SAFETY DATA SHEET

This safety data sheet complies with the requirements of:

Regulation (EC) No. 1907/2006 and Regulation (EC) No. 1272/2008

Issue Date 20-Aug-2019 Revision Date 20-Aug-2019 Version 1

Section 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING
1.1. Product identifier

Product Name AM.CO.ZA Premium Ink Cleaning Solution

Contains Butoxyethyl acetate, gamma-Butyrolactone

1.2. Relevant identified uses of the substance or mixture and uses advised against

Recommended use Cleaning solution as a washing and cleaning preparation for use in digital ink delivery
systems and digital print heads.

Uses advised against No information available

1.3. Details of the supplier of the safety data sheet

Supplier
Advanced Machinery (Pty) Ltd

For further information, please contact

Contact Point Product safety department

1.4. Emergency telephone number

Emergency Telephone During normal opening times: 011 397 1429

Section 2: HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture
Regulation (EC) No 1272/2008
Acute toxicity - Dermal Category 4 - (H312)
Acute toxicity - Inhalation (Vapours) Category 4 - (H332)
Serious eye damage/eye irritation Category 1 - (H318)

Classification according to Directive 67/548/EEC or 1999/45/EC

Full text of R-phrases: see section 16

Hazard symbols
Xn - Harmful

R-code(s)
Xn;R20/21 - Xi;R36

2.2. Label elements

Product identifier
Contains Butoxyethyl acetate, gamma-Butyrolactone

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Signal word
Danger

Hazard statements
H312 - Harmful in contact with skin
H318 - Causes serious eye damage
H332 - Harmful if inhaled

Precautionary Statements - EU (§28, 1272/2008)

P321 - Specific treatment (see supplemental instructions on the administration of antidotes on this label)
P280 - Wear eye protection/ face protection
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing
P310 - Immediately call a POISON CENTER or doctor

2.3. Other hazards

No information available

Section 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.1 Substances

Chemical Name EC No CAS No Weight-% Classification REACH Registration

according to Number
Regulation (EC) No.
1272/2008 [CLP]
Butoxyethyl acetate 203-933-3 112-07-2 85-95 Acute Tox. 4 (H312) No data available
Acute Tox. 4 (H332)
gamma-Butyrolacton 202-509-5 96-48-0 5-10 Acute Tox. 4 (H302) No data available
e Eye Dam. 1 (H318)
STOT SE 3 (H336)

Full text of R-phrases: see section 16

Full text of H- and EUH-phrases: see section 16

Section 4: FIRST AID MEASURES

4.1. Description of first aid measures

General advice If symptoms persist, call a doctor. Do not breathe dust/fume/gas/mist/vapours/spray. Do not
get in eyes, on skin, or on clothing.

Inhalation Remove to fresh air. Call a doctor. If breathing is irregular or stopped, administer artificial
respiration. Avoid direct contact with skin. Use barrier to give mouth-to-mouth resuscitation.
Immediate medical attention is not required. Move to fresh air in case of accidental
inhalation of vapours. If symptoms persist, call a doctor. Move to fresh air in case of
accidental inhalation of vapours or decomposition products.

Skin contact Consult a doctor if necessary. Wash off immediately with soap and plenty of water while
removing all contaminated clothes and shoes. Immediate medical attention is not required.
If skin irritation persists, call a doctor.
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Eye contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and
continue flushing for at least 15 minutes. Keep eye wide open while rinsing. If symptoms
persist, call a doctor. Rinse thoroughly with plenty of water for at least 15 minutes, lifting
lower and upper eyelids. Consult a doctor.

Ingestion Rinse mouth. Drink plenty of water. If symptoms persist, call a doctor. Do NOT induce
vomiting. Clean mouth with water and drink afterwards plenty of water. Never give anything
by mouth to an unconscious person. Call a doctor.

Self-protection of the first aider Use personal protective equipment as required.

4.2. Most important symptoms and effects, both acute and delayed

Symptoms No information available.

4.3. Indication of any immediate medical attention and special treatment needed

Note to doctors Treat symptomatically.

Section 5: FIRE FIGHTING MEASURES

5.1. Extinguishing media

Suitable extinguishing media

Use. Dry chemical. Carbon dioxide (CO2). Water spray (fog). Alcohol resistant foam.

