Scribd Logo
Upload

Welcome to Scribd!

  • 11 views

    2022 Answer Key 1 15

    Uploaded by

    Andrei Ainsley Dolorosa
    This document discusses the concentration of malonic acid needed for a reaction and calculates the mass of ammonium chloride needed to achieve a specific pH. It also analyzes which solution from a set of options would have the lowest pH based on the ions produced from dissociation. Additional questions are included about chemical concepts and principles.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd

    2022 Answer Key 1 15

    Uploaded by

    Andrei Ainsley Dolorosa
    11 views7 pages
    This document discusses the concentration of malonic acid needed for a reaction and calculates the mass of ammonium chloride needed to achieve a specific pH. It also analyzes which solution from a set of options would have the lowest pH based on the ions produced from dissociation. Additional questions are included about chemical concepts and principles.

    Original Title

    2022-Answer-Key-1-15

    Copyright

    © © All Rights Reserved

    Available Formats

    DOCX, PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    This document discusses the concentration of malonic acid needed for a reaction and calculates the mass of ammonium chloride needed to achieve a specific pH. It also analyzes which solution from a set of options would have the lowest pH based on the ions produced from dissociation. Additional questions are included about chemical concepts and principles.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    11 views7 pages

    2022 Answer Key 1 15

    Uploaded by

    Andrei Ainsley Dolorosa
    This document discusses the concentration of malonic acid needed for a reaction and calculates the mass of ammonium chloride needed to achieve a specific pH. It also analyzes which solution from a set of options would have the lowest pH based on the ions produced from dissociation. Additional questions are included about chemical concepts and principles.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    You are on page 1of 7

    1.

    SKIP (Chat Gpt needs the initial concentration of malonic acid)

    2. A. 4.7g
    Given data :

    Volume of water ( V ) = 250 mL = 0.25 L

    pH of solution = 4.85

    Kb = 1.8 * 10⁻⁵

    Kw = 10⁻¹⁴

    Given that the dissolution of NH₄Cl gives NH₄⁺⁺ and Cl⁻ ions the equation is written as :

    NH₄CI + H₂O ⇄ NH₃ + H₃O⁺

    where conc of H₃O⁺

    [ H₃O⁺ ] = and Ka = Kw / Kb

    ∴ Ka = 5.56 * 10⁻¹⁰

    Next step : Determine the concentration of H₃O⁺ in the solution

    pH = - log [ H₃O⁺ ] = 4.85

    ∴ [ H₃O⁺ ] in the solution = 1.14125 * 10⁻⁵

    Next step : Determine the concentration of NH₄CI in the solution

    C = [ H₃O⁺ ]² / Ka

    = ( 1.14125 * 10⁻⁵ )² / 5.56 * 10⁻¹⁰


    = 0.359 mol / L

    Determine the number of moles of NH₄CI in the solution

    n=C.V

    = 0.359 mol / L * 0.25 L = 0.08979 mole

    Final step : determine the mass of ammonium chloride that must be added to 250 mL

    mass = n * molar mass

    = 0.08979 * 53.5 g/mol

    = 4.80 g ≈ 4.7 grams

    Therefore we can conclude that the mass of ammonium chloride that must be added is 4.7 g

    3. Letter E, KCl
    To determine the solution with the lowest pH, we need to consider the nature of
    the ions in each solution and their effect on the pH.
    -KF (Potassium Fluoride): KF will dissociate into K⁺ and F⁻ ions. F⁻ ions are the
    conjugate base of HF, a weak acid. The presence of F⁻ ions can result in a
    slightly basic solution, but it won't be highly effective at accepting protons.
    -K₂O (Potassium Oxide): K₂O will dissociate into K⁺ and O²⁻ ions. O²⁻ ions are
    the conjugate base of water. The solution will be basic due to the presence of the
    oxide ion.
    -K₃N (Potassium Nitride): K₃N will dissociate into K⁺ and N³⁻ ions. N³⁻ ions are
    the conjugate base of NH₃ (ammonia), a weak base. The presence of N³⁻ ions
    can result in a basic solution, but it won't be highly effective at accepting protons.
    -KOH (Potassium Hydroxide): KOH will dissociate into K⁺ and OH⁻ ions. OH⁻
    ions are strong bases, leading to a highly basic solution.
    -KCl (Potassium Chloride): KCl will dissociate into K⁺ and Cl⁻ ions. Cl⁻ ions are
    the conjugate base of HCl, a strong acid. The solution will be neutral since Cl ⁻
    ions won't significantly affect the pH.
    Therefore, the solution with the lowest pH among the given options is KCl
    (Potassium Chloride), as it will result in a neutral solution.
    4. N/A

    5. Same as No. 3 in the 2017 quiz, Letter C: Volumetric Pipette and


    Volumetric flask.
    6. Same as No. 6 in the 2017 quiz, Letter D: 58.1g/mol. Use
    PVMM=mRT
    7. Letter B, sp2
    8. Letter D, 1.0 m of sodium laurate
    9. Letter B, IBr with a bond enthalpy of 175kJ/mol

    10. N/A
    11.
    12. Above 60 C

    13. A, Occurs by substitution rather than addition.

    14. A, 140 kJ/mol

    15. Same as No.52 in the 2017 quiz, Letter B, 3 Peaks

    You might also like