By Abhishek Tiwari sir (IIT Delhi)

________________ATOMIC STRUCTURE_______________
Test No. :1

Q1. The pair, in which ions are isoelectronic (b) J. J. Thomson suggested that the nucleus of
with Al3+ is: an atom contains protons
(a) Br– and Be2+ (b) Cl– and Li+ (c) The atomic number of an element is the
(c) S2– and K+ (d) O2– and Mg2+ same as the number of protons in the nucleus
Q2. Which of the following is isoelectronic? of its atom
(a) CO2, NO2 (b) NO-2 ,CO2 (d) The mass number of an atom is equal to the
(c) CN- ,CO (d) SO2 ,CO2 number of electrons in its shells
39 𝑒
Q3. One atom of 19𝐾 contains : Q8. The constancy of 𝑚 ratio for electrons
(a) 19p; 20n and 19e– inspite of variations of gas present in the
(b) 19p; 20n and 20e– discharge tube or of the material of the cathode
(c) 20p; 19n and 20e– shows that :
(d) 20p; 19n and 19e– (a) electrons are negatively charged
Q4. The species that has the same number of (b) electrons are universal constituents of
electrons as 3517 𝐶𝑙 is matter
32
(a) 16 𝑆 (b) 32
16 𝑆
+
(c) electrons are the lightest of all particles
(c) 40
18 𝐴𝑟
+
(d) 35
16 𝑆
2− 1
(d) mass of the electron is of the mass of
Q5. Observe the following statements 1838

regarding isotones: H-atom

I. 39K and 40Ca are isotones. Q9. If the velocity of the electron in the
II. Nuclides having different atomic (Z) and hydrogen atom in its first orbit is 2.18 × 106
mass numbers (A) but same number of ms–1, then will be the velocity of the electron in
neutrons (n) are called isotones. the second orbit of Li2+?
III. 19F and 23Na are isotones. (a) 2.18 ×106 ms-1 (b) 3.27 ×106 ms-1
The correct answer is (c) 6.54 ×106 ms-1 (d) 1.45 ×106 ms-1
(a) 1, 2 and 3 are correct Q10. The wavelength of a spectral line emitted
(b) Only 1 and 2 are correct by hydrogen atom in the Lyman series is
16
(c) Only 1 and 3 are correct cm. What is the value of n2?
15𝑅
(d) Only 2 and 3 are correct (R = Rydberg constant)
Q6. Hydrogen has three isotopes (A), (B) and (a) 2 (b) 3
(C). If the number of neutron(s) in (A), (B) and (c) 4 (d) 1
(C) respectively, are (x), (y) and (z), the sum of Q11. The position of both an electron and
(x), (y) and (z) is helium atom is known within 1.0 nm. The
(a) 4 (b) 3 momentum of the electron is known within
(c) 2 (d) 1 5.0 × 10-26 kg ms-1. The minimum uncertainty
Q7. Which one of the following statements is in the measurement of the momentum of the
correct? helium atom is
(a) Rutherford's alpha-particle scattering (a) 7.0 ×10-26 kg ms-1
experiment lead to the discovery of electron (b) 5.0 ×10-26 kg ms-1

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 By Abhishek Tiwari sir (IIT Delhi)

