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    Haloalkanes and Haloarenes: HI Ki/H Po

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    Abhiraj Chauhan

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    © All Rights Reserved
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    Haloalkanes and Haloarenes: HI Ki/H Po

    Uploaded by

    Abhiraj Chauhan
    6 views3 pages

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    8f21bb3d-47af-4fea-80cb-8f8340d6543e.pdf

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    Copyright:

    © All Rights Reserved
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    6 views3 pages

    Haloalkanes and Haloarenes: HI Ki/H Po

    Uploaded by

    Abhiraj Chauhan

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 3

    CHAPTER

    6 Haloalkanes and Haloarenes

    PCl5 NaBr+H2SO4
    H3C–CH2—OH H3C–CH2—OH

    PCl3 HI
    3H3C–CH2—OH H3C–CH2—OH
    KI/H3PO4
    Red P + Br2
    3H3C–CH2—OH Cl2/hv
    CH3–CH3
    PREPARATION

    SOCl2
    H3C–CH2—OH
    CH 3–CH 2–X HBr
    CH2=CH2
    H3C–CH2—OH SOCl2 (X=F,Cl,Br,I) CCl4
    (SN2)

    N
    H3C–CH2–COAg Br2 NaI H3C–CH2—Cl
    O
    (Hunsdiecker Reaction)
    CCl4 Acetone (Finkelstein Reaction)

    HCl/ZnCl2 AgF or Hg2F2 H3C–CH2—Cl


    H3C–CH2—OH (Swart reaction)
    Lucas Reagent

    NBS
    H3C–CH=CH2 BrH2C–CH=CH2
    (allylic substitution) CCl4

    CH3–CH2–CH2–Br
    or

    PHYSCIAL PROPERTIES
    (1) Dipole moment: CH3–Cl > CH3–F > CH3–Br > CH3–I
    (2) Bond enthalpies: CH3–F > CH3–Cl > CH3–Br > CH3–I
    (3) Boiling point: R–I > R–Br > R–Cl > R–F

    > >
    Br
    Br Br

    (4) Density: n–C3H7Cl < n–C3H7Br < n–C3H7I

    (5) Solubility → slightly soluble in water

    +
    CHO
    , KOH

    14 JEE (XII) Module-2 PW


    Wurtz-Fitting Reaction

    (A) Reactivity toward Nucleophile (B) Boiling point


    F Cl Br I
    F Cl Br I
    (i) > > >
    (i) > > >
    Cl Cl Cl
    NO2 NO2 NO2 NO2 Cl
    (ii) > >
    Cl
    Cl Cl Cl Cl
    NO2 NO2 O2N NO2 (C) Melting point
    (ii) > > Cl Cl Cl
    Cl
    NO2 NO2 (i) > >
    Cl
    Cl

    P
    W Haloalkanes and Haloarenes 15

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