PHYSICS Max Marks: 60

SECTION-I
(ONE OR MORE OPTIONS CORRECT TYPE)
This section contains 10 multiple choice equations. Each question has four choices (A) (B),(C) and (D) out of which
ONE or MORE THAN ONE are correct.
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
1. As shown below, a boy is using the rope through a fixed pulley to move a box with
constant speed v. The kinetic friction coefficient between the box and the ground is
  1 ; assume that the fixed pulley is massless and there is no friction between the rope
and the fixed pulley. Then, while the box is moving on surface, which of the following
statements is/are correct?

A) The magnitude of the force on the rope is constant.

B) The magnitude of friction between the ground and the box is decreasing.
C) The magnitude of the normal force of the ground on the box is increasing.
D) The magnitude of the normal force of the ground on the box is constant.
2. A massless bucket is initially at rest next to one end of a chain that lies in a straight line
on the floor, as shown in fig. The chain has uniform mass density  (kg/m). You push on
the bucket (so that it gathers up the chain) with the force F(t) that gives the bucket and
whatever chain is inside, a constant acceleration a at all times. ‘t’ is time. There is no
friction between the bucket and the floor.
(Assume that chain links begin to collide with bucket surface immediately after the
push)

3 2 2 5 34
A) F(t) at time t is a t B) work done by F(t) upto time t is a t
2 8
3 2 2 3 32
C) F(t) at time t is a t D) work done by F(t) upto time t is a t
4 4
3. In the figure shown find the total magnification after two successive reflections first on
M1 and then on M2 (Assume paraxial rays only)

A) +6 B) –6 C) +3 D) –3
4. A spring is placed between the jaws of screw gauge such that the spring is not at all
compressed. The main scale reads 2 divisions and circular scale reads 28 divisions. Now
we turn the circular scale by 18° such that the spring is compressed. The circular scale
has 200 divisions and the least count of the main scale in 1mm. What is the force exerted
by the spring on the jaws if the spring constant is 100 N/m. (Given pitch of the screw
gauge is same as least count of main scale)

A) 4 mN B) 3 mN C) 5 mN D) 7 mN

5. In the figure shown a conducting rod of mass m, length ‘l’ and resistance ‘R’ can
smoothly move along parallel rails in horizontal plane. Initially the rod is at rest. A

uniform magnetic field B perpendicular to the plane of motion exists in the region. Now
switch S is closed at t = 0,then:

A) The charge on the capacitor in steady state is mc / (m  2CB2l 2 )

B) The charge on the capacitor is steady state is 2mc / (m  2CB2l 2 )

C) Velocity of conducting rod in steady state is 2Blc / (m  CB2l 2 )

D) Velocity of conducting rod in steady state is Blc / (m  CB2l 2 )

6. Consider the situation shown in the figure. The switch S is open for a long time and then
closed and again steady reached then:

2CV
A) Charge flowing from X to Y is
5
CV
B) Charge flowing from Y to X is –
3

CV 2
C) Work done by battery after closing the switch is
3

2CV 2
D) Work done by battery after closing the switch is
3

7. A thin copper tube of outer radius 0.5 cm carries a liquid flowing at T = 100°C. The
copper tube loses heat according to Newtons’s law with constant of proportionality

3 × 10–3 cal/cm2. sec°C. The temperature of surrounding is 20°C. Now we coat a layer
with thermal conductivity 2.8 × 10–3 cal/cmºC sec. The layer is 0.5 cm thick. Assume
that outer surface of layer loses heat with same constant of proportionality:
(Take : ln 2  0.7)

8
A) The rate of heat loss becomes times
7
7
B) The rate of heat loss becomes time
8

C) The temperature T of outer surface of layer is approximately 90°C.

D) The temperature T of outer surface of layer is approximately 42.2°C
8. A small sphere is charged uniformly and placed at point A(x, y)m, so that at point

B(8, 7) m electric filed strength is E  54iˆ  72ˆj N/C and potential is +900 volt.

