PHP 5 Rewpq
PHP 5 Rewpq
2. A projectile travels at below horizontal 1 sec after projection as shown. What is the value of ?
1
(a) tan1 2 (b) tan1 (c) 37° (d) 53°
2
3. An electron in a research apparatus follows a circle path. On the electron’s first circuit of the
apparatus, its speed is v0 and the radius of its circular path is R. Each time it makes on circuit, it
v
passes a short region where it receives a “kick” and gains an additional speed of 0 . The
100
electron follows a circular path such that the magnitude of its acceleration is always the same.
What is the radius of the circular path after the electron has received 10 kicks?
R R
(a) (b) 1.1 R (c) 1.21 R (d)
1.1 1.21
4. A square of mass m is made of thin wire with sides of length a. Calculate the rotational inertia
about the z-axis.
7ma2 5ma2 7ma2 5ma2
(a) (b) (c) (d)
6 6 12 12
5. If we want that a simple pendulum oscillates with same time period in summer as it did in winter,
what changes to the simple pendulum should we do during summer?
(a) Increase the length (b) Decrease the length
(c) Increase mass of bob (d) Decrease mass of bob
6. An igloo, a hemispherical enclosure built of ice 1.67 J / m sC , has as inner radius of 2.50m. The
thickness of the ice is 0.5m. At what rate must thermal energy be generated to maintain the air
inside the igloo at 5C when the outside temperature is 40C? Ignore all thermal energy losses
through the ground or by air currents.
(a) 2.25 kW (b) 4.5 kW (c) 1.25 kW (d) 5 kW
7. Assume temperature of 27C, p = 10 Pa, n = 1 mole diameter of air molecules as 10 -10m, which of
5
12. In half deflection method, the resistance of resistance box in series with the galvanometer is
10,000 . When the galvanometer is shunted with 10 resistance, its reading drops to half the
initial value. The resistance of galvanometer is:-
(a) 5 (b) 10 (c) 20 (d) 25
13. Two air filled capacitors are connected as shown. The left capacitor is suddenly filled with a
dielectric of constant K. The work done by battery after that is 24J. Dielectric constant K is:-
M 80 Se 79.916521u
Which of the following decays are possible?
35 Br 36 Kr 1 e v
(i) 80 80 0
(ii) 80
35 Br 80
84 Se 1 e v
0
(iii) 80
35 Br 0
1 e 34
80
Se v
(a) all 3 (b) (i) & (iii) only (c) (ii) & (iii) only (d) (i) & (ii) only
19. Drawing power form a 12V car battery, a 9V stabilized DC voltage is required to power a car stereo
system, attached to the terminals A and B, as shown in the figure. If a Zener diode with ratings, V z
= 9V and Pmax = 0.27 W, is connected as shown in the figure, for the above purpose, the minimum
series resistance RS must be:-
20. When light of wavelength 540 nm passes through a single slit of unknown width, the diffraction
pattern displays a second maximum where the first minimum of light of an unknown wavelength
had been observed to fall. What is the unknown wavelength?
nx
1. A wave given by equation y = 1mm sin 5nt is produced in a string 100m long of mass 1 kg.
30
What is the tension (in N) in string? x is in m & t in sec.
2. You are trying to construct a compound microscope given two lenses with focal lengths f 1 = 1.0cm
and f2 = 4.0cm. How far apart (in cm) should you place the lenses in order to obtain an angular
magnification of 60? (Assume normal adjustment of microscope)
3. A small elastic ball of mass m is placed at the apex of a 45 inclined plane as shown in the figure
below. The ball is allowed to slip without friction down the plane (along the dotted line), hit the
ground (as shown) and bounce along it. If the height of the inclined plane is h and the coefficient
of restitution between the ball and the ground is 0.5, then the distance AB, as marked on the
figure, will be N × h, where N is
4. An electron moves in the field produced by a charged sphere of radius 10cm along the radius
connecting the points separated by 12 and 15 cm from the centre of the sphere. The velocity of
the electron changes thereby from 2 × 105 to 2 × 106 m/s. Determine the surface charge (in nC/m2)
density of the sphere. (Mass of electron = 9.1 × 10 -31kg)
5. In the circuit in figure we have 1 2 = 100V, R1 = 20 , R2 = 10 , R3 = 40 and R4 = 30 . Find
the reading of the ammeter (in A). Disregard the resistance of the battery and the ammeter.
