SAFETY DATA SHEET

Australian statement of hazardous nature : Classified as hazardous according to criteria of NOHSC

Section 1 - Identification
Product Name Iron (III) chloride anhydrous

Product Code AJA220

Address ThermoFisher Scientific Australia Pty Ltd
5 Caribbean Drive, Scoresby
VICTORIA 3179, Australia
Emergency Tel. CHEMTREC®
03 9757 4559 or +613 9757 4559
Telephone / Fax Numbers Tel: 1300 735 292
Fax: 1800 067 639
E-mail address [email protected]

Recommended Use Laboratory chemicals.

Section 2 - Hazard(s) Identification

Classification under the National Occupational Health and Safety Commission (NOHSC), Australia

Classified as hazardous according to criteria of NOHSC

Physical hazards
No hazards identified

Health hazards

Acute Oral Toxicity Category 4

Skin Corrosion/irritation Category 2
Serious Eye Damage/Eye Irritation Category 1
Skin Sensitization Category 1

Environmental hazards
No hazards identified

Label Elements

Exclamation Mark Corrosion

Signal Word Danger

Hazard Statements
H302 - Harmful if swallowed
H315 - Causes skin irritation
H317 - May cause an allergic skin reaction
H318 - Causes serious eye damage
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Precautionary Statements
P261 - Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray
P264 - Wash face, hands and any exposed skin thoroughly after handling
P270 - Do not eat, drink or smoke when using this product
P272 - Contaminated work clothing should not be allowed out of the workplace
P280 - Wear protective gloves/ protective clothing/ eye protection/ face protection
P302 + P352 - IF ON SKIN: Wash with plenty of soap and water
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing
P310 - Immediately call a POISON CENTER or doctor/ physician
P330 - Rinse mouth
P362 - Take off contaminated clothing and wash before reuse
P403 - Store in a well-ventilated place
P501 - Dispose of contents/ container to an approved waste disposal plant

Other information
No information available

Section 3 - Composition and Information on Ingredients

Component CAS-No Weight %
Iron(III) chloride 7705-08-0 100

Section 4 - First Aid Measures

Inhalation Move to fresh air.

Ingestion Clean mouth with water and drink afterwards plenty of water.

Skin Contact Wash off immediately with soap and plenty of water while removing all contaminated
clothes and shoes.

Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

Protection of First-aiders Ensure that medical personnel are aware of the material(s) involved, take precautions to
protect themselves and prevent spread of contamination.

First Aid Facilities Eyewash, safety shower and washroom.

Most important symptoms/effects Causes eye burns. May cause allergic skin reaction. Causes severe eye damage.
Symptoms of allergic reaction may include rash, itching, swelling, trouble breathing, tingling
of the hands and feet, dizziness, lightheadedness, chest pain, muscle pain or flushing

Notes to Physician Treat symptomatically.

Section 5 - Fire Fighting Measures

Suitable Extinguishing Media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Extinguishing media which must not be used for safety reasons

No information available.

Specific Hazards Arising from the Chemical

Thermal decomposition can lead to release of irritating gases and vapors.
Special protective equipment and precautions for fire fighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
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Section 6 - Accidental Release Measures

Emergency procedures
Ensure adequate ventilation.
Environmental Precautions
See Section 12 for additional ecological information. Do not flush into surface water or sanitary sewer system.

Reference to Other Sections

Refer to protective measures listed in Sections 8 and 13.

Section 7 - Handling and Storage

Precautions for Safe Handling
Ensure adequate ventilation.

