Safety Data Sheet

BRB Silanil© 919

Issue date 31-Mar-2016 Revision date 31-Mar-2016 Version 1.02

SECTION 1: Identification of the substance/mixture and of the

company/undertaking
1.1. Product Identifier

Product name BRB Silanil© 919

Chemical name 3-Aminopropyltriethoxysilane

EC No 213-048-4
CAS No 919-30-2
Pure substance/mixture Substance

1.2. Relevant identified uses of the substance or mixture and uses advised against

Recommended Use Intermediate

Uses advised against No information available

1.3. Details of the supplier of the safety data sheet

BRB International BV BRB Central Eastern Europe Sp. z o.o.

Branskamp12 ul
.płk.StanisławaDąbka8
6014 CB Ittervoort 30-732 Krakow
The Netherlands Poland
☎:0031- 475- 560300 ☎:0048- 12-4157922

For further information, please contact

Contact Point R&D

E-mail address [email protected]

1.4. Emergency telephone number

Emergency telephone 0031-475-560300

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Regulation (EC) No 1272/2008
.

Acute toxicity - Oral Category 4 - (H302)

Skin corrosion/irritation Category 1 A - (H314)
Serious eye damage/eye irritation Category 1 - (H318)
Skin sensitisation Category 1 - (H317)

2.2. Label Elements

Product Identifier
Contains 3-Aminopropyltriethoxysilane

_____________________________________________________________________________________________

Page 1 / 11
BRB Silanil© 919 Revision date 31-Mar-2016
_____________________________________________________________________________________________

Signal Word
DANGER

Hazard statements
H302 - Harmful if swallowed
H314 - Causes severe skin burns and eye damage
H317 - May cause an allergic skin reaction

Precautionary Statements - EU (§28, 1272/2008)

P260 - Do not breathe dust/fume/gas/mist/vapours/spray
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P303 + P361 + P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing
P310 - Immediately call a POISON CENTER or doctor

2.3. Other Hazards

May be harmful in contact with skin***

SECTION 3: Composition/information on ingredients

3.1 Substances

Chemical name EC No CAS No REACH Classification according Weight-%

registration to Regulation (EC) No.
number 1272/2008 [CLP]
3-Aminopropyltriethoxysilane 213-048-4 919-30-2 No data available Acute Tox. 4 (H302) >=95
Skin Corr. 1B (H314)
Skin Sens. 1 (H317)
Ethanol 200-578-6 64-17-5 No data available Flam. Liq. 2 (H225) 0.1-1

Full text of H- and EUH-phrases: see section 16

SECTION 4: First aid measures

4.1. Description of first aid measures

General advice Immediate medical attention is required.

Inhalation Remove to fresh air. If not breathing, give artificial respiration. Call a doctor.

Skin contact Wash off immediately with soap and plenty of water while removing all contaminated
clothes and shoes. Immediate medical attention is required. Wash contaminated clothing
before reuse.

Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep
eye wide open while rinsing. Do not rub affected area. Call a doctor immediately.

_____________________________________________________________________________________________

Page 2 / 11
BRB Silanil© 919 Revision date 31-Mar-2016
_____________________________________________________________________________________________

Ingestion Do NOT induce vomiting. Rinse mouth. Drink plenty of water. Never give anything by mouth
to an unconscious person. Call a doctor or poison control centre immediately.

Self-protection of the first aider Use personal protective equipment as required. Avoid contact with skin, eyes or clothing.

4.2. Most important symptoms and effects, both acute and delayed

Symptoms Causes severe skin burns and eye damage. allergic skin reaction.

4.3. Indication of any immediate medical attention and special treatment needed

Note to doctors Product is a corrosive material. Use of gastric lavage or emesis is contra-indicated.
Possible perforation of stomach or esophagus should be investigated. Do not give chemical
antidotes. Asphyxia from glottal edema may occur. Marked decrease in blood pressure may
occur with moist rales, frothy sputum, and high pulse pressure. Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable Extinguishing Media

Use. Carbon dioxide (CO2). Extinguishing powder. Alcohol resistant foam. Cool containers with flooding quantities of water until
well after fire is out.

