Solid State JM21
Solid State JM21
2. The unit cell of copper corresponds to a face centered cube of edge length 3.596Å with
one copper atom at each lattice point. The calculated density of copper in kg/m3 is____.
[Molar mass of Cu : 63.54 g; Avogadro Number = 6.022 × 1023]
[JEE Main, 25 Feb., 21 (Shift-2)]
Solid State
1. The ionic radius of Na+ ions is 1.02 Å. The ionic radii (in Å) of Mg2+ and Al3+,
respectively, are-
(1) 1.05 and 0.99 (2) 0.72 and 0.54
(3) 0.85 and 0.99 (4) 0.68 and 0.72
[JEE Main 18, March 21 (Shift-1)]
2. In a binary compound, atoms of element A form a hcp structure and those of element
M
occupy 2/3 of the tetrahedral voids of the hcp structure. The formula of the binary
compound
is:
(1) M2A3 (2) M4A3 (3) M4A (4) MA3
[JEE Main 18, March 21 (Shift-1)]
4. A hard substance melts at high temperature and is an insulator in both solid and in
molten state.
This solid is most likely to be a / an :
(1) Ionic solid (2) Molecular solid
(3) Metallic solid (4) Covalent solid
[JEE Main 18, March 21 (Shift-2)]
5. A certain element crystallises in a bcc lattice of unit cell edge length 27 Å. If the same
element under the same conditions crystallises in the fcc lattice, the edge length of the
unit cell in Å will be ________. (Round off to the Nearest Integer). [Assume each lattice
point has a single atom] [Assume 3 = 1.73, 2 = 1.41]
[JEE Main 16, March 21 (Shift-1)]
7. KBr is doped with 10–5 mole percent of SrBr2. The number of cationic vacancies in 1
g of KBr crystal is _____1014. (Round off to the Nearest Integer).
[Atomic Mass : K : 39.1 u, Br : 79.9 u, NA = 6.023 × 1023]
[JEE Main 17, March 21 (Shift-2)]
Solid State
1. Given below are two statements. One is labelled as
Assertion A and the other is labelled as Reason R.
Assertion A: Sharp glass edge becomes smooth on heating it upto its melting point.
Reason R: The viscosity of glass decreases on melting Choose the most appropriate
answer from the options given below.
(1) A is true but R is false
(2) Both A and R are true but R is NOT the correct explanation of A.
(3) A is false but R is true.
(4) Both A and R are true and R is the correct explanation of A.
5. A copper complex crystallising in a CCP lattice with a cell edge of 0.4518 nm has been
revealed by employing X-ray diffraction studies. The density of a copper complex is
found to be 7.62 g cm–3. The molar mass of copper complex is ______ g mol–1.
(Nearest integer)
[Given : NA = 6.022 × 1023 mol–1 ]
Solid State
1. Given below are two statements.
Statement I: Frenkel defects are vacancy as well as interstitial defects.
Statement II: Frenkel defect leads to colour in ionic solids due to presence of F-centres.
Choose the most appropriate answer for the statements from the options given below:
(1) Statement I is false but Statement II is true
(2) Both Statement I and Statement II are true
(3) Statement I is true but Statement II is false
(4) Both Statement I and Statement II are false
3. The empirical formula for a compound with a cubic close packed arrangement of anions
and with cations occupying all the octahedral sites in AxB. The value of x is
____________. (Integer answer)