Conditions for Safe Storage, Including any Incompatibilities

Keep container tightly closed in a dry and well-ventilated place.
AS/NZS 2243.10:2004, Safety in laboratories - Storage of chemicals

Section 8 - Exposure Controls and Personal Protection

Exposure limits
AUS - Exposure Standards for Atmospheric Contaminants in the Occupational Environment - Guidance Note on the Interpretation
of Exposure Standards for Atmospheric Contaminants in the Occupational Environment [NOHSC:3008(1995)]
Adopted National Exposure Standards for Atmospheric Contaminants in the Occupational Environment [NOHSC:1003(1995)]
updated in August, 2005. Safe Work Australia ACGIH - Threshold Limit Values - Ceiling (TLV-C) guidelines by the American
Conference of Governmental Industrial Hygienists (ACGIH) for controlling worker exposure to airborne chemical concentrations in
the workplace. UK - EH40/2005 Containing the workplace exposure limits (WELs) for use with the Control of Substances
Hazardous to Health Regulations (COSHH) 2002 (as amended). Updated by September 2006 official press release and October
2007 Supplement.
Component Australia New Zealand WEL ACGIH TLV The United Kingdom Germany
Iron(III) chloride TWA: 1 mg/m3 TWA: 1 mg/m3 STEL: 2 mg/m3 15 min
TWA: 1 mg/m3 8 hr

Biological limit values

This product, as supplied, does not contain any hazardous materials with biological limits established by the region specific
regulatory bodies

Exposure Controls
Engineering Measures
Ensure that eyewash stations and safety showers are close to the workstation location.

Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or
equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to
control hazardous materials at source

Personal protective equipment

Eye Protection Goggles (Australian/New Zealand Standard AS/NZS 1337 - Eye protectors for Industrial
applications)
Hand Protection Protective gloves

Glove material Breakthrough time Glove thickness AUS/NZ Standard Glove comments
Natural rubber See manufacturers - AS/NZS 2161.1 (minimum requirement)
Nitrile rubber recommendations
Neoprene
PVC
Inspect gloves before use.
Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves.
(Refer to manufacturer/supplier for information)
Ensure gloves are suitable for the task: Chemical compatability, Dexterity, Operational conditions, User susceptibility, e.g.

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sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger
of cuts, abrasion.
Remove gloves with care avoiding skin contamination.

Skin and body protection Long sleeved clothing

Repiratory Protection Use an AS/NZS 1716 approved respirator if exposure limits are exceeded or if irritation or
other symptoms are experienced. To protect the wearer, respiratory protective equipment
must be the correct fit and be used and maintained in line with AS/NZS 1715 on the use
and maintenance of repiratory protective devices
Recommended Filter type: Particulates filter conforming to EN 143 (or AUS/NZ equivalent)
Recommended half mask:- Particle filtering: EN149:2001 (or AUS/NZ equivalent)
When RPE is used a face piece Fit Test should be conducted

Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.

Environmental exposure controls Prevent product from entering drains. Do not allow material to contaminate ground water
system.

Section 9 - Physical and Chemical Properties

Information on basic physical and chemical properties

Appearance Yellow
Physical State Solid

Odor No information available

Odor Threshold No data available
pH No information available
Melting Point/Range 292 °C / 557.6 °F
Softening Point No data available
Boiling Point/Range 319 °C / 606.2 °F
Flash Point Not applicable Method - No information available
Evaporation Rate Not applicable Solid
Flammability (solid,gas) No information available
Explosion Limits No data available

Vapor Pressure No data available

Vapor Density Not applicable Solid
Specific Gravity / Density No data available
Bulk Density No data available
Water Solubility No information available
Solubility in other solvents No information available
Partition Coefficient (n-octanol/water)
Component log Pow
Iron(III) chloride -4
Autoignition Temperature Not applicable
Decomposition Temperature No data available
Viscosity Not applicable Solid
Explosive Properties No information available
Oxidizing Properties No information available

Other information
Molecular Formula FeCl3
Molecular Weight 162.21

Section 10 - Stability and Reactivity

Reactivity None known, based on information available

Stability Stable under normal conditions.

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Conditions to Avoid Heat, flames and sparks.

Hazardous Decomposition Products None under normal use conditions.

Hazardous Polymerization No information available.