6. You are given a converging lens with equal radii of curvature and a diverging lens with the same
radii of curvature as those of the converging lens. The lenses are made of material with n = 1.50,
the radii of curvature are all 35cm. They are placed at opposite ends of a tube 15cm long, and the
nearer lens which is converging is 10cm from an object. What is the location of the image that
results from the two refractions? Write the final distance (in cm) from diverging lens.
7. A calorimeter consists of 400g of water at 24C. A 500g piece of copper at 100C is thrown into
the water and the equilibrium temperature is found to be 36.5C. What is the molar heat capacity
of copper in cal/mol k, given that 1 mol of copper has a mass of 63.5g? Neglect the heat capacity
of the container.
8. The new white belt of a long horizontal conveyor is moving with a constant speed v = 3.0m/s. A
small block of carbon is placed on the belt with zero initial velocity relative to the ground. The
block will slip a bit before moving with the belt, leaving a black mark on the belt (figure). How long
is that mark (in m) if the coefficient of kinetic friction between the carbon block and the belt is
0.20 and the coefficient of static friction is 0.30?
9. In gravity free space, a bead of charge 1C and mass 3mg is threaded on a rough rod of friction
coefficient = 0.3. A magnetic field of magnitude 0.2 T exists perpendicular to the rod. The bead
is projected along the rod with a speed 4m/s. How much distance (in m) will the bead cover
before coming to rest?
10. Initially the capacitor is uncharged. What is the steady state charge on it in C after the switch
is closed?
PART 2 – CHEMISTRY
Section – I : (Maximum Marks : 80)
This section contains TWENTY questions.
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct.
For each question, darken the bubble corresponding to the correct option in the ORS.
For each question, marks will be awarded in one of the following categories :
Full Marks : +4 If only the bubble corresponding to the correct option is darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : 1 In all other cases
1. Hydrogenation of the above compound in the presence of poisoned palladium catalyst gives
6. What is the apparent molecular mass (in gm/mol) of a weak acid, HA (molar mass = 30.0 gm/mol)
in an aqueous solution, which shows elevation in boiling point by 0.0156C?
[Given: pKa (HA) = 2.0, Kb (H2O) = 0.52 K kg mol-1]
(a) 17.8 (b) 28.3 (c) 20.0 (d) 23.6
7. N-Ethyl pthalimide on hydrolysis gives-
(a) Methyl alcohol (b) Ethyl amine (c) Dimethyl amine (d) Diethyl amine
8. Consider the following reactions of 1A metals.
M + x y NH3 M NH3 x e NH3 y
1
Mam e NH3 MNH2am H2 g
2
Which of the following statement is
INCORRECT?
(a) The blue color of the solution is due to the ammoniated electron which absorbs energy in
infrared region of light
(b) In concentrated solution, the blue color changes to bronze color
(c) If concentration increases, the solution turns diamagnetic from paramagnetic
(d) The deep blue solution is conducting in nature
9. The compressibility factor of a Vanderwaal gas is 0.5 at 27C and 24 atm. The value of Vanderwaal
constant ‘a’ (in atm-L2/mol2) is (b = 0.10 L/mol, R = 0.08 L-atm/K-mol)
(b) 2.4 (b) 4.0 (c) 3.6 (d) 9.0
10.
respectively are :
11. Select the CORRECT statements?
(i) Zn(gly)2 is optically active compound
(ii) PdClBr gly exhibits geometrical isomerism
(iii) IrBr4 en exhibits cis trans isomerism
(iv) RhCl2 NH3 4 number of stereo isomers is equal to number of geometrical isomers
(a) (i), (ii), (iv) (b) (ii), (iii), (iv) (c) (ii), (iii) (d) (i), (iii), (iv)
12. A sample of hydrogen atoms de-excites from 6th excited state to the ground state in one or more
electronic transitions. If no spectral line is obtained in the Paschen and Brackett series, then the
maximum number of spectral lines of different photon energies obtained will be-
(a) 21 (b) 15 (c) 10 (d) 7
13. Hydrolysis of sucrose into (+) glucose and (-) fructose is known as-
(a) Mutarotation (b) Inversion (c) Pyrolysis (d) none of these
14. Which of the following reduction methods is correctly matched against the given metals
(commercial process)?
