Chemical Kinetics Ex - 3 Numerical Based Ques

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Eeerce DATEJ

Nimienal Baced stt


1

Ordes

-1 d(er0
2

d Bro = 1 CBr
dt 2 dt
a 0- 02
O"04

Se latb)x00 2 6
23
t"2X 10 -15 Mie-= Kx(2x 10
2600

200
DATE_

y-or X 0.10 = klo.201 (ao


0.40K[x] lo- 05l msll
1 O2 O.80

fex y O.10 = K[o 20]_[os 05J


O"90 y020 moll
1: 11 0.05
2
0+ O. 20) = 1 m L
(2+)E (0.8
5
1 o.02
0 o25 O.04

1
(2)m 1 (2)2
3

2 Ca ta
to
t+t 2.
2 = 1 Ke2+5X 10

eaati
DATE/

100
Aioe vinu
1o0
K= 2"303 log
"0088
K= 2o 303 X O
X(2303 X 0.0088)
So, 400 e = 4 00

Ke6"93X 10=tt
Aq
P
+

2P
n-1

P- P-4,-1
2P (n-1)
Pn-3)
(n-1)
Ka 693x 10-t= 2 303
1000
693X1o-1 = n-1)
2.303 (n-3)

2 n-1)

2 m9)= (n-1)
on3)
DATEJ_J
A= 16D
AL
Kcal1
Ea= (4o606+a) Koalue
K=
-tajeT
K: Ae

1 1

1 -4-6e6)
2X10-3 500

Rn= n 1o0 4:606

2" 303

2 1

L0 Eae 83.14 KT/mel

Ea = ux 10
RT
-83.14
3
B.314 X10°X 500
1 0000
500
DATEJJ
-20 Lanx. 10 t
-20 = 2. 203

2X 10-9
2

Se
DATEJ.
-20 2Ran 10
-20 = 2: B03 lag 10
-8.68 2 10

2x 10 -9 . 1O

2.

Se q-2

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