EU safety data sheet

Trade name: Marlotherm SH

Product no.: 5009201
Current version : 4.1.0, issued: 21.10.2021 Replaced version: 4.0.1, issued: 21.06.2021 Region: GB

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Trade name
Marlotherm SH
Substance name dibenzylbenzene, ar-methyl derivative
REACH registration no. 01-2119488667-17
Identification numbers
CAS no. 53585-53-8
EC no. 258-649-2

1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses of the substance or mixture
heat transfer fluids
Uses advised against
No data available.
Reference to relevant exposure scenarios
For an overview of the exact titles of the relevant exposure scenarios please refer to section 16 of this SDS.

1.3 Details of the supplier of the safety data sheet

Address
Krahn Chemie Deutschland GmbH
Grimm 10
20457 Hamburg
Deutschland
Telephone no. +49 40 320 92-0
Fax no. +49 40 320 92-322
Information provided by / telephone
+49 40 320 92-0
Advice on Safety Data Sheet
[email protected]

1.4 Emergency telephone number

For medical advice (in German and English):
+49 551 192 40 (Giftinformationszentrum Nord)
In case of transport incidents and other emergencies:
+44 (0)1235 239 670 (NCEC, National Chemical Emergency Centre)

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification in accordance with Regulation (EC) No 1272/2008 (CLP)
Repr. 1B; H360FD
Asp. Tox. 1; H304
Aquatic Chronic 1; H410
Classification information
This product is assessed and classified using the methods and criteria below referred to in Article 9 of Regulation (EC) n° 1272/2008:
Physical hazards: determined through assessment data based on the methods or standards referred to in part 2 of Annex I to CLP
Health hazards and environmental hazards: determined through toxicological and ecotoxicological assessment data based on the
methods or standards referred to in Part 3 and 4 of Annex I to CLP.

2.2 Label elements

Labelling according to Regulation (EC) No 1272/2008 (CLP Regulation)

Product identifier
53585-53-8 (dibenzylbenzene, ar-methyl derivative)
Hazard pictograms

GHS08 GHS09
Signal word
Danger
Hazard statement(s)

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EU safety data sheet
Trade name: Marlotherm SH
Product no.: 5009201
Current version : 4.1.0, issued: 21.10.2021 Replaced version: 4.0.1, issued: 21.06.2021 Region: GB

H304 May be fatal if swallowed and enters airways.

H360FD May damage fertility. May damage the unborn child.
H410 Very toxic to aquatic life with long lasting effects.
Precautionary statement(s)
P201 Obtain special instructions before use.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P331 Do NOT induce vomiting.
P405 Store locked up.
P501 Dispose of contents/container to a facility in accordance with local/regional/national/international
regulations.
Supplemental label elements
"Restricted to professional users"

2.3 Other hazards

This product does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or
Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
PBT assessment
The components of this product are not considered to be a PBT.
vPvB assessment
The components of this product are not considered to be a vPvB.

SECTION 3: Composition/information on ingredients

3.1 Substances
Chemical characterization
Substance name dibenzylbenzene, ar-methyl derivative
Identification numbers
CAS no. 53585-53-8
EC no. 258-649-2
Other information
Note Specific concentration limits M-factor (acute) M-factor
(chronic)
- - - M = 10

3.2 Mixtures
Not applicable. The product is not a mixture.

SECTION 4: First aid measures

4.1 Description of first aid measures
General information
In case of persisting adverse effects, consult a physician. Remove contaminated clothing and shoes immediately, and launder thoroughly
before reusing. If the patient is likely to become unconscious, place and transport in stable sideways position.
After inhalation
Ensure supply of fresh air. Remove affected person from the immediate area.
After skin contact
When in contact with the skin, clean with soap and water.
After eye contact
Remove contact lenses. Rinse eye thoroughly under running water keeping eyelids wide open and protecting the unaffected eye (at least
10 to 15 minutes).
After ingestion
Call a doctor immediately. Do not induce vomiting - aspiration hazard. Never give anything by mouth to an unconscious person. In case
of vomiting keep head of person in face-down position to prevent penetration of vomitus into the trachea.

4.2 Most important symptoms and effects, both acute and delayed
Effects
In the case of swallowing with subsequent vomiting, aspiration of the lungs can occur which can lead to chemical pneumonia or
asphyxiation.