The di-electric strength of air is 3 × 106 v/m. Choose the CORRECT option(s):
 A) Co-ordinate of point A are (2, 1) m
B) Charge of the sphere is 2 C

C) Minimum possible radius of sphere is 30 cm so that air does not break down.
D) None of the above
9. In the circuit shown both cells are ideal and of fixed emf, the resistor of resistance R1 has
fixed resistance and the resistance of resistor R2 can be varied (but the value of R2 is not
zero). Then:

A) The electric power delivered to resistor of resistance R1 is independent of R2

B) Electric power delivered by E1 is dependent on R2
C) Electric power delivered by E1 is dependent on R2
D) Electric power delivered to R1 is dependent on R2
10. An insect of mass m. moves on a rough inclined surface from point A. As the surface is
very sticky, the coefficient of friction between the insect and the incline is  = 1.
Assume that it can move in any direction; up the incline or down the incline then
(g = 10 m/s2). Choose the correct option:

A) The maximum possible acceleration of the insect is 18 m/sec2

B) The maximum possible acceleration of the insect is 2 m/sec2
C) The insect can move with a constant velocity
D) No friction force will act on insect when it moves with constant velocity.
 SECTION-II
INTEGER TYPE
This section contains 10 questions. The answer to each question is a single digit integer, ranging from 0 to 9
(both inclusive).
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.

11. Suppose a hypothetical magnetic field exists in space B  B0 uˆ r above the earth surface
where û r is a unit vector directed radially outward from origin. Origin is on surface of
earth. A light charged particle has to perform uniform circular motion in the combined
uniform (vertical) gravitational field of earth and magnetic field with speed v and radius
r. Height of the plane of motion from earth surface will be
2
h = nv . Find n.
g

12. ABCD is a square frame of conductor of electrical resistivity . The frame lies in a
vertical plane. PQ is an imaginary boundary separating space into two parts. Left of PQ,
a uniform gravitational field g exists (figure) whereas no gravitational field is present
k mgh
right of PQ. The electrical potential difference between A and B will be . e is
4 e

charge on an electron and m is mass of electron . Find k.

13. A shell of radius 1 m is coated with a thin layer of   active material. It’s initial charge is
4
zero and initial number of active atoms is  1012 . If half life of decay is 1 hr and all the
3

electron are emitted with an energy of 1.44 keV, find the time (in hr). after which charge
on the sphere becomes constant. Neglect the time taken by electron to return back.
14. In the circuit shown, find the current in Amp through the battery at t = 0.1 In 2 sec, if
switch is closed at t = 0.

15. A ball is projected with initial velocity 40 2 m/s at an angle of 60° with horizontal as
shown in figure. When its velocity is making an angle of 45° with downward vertical, it
collides a vertically hanging ball of same mass and sticks to it as shown in figure. Find
the maximum value of length l (in m) of the string, so that the combined mass completes
the vertical circle in subsequent motion.

16. A square frame of resistance ln(2)  and side a = 20 cm and a long straight wire carrying
a current I = 10 amp are located in the same plane. The frame is rotated through an angle
of 120° about the side PQ. The amount of charge flows through the loop during this time
is q × 10–7 coulomb, find the value q.

17. A syringe is filled with water upto volume 20 cm3. The area of cross – section of the
cylinder is 5 cm2. The syringe is held vertically and its 90 gm pistion is pushed upward
by external agent with constant speed. A water beam coming out of the small nozzle
(hole area 1 mm2) has speed 2 m/s. Neglecting friction and viscous nature of water, find
the work done by the agent [in 10–2J] in fully emptying the syringe. (Take g = 10 m/s2)
18. A horizontal tube of small thickness having inner radius r = R/2 is placed in gravity
free space. Magnetic field of strength B is present perpendicular to plane of circular
qBR
tube. A charged particle (q, m) inside the tube is given tangential velocity V0  . The
m

work done by friction until a long time after motion starts is

kq 2 B2 R 2
– . Find the value of k (inner surface of the tube is rough)
8m

19. A uniformly charged hemisphere of radius b and charge density  has a hemispherical
 b
cavity of radius aa   cut from its centre. If the potential at the centre of curvature of
 2
n b2
the cavity is then n = ?
16 0

