Safety Data Sheet

Videojet®
V489-C
Page : 1 / 10
Version : GHS (US) ENGLISH
Version number : 4.04
Date of issue/ Date of revision : 12/6/2023
Date of previous issue : 8/11/2023 (4.03)

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Product name : V489-C
CAS number : Not applicable.

1.2 Relevant identified uses of the substance or mixture and uses advised against
Material uses : Industrial applications: Ink for use in a continuous ink jet process.

1.3 Details of the supplier of the safety data sheet

Website: www.videojet.com
Email: [email protected]

Videojet Technologies Inc., 1500 Mittel Boulevard, Wood Dale, IL, 60191-1073 U.S.A
Tel: 1-800-843-3610 Fax: 1-800-582-1343

1.4 Emergency telephone number

Medical 3E: (US) +1 866 519 4752
3E Code: 334466
Transporters CHEMTREC: (US) +1 800 424 9300
CHEMTREC Code: CCN 23846
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
GHS Classification
1) FLAMMABLE LIQUIDS - Category 2 Highly flammable liquid and vapor.
2) SERIOUS EYE DAMAGE - Category 1 Causes serious eye damage.
3) SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) May cause drowsiness or dizziness.
(Narcotic effects) - Category 3

Ingredients of unknown : Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 0%.
toxicity
Ingredients of unknown : Percentage of the mixture consisting of ingredient(s) of unknown hazards to the
ecotoxicity aquatic environment: 7.9%

2.2 Label elements

GHS label elements

Danger. Highly flammable liquid and vapor. Causes serious eye damage. Causes mild skin irritation. May cause
drowsiness or dizziness. Wear eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or physician.
Hazardous ingredients : 1) butanone
2) cyclohexanone
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2.3 Other hazards

Other hazards which do : None known.
not result in classification
Additional guidance : Avoid breathing vapor. IF INHALED: Call a POISON CENTER or physician if you
feel unwell. Keep container tightly closed. Store in a well-ventilated place.

SECTION 3: Composition/information on ingredients

Substance/mixture : Mixture
Product/ingredient name CAS # % GHS Classification
1) butanone 78-93-3 75 - <85 FLAMMABLE LIQUIDS - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3
2) cyclohexanone 108-94-1 2 - <5 FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (oral) - Category 4
ACUTE TOXICITY (dermal) - Category 4
ACUTE TOXICITY (inhalation) - Category 4
SKIN IRRITATION - Category 2
SERIOUS EYE DAMAGE - Category 1

Occupational exposure limits, if available, are listed in Section 8.

SECTION 4: First aid measures

4.1 Description of first aid measures
Eye contact : Get medical attention immediately. Call a poison center or physician. Immediately
flush eyes with plenty of water, occasionally lifting the upper and lower eyelids.
Check for and remove any contact lenses. Continue to rinse for at least 10 minutes.
Chemical burns must be treated promptly by a physician.
Inhalation : Get medical attention immediately. Call a poison center or physician. Remove
victim to fresh air and keep at rest in a position comfortable for breathing. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
It may be dangerous to the person providing aid to give mouth-to-mouth
resuscitation. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie,
belt or waistband. In case of inhalation of decomposition products in a fire,
symptoms may be delayed. The exposed person may need to be kept under
medical surveillance for 48 hours.
Skin contact : Get medical attention immediately. Call a poison center or physician. Flush
contaminated skin with plenty of water. Remove contaminated clothing and shoes.
Wash contaminated clothing thoroughly with water before removing it, or wear
gloves. Continue to rinse for at least 10 minutes. Chemical burns must be treated
promptly by a physician. Wash clothing before reuse. Clean shoes thoroughly
before reuse.
Ingestion : Get medical attention immediately. Call a poison center or physician. Wash out
mouth with water. Remove dentures if any. If material has been swallowed and the
exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Chemical burns must be treated
promptly by a physician. Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or
waistband.

4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness.
Skin contact : No known significant effects or critical hazards.
Ingestion : Can cause central nervous system (CNS) depression.
Over-exposure signs/symptoms
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Eye contact : Adverse symptoms may include the following:

pain
watering
redness
Inhalation : Adverse symptoms may include the following:
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
Ingestion : Adverse symptoms may include the following:
stomach pains

4.3 Indication of any immediate medical attention and special treatment needed
Treat symptomatically. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The
exposed person may need to be kept under medical surveillance for 48 hours.

SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable extinguishing : Use dry chemical, CO₂, water spray (fog) or foam.
media
Unsuitable extinguishing : Do not use water jet.
media

5.2 Special hazards arising from the substance or mixture

Hazards from the : Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion
substance or mixture hazard. In a fire or if heated, a pressure increase will occur and the container may
burst, with the risk of a subsequent explosion.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
nitrogen oxides
halogenated compounds

5.3 Advice for firefighters

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without
suitable training. Move containers from fire area if this can be done without risk.
Use water spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate.
Put on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".
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6.2 Environmental precautions

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant
authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

6.3 Methods and materials for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble.
Alternatively, or if water-insoluble, absorb with an inert dry material and place in an
appropriate waste disposal container. Dispose of via a licensed waste disposal
contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Wash spillages into an
effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth
and place in container for disposal according to local regulations (see Section 13).
Dispose of via a licensed waste disposal contractor. Contaminated absorbent
material may pose the same hazard as the spilled product. Note: see Section 1 for
emergency contact information and Section 13 for waste disposal.

6.4 Reference to other sections

See Section 8 for information on appropriate personal protective equipment. See Section 13 for additional waste
treatment information.

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not get in
eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only
with adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Do not enter storage areas and confined spaces unless adequately
ventilated. Keep in the original container or an approved alternative made from a
compatible material, kept tightly closed when not in use. Store and use away from
heat, sparks, open flame or any other ignition source. Use explosion-proof electrical
(ventilating, lighting and material handling) equipment. Use only non-sparking tools.
Take precautionary measures against electrostatic discharges. Empty containers
retain product residue and can be hazardous. Do not reuse container.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8 for additional
information on hygiene measures.

7.2 Conditions for safe storage, including any incompatibilities

Store in accordance with local regulations. Store in a segregated and approved area. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section
10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed
and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid
environmental contamination. See Section 10 for incompatible materials before handling or use.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
Occupational exposure limits
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Product/ingredient name Exposure limit values

butanone OSHA PEL 1989 (United States, 3/1989).

TWA: 200 ppm 8 hours.
TWA: 590 mg/m³ 8 hours.
STEL: 300 ppm 15 minutes.
STEL: 885 mg/m³ 15 minutes.
OSHA PEL (United States, 5/2018).
TWA: 200 ppm 8 hours.
TWA: 590 mg/m³ 8 hours.

cyclohexanone OSHA PEL 1989 (United States, 3/1989). Absorbed through skin.
TWA: 25 ppm 8 hours.
TWA: 100 mg/m³ 8 hours.
OSHA PEL (United States, 5/2018).
TWA: 50 ppm 8 hours.
TWA: 200 mg/m³ 8 hours.

Biological exposure indices

Product/ingredient name Exposure indices
butanone ACGIH BEI (United States, 1/2022)
BEI: 2 mg/l, methyl ethyl ketone [in urine]. Sampling time: end of shift.
cyclohexanone ACGIH BEI (United States, 1/2022)
BEI: 80 mg/l [Semi-quantitative: The determinant is an indicator of exposure to the chemical, but
the quantitative interpretation of the measurement is ambiguous. These determinants should be
used as a screening test if a quantitative test is not practical or as a confirmatory test if the
quantitative test is not specific and the origin of the determinant is in question.],
1,2-cyclohexanediol [in urine]. Sampling time: end of shift at end of workweek.
BEI: 8 mg/l [Semi-quantitative: The determinant is an indicator of exposure to the chemical, but
the quantitative interpretation of the measurement is ambiguous. These determinants should be
used as a screening test if a quantitative test is not practical or as a confirmatory test if the
quantitative test is not specific and the origin of the determinant is in question.], cyclohexanol [in
urine]. Sampling time: end of shift.

Recommended monitoring : Reference should be made to appropriate monitoring standards. Reference to

procedures national guidance documents for methods for the determination of hazardous
substances will also be required.