4.3 Indication of any immediate medical attention and special treatment needed
No data available.

SECTION 5: Firefighting measures

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EU safety data sheet
Trade name: Marlotherm SH
Product no.: 5009201
Current version : 4.1.0, issued: 21.10.2021 Replaced version: 4.0.1, issued: 21.06.2021 Region: GB

5.1 Extinguishing media

Suitable extinguishing media
Carbon dioxide; Dry chemical extinguisher; Water mist
Unsuitable extinguishing media
High power water jet

5.2 Special hazards arising from the substance or mixture

In the event of fire, the following can be released: Carbon monoxide (CO); Carbon dioxide (CO2)

5.3 Advice for firefighters

Use self-contained breathing apparatus. Wear protective clothing. Run-off water from fire fighting must not be discharged into drains or
enter surface water. Fire residues and contaminated firefighting water must be disposed of in accordance with the local regulations.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency personnel
Refer to protective measures listed in sections 7 and 8.
For emergency responders
No data available. Personal protective equipment (PPE) - see Section 8.

6.2 Environmental precautions

Do not discharge into the drains/surface waters/groundwater. Do not discharge into the subsoil/soil.

6.3 Methods and material for containment and cleaning up

Take up with absorbent material (e.g., sand, kieselguhr, universal binder). When collected, handle material as described under the
section heading "Disposal considerations".

6.4 Reference to other sections

No data available.

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Advice on safe handling
Provide good ventilation at the work area (local exhaust ventilation, if necessary). If workplace exposure limits are exceeded, respiratory
protection approved for this particular job must be worn. Risks inherent to handling the product must be minimised by applying the
appropriate protective and preventive measures. Working processes should - so far as possible, according to the state of the art - be
designed to rule out bodily contact or the release of hazardous substances. Observe information on personal protection equipment (see
section 8).
General protective and hygiene measures
Do not eat, drink or smoke during work time. Keep away from food, drink and animal feeding stuffs. Wash hands before breaks and after
work. Avoid contact with eyes and skin. Do not inhale vapours. Remove soiled or soaked clothing immediately.
Advice on protection against fire and explosion
Keep away from sources of heat and ignition. Vapours may form explosive mixtures with air.

7.2 Conditions for safe storage, including any incompatibilities

Technical measures and storage conditions
Keep container tightly closed and dry in a cool, well-ventilated place.
Requirements for storage rooms and vessels
Containers which are opened must be carefully closed and kept upright to prevent leakage. Always keep in containers of same material
as the original.
Incompatible products
Do not store together with: oxidizing agents

7.3 Specific end use(s)

No data available.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
DNEL, DMEL and PNEC values

DNEL values (worker)

No Substance name CAS / EC no
Route of exposure Exposure time Effect Value
1 dibenzylbenzene, ar-methyl derivative 53585-53-8

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EU safety data sheet
Trade name: Marlotherm SH
Product no.: 5009201
Current version : 4.1.0, issued: 21.10.2021 Replaced version: 4.0.1, issued: 21.06.2021 Region: GB

258-649-2
dermal Long term (chronic) systemic 0.37 mg/kg/day
0
inhalative Long term (chronic) systemic 0.259 mg/m³
DNEL value (consumer)
No Substance name CAS / EC no
Route of exposure Exposure time Effect Value
1 dibenzylbenzene, ar-methyl derivative 53585-53-8
258-649-2
oral Long term (chronic) systemic 18.5 µg/kg/day
dermal Long term (chronic) systemic 0.185 mg/kg/day
0
inhalative Long term (chronic) systemic 64 µg/m³
PNEC values
No Substance name CAS / EC no
ecological compartment Type Value
1 dibenzylbenzene, ar-methyl derivative 53585-53-8
258-649-2
water fresh water 0.028 µg/L
water marine water 0.003 µg/L
water fresh water sediment 110 µg/kg dry weight
water marine water sediment 110 µg/kg dry weight
soil - 2 mg/kg dry weight
sewage treatment plant - 1.00 g/L
0
secondary poisoning - 11.10 mg/kg food

