1

Arjuna JEE AIR (2024)

PERIODIC TABLE ASSIGNMENT-02

1. Ionisation energy order is: 9. Which of the following is only incorrect increasing
(1) Li < Be > B (2) Be < B < C order of first ionisation energy of the atoms or ions
(3) C < N < O (4) N < O < F mentioned?
(1) Mg+ < Al2+ < Na+
(2) I– < I < I+
2. The incorrect order of IInd ionisation energy is (3) Li < B < Be
(1) Cu > Zn (2) Cr > Mn (4) Br– < Cl– <F–
(3) Na>Mg (4) Mg > Al
10. Which of the following case is affected by
lanthanoid contraction according to their given
3. Select the correct order of IInd I.E. of C, N, O, F. properties?
(1) C > N > O > F (2) C < N < O < F (1) Stable oxidation state of thallium is +1 .
(3) C < N < O > F (4) C < N > O < F (2) Atomic radius of Zr ≃ Hf.
(3) Ionisation potential of Tl > In
(4) all of these
4. Successive ionization enthalpies (in eV/atom) of an
element are 5, 8, 9, 90, 100. The number of valence
11. In which of the following, the energy change
electrons are:
corresponds to first ionisation potential?
(1) 1 (2) 2
(1) X(g) → X+(g) +e–
(3) 3 (4) 4
(2) 2X(g) → 2X+(g) + 2e–
5. Which of the following element will have highest (3) X(s) → X+(g) + e–
ionization energy? (4) X(aq) → X+(aq) + e–
(1) H (2) He
12. Out of N, O, Ne, Na and Na+, select the species
(3) Ne (4) F
which have minimum and maximum ionisation
energy respectively.
6. The correct order of second ionisation energy. (1) N, Ne (2) O, Na+
(1) N > O (2) Li > Ne (3) Na, Ne (4) Na, Na+
(3) P > N (4) Br > Cl
13. The first ionisation enthalpies of four consecutive
elements present in the second period of the periodic
7. I and III ionisation energies of an element are 40 and table are 8.3, 11.3, 14.5 and 13.6eV respectively.
60eV/atom respectively. II ionization energy can be Which one of the following is the first ionisation
(1) 51eV/atom (2) 39eV/atom enthalpy of nitrogen?
(3) 65eV/atom (4) 100eV/atom (1) 13.6 (2) 14.5
(3) 11.3 (4) 8.3
8. Which of the following is incorrect statement(s):
(1) Tl3+> Tl+ (Stability order) 14. Stability of ions of Ge, Sn and Pb will be in the
(2) Pb2+ > Pb4+ (Stability order) order:
(3) Fe+ > Fe2+ > Fe3+ (Radius order) (1) Ge2+ > Sn2+ > Pb2+ (2) Ge4+ > Sn4+ > Pb4+
(4) O2– > F– > Na+ (radius order) (3) Sn4+ < Sn2+ (4) Pb2+ < Pb4+
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15. M ⎯⎯ X
→M+ ⎯⎯ 5
→M+2 22. Which of the following represent second ionization
Select the correct statement regarding the value of energy?
‘X’: (1) O ( g ) ⎯⎯
→O2+ ( g ) + 2e−
(1) The value of ‘X’ is equal to ionisation potential
(2) O ( g ) ⎯⎯
→O22+ ( g ) + 2e−
of M.
(2) The value of ‘X’ is equal to magnitude of (3) O+ ( g ) ⎯⎯
→O2+ ( g ) + e−
electron affinity of M+. (4) All of these
(3) Any information about ‘X’ can not |X| = |Y|
(4) Both option (A) and (B) regarding ‘X’ are 23. The element having maximum tendency to form
correct. ionic bonds is
(1) Cs (2) Rb
16. The correct order of ionisation energy among the (3) K (4) Li
following is :
(1) O > S > O– > S– 24. Which of the following has maximum ionisation
(2) O > O– > S > S– energy?
(3) O > S > S– > O– (1) Li+ (2) He
(4) S > O > S– > O– (3) Ne (4) Na

17. Element which has maximum ionisation energy. 25. The strongest reducing agent in gaseous phase is
(1) Li (2) Na
(1) Zn (2) Cu (3) K (4) Cs
(3) Cd (D) Hg
26. M ( g ) ⎯⎯→
IP
M+ ( g ) ⎯⎯
IP
→ M+2 ( g ) ⎯⎯
⎯ x
→ M+3 ( g )
1 2