(a) Cu, Pb Self reduction (b) (Au, Ag)
Electrolytic reduction
low grade low grade
(c) (Cr, Mn) Thermite reduction (d) (Fe, Al) Carbon reduction
15. An equilibrium mixture contains 2.0 moles of A(g) and 4.0 moles of B(g). Now, 2.0 moles of A(g) is
added in this equilibrium mixture and the system is allowed to re-achieve equilibrium at constant
volume and temperature. Now, the volume of system is doubled at constant temperature. What
should be the moles of B(g) at new equilibrium? The reaction involved is
A g 2 Bg .
(a) 3.86 (b) 5.86 (c) 4.86 (d) 6.58
16. Nylon-66 is obtained by condensation polymerization of-
(a) Adipic acid and hexamethylene diamine (b) Phenol and formaldehyde
(c) Terephthalic acid and ethylene glycol (d) Succinic acid and hexamethylene diamine
17.
If Q is a colourless gas with rotten fish smell then select CORRECT statement.
(a) (Q) also produced on heating of H3PO4
(b) Structure of (P) is polymeric
(c) Only two oxy bridges are present in (S)
(d) Zero acidic hydrogen present in anionic part of (R)
18. Which reagent can not be used to distinguish t-Butyl alcohol and isopropyl alcohol:
(a) KMnO4 (b) HCl + Anhy ZnCl2 (c) Ammonical AgNO3 (d) K2Cr2O7
19. The only INCORRECT information is
(a) In isothermal expansion of an ideal gas, internal energy of the gas remains unchanged.
(b) In adiabatic free expansion of an Vanderwaal gas, the internal energy of gas remains
unchanged.
(c) In adiabatic free expansion of an ideal gas, the initial and final temperature of the gas remains
same.
(d) In adiabatic free expansion of a Vanderwaal gas, the initial and final temperature of gas will
remains same.
20. X 1) O
3
2) Zn/H O
Y Z ,
2
C 6H12
(Y) & (Z) both show disproportination with conc. NaOH. Then X will be-
SECTION-II: (Maximum Marks: 20)
This section contains TEN questions. Attempt any 5 questions. First 5 attempted questions will be
considered for marking.
The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value (If the numerical value has more than two
decimal places, truncate/round-off the value to TWO decimal places; e.g. 6.25, 7.00, 0.33, .30,
30.27, 127.30, if answer is 11.36777….. then both 11.36 and 11.37 will be correct) by darken the
corresponding bubbles in the ORS.
For Example: If answer is 77.25, 5.2 then fill the bubbles as follows.
Answer to each question will be evaluated according to the following marketing scheme: Full
Marks : +4 If ONLY the correct numerical value is entered as answer.
Zero Marks : 0 In all other cases
4. Find out the number of following orders which are INCORRECT against the mentioned properties:
(i) Ortho hydrogen > Para hydrogen (Stability at low temperature)
(ii) Ethanol > Glycerol (Viscosity)
(iii) D2 < He (Boiling point)
(iv) HF > H2O (Melting point)
(v) H3BO3 > BF3 (Melting point)
(vi) NH3 < SbH3 (Boiling point)
(vii) H2O2 > H2O (Strength of hydrogen bond)
(viii) H2O < D2O (Freezing point)
(ix) HF2 < HF (Strength of hydrogen bond)
(x) D2O < H2O (Bond energy)
5. A metal crystallises as simple cubic crystal. The distance between the nearest neighbours of each
258.36
atom is pm. The atomic radius of metal atoms (in pm) is
2
6. Nitric oxide is formed in the combustion of fuel. An internal combustion engine produces 600 ppm
(600 mg L-1) of NO was oxidized to NO2. The NO2 formed was dissolved in 10L of water. The pH of
the resulting solution is
(log 2 = 0.30, log 3 = 0.48)
7. A thin circular-disk earrings 10.0cm in diameter is plated with a coating of gold 0.20mm thick from
an Au3+ bath. How many days (approx.) does it take to deposit the gold on one side of one earring
if the current is 0.193 ampere.