Unsuitable extinguishing media

No information available

5.2. Special hazards arising from the substance or mixture

Keep product and empty container away from heat and sources of ignition Risk of ignition

5.3. Advice for firefighters

Wear self-contained breathing apparatus and protective suit. Use personal protective equipment as required.

Section 6: ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions
Use personal protective equipment as required. Remove all sources of ignition. Evacuate personnel to safe areas. Keep people
away from and upwind of spill/leak. Pay attention to flashback. Take precautionary measures against static discharges.

For emergency responders

Use personal protection recommended in Section 8.

6.2. Environmental precautions

Prevent entry into waterways, sewers, basements or confined areas. Do not flush into surface water or sanitary sewer system.
Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. See section 12 for additional ecological
information.

6.3. Methods and material for containment and cleaning up

Methods for containment Prevent further leakage or spillage if safe to do so.

Methods for cleaning up Cover liquid spill with sand, earth or other non-combustible absorbent material. Cover
powder spill with plastic sheet or tarp to minimise spreading. Pick up and transfer to

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properly labelled containers. Soak up with inert absorbent material. Dam up. Take
precautionary measures against static discharges.

6.4. Reference to other sections

See section 8 for more information. See section 13 for more information.

Section 7: HANDLING AND STORAGE

7.1. Precautions for safe handling

Advice on safe handling

Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Wash contaminated clothing before
reuse. Do not breathe dust/fume/gas/mist/vapours/spray. Do not eat, drink or smoke when using this product. Use with local
exhaust ventilation. All equipment used when handling the product must be grounded. Keep away from heat/sparks/open
flames/hot surfaces. - No smoking. Take necessary action to avoid static electricity discharge (which might cause ignition of
organic vapours).

General Hygiene Considerations

When using do not eat, drink or smoke. Regular cleaning of equipment, work area and clothing is recommended.

7.2. Conditions for safe storage, including any incompatibilities

Storage Conditions
Keep container tightly closed in a dry and well-ventilated place. Keep out of the reach of children. Keep containers tightly closed in
a cool, well-ventilated place. Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and
static electricity). Keep in properly labelled containers. Keep away from heat.

Incompatible materials
None known based on information supplied.

7.3. Specific end use(s)

Risk Management Methods (RMM)

The information required is contained in this Material Safety Data Sheet.

Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

Chemical Name European Union United Kingdom France Spain Germany

Butoxyethyl acetate TWA 20 ppm TWA: 20 ppm TWA: 10 ppm TWA: 20 ppm TWA: 10 ppm
112-07-2 TWA 133 mg/m3 TWA: 133 mg/m3 TWA: 66.5 mg/m3 TWA: 133 mg/m3 TWA: 65 mg/m3
STEL 50 ppm STEL: 50 ppm STEL: 50 ppm STEL: 50 ppm H*
STEL 333 mg/m3 STEL: 332 mg/m3 STEL: 333 mg/m3 STEL: 333 mg/m3
* Sk* * vía dérmica*
Chemical Name Italy Portugal Netherlands Finland Denmark
Butoxyethyl acetate TWA: 20 ppm TWA: 20 ppm TWA: 135 mg/m3 TWA: 20 ppm TWA: 20 ppm
112-07-2 TWA: 133 mg/m3 TWA: 133 mg/m3 STEL: 333 mg/m3 TWA: 130 mg/m3 TWA: 134 mg/m3
STEL: 50 ppm STEL: 50 ppm H* STEL: 50 ppm H*
STEL: 333 mg/m3 STEL: 333 mg/m3 STEL: 330 mg/m3
pelle* P* iho*
gamma-Butyrolactone - - - TWA: 50 ppm -
96-48-0 TWA: 14 mg/m3
STEL: 250 ppm
STEL: 70 mg/m3
iho*
Chemical Name Austria Switzerland Poland Norway Ireland
Butoxyethyl acetate TWA: 20 ppm TWA: 10 ppm STEL: 300 mg/m3 TWA: 10 ppm TWA: 20 ppm
112-07-2 TWA: 133 mg/m3 TWA: 66 mg/m3 TWA: 100 mg/m3 TWA: 65 mg/m3 TWA: 133 mg/m3
STEL 40 ppm STEL: 20 ppm STEL: 15 ppm STEL: 50 ppm
STEL 270 mg/m3 STEL: 132 mg/m3 STEL: 97.5 mg/m3 STEL: 333 mg/m3
H* H* H* Sk*

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Chemical Name European Union United Kingdom France Spain Germany

Butoxyethyl acetate - - - - 100 mg/L
112-07-2 150 mg/L
Chemical Name Austria Switzerland Poland Norway Ireland
Butoxyethyl acetate - 100 - - -
112-07-2 200
Derived No Effect Level (DNEL) No information available.