IP X
18. Element which has minimum first ionisation energy The ratio of 1 =
is- IP2 2
(1) N (2) P Then calculate the value of IP1 and IP2 if
(3) O (D) S M ( g ) ⎯⎯
→M+3 ( g ) , H = 5X

19. Element which has minimum first ionisation energy 8X 4X 8X 4X2

(1) , (2) ,
is- 3+ X 2+ X 2+X 2+X
(1) N (2) P 4X2 8X2 4X 8X
(3) , (4) ,
(3) O (D) S 2+X 2+X 2+ X 3+ X

20. The ionisation energies for B, T and In are X, Y 27. The ionisation potential value for process
and Zkcal/mol respectively, Choose the correct → M(+g )
M( g ) ⎯⎯ is ‘X’. Then choose the correct
relationship between them-
code if ionisation potential value for
(1) Z > X = Y (2) X > Y > Z
(3) X > Y = Z (4) X < Y > Z M(−g ) → M ( g ) process is ‘Y’.
⎯⎯

21. For an element having only one valence shell (1) X = Y (2) X > Y
electron, then which of the following ionisation
energy difference will have the maximum value- (3) X < Y (4) Data Insufficient
(1) IE2 – IE1 (2) IE3 – IE2
(3) IE3 – IE1 (4) can’t predict
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28. Which process can produce maximum number of 34. If ΔegH of A+(g) = –xkJ/mol, ΔegH of A(g) = –
Fe2+ ions from iron atom by absorbing energy from ykJ/mol and Δionisation H– of A+(g) = + zkJ/mol, then
the given species. ΔH for the process : A–(g) → A2+(g), is
Considering equal number of given species. (1) (x + y + z) kJ/mol (2) (z – x – y) kJ/mol
(1) Formation of N– from N-atom. (3) (x + y – z) kJ/mol (4) (x – y + z) kJ/mol
(2) Formation of F– from F-atom.
(3) Formation of Cl– from Cl-atom. 35. Which of the following are correct?
(4) Formation of S– from S-atom.
(I) 1st Ionisation Energy of N > O
29. In which of the following process, maximum (II) 2nd Ionisation Energy of O > N
amount of energy involved. (III) 1 st Electron Affinity of N < O
(1) Cl → Cl– (2) Br– → Br (IV) 1 st Electron Affinity of Be < B
(3) F– → F (4) I → I– (1) I & II (2) I and III
(3) I, II, III (4) All of these
30. Which of the following statement is correct.
(1) The 1st ionisation potential of N is greater than 36. Which of the following would require least energy?
that of O+. (1) Si− ( g ) ⎯⎯
→Si ( g ) + e−
(2) The 1st ionisation potential of N is equal to that
(2) P− ( g ) ⎯⎯
→ P ( g ) + e−
of O+
(3) The 1st ionisation potential of N is less than that (3) Si− ( g ) ⎯⎯
→S( g ) + e−
of O+.
(4) Cl− ( g ) ⎯⎯
→Cl ( g ) + e−
(4) The electron affinity of ‘N’ is greater than that
of ‘O’.
37. Which of the following represents correct order of
31. Choose the correct order of the property given electron affinity?
below: (1) O < S < F < Cl
(1) N3– < O2–: ionic radius (2) O < F < S < Cl
(2) N > O: Ist ionisation energy (3) F > O > Cl > S
(3) N > O : 2nd ionisation energy (4) F > Cl > O > S
