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Thermochemistry Tutorial Sheet

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34 views3 pages

Thermochemistry Tutorial Sheet

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onyealiimelda
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Thermochemistry Tutorial sheet

Introductory Physics (University of Zambia)

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CHE1000 Thermochemistry Tutorial sheet

Answer questions 1a, 1b, 3a, 3b and 5 Deadline: After the term break
1.
a. The first step in the industrial recovery of zinc from the zinc sulfide ore is roasting,
that is, the conversion of ZnS to ZnO by heating:

Draw the profile diagram for the reaction.


b. Combustion reactions involve reacting a substance with oxygen. When compounds
containing carbon and hydrogen are combusted, carbon dioxide and water are the
products. Using the enthalpies of combustion for C4H4 (-2341 kJ/mol), C4H8 (-2755
kJ/mol), and H2 (-286 kJ/mol), calculate H for the reaction
2.
a. A system releases 125 kJ of heat while 104 kJ of work is done on it. Calculate
b. Calculate for each of the following:
i. q = 5 247 kJ, w = 5 188 kJ
ii. q = 5 182 kJ, w =5 247 kJ
iii. q= 5 147 kJ, w 5 0
iv. In which of these cases do the surroundings do work on the system?
3. The specific heat capacity of silver is 0.24 J/.g.
a. Calculate the energy required to raise the temperature of 150.0 g Ag from 273 K to
298 K
b. It takes 1.25 kJ of energy to heat a sample of pure silver from 12.08 to 15.28.
Calculate the mass of the sample of silver.

4. Using the Hess’s law and the enthalpies of the given reactions,
calculate the enthalpy of the combustion reaction of CH3Cl:

CH3Cl(g) + O2(g) → CO(g) + HCl(g) + H2O(l), ΔH = ?

1) CO(g) + 2H2(g) → CH3OH(g), ΔHo = -139 kJ

2) 2H2(g) + O2(g) → 2H2O(g), ΔHo = -571 kJ

3) CH3OH(g) + HCl(aq) → CH3Cl(g) + H2O(l), ΔHo = -28 kJ

5. Determine the enthalpy of the following reaction:

CH3CH=CH2 + 4.5O=O ---> 3O=C=O + 3H−O−H

using the following bond enthalpy values:

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Bond Bond Energy


C−C 347
C=C 611
C−H 414
C=O 736
O=O 498
O−H 464

6. Calculate the bond dissociation energy for one mole of O−F bonds, given the following
data. (Hint: oxygen is the central atom of OF2)

F−F bond dissociation energy = 159 kJ


O=O bond dissociation energy = 498 kJ

F2(g) + 1⁄2O2(g) ---> OF2 (g) ΔH = 28 kJ

7. A 0.88 g gummy bear is burned in a bomb calorimeter. The temperature started at 21.5 °C
and leveled off at 24.2 °C. The manufacturer of the bomb calorimeter determined the heat
capacity of the calorimeter to be 11.4 kJ/°C. Calculate the heat of combustion per gram of
gummy bear.

8. A 1.5 kg block of Ni at 100 °C is placed into 500 mL of water that has a temperature of
21 °C. What is the final temperature assuming the specific heat of Ni is 0.44 J/g-°C and
the specific heat of water is 4.184 J/g-°C. Hint: the total heat lost is equal to the total heat
gained!
o
9. What is the chemical reaction corresponding to the ΔH f for HClO ?

10. A common gasoline additive is octane, C8H18. When octane is burned it produces heat
according to the following equation.

2C8H18(l) + 25O2(g) → 18H2O(g) + 16CO2(g) ΔH = 1.02 x 104 kJ

How much heat is produced per mole of octane?

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