Section 11 - Toxicological Information

Information on Toxicological Effects

Product Information
(a) acute toxicity;
Oral Category 4
Dermal Based on available data, the classification criteria are not met
Inhalation Based on available data, the classification criteria are not met

Component LD50 Oral LD50 Dermal LC50 Inhalation

Iron(III) chloride 450 mg/kg ( Rat )
316 mg/kg ( Rat )
(b) skin corrosion/irritation; Category 2

(c) serious eye damage/irritation; Category 1

(d) respiratory or skin sensitization;
Respiratory Based on available data, the classification criteria are not met
Skin Category 1

No information available

(e) germ cell mutagenicity; Based on available data, the classification criteria are not met

(f) carcinogenicity; Based on available data, the classification criteria are not met
There are no known carcinogenic chemicals in this product
(g) reproductive toxicity; Based on available data, the classification criteria are not met
(h) STOT-single exposure; Based on available data, the classification criteria are not met

(i) STOT-repeated exposure; Based on available data, the classification criteria are not met

Target Organs None known.

(j) aspiration hazard; Not applicable
Solid

Symptoms / effects,both acute and Symptoms of allergic reaction may include rash, itching, swelling, trouble breathing, tingling
delayed of the hands and feet, dizziness, lightheadedness, chest pain, muscle pain or flushing

Section 12 - Ecological Information

Ecotoxicity effects Contains a substance which is:. Harmful to aquatic organisms. The product contains
following substances which are hazardous for the environment. Toxic to aquatic organisms.
Component Freshwater Fish Water Flea Freshwater Algae Microtox
Iron(III) chloride LC50: = 75.6 mg/L, 96h EC50: = 9.6 mg/L, 48h
static (Gambusia affinis) Static (Daphnia magna)
LC50: 20.95 - 22.56 EC50: = 27.9 mg/L, 48h
mg/L, 96h semi-static (Daphnia magna)
(Pimephales promelas)
LC50: = 20.26 mg/L,
96h semi-static
(Lepomis macrochirus)
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Persistence and Degradability No information available

Persistence Persistence is unlikely.
Degradability Not relevant for inorganic substances.
Degradation in sewage Contains substances known to be hazardous to the environment or not degradable in waste
treatment plant water treatment plants.
Bioaccumulative Potential Bioaccumulation is unlikely

Component log Pow Bioconcentration factor (BCF)

Iron(III) chloride -4 2756 - 9622
Mobility No information available.
Endocrine Disruptor Information This product does not contain any known or suspected endocrine disruptors
Persistent Organic Pollutant This product does not contain any known or suspected substance
Ozone Depletion Potential This product does not contain any known or suspected substance

Section 13 - Disposal Considerations

Waste from Residues / Unused Do not allow into drains or watercourses or dispose of where ground or surface waters may
Products be affected. Wastes, including emptied containers, are controlled wastes and should be
disposed of in accordance with all federal, E.P.A., state and local regulations. Assure
conformity with all applicable regulations.

Contaminated Packaging Dispose of this container to hazardous or special waste collection point.

Other Information Chemical wastes should be disposed through a licensed commercial waste collection
service. Do not dispose of waste into sewer. Waste codes should be assigned by the user
based on the application for which the product was used. Do not empty into drains.

Section 14 - Transport Information

IMDG/IMO

UN-No UN1773
Proper Shipping Name FERRIC CHLORIDE, ANHYDROUS
Technical Shipping Name Iron (III) Chloride Anhydrous
Hazard Class 8
Packing Group III

ADG

UN-No UN1773
Proper Shipping Name FERRIC CHLORIDE, ANHYDROUS
Technical Shipping Name Iron (III) Chloride Anhydrous
Hazard Class 8
Packing Group III
Component Hazchem Code
Iron(III) chloride 2X
7705-08-0 ( 100 )
IATA