________________ATOMIC STRUCTURE_______________
Test No. :1

(c) 8.0 ×10-26 kg ms-1 Q17. The longest wavelength present in Balmer
(d) 6.0 ×10-26 kg ms-1 series lines is
Q12. The energy of an electron in nth orbit of [Given Rydberg constant = 1.097 x 107 m-1]
hydrogen atom is (a) 640 nm (b) 656 nm
13.6 13.6
(a) 𝑒𝑉 (b) 𝑒𝑉 (c) 662 nm (d) 670 nm
𝑛4 𝑛3
13.6 13.6 Q18. Two particles of masses m & 2m have
(c) − 𝑒𝑉 (d) 𝑒𝑉
𝑛2 𝑛 equal kinetic energies. The de-Broglie
Q13. Given below are two statements: wavelength are in the ratio of_____ ]
Statement-I Rutherford's gold foil experiment (a) 1 : 1 (b) 1 : 2
cannot explain the line spectrum of hydrogen (c) 1 : 2 (d) 2 :1
atom. Q19. The ratio of de-Broglie wavelength of two
Statement-II Bohr's model of hydrogen atom particles A and B is 2 : 1. If the velocities of A
contradicts Heisenberg's uncertainty principle. and B are 0.05 ms–1 and 0.02 ms–1 respectively
In the light of the above statements, choose the then the ratio of their masses MA : MB must be
most appropriate answer from the options ______.
given below: (a) 5 : 1 (b) 10 : 1
(a) Statement I is false but statement II is true. (c) 1 : 5 (d) 1 : 8
(b) Statement I is true but statement II is false. Q20. The work functions of Ag, Mg, K and Na
(c) Both statement I and statement II are false. respectively in eV are 4.3, 3.7, 2.25, 2.30, When
(d) Both statement I and statement II are true. an electromagnetic radiation of wavelength of
Q14. For d-electron, the orbital angular 300 nm is allowed to fall on these metal
momentum is surface, the number of metals from which the
6ℎ 2ℎ
(a) 2𝜋 (b) electrons are ejected is
2𝜋
ℎ 2ℎ (1ev = 1.6022 × 10–19J)
(c) 2𝜋 (d) 𝜋 (a) 4 (b) 3
Q15. The energy of mole of photons of (c) 2 (d) 5
radiation of wavelength 300 nm is Q21. Which of the following statements is
(given h = 6.63 × 10–34Js, correct about photoelectric effect ?
NA= 6.02 × 1023 mol–1 C = 3 × 108 ms–1) (A) The number of electrons ejected from
(a) 235 kJ mol–1 (b) 325 kJ mol–1 metal surface is inversely proportional to
(c) 399 kJ mol–1 (d) 435 kJ mol–1 intensity of light.
Q16. The minimum energy that must be (B) Below threshold frequency, photoelectric
possessed by photons in order to produce the effect can be observed.
photoelectric effect with platinum metal is (C) At higher frequency than threshold
[Given: The threshold frequency of platinum is frequency, the ejected electrons have certain
1.3× 1015 s–1 and h = 6.6 × 10–34 Js.] kinetic energy.
(a) 3.21 × 10–14 J (b) 6.24 × 10–16 J (D) At higher frequency than threshold
(c) 8.58 × 10–19 J (d) 9.76 × 10–20 J frequency, the electron is still on the metal
surface.
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 By Abhishek Tiwari sir (IIT Delhi)

________________ATOMIC STRUCTURE_______________
Test No. :1

(a) 1 (b) 2 [m=9.1×10-31 kg; c=3.0×108 ms-1;

