JEE (Main + Advanced) 2025

NURTURE COURSE

INORGANIC CHEMISTRY QUIZ # 13 TIME : 30 Min.

SECTION–I : (i) Only One option correct Type

This section contains 9 multiple choice questions. Each question has four choices (A), (B), (C) and
(D) out of which ONLY ONE is correct. 3(–1)
1. Which of the following bond angle order is INCORRECT :-
(A) O(CH3)2 < O(C2H5)2 (B) H2O < O(Me)2
(C) H2O < OCl2 (D) NH3 < NF3
2. Select the pair given below which have maximum difference of bond angle :-
(A) NH3, CCl4 (B) BCl3, XeO4 (C) NH4Å, CO2 (D) SO2, SO3
3. The maximum number of 90° bond angles are present in :-
(A) PCl4Å (B) PCl6 (C) PCl5 (D) XeF2
4. Give the CORRECT order for adjacent bond angle of BrF 5 , XeF4 , XeF2 , SO 3
(A) XeF4 > BrF5 > XeF2 > SO3 (B) XeF2 > SO3 > XeF4 > BrF5
(C) BrF5 > SO3 > XeF2 > XeF4 (D) XeF2 > SO3 > BrF5 > XeF4
5. What are the number of lone pair-bond pair repulsion at 90° in I(CN)2– :-
(A) 2 (B) 3 (C) 6 (D) 4
6. Which of the following molecule is non-linear :-
(A) (CN)2 (B) C3O2 (C) NO2– (D) NO2+
7. In ClF 3 Total number of lone pair -bond pair repulsions on central atom at 90° are (With
out consideration of distortion):-
(A) 6 (B) 4 (C) 8 (D) 3
8. Select the CORRECT order of bond angle :-
(A) SF2 > OF2 (B) PBr3 > PI3 (C) CCl4 > CBr4 (D) OBr2 > OCl2
9. Which of the following pair of moleucle the p bond nature is only pp–pp :-
(A) XeO3 , XeO4 (B) SO2 , SO3 (C) POCl3 , SO2Cl2 (D) CO2 , CS2
SECTION–I : (ii) One or more options correct Type
This section contains SIX multiple choice questions. Each question has four choices (A), (B), (C) and
(D) out of which ONE or MORE are correct. 4(–1)

10. Which of the following order is/are correct.

(A) O2SF2 < O2SCl2 (X – Ŝ –X bond angle)

(B) O2SF2 > O2SCl2 (O– Ŝ –O bond angle)

(C) O2SF2 < O2SCl2 (Total number of lone pair)
(D) O2SF2 > O2SCl2 (S–X bond length)
11. Option showing correct order of bond angles is/are (M = central atom, X = Surrounding atom)

(A) PCl4+ < PBr4+ < PI4+ (X – M̂ –X) (B) XeO4 = SiCl4 = SO4–2 (X – M̂ –X)
+ –
(C) NH4 < NH3 < NH2 (X– M̂ –X) (D) NH3 > PH3 > AsH3 (X– M̂ –X)

1/1 INORGANIC CHEM. / QUIZ # 13

 JEE (MAin + Advanced) 2025
NURTURE COURSE
12. Which of the given order of bond angle is/are CORRECT ?
(A) OF2 > OCl2 > OBr2 (B) CH3Å > CH4 > CH3
(C) NO2Å > NO3 > NO2 (D) NH2 > NH3 > NH4Å
13. In which of the following presence of double bonds on central atom (M) does NOT affect
F–M–F idealized bond angle as per hybridization :-
(A) IOF5 (B) XeO2F4 (C) XeO3F2 (D) SO2F2
14. Select the CORRECT order of bond angle in :-
(A) PH3 < AsH3 (B) CH4 > H2O (C) CH4 > CCl4 (D) CCl4 < BF3
15. Select in which all the F–M–F bond angles are identical :-
(A) NF4+ (B) XeF5+ (C) PF 5 (D) CF3+
SECTION–I : (iii) Paragraph Type
This section contains 1 paragraph each describing theory, experiment, data etc. TWO questions relate
to two paragraphs with two questions on each paragraph. Each question of a paragraph has only one
correct answer among the four choices (A), (B), (C) and (D). 3(0)
Paragraph
Hybridisation theory' used to predict the exact geometry of the molecule after finding the
number of bond pairs and lone pair of electrons.
Lone pair electrons in molecule occupy more space as compared to bond pairs of electrons.
The geometry of molecule or electrons are in such a way to minimized electronic repulsions.
16. CORRECT shape and example of the ABn type molecule is (A = Central atom. B = Surrounding atom)
(A) Pentagonal bipyramidal. PCl5 (B) Trigonal planar. BCl3
(C) Square bipyramidal. IF7 (D) Tetrahedral. SF6
17. Types of d-orbitals which may participate in sp3d3 hybridisation are :-
(A) dxy, dyz ,dxz (B) dx2–y2 , dxz ,dyz (C) dx2–y2 , dz2 ,dxy (D) dz2, dyz ,dxz
(iv) Matching List Type
This Section contains One multiple choice questions. Each question has matching lists. The codes
for the lists. have choices (A), (B), (C) and (D) out of which ONLY ONE is correct. 4(0)
18. Select CORRECT code for p-bond in given molecule :-
Column-I Column-II
(Molecule) (If one atom use it's 'np' orbital for p bond formation
then type of orbital used for p bond formation by other atom)
(P) SOF4 (1) np
(Q) CS 3
2–
(2) (n + 1) p
(R) CO (3) (n + 1) d
(S) BrO3– (4) (n + 2) d
Code: (P) (Q) (R) (S)
(A) 2 3 1 4
(B) 3 4 1 2
(C) 3 2 1 4
(D) 4 2 1 3

2 /3 INORGANIC CHEM. / QUIZ # 13

 JEE (MAin + Advanced) 2025
NURTURE COURSE
SECTION–II MATRIX MATCH
Marking scheme :
For each entry in Column-I
+2 If only the bubble(s) corresponding to all the correct matche(es) is (are) darkened
0 In none of the bubbles is darkened
–1 In all other cases
1. Match the column
Column I Column II
(Molecules/ions) (Properties)
(A) ICl4 (P) dz2 orbital is involved in hybridisation of central atom
(B) OClF3 (Q) Maximum number of atoms in a plane = 5
(C) POCl3 (R) The axial (M-X) bond length is shorter than the equitorial (M-X)
bond length
(D) IF7 (S) It has atleast one angle less than 120°
(T) It has two lone pair on central atom
SECTION-IV : (Integer Value Correct Type)
This section contains 5 questions. The answer to each question is a single digit Integer, ranging from
0 to 9 (both inclusive) 4(–1)
1. Which of the following chemical species having bond angle greater than the bond angle
of Cl– Ô –Cl angle in OCl2 :
OBr2 , OF2 , H2O , BCl3 , NF3
2. Considering VSEPR and find number of molecule(s) in which two “O” atoms are opposite to
each other at central atom :-
O3, CO2, SO2Cl2, XeO3F2, XeO2F4, XeO4
3. Find the maximum number of atom in one plane in given species CF2(CF3)2
4. Find the number of species which do not exist in ordinary condition :
NH4+ , SF6 , OF4 , S2 , P2 , SiO2 , BeCl4–2 , NCl5 , AlF6–3 , CF6–2
5. Find the number of specie which have maximum four atoms lying in the same plane.
PCl2F3 , AlBr3 , ICl4– , BrF3 , PI4+ , H3O+ , NO3–

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