can not have a strong covalent sigma
bond as Exo P = O. As there are two types of P − O bonds, B could not be the reason The
answer is A and C

48. Refer NCERT

49. LUMO of N2 is pi∗ and LUMO of C2 is sigma

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50. Ninhydrin (a) and 1, 1, 1, 3, 3, 3-hexafluoropropan-2-one (c) will form stable hydrates due
to their capability to take part in intramolecular Hydrogen bonding.

52. A is yellow while (B), (C) and (D) all are blue

53. butanal and phenylmagnesium bromide followed by hydrolysis gives 1-phenyl-2butanol.

54. h × d(glycerine) = h × d(mercury)


5 × 2.72 = h × 13.6
h=1m
Pgas = 1760 mmHg OR (1000 + 760)mmHg
PV = nRT
1760
× 10 = n × 0.082 × 300
760
n = 0.94 mol

APNI KAKSHA 30

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