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Assignment 4 Question

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Arghya Shakharu
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Assignment 4 Question

Uploaded by

Arghya Shakharu
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© © All Rights Reserved
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fiziks

Institute for NET/JRF, GATE, IIT-JAM, M.Sc. Entrance, JEST, TIFR and GRE in Physics

Assignment-4
(Thermodynamical Potential)
1  V  1  V 
Q1. If     ,   then prove that for an ideal gas prove that
V  T  P V  P T

(a) dU   CP   PV  dT  V   P  T  dP

(b) dH  CP dT  V 1  T  dP

(c) dF    PV   S  dT  PV  dP

Q2. The Helmholtz free energy of a system given by, F  A  BT 1  ln T   CT ln V where

A , B , C are constant. Obtain expression for pressure, entropy, internal energy, enthalpy
and gibbs energy?
Q3. The specific Gibbs energy of an ideal gas is given as-
P
G  RT ln    BP
 P0 
where B is a function of T only obtain the equation of state of gas?
Q4. Prove that for n -moles of an ideal gas
CV
(a) F  n  CV dT  T  dT  nRT ln V  a1T  a2
T
CP
(b) G  n  CP dT  T  dT  nRT ln P  b1T  b2
T
where a1 , a2 , b1 and b2 are constant parameter.
Q5. The equation of state of a gas is given by
RT b
V  
P T
where R is the gas constant and b is another constant parameter. Show that the specific
heat at constant pressure C P and the specific heat at constant volume CV for this gas is
2
 bP 
related by CP  CV  R 1  2 
 RT 

H.No. 40-D, Ground Floor, Jia Sarai, Near IIT, Hauz Khas, New Delhi-110016
Phone: 011-26865455/+91-9871145498
Website: www.physicsbyfiziks.com | Email: [email protected]
Revised Edition 2019 1
fiziks
Institute for NET/JRF, GATE, IIT-JAM, M.Sc. Entrance, JEST, TIFR and GRE in Physics

RT
Q6. If equation of state is given P 
b
V
T
 U 
(a) Find the  
 V T
(b) If volume is expanded from V1 to V2 at very high temperature then what will be

change in internal energy?


Q7. Helmholtz free energy is given by VT 4 where   0 .
(a) Find the value of internal energy
(b) For the adiabatic process prove that VT 3  K , where K is constant parameter.
Q8. The entropy function of a system is given by S E   aEE0  E  where a and E0 are

positive constants.
(a) For what is condition that energy E temperature is negative .
(b) Plot temperature with energy of the system .
Q9. For a particular thermodynamic system the entropy S is related to the internal energy U
and volume V by
S  cU 3 / 4V 1 / 4
where c is a constant. Find the Gibbs energy of the system ,
Q10. Calculate the Variation of C P with pressure at constant temperature for a substance

RT C
whose equation of state is given by relation V   .
P T3

H.No. 40-D, Ground Floor, Jia Sarai, Near IIT, Hauz Khas, New Delhi-110016
Phone: 011-26865455/+91-9871145498
Website: www.physicsbyfiziks.com | Email: [email protected]
Revised Edition 2019 2

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