(4) N > O : Electron affinity order
38. Which of the following has the lowest electron
32. Calculate the value of electron gain enthalpy affinity?
(ΔegH) at 300 K if electron affinity of Cl is 90Kcal. (1) O (2) S
(1) –91.5 Kcal (2) +88.5 Kcal (3) F (4) Cl
(3) –88.5 Kcal (4) –1590 Kcal
39. The incorrect order of electron affinity is:
33. The electron gain enthalpy (Δeg H) of an element ‘A’ (1) F < Cl (2) N > P
 1 (3) O < S (4) Cl > Br
is  −  times of its ionisation enthalpy (Δi H).
 2
When one mole of A+(g) is completely converted 40. The first ionisation potential of Na is 5.1 eV. The
into A– (g), 900 kJ heat is released. The ΔegH of value of electron gain enthalpy of Na+would be
element ‘A’ is: (1) –2.55eV
(1) –300 kJ/mol (2) –600 kJ/mol (2) –5.1eV
(3) 600 kJ/mol (4) 300 kJ/mol (3) –10.2eV
(4) 2.55eV
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41. The least stable anion is: 49. Which of the following statements is correct?
(1) Li– (2) Be– (1) Ionisation energy of A– is greater than A when
(3) B– (4) C– A is a halogen atom.
(2) Ionisation energy of A+ is greater than that of
42. The increasing order of electron affinity is: A2+ when A is the member of alkali metals.
(1) N < O < Cl < Al (3) Successive ionisation energy is always
(2) O < N < Al < Cl increasing for 1st and 2nd period element.
(3) Al < N < O < Cl (4) Electron affinity value of A++ is numerically
(4) Cl < N < O < Al identical with the ionisation potential of A– [for
any atom].
43. Which is the correct order of ionisation energies?
(1) F– > F > Cl– > Cl 50. Which of the following is exothermic:
(2) F > Cl > Cl > F– (1) N(g) + 1e– → N–(g)
(3) F– > Cl– > Cl > F (2) P(g) + 1e– → P–(g)
(4) F– > G– > F > Cl (3) Na(g) → Na+(g) + 1e–
(4) 1e– + Be(g) → Be–(g)
44. Which of the following statement is correct
regarding following process. 51. In which transition maximum amount of energy will
E.A.
(i) Cl ⎯⎯⎯ →Cl− (ii) Cl− ⎯⎯
I.E.
⎯→Cl be released.
(1) S(g) + 1e– → S– (g)
I.E.
(iii) Cl ⎯⎯ ⎯→Cl+ (iv) Cl+ ⎯⎯
I.E.
⎯→Cl2+
(2) O(g)+1e– → O– (g)
(3) N(g) → N+(g) + 1e–
45. Select incorrect order of E. A.
(4) He(g) + 1e– → He– (g)
(1) Cl > F (2) O < S
(3) N > P (4) C < Si
52. Which of the following is incorrect order of electron
affinity:
46. Select correct relationship for Na atom.
(1) Li < Na
(1) ∣I.E. of Na| < |E.A. of Na∣
(2) Al > B
(2) ∣I.E.of Na| > |I.E. of Na–∣
(3) Si > C
(3) ∣I.E. of Na| > | I.E. of Na+∣ (4) Cl > F
(4) ∣E.A. of Na| = |I.E.of Na+∣
53. Which of the following process is endothermic?
47. The correct order of electron affinity is
(1) Na ( g ) + le− ⎯⎯
→ Na − ( g )
(1) N > P > S > Cl
(2) P > N > S > Cl (2) O+ ( g ) + le− ⎯⎯
→O ( g )
(3) Cl > N > P > S
(4) Cl > S > P > N (3) O− ( g ) + le− ⎯⎯
→O2− ( g )