20. Two sound waves of frequencies 100 Hz and 102 Hz having same amplitude ‘A’ are
interfering. At a stationary detector, which can detect resultant amplitude greater than or
equal to A. So, in a given time interval of 12 seconds, find the total duration in which
detector is active.
CHEMISTRY Max Marks: 60
SECTION-I
(ONE OR MORE OPTIONS CORRECT TYPE)
This section contains 10 multiple choice equations. Each question has four choices (A) (B),(C) and (D) out of which
ONE or MORE THAN ONE are correct.
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
21. When PbF2 is shaken in pure water at 25 C, the solubility is found to be 2 103 . The
value of Ksp can be calculated by two methods, first by solubility i.e. ksp = 4s3 and was
found to be 3.2 108 , second by concentration of ions i.e. ksp = [Pb2+] [F-]2 and was
found to be 2 108 , correct options are -

A) Correct value of ksp is 3.2 108 .

B) Correct value of ksp is 2 108 .

C) While calculating ksp from solubility we have assumed that PbF2 dissolved is 100%
dissociated.

D) While calculating ksp from solubility we have assumed that dissolved salt exist only
in Pb2+ and F.

22. In the titration of 40 ml of 0.1M NH3 with 0.1M HCl following graph is obtained -

If pKb for NH4OH is 4.74 then x and y coordinates of A and B points are [where A
point denotes the neutral point of buffer solution where pOH = pKb and B point denotes
equivalence point]

A) A point x = 20 y = 9.26 B) A point x = 20 y = 4.76

C) B point x = 40 y = 5.28 D) B point x = 40 y = 8.72

23. The temperature versus pressure graph for a pure substance is drawn experimentally

Which of the following statements are correct regarding this substance

A) The favorable conditions for freezing of liquid to solid is high pressure and low
temperature

B) The favorable conditions for freezing of liquid to solid is low pressure and low
temperature.

C) At point A and C the substance exist in two phases.

D) At point A, B and C the substance exist in three phases.

24. Select correct about ionization energy of Ne, Na, Mg and Al.

(Atomic numbers: Ne = 10, Na = 11, Mg = 12, Al = 13)

A) IE1 : Na < Mg B) IE1 : Mg > Al C) IE1 : Ne > Na D) IE2 : Mg > Na

25. If all the cobalt’s are in same oxidation state, then select the correct about complex

which is:-

A) Oxidation number of each cobalt is +3

B) It is optically active complex

C) It has total 18, O–Co–N bond angle

D) It show geometrical isomerism

26. An organic compound X (m.f. C3H8O2) reduces HIO4. When organic compound X is
treated with

then product formed is:

A) B)

C) D)

27.

Correct statement is/are

A) Formation of Q is Schimdt reaction
B) Q can be obtained by P using NaOBr
C) Q is less basic than P
D) Formation of P is Hofmann bromoimide degradation
28. In following reaction final product mixture contains

CH 3  CH 2  COOH 
Red P
 P 
Aq . KOH
 Q 
Slight

 R   Product mixture
Br2 H

A) Two optically active organic compound

B) One optically inactive organic compound
C) Two optically inactive organic compound
D) None of these
29. A d-block metal ion with dn configuration forms tetrahedral complex but its spin

magnetic moment remains same either with 4H2O or with 4Cl- ligand, which of the

following statements are incorrect ?