8.2 Exposure controls

Appropriate engineering controls
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If
applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below
recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level.
Personal protective equipment
Respiratory protection
If workplace exposure limits are exceeded, a respiration protection approved for this particular job must be worn. In case of aerosol,
vapour and mist formation, take appropriate measures for breathing protection in the event workplace threshold values are not specified.
Eye / face protection
Safety glasses with side protection shield (EN 166)
Hand protection
Sufficient protection is given wearing suitable protective gloves checked according to i.e. EN 374, in the event of risk of skin contact with
the product. Before use, the protective gloves should be tested in any case for its specific work-station suitability (i.e. mechanical
resistance, product compatibility and antistatic properties). Adhere to the manufacturer’s instructions and information relating to the use,
storage, care and replacement of protective gloves. Protective gloves shall be replaced immediately when physically damaged or worn.
Design operations thus to avoid permanent use of protective gloves.
Other
Make sure when selecting personal protective equipment (PPE), that it is suitable for the activity, workplace conditions in which it will be
used according to the applying European CEN standards and upon consultation with the PPE supplier. Chemical-resistant work clothes.
Environmental exposure controls
No data available.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
State of aggregation
2038
liquid
Form/Colour
liquid
270
colourless; yellow
10

Odour
70
weak
pH value
No data available
Boiling point / boiling range
Value 390 °C 390

Melting point/freezing point

Value - 39
-39 - -32 °C - 32

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EU safety data sheet
Trade name: Marlotherm SH
Product no.: 5009201
Current version : 4.1.0, issued: 21.10.2021 Replaced version: 4.0.1, issued: 21.06.2021 Region: GB

Decomposition temperature
No data available
Flash point
Value 212 °C
Method Pensky-Martens closed cup 212

Ignition temperature
No data available
Flammability
No data available
Lower explosion limit
No data available
Upper explosion limit
No data available
Vapour pressure
Value < 0.01 hPa
Reference temperature
2
20 °C 0. 01

Relative vapour density

No data available
Relative density
Value
3
> 1 1

Density
No data available
Solubility in water
Value
2
< 0.1 mg/l 0. 1

Solubility
No data available
Partition coefficient n-octanol/water (log value)
No Substance name CAS no. EC no.
1 dibenzylbenzene, ar-methyl derivative 53585-53-8 258-649-2
log Pow > 6
Reference temperature 22 °C
Method OECD 117
Source
3
ECHA 6

Viscosity
Value 16 mm²/s
Reference temperature 40 °C
Type kinematic
Value 48 mm²/s
Reference temperature 20 °C
Type
20
kinematic
Particle characteristics
No data available

9.2 Other information

Other information
No data available.

SECTION 10: Stability and reactivity

10.1 Reactivity
Dangerous reactions are not expected if the product is handled according to its intended use.

10.2 Chemical stability

Stable under recommended storage and handling conditions (See section 7).

10.3 Possibility of hazardous reactions

Dangerous reactions are not to be expected when handling product according to its intended use. Vapours may form an explosive
mixture with air.

10.4 Conditions to avoid

Heat, naked flames and other ignition sources. Protect from sun.

10.5 Incompatible materials

Oxidizing agents

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EU safety data sheet
Trade name: Marlotherm SH
Product no.: 5009201
Current version : 4.1.0, issued: 21.10.2021 Replaced version: 4.0.1, issued: 21.06.2021 Region: GB

10.6 Hazardous decomposition products

No hazardous decomposition products known.

SECTION 11: Toxicological information

11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008
Acute oral toxicity
No data available
Acute dermal toxicity
No Substance name CAS no. EC no.
1 dibenzylbenzene, ar-methyl derivative 53585-53-8 258-649-2
LD50 > 2000 mg/kg bodyweight
Species rat
Method
3 Lk. 6866
OECD 402
Acute inhalational toxicity
No data available
Skin corrosion/irritation
No data available
Serious eye damage/irritation
No Substance name CAS no. EC no.
1 dibenzylbenzene, ar-methyl derivative 53585-53-8 258-649-2
Source ECHA
Evaluation
Lk. 8973
non-irritant
Respiratory or skin sensitisation
No Substance name CAS no. EC no.
1 dibenzylbenzene, ar-methyl derivative 53585-53-8 258-649-2
Route of exposure Skin
Method OECD 406
Source ECHA
Evaluation
Lk. 3647 Lk. 8983
non-sensitizing
Germ cell mutagenicity
No data available
Reproduction toxicity
No Substance name CAS no. EC no.
1 dibenzylbenzene, ar-methyl derivative 53585-53-8 258-649-2
NOAEL 80 mg/kg bw/d
Species rats (male/female)
Method OECD 421
Source
Lk. 8997
ECHA
Carcinogenicity
No data available
STOT - single exposure
No data available
STOT - repeated exposure
No data available
Aspiration hazard
In the case of swallowing with subsequent vomiting, aspiration of the lungs can occur which can lead to chemical pneumonia or
asphyxiation.
903

11.2 Information on other hazards

Endocrine disrupting properties
Pursuant to REACH Article 57(f) or Commission Delegated Regulation (EU) 2017/2100 or Commission Delegated Regulation (EU)
2018/605, the product does not contain any endocrine disruptors in a concentration of 0.1% weight by weight and above.
Other information
No data available.