→S− ( g )
(4) S + le− ⎯⎯
48. Choose the incorrect statement.
(1) 2nd electron gain enthalpy for any element is (+)
ve.
(2) E.A. of an element ∝ Zeff
(3) The ionisation energy order : F– > Cl–
(4) The ionisation energy order : F– < Cl–
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54. Which of the following is incorrect? 59. Which of the following speices has maximum
(1) For A ( g ) + e− ⎯⎯
→ A− ( g ) , H may be tendency to accept electron cloud?
(1) O2– (2) O–1
positive +1
(3) O (4) O+2
(2) For A− ( g ) + e− ⎯⎯
→A2− ( g ) , H may be
negative 60. Select the correct order of electron affinity:

(3) For A− ( g ) + e− ⎯⎯
→A2− ( g ) , H must be (1) F– > Cl– (2) F > Cl
(3) Cl > F (4) F– > F
positive
(4) For A+ ( g ) + e− ⎯⎯
→ A+ ( g ) , H must be 61. The numerical value of energy involved in the given
negative process ;S → S– is less than, which of the following
process:
55. If electron gain enthalpy of X(g) is –4.0eV, then the (1) S– → S (2) Se → Se–
ionisation enthalpy of X(g) at the same temperature (3) S → S+ (4) (2) and (3) both
may be:
(1) 4.0eV (2) 3.5eV 62. Which of the following process is exothermic?
(3) 5.5eV (4) any of these values (1) P → P+ (2) P → P–
(3) P– →P (4) P+ → P+2
56. The correct order of increasing electron affinity of
halogens is : 63. Which is correct order of electron affinity?
(1) Li < Be (2) Be > B
(1) F < Cl < Br < I
(3) Li > B (4) Li > C
(2) I < Br < F < Cl
64. Which element has highest Electron Affinity?
(3) I < Br < Cl < F (1) Be (2) B
(3) Li (4) C
(4) Br < I < F < Cl
65. If the amount of energy required in the process X– to
57. For the process X– is –8 kJ/mole then calculate how many energy is
required in X to X+ process
X ( g ) + e− ⎯⎯
→ X− ( g ) , H = x and (1) –8 kJ/mole (2) >8 kJ/mole
(3) < 8 kJ/mole (4) 8 kJ/mole
X− ( g ) ⎯⎯
→ X ( g ) + e− , H = y
Select correct alternate: 66. Select the atom which has maximum electron
(1) Ionization energy of X– (g) is y affinity –
(2) Electron affinity of X(g) is –X (1) C (2) Si
(3) Electron affinity of X(g) is +y (3) N (4) P
(4) All are correct statements
67. Which of the following process is associated with
58. If the amount of energy required in the process X to the energy release.
X– is –5 kJ/mole then calculate how many energy is →Li+
(1) Li ⎯⎯ (2) O− ⎯⎯
→O2−
required in X to X+ process
(3) Cl+ ⎯⎯
→Cl → Be−
(4) Be ⎯⎯
(1) –5 kJ/mole (2) >5 kJ/mole
(3) < 5 kJ/mole (4) 5 kJ/mole
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68. In which of the following process, maximum 76. Select the correct statement regarding oxides.
amount of energy involved. (1) As the electronegativity of element increase
(1) Cl → Cl– (2) Br–→ Br acidic character of oxide increases.
–
(3) F → F (4) I → I– (2) Down the group the acidic nature of oxide
increase.
69. The most acidic oxide is: (3) B2O3 and Al2O3 are both acidic oxides.
(4) Nitrogen forms all the three types of oxides
(1) SO3 (2) P2O5
(neutral, basic & acidic)
(3) Cl2 O7 (4) P2O3
77. A student went to meet his friend, where he saw that
70. The E.N. of H, X, O are 2.2, 3.0 and 3.5 respectively his friend was doing the study of a particular
comment on the nature of the compound H – O – X, chemistry book. But he could not find the theoretical
that is: value of bond length in H-F but he found that rH & rF
(1) Basic (2) Acidic are 0.37 Å and 0.72 Å respectively &
(3) Amphoteric (4) Can’t be predicted electronegativity of F & H are 4.0 and 2.1
respectively. What is bond length of H–F bond.
(1) 1.09 (2) 1.784
71. Find the incorrect acidic strength order:
(3) 0.92 (4) 0.46
(1) K2 O > Rb2 O > Cs2 O
(2) N2 O < NO2 < N2 O3
78. Calculate the electronegativity of Cl in Pauling scale
(3) Li2 O < BeO < N2 O5
[Given: E.A. (Cl) = 4.0 eV/atom and I.E. (Cl) = 13.0
(4) Cl2 O7 > P2 O 5 > SiO2 eV/atom]
(1) 2 (2) 3.03
72. The correct order of electronegativity of C in C2 H2, (3) 3.5 (4) 4.0
C2 H4 and C2 H6 is
(1) C2H2 > C2 H6 > C2H4 79. Which of the following is strongest in basic
(2) C2H2>C2H4 > C2H6 character?
(3) C2H6 > C2H4 > C2H2 (1) Be(OH)2 (2) Mg(OH)2
(4) C2H4 > C2H2 > C2H6 (3) Al(OH)3 (4) Si(OH)4

73. Ionisation energy and electron affinity of fluorine are 80. For an inert gas element the atomic number is z, then
respectively 17.42 eV and 3.45 eV, then which of the following element having atomic
electronegativity of F atom on Pauling scale will be number ‘_____’ is having highest electronegativity.
(1) 10.44 (2) 4.0 (1) z – 2 (2) z – 1
(3) 3.72 (4) None of these (3) z + 1 (4) z + 2