A) Element always form a colorless compound

B) Number of electrons in e-set of d-orbitals are always higher than in t2 – set of d-

orbitals

C) It can have d5 and d8 configuration

D) Colour of the complexes must be same

30. Identify reaction correctly match with its product?

A)

B)

C)

D)
 SECTION-II
INTEGER TYPE
This section contains 10 questions. The answer to each question is a single digit integer, ranging from 0 to 9
(both inclusive).
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.

31. A mixture of H2C2O4 (oxalic acid) and NaHC2O4 weighing 2.02 gm was dissolved in
water and this solution was made upto one litre, 10 ml of this solution required 3 ml of
0.1N NaOH for complete neutralization. Calculate the mole ratio of H2C2O4 with
respect to NaHC2O4 in the mixture.
32. The dissociation constant of conjugate acid of a weak monoacidic base in aqueous
medium is 10-6. Find the pH of 0.01M solution of weak monoacidic base at 25C .
33. Out of the following complex salt select number of complex which absorbs higher
wavelength as ompared to yellow radiation.
[Cr(H2O)6]2(SO4)3 (Green)
[CoCl4]2- (Blue)
[Ni(en)3]SO4 (Violet)
[Co(NH3)5 (H2O)]Cl3 (Red)
[Co(H2O)4Cl2]Cl.2H2O (Dark Green)
K4[Fe(CN)6] (Pale yellow)
34. Find the number of species which are larger as compared to V+5 ion

V4+, Ti4+, Cr+6, K+, Ca+2, Cl-, Sc .

35. Number of reactions in which carboxylic acid is formed in product.

36. Number of tests by which can be distinguished.

(i) Isocynide test (ii) Hinsberg’s test (iii) Musturd oil test (iv) Azodye test

(v) Lucas test (vi) Victor-mayer’s test

37. The conductance of a salt solution (AB) measured by two parallel electrodes of area 100
cm2 separated by 10 cm was found to be 0.0001  1 . If volume enclosed between two
electrode contain 0.5 mole of salt, what is the molar conductivity (S cm2 mol-1) of salt at
same conc.
[Express your answer as molar conductivity in S cm2mol-1  100]

38. In how many of these all combining atoms are in one plane

ICI 4 , PCl4 ,[ PtCl4 ]2 , SF4 XeF4 , CIF3 , XeO2 F2 , XeOF4

39.

Total number of moles of CO2 released when A reacts with O3/H2O2 at high
temperature.
40. Identify total number of esters having molecular formula C4H8O2 which give “EtOH”
as one of the product on hydrolysis.
MATHEMATICS Max Marks: 60
SECTION-I
(ONE OR MORE OPTIONS CORRECT TYPE)
This section contains 10 multiple choice equations. Each question has four choices (A) (B),(C) and (D) out of which
ONE or MORE THAN ONE are correct.
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
41. Which of the following statement (s) is/are true?
A) Two disjoint events E and F defined on sample space ‘S’ are such that
P ( E )  0, P ( F )  0 can be independent.

B) The events E , E  F and E  F defined on a sample space ‘S’ are exhaustive.

C) If P    P( E ), then P    P( F )
E F
F E

D) Probability that a positive integer randomly selected will not be divisible by both 2
1
and 3 is .
2

2 3 6 
7 7 7 
 1  1   
Let a  (2i  3 j  6k ), b  (6i  2 j  3k ), c  c1 i  c2 j  c3 k and matrix A  
         6 2 3
42.  .
7 7 7 7 7
 
c1 c2 c3 
 

If AAT  I , then c can be
1    1
A) (3i  6 j  2k ) B)  (3i  6j  2k)
7 7
1    1
C) (3i  6 j  2k ) D)  (3i  6j  2k)
7 7
2 x 2 sec 2 xdx
43. If  ( x sec2 x  tan x)2  f ( x)  cot x  x  C , where C is constant of integration, and
f ( x) is a continuous function in its domain such that lim f ( x )  0 then
cos x  0