(c) 3 (d) 4 1eV=1.6×10-19 Js]
Q22. If two particles A and B are moving with Q26. de Broglie relationship has no significance
the same velocity. But wavelength of A is found for
to be double than that of B. Which of the (a) An electron (b) A proton
following statements are correct? (c) A neutron (d) An iron bal
(a) Both A and B have same mass Q27. If the kinetic energy of a particle is
(b) Mass of A is half that of B reduced to half, de-Broglie wavelength
(c) Mass of B is half that of A becomes :
(d) Mass of B is one-fourth that of A (a) 2 times (b) 1/ 2 times
Q23. Identify the correct statements regarding (c) 4 times (d) 2 times
Balmer series: The wave number of each line in Q28. The basis of quantum mechanical model
the spectrum of atomic hydrogen is given the of an atom is
1 1
equation 𝑣 = 𝑅𝐻 − 𝑛 2 where RH is a (a) Angular momentum of electron
𝑛 12 2
constant and n1 and n2 are integers. (b) Quantum numbers
(c) Dual nature of electron
(i) As wave length decrease, the lines in the
series constant (d) Black body radiation
(ii) The integer n1 is equal to 2 Q29. A certain metal when irradiated by light
(iii) The ionization energy of hydrogen can be (r = 3.2 × 1016Hz) emits photoelectrons with
calculated from the wave number of these lines twice kinetic energy as did photoelectrons
(iv) The line of longest wavelength when the same metal is irradiated by light
corresponds to n2 = 3 (r = 2. 0 × 1016Hz). The v0 of metal is
(a) (i), (ii) & (iii) only (a) 1.2 × 1014 Hz (b) 8 × 1015 Hz
(b) (i), (iii) & (iv) only (c) 1.2 × 1016 Hz (d) 4 × 1012 Hz
(c) (ii) & (iv) only Q30. Assertion: Threshold frequency is the
(d) (ii), (iii) & (iv) only maximum frequency required for the ejection
Q24. Which of the following relations is correct, of electron from the metal surface.
if the wavelength (λ) is equal to the distance Reason: Threshold frequency is characteristic
travelled by the electron in one second? of a metal.
h is the Planck's constant and m is the mass of (a) If both Assertion and Reason are correct
and the Reason is the correct explanation of
electron
(a) λ = h/p (b) λ = h/m Assertion
(b) If both Assertion and Reason are correct,
(c) λ = ℎ/𝑝 (d) λ = ℎ/𝑚
but Reason is not the correct explanation of
Q25. When light of wavelength 248nm falls on Assertion.
a metal of threshold energy 3.0 eV, the (c) If Assertion is correct but Reason is
deBroglie wavelength of emitted electrons incorrect.
is______Å. (Round off to the Nearest Integer). (d) If both the Assertion and Reason are
incorrect
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 By Abhishek Tiwari sir (IIT Delhi)

________________ATOMIC STRUCTURE_______________
Test No. :1

Q31. Assertion: All photons possess the same ℎ 1 ℎ

(c) ∆𝑣 ≥ (d) ∆𝑣 ≥ 𝑚
amount of energy. 𝜋 𝜋
Reason: Energy of photon does not depend Q35. A proton and a Li3+ nucleus are
upon wavelength of light used. accelerated by the same potential. If λLi and λP
(a) If both Assertion and Reason are correct denote the de Broglie wavelengths of Li3+ and
and the Reason is a correct explanation of the λ 𝐿𝑖
proton respectively, then the value of is
λ𝑃
Assertion.
𝑥 × 10-1. The value of x is _____
(b) If both Assertion and Reason are correct
(Rounded off to the nearest integer)
but Reason is not a correct explanation of the
[Mass of Li3+ = 8.3 mass of proton]
Assertion.
Q36. Which of the following pairs is not
(c) If the Assertion is correct but Reason is
correctly matched?
incorrect.
(a) Hund’s rule In orbitals of
(d) If both the Assertion and Reason, are
equivalent energy
incorrect.
electron spins remain
(e) If the Assertion is incorrect but the Reason
unpaired if possible.
is correct.
Q32. The mass of a photon with wavelength (b) Pauli's exclusion No two electrons can
3.6Å shall be principle have all the four
(a) 61.35×10-34 kg (b) 6.135×10-29 kg quantum number
(c) 7.185×10-29 kg (d) 71.85×10-29 kg identical.
Q33. Which one is the wrong statement? (c) Zeeman effect the effect of magnetic
ℎ field on the atomic
(a) The uncertainty principle is ∆𝐸 × ∆𝑡 ≥ 2𝜋
spectra.
(b) Half filled and fully filled orbital have (d) Uncertainty It is impossible to
greater stability due to greater exchange principle determine the
energy, greater symmetry and more balanced position of an
arrangement. electron.
(c) The energy of 2s-orbital is less than the Q37. The de Broglie wavelength of an electron
energy of 2p-orbital in case of hydrogen like in the 4 th Bohr orbit is
atoms. (a) 6πa0 (b) 2πa0
ℎ
(d) de-Broglie's wavelength is given by 𝜆 = 𝑚𝑣 , (c) 8πa0 (d) 4πa0
where m = mass of the particle, v = group Q38. When an electron in an excited hydrogen
velocity of the particle atom jumps from an energy level for which n =
Q34. If the uncertainty in momentum and 5 to level for which n = 2, the spectral line is
uncertainty in the position of a particle are observed in the which series of the hydrogen
equal. then the uncertaintiy in its velocity spectrum?
would be given by _______. (a) Lyman (b) Balmer
ℎ 1 ℎ (c) Paschen (d) pfund
(a) ∆𝑣 ≥ (b) ∆𝑣 ≥ 2𝑚
2𝜋 𝜋