81. The electronegativity of ‘N’ is maximum in which

74. Which of the following order is wrong.
of the following compound of N.
(1) NH3 <PH3 < AsH3 – Acidic
(1) N2O (2) N2O3
(2) Li < Be < B < C - (IE) 1
(3) NO (4) N2O4
(3) Al2 O3 < MgO < Na2 O < K2 O – Basic
(4) Li+(g) < Na+(g) < K+(g) < Cs+(g) – Ionic radius
82. Which of the following acidic order is correct.
(1) HI > HCl > HBr > HF
75. Comment on the electronegativity (EN) of As in (2) HI < HCl < HBr < HF
AsF3 and AsF5. (3) HOCl > HOBr > HOI
(1) E.N. of As (AsF3) > E.N. of As (AsF5) (4) HOCl < HOBr < HOI
(2) E.N. of As (AsF3) < E.N. of As (AsF5)
(3) E.N. of As is identical in both cases
(4) No comment can be predicted.
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83. The correct order of Electronegativity is: 89. The correct order of acidic strength of these hydra
(1) F > O > N (2) N > O > F acids is :
(3) O > N > F (4) N = O > F (1) HCl < HBr < HI < HF
(2) CH4 < SiH4 < GeH4
84. Which of the following statement is incorrect? (3) NH3 < CH4 < H2 O < HF
(1) Order of acidic strength N2 O < N2O3 < NO2. (4) HBr < H2S < NH3
(2) Electron Affinity of O is more than that of Cl.
(3) Percent ionic character of As – H bond is less 90. Which of the following is the most electropositive?
than that of Sb – H bond. (1) Li (2) Na
(4) A ‘sp’ hybridised carbon is more (3) K (4) Cs
Electronegative than a sp2 hybridised carbon.
91. The most electronegative element is
85. An element X has electronegativity of 3.0 on Pauling (1) O (2) F
scale. Which of the statements is correct? (3) Cl (4) N
(1) The ionisation energy (IE) of X > 8.4eV/atom
92. Which of the following relations is correct? (E.N, is
(2) The electron affinity (EA) of X > 8.4eV/atom on Mulliken scale)
(3) Both IE and EA > 8.4eV/atom. (1) 2 I.P. – E.A. - E.N. = 0
(4) Both IE and EA < 8.4eV/atm. (2) 2 I.P. – E.N. + E.A. = 0
(3) 2 E.N. – I.P. – E.A. = 0
86. The bond energies of A – A, B – B and A – B bonds (4) E.N. – I.P. – E.A. = 0
are 81,100 and 115kcal/mol, respectively. If the
electronegativity of B is 3.0 and B is more 93. Calculate the percentage ionic character for
electronegative than A, then from Pauling's Scale, molecule AB, if electronegativity difference
the electronegativity of A is: between AB molecule is 1.5.
(1) 4.04 (2) 1.96 (1) 20.8 (2) 10.2
(3) 2.96 (4) 2.04 (3) 31.8 (4) None of these

87. The bond lengths of A – A and B – B bonds are 1.6

94. Ionisation energy and electron affinity of fluorine
and 2.0 Å, respectively. If the electronegativities of
are respectively 18.42 eV and 2.45 eV, then
A and B are 2.8 and 2.1, respectively, the according
to Schomaker and Stevenson's Equation, the bond electronegativity of F atom on Pauling scale will be
length of A – B bond should be: (1) 3.72 (2) 4.0
(1) 3.537 Å (3) 10.44 (4) None of these
(2) 2.97 Å
(3) 1.737 Å 95. Which of the following has maximum difference in
(4) 1.17 Å bond length if the electronegativity difference is
considered and not considered?
88. If X – Y bond is 30% ionic in character, then (1) HCl (2) HF
according to Hanny and Smyth Equation, the (3) HI (4) HBr
electronegativity difference between X and Y is:
11
(1) 1.0 (2) 96. Which of the following is amphoteric in nature?
7
(1) HClO4 (2) NaOH
10 9
(3) (4) (3) Zn(OH)2 (4) N2O
7 7
 8

