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Solid State JM21

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22 views4 pages

Solid State JM21

Uploaded by

himanshipant2007
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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Solid State

1. The coordination number of an atom in a body centered cubic structure is_______


[Assume that the lattice is made up of atoms]
[JEE Main, 24 Feb., 21 (Shift-1)]

2. The unit cell of copper corresponds to a face centered cube of edge length 3.596Å with
one copper atom at each lattice point. The calculated density of copper in kg/m3 is____.
[Molar mass of Cu : 63.54 g; Avogadro Number = 6.022 × 1023]
[JEE Main, 25 Feb., 21 (Shift-2)]

3. The number of octahedral voids per lattice site in a lattice is _____.


(Rounded off to the nearest integer)
[JEE Main, 26 Feb., 21 (Shift-2)]

Solid State
1. The ionic radius of Na+ ions is 1.02 Å. The ionic radii (in Å) of Mg2+ and Al3+,
respectively, are-
(1) 1.05 and 0.99 (2) 0.72 and 0.54
(3) 0.85 and 0.99 (4) 0.68 and 0.72
[JEE Main 18, March 21 (Shift-1)]

2. In a binary compound, atoms of element A form a hcp structure and those of element
M
occupy 2/3 of the tetrahedral voids of the hcp structure. The formula of the binary
compound
is:
(1) M2A3 (2) M4A3 (3) M4A (4) MA3
[JEE Main 18, March 21 (Shift-1)]

3. The oxide that shows magnetic property is :


(1) SiO2 (2) Mn3O4 (3) Na2O (4) MgO
[JEE Main 18, March 21 (Shift-2)]

4. A hard substance melts at high temperature and is an insulator in both solid and in
molten state.
This solid is most likely to be a / an :
(1) Ionic solid (2) Molecular solid
(3) Metallic solid (4) Covalent solid
[JEE Main 18, March 21 (Shift-2)]
5. A certain element crystallises in a bcc lattice of unit cell edge length 27 Å. If the same
element under the same conditions crystallises in the fcc lattice, the edge length of the
unit cell in Å will be ________. (Round off to the Nearest Integer). [Assume each lattice
point has a single atom] [Assume 3 = 1.73, 2 = 1.41]
[JEE Main 16, March 21 (Shift-1)]

6. Ga (atomic mass 70 u) crystallizes in a hexagonal close packed structure. The total


number of voids in 0.581 g of Ga is _______ × 1021. (Round off to the Nearest Integer).
[JEE Main 16, March 21 (Shift-2)]

7. KBr is doped with 10–5 mole percent of SrBr2. The number of cationic vacancies in 1
g of KBr crystal is _____1014. (Round off to the Nearest Integer).
[Atomic Mass : K : 39.1 u, Br : 79.9 u, NA = 6.023 × 1023]
[JEE Main 17, March 21 (Shift-2)]

Solid State
1. Given below are two statements. One is labelled as
Assertion A and the other is labelled as Reason R.
Assertion A: Sharp glass edge becomes smooth on heating it upto its melting point.
Reason R: The viscosity of glass decreases on melting Choose the most appropriate
answer from the options given below.
(1) A is true but R is false
(2) Both A and R are true but R is NOT the correct explanation of A.
(3) A is false but R is true.
(4) Both A and R are true and R is the correct explanation of A.

2. The parameters of the unit cell of a substance are


a = 2.5, b = 3.0, c = 4.0, a =90°, b =120°, g =90°.
The crystal system of the substance is :
(1) Hexagonal (2) Orthorhombic
(3) Monoclinic (4) Triclinic

3. Select the correct statements.


(A) Crystalline solids have long range order.
(B) Crystalline solids are isotropic.
(C) Amorphous solid are sometimes called pseudo solids.
(D) Amorphous solids soften over a range of temperatures.
(E) Amorphous solids have a definite heat of fusion.
Choose the most appropriate answer from the options given below.
(1) (A), (B), (E) only
(2) (B), (D) only
(3) (C), (D) only
(4) (A), (C), (D) only
4. Diamond has a three dimensional structure of C atoms formed by covalent bonds. The
structure of diamond has face centred cubic lattice where 50% of the tetrahedral voids
are also occupied by carbon atoms. The number of carbon atoms present per unit cell
of diamond is______________.

5. A copper complex crystallising in a CCP lattice with a cell edge of 0.4518 nm has been
revealed by employing X-ray diffraction studies. The density of a copper complex is
found to be 7.62 g cm–3. The molar mass of copper complex is ______ g mol–1.
(Nearest integer)
[Given : NA = 6.022 × 1023 mol–1 ]

Solid State
1. Given below are two statements.
Statement I: Frenkel defects are vacancy as well as interstitial defects.
Statement II: Frenkel defect leads to colour in ionic solids due to presence of F-centres.
Choose the most appropriate answer for the statements from the options given below:
(1) Statement I is false but Statement II is true
(2) Both Statement I and Statement II are true
(3) Statement I is true but Statement II is false
(4) Both Statement I and Statement II are false

2. Match items of List–I with those of List–II :


List–I List–II
(Property) (Example)
(a) Diamagnetism (i) MnO
(b) Ferrimagnetism (ii) O2
(c) Paramagnetism (iii) NaCl
(d) Antiferromagnetism (iv) Fe3O4
Choose the most appropriate answer from the options given below:
(1) (a)–(ii), (b)–(i), (c)–(iii), (d)–(iv)
(2) (a)–(i), (b)–(iii), (c)–(iv), (d)–(ii)
(3) (a)–(iii), (b)–(iv), (c)–(ii), (d)–(i)
(4) (a)–(iv), (b)–(ii), (c)–(i), (d)–(iii)

3. The empirical formula for a compound with a cubic close packed arrangement of anions
and with cations occupying all the octahedral sites in AxB. The value of x is
____________. (Integer answer)

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