Unsuitable Extinguishing Media

Do not use a solid water stream as it may scatter and spread fire

5.2. Special hazards arising from the substance or mixture

The product causes burns of eyes, skin and mucous membranes Thermal decomposition can lead to release of irritating and toxic
gases and vapours In the event of fire and/or explosion do not breathe fumes

Hazardous combustion productsCarbon dioxide (CO2), Carbon monoxide, Nitrogen oxides (NOx).

5.3. Advice for firefighters

In the event of fire and/or explosion do not breathe fumes. Use water spray jet to protect personnel and to cool endangered
containers. Wear self-contained breathing apparatus and protective suit. Use personal protective equipment as required. Do not
allow run-off from fire-fighting to enter drains or water courses.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions
Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Evacuate personnel to safe areas. Keep
people away from and upwind of spill/leak. Special danger of slipping by leaking/spilling product. Ensure adequate ventilation,
especially in confined areas. Do not breathe gas/fumes/vapour/spray.

For emergency responders

Use personal protection recommended in Section 8.

6.2. Environmental precautions

Do not allow into any sewer, on the ground or into any body of water. Should not be released into the environment. Do not flush
into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. Prevent product from entering
drains. See Section 12 for additional Ecological Information.

6.3. Methods and material for containment and cleaning up

Methods for Containment Prevent further leakage or spillage if safe to do so.

_____________________________________________________________________________________________

Page 3 / 11
BRB Silanil© 919 Revision date 31-Mar-2016
_____________________________________________________________________________________________

Methods for cleaning up Use personal protective equipment as required. Dam up. Cover liquid spill with sand, earth
or other non-combustible absorbent material. Take up mechanically, placing in appropriate
containers for disposal. Clean contaminated surface thoroughly.

6.4. Reference to other sections

See section 8 for national exposure control parameters. See Section 12 for additional Ecological Information.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Advice on safe handling

Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Ensure adequate ventilation, especially in
confined areas. In case of insufficient ventilation, wear suitable respiratory equipment. Use only with adequate ventilation and in
closed systems. Do not breathe gas/fumes/vapour/spray. In case of gas escape or of entry into waterways, soil or drains, inform
the responsible authorities.

General hygiene considerations

Wash contaminated clothing before reuse. When using do not eat, drink or smoke. Keep away from food, drink and animal feeding
stuffs. Contaminated work clothing should not be allowed out of the workplace. Regular cleaning of equipment, work area and
clothing is recommended. Avoid contact with skin, eyes or clothing. Take off all contaminated clothing and wash it before reuse.
Wear suitable gloves and eye/face protection.

7.2. Conditions for safe storage, including any incompatibilities

Storage Conditions
Keep out of the reach of children. Keep containers tightly closed in a dry, cool and well-ventilated place. Keep in properly labelled
containers. Ensure adequate ventilation. Keep only in original container. Do not allow to enter into soil/subsoil. Restrict access to
stockrooms.

7.3. Specific end use(s)

Risk Management Methods (RMM)

The information required is contained in this Material Safety Data Sheet.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Exposure Limits .

Chemical name European Union United Kingdom France Spain Germany

Ethanol - STEL: 3000 ppm TWA: 1000 ppm STEL: 1000 ppm TWA: 500 ppm
64-17-5 STEL: 5760 mg/m3 TWA: 1900 mg/m3 STEL: 1910 mg/m3 TWA: 960 mg/m3
TWA: 1000 ppm STEL: 5000 ppm Ceiling / Peak: 1000
TWA: 1920 mg/m3 STEL: 9500 mg/m3 ppm
Ceiling / Peak: 1920
mg/m3
Skin

Chemical name Italy Portugal Netherlands Finland Denmark

Ethanol - TWA: 1000 ppm Skin TWA: 1000 ppm TWA: 1000 ppm
64-17-5 STEL: 1900 mg/m3 TWA: 1900 mg/m3 TWA: 1900 mg/m3
TWA: 260 mg/m3 STEL: 1300 ppm
STEL: 2500 mg/m3
Chemical name Austria Switzerland Poland Norway Ireland
Ethanol STEL 2000 ppm STEL: 1000 ppm TWA: 1900 mg/m3 TWA: 500 ppm STEL: 1000 ppm
64-17-5 STEL 3800 mg/m3 STEL: 1920 mg/m3 TWA: 950 mg/m3
TWA: 1000 ppm TWA: 500 ppm STEL: 500 ppm
TWA: 1900 mg/m3 TWA: 960 mg/m3 STEL: 950 mg/m3
_____________________________________________________________________________________________