97. Which of the following is the most acidic in nature? 103. Which is incorrect order of acidic strength?
(1) SiO2 (2) P4O10 (1) N2O < NO < N2 O3 < NO2
(3) CO2 (4) SO3 (2) SO2 < SO3
(3) HOCl < HClO2 < HClO3 < HClO4
98. The correct order of basic nature of given oxides is (4) CO2 < B2O3 < BeO <Li2O
(1) V2O3 < V2 O5 < V2 O4
(2) V2 O3 < V2 O4 < V2O5 104. Which of the following is correct?
(3) V2O5 < V2 O4 < V2 O3 (1) Pauling scale is based on bond energy data.
(4) V2O5 < V2O3 < V2O4 (2) Muliken scale is based on IE and EA data
(3) Allred Roschow is based on electrostatic
99. Following is the graph representating attraction.
Electronegativity of certain elements A1, A2, A3, A4, (4) All are correct
A5. Which of the following option(s) representing
corresponding elements can be correct? 105. The order in which the following oxides are
arranged according to decreasing basic nature is-
(1) CuO, Na2 O, MgO, Al2 O3
Electronegativity

(2) Al2O3, MgO, CuO, Na2 O

(3) MgO, Al2 O3, CuO, Na2 O
(4) Na2O, MgO, Al2O3, CuO

106. Identify the oxidation state of unknown element ‘M’

in following structure Electronegativity of H <
A1 A2 A3 A4 A5 Oxygen atom but M > Hydrogen atom
(1) A1 = N, A2 = P, A3 = F, A4 = Cl, A5 = Al
H
(2) A1 = Cl, A2 = P, A3 = O, A4 = N, A5 = Al
(3) A1 = N, A2 = P, A3 = O, A4 = Si, A5 = Al O
(4) None
M
O H
100. Identify incorrect order of acidic strength:
(1) N2O < NO < N2 O3 < N2O5 O
H
(2) CaO < CO < CO2
(1) +5 (2) + 6
(3) H2O < Na2 O < MgO
(3) +3 (4) +4
(4) H2SO3 < H2SO4
107. On Muliken scale if electronegativity of particular
101. Find % covalent character of NO [Given:
atom ‘X’ is ‘P’ and electron affinity of atom ‘X’ is Q
Electronegativity of N = 3 and O = 3.5]
eV then identify the approximate value of
(1) 8.875% (2) 91.125%
electronegativity of ‘X’ on Pauling scale-
(3) 20.2% (4) 60.8%
2P − Q
(1) (2) P  2.8
2.8
102. Two elements A and B are such that Bond energy of
P
A-A, B-B & A-B are respectively 81kcal/mol, (3) (3) (2P–Q)  2.8
64kcal/mol and 88kcal/mol. If electronegativity of 𝐵 2.8
is 3 then electronegativity of A may be
(1) 1.9 (2) 2.168 108. Select the neutral oxide in following –
(3) 3.832 (4) 4.2 (1) CO2 (2) CO
(3) P4O10 (4) NO2
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109. What will be the C–X bond length if C–C bond x F

length is 1.54 Å, X–X bond length is 1.00 Å and
4
electronegativity values of C and X are 2.0 and 3.0 3 Cl
respectively. (4) 2
(1) 2.45 Å (2) 1.18 Å
(3) 2.54 Å (4) 1.81 Å q

110. Which is amphoteric in nature. 113. Which of the following oxide is basic in nature?
(1) ZnO (2) Be(OH)2 (1) B(OH)3 (2) I(OH)
(3) PbO2 (4) All of these (3) Cl(OH) (4) Cs(OH)

114. Which of the following nitrogen oxide is neutral?

111. Electronegativity of H-atom is 2.1 and F-atom is 4.1,
(1) NO2 (2) N2O5
find % ionic character of HF.
(3) N2O (4) N2O3
(1) 26% (2) 32%
(3) 46% (4) 62%
115. Which of the following compound has maximum
acidic character?
112. On study it is seen that the electronegativity of the (1) CO2 (2) SiO2
atom linearly increases with the partial ionic charge
(3) NH3 (4) H2O
(q). Thus electronegativity can be written as, x = a +
bq, where large and soft atoms have low value of b,
116. Calculate the bond length of P – Q molecule if
while small and hard atoms have a large value of b,
internuclear distance of P2 is X and internuclear
and a is constant, then which of the following given
3X
plot describes the electronegativity variation of F and distance of Q2 is and electronegative difference
Cl accurately? 2
X
of P and Q elements is .
[Given : XF =4, XCl = 3 and XH = 2] 2
3X
x (1) (2) 1.20 X
F 2
4 (3) 0.50 X (4) 0.20 X
3 Cl
(1) 2
117. Least stable hydride is
(1) stannane (2) Silane
q
(3) Plumbane (4) Germane
x Cl
118. Calculate the % ionic character for metal fluoride
4 where the electronegativity of electropositive
3 F
(2) 2 element is 2.1
(1) 43.03% (2) 56.8%
q (3) 50% (4) 12%
x F
119. Select the gas-phase reaction(s) which can proceed
4 Cl spontaneously?
3
(3) 2 (1) Cl− + I ⎯⎯
→I− + Cl
(2) Cl+ + Cl ⎯⎯ →Si + Cl+
q
(3) Both (1) & (2)
(4) Kr + He+ ⎯⎯
→Kr+ + He
 10