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 By Abhishek Tiwari sir (IIT Delhi)

________________ATOMIC STRUCTURE_______________
Test No. :1

Q39. Which one of the following series of lines Q44. Which of the following atomic orbitals is
is found in the UV region of atomic spectrum of not directed along the axis?
hydrogen? (a) px (b) 𝑑𝑥 2 −𝑦 2
(a) Balmer (b) Paschen (c) dxy (d) 𝑑𝑧 2
(c) Brackett (d) Lyman Q45. The orbital angular momentum of a p-
Q40. The ratio of the highest to the lowest electron given as
wavelength of Lyman series is (a)
ℎ
(b) 3
ℎ

(a) 4 : 3 (b) 9 : 8 2𝜋 2𝜋
3ℎ ℎ
(c) 27 : 5 (d) 16 : 5 (c) (d) 6 2𝜋
2𝜋
Q41. Which of the following orbitals will have
zero probability of finding the electron in the Q46. Quantum numbers l = 2 and m = 0
yz plane? represent the orbital
(a) px (b) py (a) dxy (b) 𝑑𝑥 2 −𝑦 2
(c) pz (d) dyz (c) 𝑑𝑧 2 (d) dxz
Q42. Identity the incorrect statement from the Q47. The total number of orbitals in the fifth
following energy level is
(a) All the five 4d orbitals have shapes similar (a) 5 (b) 10
to the respective 3d orbitals. (c) 18 (d) 25
(b) In an atom, all the five 3d orbitals are equal Q48. Which one of the following electronic
in energy in free state. arrangements is absurd?
(c) The shapes of dxy, dyz and dxz orbitals are (a) n=3,l=1,m= –1
similar to each other; and 𝑑𝑥 2 −𝑦 2 and 𝑑𝑧 2 are (b) n=3, l =0, m= 0
similar to each other. (c) n=2, l =0, m= –1
(d) All the five 5d orbitals are different in size (d) n=2, l =1, m= 0
when compared to the respective 4d orbitals. Q49. Consider the following pairs of electrons
Q43. Which of the following statements are (A) (a) n = 3 , l = 1 , m1 = 1 , ms = +1/2
correct? (a) The electronic configuration of Cr (b) n = 3 l = 2, m1 = 1 , ms= +1/2
is (Ar) 3d5 4s1 (B) (a) n = 3 , l = 2 , m1= - 2, ms= - 1/2
(b) The magnetic quantum number may have a (b) n = 3 , l = 2 , m1= - 1 , ms= - 1/2
negative value (C) (a) n = 4, l = 2, m1= 2, ms= +1/2
(c) In the ground state of an atom, the orbitals (b) n = 3 , l = 2 , m1= 2 , ms= +1/2
are filled in order of their increasing energies The pairs of electrons present in degenerate
(d) The total number of nodes are given by n–2 orbitals is/are:
Choose the most appropriate answer from the (a) Only (A) (b) Only (B)
options given below: (c) Only (C) (d) (B) and (C)
(a) (a), (c) and (d) only Q50. The orbital with 4 radial and 1 angular
(b) (a) and (b) only nodes is
(c) (a) and (c) only (a) 5py (b) 6pz
(d) (a), (b) and (c) only (c) 4dxy (d) 5dyz

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