SECTION 12: Ecological information

12.1 Toxicity
Toxicity to fish (acute)
No Substance name CAS no. EC no.
1 dibenzylbenzene, ar-methyl derivative 53585-53-8 258-649-2

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EU safety data sheet
Trade name: Marlotherm SH
Product no.: 5009201
Current version : 4.1.0, issued: 21.10.2021 Replaced version: 4.0.1, issued: 21.06.2021 Region: GB

LC50 > 50 mg/l

Duration of exposure 96 h
Species Danio rerio
Method OECD 203
Source
Lk. 9016
ECHA
Toxicity to fish (chronic)
No Substance name CAS no. EC no.
1 dibenzylbenzene, ar-methyl derivative 53585-53-8 258-649-2
NOEC > 0.46 mg/l
Duration of exposure 14 day(s)
Species Leuciscus idus melanotus
Method OECD 204
Source
NO EC
ECHA
Toxicity to Daphnia (acute)
No data available
Toxicity to Daphnia (chronic)
No Substance name CAS no. EC no.
1 dibenzylbenzene, ar-methyl derivative 53585-53-8 258-649-2
NOEC 1.4 µg/l
Duration of exposure 21 day(s)
Species Daphnia magna
Method OECD 211
Source
NO EC
ECHA
Toxicity to algae (acute)
No data available
Toxicity to algae (chronic)
No Substance name CAS no. EC no.
1 dibenzylbenzene, ar-methyl derivative 53585-53-8 258-649-2
NOEC > 16 µg/l
Duration of exposure 72 day(s)
Species Skeletonema costatum
Source
NO EC
ECHA
Bacteria toxicity
No data available

12.2 Persistence and degradability

No data available.

12.3 Bioaccumulative potential

Partition coefficient n-octanol/water (log value)
No Substance name CAS no. EC no.
1 dibenzylbenzene, ar-methyl derivative 53585-53-8 258-649-2
log Pow > 6
Reference temperature 22 °C
Method OECD 117
Source
3
ECHA 6

12.4 Mobility in soil

No data available.

12.5 Results of PBT and vPvB assessment

Results of PBT and vPvB assessment
PBT assessment The components of this product are not considered to be a PBT.
Lk. 2045
vPvB assessment
Lk. 2046
The components of this product are not considered to be a vPvB.

12.6 Endocrine disrupting properties

Endocrine disrupting properties
Pursuant to REACH Article 57(f) or Commission Delegated Regulation (EU) 2017/2100 or Commission Delegated Regulation (EU)
Pur suant t o REACH Ar t icle 57( f )
or Com m ission Delegat ed
2018/605, the product does not contain any endocrine disruptors in a concentration of 0.1% weight by weight and above.
Regulat ion ( EU) 2017/ 2100 or
Com m ission Delegat ed Regulat ion
( EU) 2018/ 605, t he pr oduct
does not cont ain any endocr ine
disr upt or s in a concent r at ion of
0. 1% weight by weight and
above.

12.7 Other adverse effects

No data available.

12.8 Other information

Other information
710
Do not discharge product unmonitored into the environment.

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EU safety data sheet
Trade name: Marlotherm SH
Product no.: 5009201
Current version : 4.1.0, issued: 21.10.2021 Replaced version: 4.0.1, issued: 21.06.2021 Region: GB

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product
Disposal of the product should be carried out in accordance with all applicable regulations following consultation with the responsible
local authority and the disposal company in an authorised and suitable disposal facility.
Allocation of a waste code number, according to the European Waste Catalogue, should be carried out in agreement with the regional
waste disposal company.
Packaging
Residues must be removed from packaging and when emptied completely disposed of in accordance with the regulations for waste
removal. Incompletely emptied packaging must be disposed of in the form of disposal specified by the regional disposer.