120. Comment on the electronegativity (E.N.) of P in PF3 128. Which of the following is incorrect order of the
and PF5. mentioned property in increasing order?
(1) Electronegativity of P(PF3) > Electronegativity (1) First ionization potential : Na < Al < Mg < Si
of P(PF5) (2) Ionization energy : Be+ < C+ < B+ < N+ < F+ <
O+ < Li+
(2) Electronegativity of P(PF3) < Electronegativity (3) Hydrated radius order : Ba2+(aq) < Sr2+(aq) <
of P(PF5) Mg2+(aq)
(3) Electronegativity of P is identical in both cases (4) Polarity order : N – H < Sb – H < As –H < P –
(4) No comment can be predicted H

121. The amphoteric oxide among the following is: 129. The correct order of increasing hydration energy of
following ion is
(1) Na2 O (2) ZnO
(1) Fe+2 < Co+2 < Fe+3
(3) SO2 (4) B2O3 (2) Fe+2 < Co+2 > Fe+3
(3) Fe+2 > Co+2 > Fe+3
(4) Fe+2 < Fe+3 < Co+2
122. The correct order of acidic nature of the oxides of
chlorine is :
130. Select the correct radius order:
(1) Cl2O < ClO2 < Cl2O6 < Cl2 O7
(1) Li+(aq) < Na+(aq) < K+(aq)
(2) ClO2 < Cl2 O < Cl2 O6 < Cl2O7
(2) Li+(g) < Be2+(g)
(3) Cl2O < ClO2 < Cl2 O7 < Cl2O6
(3) Na(g) < Mg(g) < Al(g)
(4) Cl2O7 < Cl2O6 < ClO2 < Cl2O
(4) Li+(g) > Al3+(g)
123. Which one of the following is most acidic?
131. Choose the correct statement:
(1) SO3 (2) Cl2O7
(3) P2O5 (4) SiO2 (1) Na +( g )  Mg2( g )  Al3+( g ) ( Hydration energy)
124. Calculate the % ionic character of molecule AB (2) Li+( aq )  Na +( aq )  K+( aq ) ( Ionic Mobility )
where the electronegative atom A is 3 and B is 2.1?
(1) 17.2% (2) 19%
(3) F−( aq )  Cl−( aq )  Br −( aq ) ( Hydrated radius )
(3) 34% (4) 50% (4) CaF2  CaO ( Lattice energy )
125. Which of following oxides is amphoteric in nature?
132. Which of the following ions attach the least number
(i) ZnO (ii) N2O
of water molecules to itself when dissolved in
(iii) Cl2 O7 (iv) BeO
water?
(1) (i), (iv) (2) (i), (ii)
(1) Mg2+
(3) (iii) & (ii) (4) (i), (iv), (ii)
(2) Li+
(3) [(CH3)4N]+
126. Choose the correct ionic mobility order in water.
(1) Be2+ > Ba2+ (2) Li+ > Rb+ (4) NH+4
(3) I– < Cl (4) Na+ > Mg2+ > Al3+ 133. The ion having highest mobility in aqueous solution
is :
(1) Be2+
127. The compound having least lattice energy is (2) Mg2+
(1) BeO (2) BaO (3) Ca2+
(3) BeS (4) BaS (4) Ba2+
 11