8.2 Exposure controls

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust
controls ventilation or other engineering controls to keep worker exposure to airborne
contaminants below any recommended or statutory limits. The engineering controls
also need to keep gas, vapor or dust concentrations below any lower explosive
limits. Use explosion-proof ventilation equipment.
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and
safety showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn,
unless the assessment indicates a higher degree of protection: safety glasses with
side-shields.
Hand protection : Recommended: EN374 B
May be used (Short term exposure): Latex gloves. Nitrile gloves. Use gloves only
once. Gloves should be replaced regularly and if there is any sign of damage to the
glove material. The user must check that the final choice of type of glove selected
for handling this product is the most appropriate and takes into account the
particular conditions of use, as included in the user's risk assessment.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Recommended: organic vapor filter (Type A)
Additional information: In situations where misting or flying may occur, use
appropriate certified respirators. Use a properly fitted, particulate filter respirator
complying with an approved standard if a risk assessment indicates this is
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necessary.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Appearance
Physical state : Liquid.
Color : Black.
Odor : Not available.
Odor threshold : Estimated.: ≥ 4 ppm (cyclohexanone).
pH : Not applicable.
Melting point/freezing : Estimated.: ≤ -31 °C (cyclohexanone).
point
Initial boiling point and : Estimated.: ≥ 80 °C (butanone).
boiling range
Flash point : -9 °C [ASTM D 56]
Evaporation rate (butyl : Estimated.: ≤ 7 [butyl acetate = 1] (butanone).
acetate = 1)
Flammability (solid, gas) : Not applicable. ( Liquid )
Upper/lower flammability : Estimated.: ≥ 2 % (butanone).
or explosive limits Estimated.: ≤ 12 % (butanone).
Vapor pressure : Estimated.: ≤ 11 kPa (79 mm Hg) at 20°C (butanone).
Vapor density : Estimated.: ≥ 2 [Air = 1] (butanone).
Relative density (Water = 1) : 0.859 [OECD 109]
Solubility(ies) : Not available.

Partition coefficient: n- : Not applicable.

octanol/water
Auto-ignition temperature : Estimated.: ≥ 404 °C (butanone).
Decomposition : Thermally stable.
temperature
Viscosity : Not available.
Explosive properties : Not applicable. Not classified.
Oxidizing properties : Not applicable. Not classified.
Particle characteristics
Median particle size : Not applicable.

9.2 Other information

Volatility (w/w) :85 %.
VOC Volatility (w/w) :85 %.

SECTION 10: Stability and reactivity

10.1 Reactivity
No specific test data related to reactivity available for this product or its ingredients.

10.2 Chemical stability

The product is stable.

10.3 Possibility of hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.
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10.4 Conditions to avoid

Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or
expose containers to heat or sources of ignition.

10.5 Incompatible materials

Reactive or incompatible with the following materials:
oxidizing materials

10.6 Hazardous decomposition products

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
butanone LC50 Inhalation Vapor Rat 23.5 mg/l 8 hours
LD50 Dermal Rabbit - Male >8000 mg/kg -
LD50 Oral Rat 3460 mg/kg -
cyclohexanone LC50 Inhalation Vapor Rat 8000 ppm 4 hours
LD50 Dermal Rabbit 794 to 3160 mg/kg -
LD50 Oral Rat 1890 mg/kg -

Conclusion/Summary : Not classified. No known significant effects or critical hazards.

Acute toxicity estimates
Route ATE value
Oral 40001.72 mg/kg
Dermal 41843.07 mg/kg
Inhalation (vapors) 232.81 mg/l

Irritation/Corrosion
Conclusion/Summary
Skin : Causes mild skin irritation.
Eyes : Causes serious eye damage.
Respiratory : Not classified. No known significant effects or critical hazards.
Sensitization
Product/ingredient name Route of exposure Species Result
butanone skin Guinea pig Not sensitizing

Conclusion/Summary
Skin : Not classified. No known significant effects or critical hazards.
Respiratory : Not classified. No known significant effects or critical hazards.
Mutagenicity
Conclusion/Summary : Not classified. No known significant effects or critical hazards.
Carcinogenicity
Conclusion/Summary : Not classified. No known significant effects or critical hazards.
Reproductive toxicity
Conclusion/Summary : Not classified. No known significant effects or critical hazards.
Specific target organ toxicity (single exposure)
Product/ingredient name Category Route of exposure Target organs
butanone Category 3 - Narcotic effects

Specific target organ toxicity (repeated exposure)

Not classified. No known significant effects or critical hazards.