(Au = 197, density of Au = 19.7 g/cm3, 1 F = 96500 C, 86400 = 27500 p)
8. Consider the following orders given below.
(i) S > Se > Te > O (Electron Affinity)
(ii) N3 O2 F Na Mg 2 (Ionic Size)
(ii) Fe2+ > Fe3+ > Fe4+ (Ionization Enthalpy)
(iv) H < B < P < C < Cl (Electronegativity)
(v) Na+ < Mg2+ < Al3+ (Extent of hydration)
(vi) Li > Na > K > Rb > Cs (Reducing Nature)
(vii) LiF(s) > LiCl(s) > LiBr(s) (Lattice Energy)
If x = number of correct orders
y = number of incorrect orders
y
then the value of 1 is.
x
9. Among the following oxides Cr2O3, V2O5, FeO, Mn2O7, ZnO, Cu2O, MnO2, CrO3, NiO
If x = number of basic oxides
y = number of acidic oxides
z = number of amphoteric oxides
(a) (b) (c) (d)
2 8 4
3. Number of integers in the domain of the function, f(x) = 3 2x 21 x
(a) 1 (b) 4 (c) 2 (d) 3
4. If one of the root of the quadratic equation x x 1 = 0 is less than 1 and other is greater
2
2x y z 1 from point P measured along a line inclined at an angle 45 with the line L and is
minimum, then value of PQ equals
(a) 3 (b) 4 (c) 5 (d) 6
sinx
5cosx cos3 x
19. If f(x) = 2 loge 2 dx and f(0) = 1 then value of f(/2) equals
2 sinx 3 cos2 x
3e 3e
(a) 3e (b) (c) (d) 3e
2 2
20. Let A(z1), B(z2) and C(z3) lie on the circle z i =1 and satisfy the equation 3z1 + i 2z2 + 2z3. If D is the
centre of the circle z i 1, then area of quadrilateral ABCD equals:-
3 5 11 7
(a) (b) (c) (d)
4 4 4 4
1. If the slope of tangent to the curve y = ax3 – bx2 at x = 1 is equal to 3, where a [1,2] then number
of possible integral values of b is
A 1 B 1
2. It is given that events A and B of an experiment are such that P and P and
B 4 A 12
1
chance of occurrence of an event “only A” is (where P(x) denote the probability of occurrence
12
of event ‘x’). Value of 22P(B) equals
3. If the system of equations
x + 6y + 6z = x
4x – y + 4z = y
2x 2y z 5z
has non-trivial solution then the value of equals (where R)
g' 1
4. If the function f(x) = 2 + x2 – e-x and g(x) = f1(x), then value of equals
4
5. If x1 lim
cot 1 x 1 x then
3e x1
x2
equals
x 2x 1
1
x
4
sec
x 1
4
2
6. Assume e 5
. If x, y satisfy, y = ex and the minimum value of (x2 + y2) is expressed in the form of
5
m
tehn
2m n equals (where m & n are coprime natural numbers)
n 5
7. Let f(x) be non-constant thrice differentiable function defined on , such that f(x) = f(6 – x)
and f’(0) = 0 = f’(2) = f’(5). If ‘n’ is the minimum number of roots of (f”(x))2 + f(x)f”(x) = 0 in the
interval x [0, 6] then sum of digits of n equals
x2 y z y2 x z z2 x y xyz
8. If a,b,c,x,y,z are non-zero real numbers and 3
3
3
1 , then the
a b c abc
value of (a3 + b3 + c3 + abc) equals
9. If the co-ordinate of the vertex of the vertex of the parabola whose parametric equation is x = t 2 –
t + 1 and y = t2 + t + 1, t R is (a, b) then (2a + 4b) equals
1 sinA cosB sinA sinB f(A,B)
10. If f(A, B) = and g(A, B) = and h(A,B) = then the
cos A 1 sinB sin A B cos A cosB g(A,B)
value of h 18, 36 . (wherever defined)