Predicted No Effect Concentration No information available.

(PNEC)

8.2. Exposure controls

Engineering Controls Ensure adequate ventilation, especially in confined areas.

Personal protective equipment

Eye/face protection Tight sealing safety goggles. Face protection shield.
Skin and body protection Suitable protective clothing. Apron. Gloves made of plastic or rubber. Wear chemical
resistant clothing such as gloves, apron, boots or whole bodysuits made from neoprene, as
appropriate. Antistatic footwear.

Environmental exposure controls Do not allow into any sewer, on the ground or into any body of water.

Section 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties
Physical state liquid
Appearance Liquid Odour Characteristic
Colour clear Odour threshold No information available

Property Values Remar ks •Met hod

pH No information available
Melting point / freezing point No information available
Boiling point / boiling range 145 °C / 293 °F
Flash point > 100 °C / > 212 °F
Evaporation rate No information available
Flammability (solid, gas) No information available
Flammability Limit in Air
Upper flammability limit: No information available
Lower flammability limit No information available
Vapour pressure No information available
Vapour density No information available
Relative density No information available
Water solubility partially soluble
Solubility(ies) No information available
Partition coefficient No information available
Autoignition temperature No information available
Decomposition temperature No information available
Kinematic viscosity No information available
Dynamic viscosity No information available
Explosive properties Not an explosive
Oxidising properties Not applicable

9.2. Other information

Softening point No information available
Molecular weight No information available
VOC Content (%) No information available
Density No information available
Bulk density No information available

Section 10: STABILITY AND REACTIVITY

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10.1. Reactivity

No data available.

10.2. Chemical stability

Stable under normal conditions.

Explosion data
Sensitivity to Mechanical Impact None.
Sensitivity to Static Discharge None.

10.3. Possibility of hazardous reactions

Possibility of Hazardous Reactions

None under normal processing.

10.4. Conditions to avoid

Heat, flames and sparks.

10.5. Incompatible materials

No information available.

10.6. Hazardous decomposition products

None under normal use conditions.

Section 11: TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects

Acute toxicity

Product Information
Product does not present an acute toxicity hazard based on known or supplied information.
Inhalation No data available.
Eye contact No data available.
Skin contact No data available.
Ingestion No data available.

The following values are calculated based on chapter 3.1 of the GHS document
ATEmix (oral) 15,556.00 mg/kg
ATEmix (dermal) 1,665.00 mg/kg ppm mg/l
ATEmix (inhalation-vapour) 12.00 mg/l
Unknown acute toxicity
9.9 % of the mixture consists of ingredient(s) of unknown toxicity.
0 % of the mixture consists of ingredient(s) of unknown acute oral toxicity.
0 % of the mixture consists of ingredient(s) of unknown acute dermal toxicity.
0 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (gas).
9.9 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (vapour).
0 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (dust/mist).

Chemical Name Oral LD50 Dermal LD50 Inhalation LC50

Butoxyethyl acetate = 2400mg/kg ( Rat ) = 1500 mg/kg ( Rabbit ) > 400 ppm ( Rat ) 4 h
gamma-Butyrolactone = 1540 mg/kg ( Rat ) > 5100 mg/m3 ( Rat ) 4 h

Skin corrosion/irritation No information available.

Serious eye damage/eye irritation No information available.

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Sensitisation No information available.

Germ cell mutagenicity No information available.

Carcinogenicity No information available.

Reproductive toxicity No information available.

STOT - single exposure No information available.

STOT - repeated exposure No information available.

Target Organ Effects blood, Central nervous system, Eyes, Hematopoietic System, kidney, liver, Respiratory
system, Skin.

Aspiration hazard No information available.