UN-No UN1773
Proper Shipping Name FERRIC CHLORIDE, ANHYDROUS
Technical Shipping Name Iron (III) Chloride Anhydrous
Hazard Class 8
Packing Group III

Environmental hazards No hazards identified

Special Precautions No special precautions required
Additional information None known

Section 15 - Regulatory Information

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Safety, health and environmental regulations/legislation specific for the substance or mixture

International Inventories X = listed

Component AICS NZIoC EINECS ELINCS TSCA DSL NDSL PICCS ENCS IECSC KECL
Iron(III) chloride X X 231-729- - X X - X X X X
4
Standard for the Uniform
Scheduling of Medicines and
Poisons
Component Standard for the Uniform Scheduling of Health Surveillance
Medicines and Poisons
Iron(III) chloride Schedule 2 listed
Schedule 4 listed - in injectable preparations
for human use
Schedule 5 listed - for the treatment of
animals except up to 1% of Iron oxides when
present as an excipient;in preparations for
injection except in preparations containing
<=0.1% of Iron
Schedule 5 listed - for the treatment of
animals except up to 1% of Iron oxides when
present as an excipient;in other preparations
except in liquid or gel preparations
containing <=0.1% of Iron;or in animal feeds
or feed premixes
Schedule 5 listed - In garden preparations
except in preparations containing <=4% of
Iron
Schedule 6 listed - except up to 1% of Iron
oxides when present as an excipient. For the
treatment of animals except when included in
Schedule 5;in liquid or gel preparations
containing <=0.1% of Iron;or in animal feeds
or feed premixes
Prohibition or notification/licensing Shown below are details of specific prohibition/notifications or licencing requirements when
requirements they apply.

Section 16 - Other Information

Legend

AICS - Australian Inventory of Chemical Substances NZIoC - New Zealand Inventory of Chemicals
TSCA - United States Toxic Substances Control Act Section 8(b) EINECS/ELINCS - European Inventory of Existing Commercial Chemical
Inventory Substances/EU List of Notified Chemical Substances
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic ENCS - Japanese Existing and New Chemical Substances
Substances List
IECSC - Chinese Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances CAS - Chemical Abstracts Service
TWA - Time Weighted Average ACGIH - American Conference of Governmental Industrial Hygienists
IARC - International Agency for Research on Cancer PNEC - Predicted No Effect Concentration
ICAO/IATA - International Civil Aviation Organization/International Air IMO/IMDG - International Maritime Organization/International Maritime
Transport Association Dangerous Goods Code
MARPOL - International Convention for the Prevention of Pollution from ADG Australian Code for the Transport of Dangerous Goods by Road
Ships and Rail
NZS 5433:2012 - Transport of Dangerous Goods on Land OECD - Organisation for Economic Co-operation and Development
LD50 - Lethal Dose 50% LC50 - Lethal Concentration 50%
EC50 - Effective Concentration 50% ATE - Acute Toxicity Estimate
WEL - Workplace Exposure Limit RPE - Respiratory Protective Equipment
DNEL - Derived No Effect Level NOEC - No Observed Effect Concentration
POW - Partition coefficient Octanol:Water BCF - Bioconcentration factor
vPvB - very Persistent, very Bioaccumulative PBT - Persistent, Bioaccumulative, Toxic
VOC - Volatile Organic Compounds

Key literature references and sources for data

Suppliers safety data sheet, Chemadvisor - LOLI, Merck index, RTECS

Training Advice
Chemical hazard awareness training, incorporating labelling, Safety Data Sheets (SDS), Personal Protective Equipment (PPE) and
hygiene.
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Use of personal protective equipment, covering appropriate selection, compatibility, breakthrough thresholds, care, maintenance, fit
and standards.
First aid for chemical exposure, including the use of eye wash and safety showers.

Revision Date 18-May-2016

Revision Summary Update to Format.

This safety data sheet complies with the requirements of Safe Work Australia WHS
Regulation
Disclaimer

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text

End of Safety Data Sheet

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