Chemical Kinetics
Chemical Kinetics
Chemical Kinetics
Definition of terms:
Reaction rate
It is the measure of the change in concentration of the reactants or the change in
concentration of the products per unit time.
1 d[A] 1 d [B]
a dt
= b dt
= k [ A ]a [B ]b
d [CH 3 COOC 2 H 5]
Rate = dt
d [NaOH ]
= - dt
= k[CH3COOC2H5]^1 [NaOH]^1
Reaction order
It is the relationship between the concentrations of species and the rate of a reaction.
a b
k [ A ] [B ]
Molecularity
A reaction whose overall order is measured can be considered to occur through
several steps or elementary reactions.
Simplified term: It is the number of molecules, atoms, or ions reacting in an
elementary process.
Bimolecular - It is because two molecules, one of H2 and one of I2, must come
together to form the product HI.
H2 + I2 -> 2HI
Termolecular - reactions , that is. Processes in which three molecules must come
together simultaneously, are rare.