   
A) f    B) f   
 4  4  2  4  2  4

   
C) f     D) f    
 4  4  2  4  2  4
44. The normal at a point P ( x, y ) of a curve meets the x-axis at Q & N is foot of the
x(1  y 2 )
perpendicular from P on x-axis. If NQ  , then the curve passing through
1  x2
(3,1) also passes through

A)  2, 0  B)  0, 2  C)  3, 1 D) 1,3

45. An equilateral triangle is inscribed in ellipse whose equation is x 2  4 y 2  4 . One

vertex of triangle is (0,1) and one altitude is contained in y – axis & length of each
a b
side is (where a,b & c are relatively prime integers), then which of the
c
following is possible

A) a+c=14 B) b+c=16 C) a+b=19 D) c=16

46. Consider right triangle ABC with hypotenuse AB and AC = 15. Altitude CH divides AB
into segments AH & HB with HB = 16. Then
A) Biggest altitude is 20 B) Area of triangle is 150
C) Smallest altitude is 15 D) Area of triangle is 300

  5 7 a
47. The value of sin sin sin sin  , (a,b being coprime integers) then which of
16 16 16 16 b
the following is possible
a 1
A) a = 2 B) b = 32 C) a + b = 18 D) 
b 16
 
 sin x 0  x  2
48. Consider g ( x)   and a continuous function y  f ( x ) satisfies
cos x 
x
 2
5dy
 5 y  g ( x) , f  0   0 , then –
dx
 e  /4  e /4  1
A) f    B) f   
 4  10 4 10
 e  /2  1  e /2  1
C) f    D) f   
2 10 2 10
 3 2 2
y 1 y z y x
49. Let positive integers x,y,z satisfy the equation yz 2 3
z 1
2
z x  11 , then
2 2 3
yx x z x 1

A) xyz=2 B) x + y + z = 4

C) xy + yz + zx = 4 D) x 2  y 2  z 2  9

50. The projection of line 3x  y  2z  1  0  x  2y  z  2 on the plane 3x  2y  z  0 is

x 1 y 1 z 1
A)   B) 3x  8y  7z  4  0  3x  2y  z
11 9 15

x  12 y  8 z  14 x  12 y  8 z  14
C)   D)  
11 9 15 11 9 15

SECTION-II
INTEGER TYPE
This section contains 10 questions. The answer to each question is a single digit integer, ranging from 0 to 9
(both inclusive).
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
1
51. Let z be a complex number such that 5 z   3 and arg (z) =  , then the absolute value
z

of maximum value of 30 cos  2  is –

52. If the equations x 3  10 x 2  ax  b  0 and x 3  4 x 2  ax  c  0 have two roots in common,
then the difference of uncommon roots of two equations is
n

53. If n  N and H is harmonic mean of numbers (n  1), (n  2), (n  3)....2n, then lim
n 
e H

is-

54. Let f ( x)  lim(1

n 
 x3  x3e1/ n ) n , x  (, 0) then number of integral value (s) in range of

5sin( f ( x)) is–

   n 4  3n 2  10n  10 
55. The value of 10  n   5 is
 2 2 n
( n 4
 4) 

1  x2
56. The greatest integer less than the value of  dx
 1  sin x  1  sin 2 x is

57. For the circle x 2  y 2  r 2 the value of r for which the area enclosed by the tangents from
the point P(6, 8) to the circle and the chord of contact is maximum is ________

58. If (1  x  x 2 )n  a0  a1 x  a2 x 2  ...  a2 n x 2 n
3a  1
Then the value of (a0  a1  ....  an )3  (an  a( n 1)  ....  a2 n )3 for n  8 is , then a 
2

59. ABCD and PQRS are two variable rectangles, such that A, B, C and D lie on PQ, QR, RS
and SP respectively and perimeter ' x' of ABCD is constant. If the maximum area of
x
PQRS is 32, then 
4

60. The area of the rhombus ABCD is 24. The equation of the diagonal BD is 4x+3y+2=0
and A  (3, 2) . The length of the side of the rhombus is