134. Which of the following property increases down the (2) Mg2+ ( aq )  Sr 2+ ( aq )  Ba 2+ ( aq ) : Hydrated radius order
group in a aqueous solution? (3) Mg2+ ( aq )  Sr2+ ( aq )  Ba 2+ ( aq ) : Ionic mobility order
(1) Hydration energy
(4) NaF  MgO  SrO: Lattice energy order
(2) Ionic mobility
(3) Ionic size
(4) All of these 138. Which one of the following is correct sequence
followed by molar ionic conductance of the ions in
135. Given aqueous solution.
Reaction Energy Change (in kJ) (1) Li+ < Na+ < K+ < Rb+
Li(s) → Li(g) 161 (2) Rb+ < K+ < Na+ < Li+
Li(g) → Li+(g) 520 (3) Sr2+ < Ca2+ < Mg2+ < Be2+
1 77 (4) Na+ < K+ < Li+ < Rb+
F2 ( g ) → F ( g )
2
F(g) + e– → F–(g) (Electron gain enthalpy) 139. Choose the correct statement
Li+(g) + F–(g) → LiF(s) –1047 (1) Ionic mobility Al3+ is greater than Mg2+ in water
1 –617 (2) K+(aq) is having lesser ionic mobility than Ca2+
Li ( s ) + F2 ( g ) → LiF ( s ) (aq)
2
(3) Cl–(aq) is having highest ionic mobility among
Based on data provided, the value of electron gain halide (aq) ions
enthalpy of fluorine would be : (4) Ionic mobility of Cs+(aq) is the highest among
(1) –300 kJ mol–1 (2) –228 kJ mol–1 the alkali metal ions
–1
(3) –328 kJ mol (4) –350 kJ mol–1
140. The incorrect hydrated radius order is :
136. Identify the correct order of conductivity in an (1) Li+(aq) < Be2+(aq)
aqueous solution. (2) Na+(aq) < Al3+(aq)
[Where M is the d-block metal] (3) I–(aq) > Cl–(aq)
+2 +4 (4) Ba2+(aq) < Ca2+(aq)
(1) M ( H2O)x   M ( H2O)y 
 
+2 +4 141. The correct order of the lattice energy of the
(2) M ( H2O)x   M ( H2O)y 
  following hypothetical ionic compounds AB, A2
+2 +4 B&A2B3 where in all compounds B is in –2
(3) M ( H2O)x  = M ( H2O)y 
  oxidation state & A has variable oxidation state.
(4) we can not predict (1) A2B > AB > A2B3
(2) A2B3 > AB > A2B
137. Choose the correct order of the following: (3) AB > A2B > A2B3
(1) Na + ( g )  Mg2+ ( g )  Al3+ ( g ) : Hydration energy (4) A2B3 > A2B > AB
 12

Answer Key
1. (1) 30. (3) 59. (4) 88. (3) 117. (3)
2. (4) 31. (2) 60. (3) 89. (2) 118. (1)
3. (3) 32. (1) 61. (2) 90. (4) 119. (4)
4. (3) 33. (1) 62. (3) 91. (2) 120. (2)
5. (2) 34. (1) 63. (3) 92. (3) 121. (2)
6. (2) 35. (4) 64. (4) 93. (3) 122. (1)
7. (1) 36. (2) 65. (2) 94. (1) 123. (2)
8. (1) 37. (1) 66. (2) 95. (2) 124. (1)
9. (4) 38. (1) 67. (3) 96. (3) 125. (1)
10. (4) 39. (2) 68. (1) 97. (4) 126. (4)
11. (1) 40. (2) 69. (3) 98. (3) 127. (4)
12. (4) 41. (2) 70. (2) 99. (3) 128. (4)
13. (2) 42. (3) 71. (2) 100. (3) 129. (1)
14. (2) 43. (2) 72. (2) 101. (2) 130. (4)
15. (4) 44. (1) 73. (3) 102. (2, 3) 131. (2)
16. (3) 45. (3) 74. (2) 103. (4) 132. (3)
17. (4) 46. (2) 75. (2) 104. (4) 133. (4)
18. (4) 47. (4) 76. (1) 105. (4) 134. (2)
19. (1) 48. (3) 77. (3) 106. (3) 135. (3)
20. (2) 49. (3) 78. (2) 107 (3) 136. (1)
21. (3) 50. (2) 79. (2) 108. (2) 137. (2)
22. (3) 51. (1) 80. (2) 109. (2) 138. (1)
23. (1) 52. (1) 81. (4) 110. (4) 139. (4)
24. (1) 53. (3) 82. (3) 111. (3) 140. (3)
25. (4) 54. (2) 83. (1) 112. (4) 141. (2)
26. (3) 55. (3) 84. (2) 113. (4)
27. (2) 56. (2) 85. (1) 114. (3)
28. (3) 57. (4) 86. (2) 115. (1)
29. (1) 58. (2) 87. (3) 116. (2)

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