Section 12: ECOLOGICAL INFORMATION

12.1. Toxicity

Unknown aquatic toxicity 0 % of the mixture consists of component(s) of unknown hazards to the aquatic environment
0 % of the mixture consists of component(s) of unknown hazards to the aquatic environment

Chemical Name Algae/aquatic plants Fish Crustacea

Butoxyethyl acetate 500: 72 h Desmodesmus - 37: 48 h Daphnia magna mg/L
subspicatus mg/L EC50 EC50
gamma-Butyrolactone 360: 72 h Desmodesmus 220 - 460: 96 h Leuciscus idus mg/L 500: 48 h Daphnia magna Straus
subspicatus mg/L EC50 79: 96 h LC50 static mg/L EC50
Desmodesmus subspicatus mg/L
EC50

12.2. Persistence and degradability

No information available.

12.3. Bioaccumulative potential

No information available.

Chemical Name Partition coefficient

Butoxyethyl acetate 1.51
gamma-Butyrolactone -0.566

12.4. Mobility in soil

Mobility in soil
No information available.

12.5. Results of PBT and vPvB assessment

No information available.

12.6. Other adverse effects

No information available

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Section 13: DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods

Waste from residues/unused Disposal should be in accordance with applicable regional, national and local laws and
products regulations.

Contaminated packaging Improper disposal or reuse of this container may be dangerous and illegal.

Other Information Waste codes should be assigned by the user based on the application for which the product
was used.

Section 14: TRANSPORT INFORMATION

IMDG
14.1 UN/ID no Not regulated
14.2 Proper Shipping Name Not regulated
14.3 Hazard Class Not regulated
14.4 Packing Group Not regulated
14.5 Marine pollutant Not applicable
14.6 Special Provisions None
14.7 Transport in bulk according to No information available
Annex II of MARPOL 73/78 and the
IBC Code

RID
14.1 UN/ID no Not regulated
14.2 Proper Shipping Name Not regulated
14.3 Hazard Class Not regulated
14.4 Packing Group Not regulated
14.5 Environmental hazard Not applicable
14.6 Special Provisions None

ADR
14.1 UN/ID no Not regulated
14.2 Proper Shipping Name Not regulated
14.3 Hazard Class Not regulated
14.4 Packing Group Not regulated
14.5 Environmental hazard Not applicable
14.6 Special Provisions None

IATA
14.1 UN/ID no Not regulated
14.2 Proper Shipping Name Not regulated
14.3 Hazard Class Not regulated
14.4 Packing Group Not regulated
14.5 Environmental hazard Not applicable
14.6 Special Provisions None

Section 15: REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

France
Occupational Illnesses (R-463-3, France)
Chemical Name French RG number Title
Butoxyethyl acetate RG 84 -
112-07-2
gamma-Butyrolactone RG 84 -
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96-48-0

European Union

Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents
at work

Authorisations and/or restrictions on use:

This product does not contain substances subject to authorisation (Regulation (EC) No. 1907/2006 (REACH), Annex XIV) This
product does not contain substances subject to restriction (Regulation (EC) No. 1907/2006 (REACH), Annex XVII)

Persistent Organic Pollutants

Not applicable

Ozone-depleting substances (ODS) regulation (EC) 1005/2009 Not applicable

International Inventories
All of the components in the product are on the following Inventory lists TSCA (United States), Canada (DSL/NDSL),
Europe (EINECS/ELINCS/NLP), Australia (AICS), South Korea (KECL), China (IECSC), ENCS (Japan), Philippines (PICCS).

15.2. Chemical safety assessment

No information available

Section 16: OTHER INFORMATION

Key or legend to abbreviations and acronyms used in the safety data sheet

Full text of R-phrases referred to under sections 2 and 3

R22 - Harmful if swallowed
R67 - Vapours may cause drowsiness and dizziness
R41 - Risk of serious damage to eyes
R36 - Irritating to eyes
R20/21 - Harmful by inhalation and in contact with skin

Full text of H-Statements referred to under section 3

H312 - Harmful in contact with skin
H332 - Harmful if inhaled
H302 - Harmful if swallowed
H318 - Causes serious eye damage
H336 - May cause drowsiness or dizziness

Legend
SVHC: Substances of Very High Concern for Authorisation:

Legend Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit)
Ceiling Maximum limit value * Skin designation

Issue Date 20-Aug-2019

Revision Date 20-Aug-2019

Revision Note Not applicable.

This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006

End of Safety Data Sheet

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