Aspiration hazard
V489-C GHS (US) ENGLISH Version: 4.04 Page: 8/10

Conclusion/Summary : Not classified. No known significant effects or critical hazards.

Potential chronic health effects, Other
Conclusion/Summary : No known significant effects or critical hazards.

SECTION 12: Ecological information

12.1 Toxicity
Product/ingredient name Result Species Exposure
butanone Acute EC50 2029 mg/l Fresh water Algae - Pseudokirchnerella 96 hours
subcapitata
Acute EC50 308 mg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 2993 mg/l Fresh water Fish - Pimephales promelas 96 hours
Chronic NOEC 1240 mg/l Fresh water Algae - Pseudokirchnerella 96 hours
subcapitata
cyclohexanone Acute LC50 527000 µg/l Fresh water Fish - Pimephales promelas 96 hours

Conclusion/Summary : Not available.

12.2 Persistence and degradability

Product/ingredient name Aquatic half-life Photolysis Biodegradability
butanone - - Readily
cyclohexanone - - Readily

Conclusion/Summary : Not available.

12.3 Bioaccumulative potential

Product/ingredient name LogPow BCF Potential
butanone 0.3 - Low
cyclohexanone 0.86 - Low

12.4 Mobility in soil

Soil/water partition : Not available.
coefficient (KOC)
Mobility : Not available.

12.5 Results of PBT and vPvB assessment

This mixture does not contain any substances that are assessed to be a PBT or a vPvB.

12.6 Other adverse effects

No known significant effects or critical hazards.

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product
Methods of disposal : The generation of waste should be avoided or minimized wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation and
any regional local authority requirements. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Avoid dispersal of spilled
material and runoff and contact with soil, waterways, drains and sewers.
Packaging
Methods of disposal : The generation of waste should be avoided or minimized wherever possible. Waste
packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible.
Special precautions : None.
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SECTION 14: Transport information

UN IMDG IATA US DOT

14.1 UN number UN1210 UN1210 UN1210 UN1210

14.2 UN proper Printing Ink Printing Ink Printing Ink Printing Ink
shipping name

14.3 Transport hazard 3 3 3 3

class(es)

14.4 Packing group II II II II

14.5 Environmental No. No. No. No.

hazards

Additional information - - - -

14.6 Special precautions for user

No special measures required.

14.7 Transport in bulk according to IMO instruments

Not available.

SECTION 15: Regulatory information

CERCLA: Hazardous : The following components are listed: butanone (75 - <85%); cyclohexanone (2 -
substances. <5%)
SARA 313 : The following components are listed: None.
California Prop. 65 : This product contains a chemical or chemicals known to the state of California to
cause cancer. The following components are listed: ethyleneimine (<0.0001%);
vinyl chloride (<0.0001%).
National Fire Protection : Flammability
Association (U.S.A.) 3
Health 1 0 Reactivity

special hazard
Tariff Code - harmonized : 3215.11 Printing ink: Black.
system USA ...90.60
EU ...10
Heavy Metals : Total concentration: Pb, Hg, Cd, Cr(VI) < 100 ppm
California, VOC Content : 738 grams volatile organic / liter less water or exempt volatile.
Chemical Weapons Convention List Chemical Weapons Convention List Chemical Weapons Convention List
Schedule I Chemicals Schedule II Chemicals Schedule III Chemicals

Not listed Not listed Not listed

SECTION 16: Other information

Revision comments : Indicates information that has changed from previously issued version.
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Abbreviations and : ATE = Acute Toxicity Estimate

BCF = Bioconcentration Factor
acronyms GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the
Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
Procedure used to derive the classification
Classification Justification
FLAMMABLE LIQUIDS - Category 2 On basis of test data
SERIOUS EYE DAMAGE - Category 1 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Calculation method

Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its
subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination
of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with
caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.