SECTION 14: Transport information

14.1 Transport ADR/RID/ADN
Class 9
Classification code M6
Packing group III
Hazard identification no. 90
UN number UN3082
Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Technical name dibenzylbenzene, ar-methyl derivative
Tunnel restriction code -
Label 9
Environmentally hazardous Symbol "fish and tree"
substance mark

14.2 Transport IMDG

Class 9
Packing group III
UN number UN3082
Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Technical name dibenzylbenzene, ar-methyl derivative
EmS F-A, S-F
Label 9
Marine pollutant mark Symbol "fish and tree"

14.3 Transport ICAO-TI / IATA

Class 9
Packing group III
UN number UN3082
Proper shipping name Environmentally hazardous substance, liquid, n.o.s.
Technical name dibenzylbenzene, ar-methyl derivative
Label 9
Environmentally hazardous Symbol "fish and tree"
substance mark

14.4 Other information

No data available.

14.5 Environmental hazards

Information on environmental hazards, if relevant, please see 14.1 - 14.3.

14.6 Special precautions for user

No data available.

14.7 Maritime transport in bulk according to IMO instruments

Not relevant

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulations

Regulation (EC) No 1907/2006 (REACH) Annex XIV (List of substances subject to authorisation)
In accordance with the REACH regulation (EC) 1907/2006, the product does not contain any substances that are considered as subject
to listing in annex XIV, inventory of substances requiring authorisation.
REACH candidate list of substances of very high concern (SVHC) for authorisation
In accordance with article 57 and article 59 of the Reach regulation (EC) 1907/2006, this substance is not considered as subject to listing
in annex XIV, inventory of substances requiring authorisation ("Authorization list").

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EU safety data sheet
Trade name: Marlotherm SH
Product no.: 5009201
Current version : 4.1.0, issued: 21.10.2021 Replaced version: 4.0.1, issued: 21.06.2021 Region: GB

Regulation (EC) No 1907/2006 (REACH) Annex XVII: RESTRICTIONS ON THE MANUFACTURE, PLACING ON THE MARKET
AND USE OF CERTAIN DANGEROUS SUBSTANCES, MIXTURES AND ARTICLES
The substance is not subject to the provisions of annex XVII (restriction entries) of the Reach regulation (EC) 1907/2006.
Directive 2012/18/EU on the control of major-accident hazards involving dangerous substances
This product is subject to Part I of Annex I, risk category: E1
Directive 2010/75/EU on industrial emissions (integrated pollution prevention and control)
Comments not applicable
Other regulations
Observe employment restrictions for child bearing mothers and nursing mothers.
Observe employment restrictions for women of child-bearing age.
Observe employment restrictions for young people.
National regulations

National chemical inventories

USA (TSCA) listed
DSL/NDSL (Canada) DSL listed
ENCS (Japan) ENCS/ISHL listed
ECL (Korea) listed
AICS (Australia) listed
IECSC / NEPA (China) listed
PICCS (Philippines) listed
CSNN (Taiwan) TCSI listed

15.2 Chemical safety assessment

A chemical safety assessment has been carried out for this substance.

SECTION 16: Other information

Sources of key data used to compile the data sheet:
Regulation (EC) No 1907/2006 (REACH), 1272/2008 (CLP) as amended in each case.
Directives 2000/39/EC, 2006/15/EC, 2009/161/EU, (EU) 2017/164.
National Threshold Limit Values of the corresponding countries as amended in each case.
Transport regulations according to ADR, RID, IMDG, IATA as amended in each case.
The data sources used to determine physical, toxic and ecotoxic data, are indicated directly in the corresponding section.
List of existing exposition scenarios
ES001 Exposure scenario/s of the manufacturer
Creation of the safety data sheet
UMCO GmbH
Georg-Wilhelm-Str. 187, D-21107 Hamburg
Tel.: +49 40 / 555 546 300 Fax: +49 40 / 555 546 357 e-mail: [email protected]
This information is based on our present knowledge and experience.
The safety data sheet describes products with a view to safety requirements.
It does not however, constitute a guarantee for any specific product properties and shall not establish a legally valid contractual
relationship.

Alterations/supplements:
Alterations to the previous edition are marked in the left-hand margin.
Document protected by copyright. Alterations or reproductions require the express written permission of UMCO GmbH.
.
Prod-ID 758397

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