Page 4 / 11
BRB Silanil© 919 Revision date 31-Mar-2016
_____________________________________________________________________________________________

Chemical name Sweden Belgium Greece Turkey Czech Republic

Ethanol 500 ppm LLV; 1000 1000 ppm TWA; 1907 1000 ppm TWA; 1900 - Ceiling: 3000 mg/m3
64-17-5 mg/m3 LLV mg/m3 TWA mg/m3 TWA TWA: 1000 mg/m3
1000 ppm STV; 1900
mg/m3 STV

Derived No Effect Level (DNEL) No information available

Predicted No Effect Concentration No information available.

(PNEC)

8.2. Exposure controls

Engineering controls Provide adequate ventilation as well as local exhaustion at critical locations. Eyewash
stations.

Personal Protective Equipment

Eye/face Protection Face protection shield.
Hand protection Wear protective gloves. To protect the wearer, gloves must be the correct fit and be used
properly. Ensure that the breakthrough time of the glove material is not exceeded. Refer to
glove supplier for information on breakthrough time for specific gloves.
Skin and Body Protection Suitable protective clothing. Wear impervious protective clothing, including boots, gloves,
lab coat, apron or coveralls, as appropriate, to prevent skin contact. Wear protective gloves.
To protect the wearer, gloves must be the correct fit and be used properly. Ensure that the
breakthrough time of the glove material is not exceeded. Refer to glove supplier for
information on breakthrough time for specific gloves. Gloves must conform to standard EN
374
Respiratory protection None under normal use conditions.

Environmental exposure controls Local authorities should be advised if significant spillages cannot be contained.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical State Liquid
Appearance No information available Odour characteristic
Colour light yellow*** Odour threshold No information available

Property Values Remar ks •Met hod

pH approx.*** 11.3*** 500 g/L @ 20 °C***
Melting point/freezing point <*** -70*** °C*** /*** -94*** °F*** ***
Boiling point / boiling range approx. 217 °C / 423 °F
Flash Point approx. 96 °C / 205 °F
Evaporation Rate No information available
Flammability (solid, gas) No information available
Flammability Limit in Air
Upper flammability limit: No data available
Lower flammability limit No data available
Vapour pressure <= 13.0 hPa @ 20°C
Vapour Density No information available
Specific gravity No data available @ 20⁰C
approx. 0.950*** g/cm3 @ 25°C
Water solubility No data available @ 20⁰C
Solubility(ies) Water reactive No information available
Partition coefficient No information available
Autoignition Temperature No information available
Decomposition temperature No information available
Kinematic viscosity No data available @ 40 °C

_____________________________________________________________________________________________

Page 5 / 11
BRB Silanil© 919 Revision date 31-Mar-2016
_____________________________________________________________________________________________

approx. 1.6 mm2/s @ 25°C

Dynamic viscosity No data available @ 40 °C
Explosive properties No information available
Oxidising properties No information available

9.2. Other information

No information available

SECTION 10: Stability and reactivity

10.1. Reactivity

No data available.

10.2. Chemical stability

Stable under normal conditions.

10.3. Possibility of hazardous reactions

Reacts with: water , basic substances and acids . Reaction causes the formation of: ethanol.

10.4. Conditions to avoid

Exposure to air or moisture over prolonged periods.

10.5. Incompatible materials

Incompatible with oxidising agents. Acids.

10.6. Hazardous decomposition products

Thermal decomposition can lead to release of irritating and toxic gases and vapours. Carbon dioxide (CO2). Carbon monoxide.
Nitrogen oxides (NOx). Ethanol.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute Toxicity

Product Information
Product does not present an acute toxicity hazard based on known or supplied information.
Inhalation No data available.
Eye Contact No data available.
Skin contact No data available.
Ingestion No data available.

The following values are calculated based on chapter 3.1 of the GHS document
Unknown acute toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity.
ATEmix (oral) 503.00 mg/kg

Chemical name Oral LD50 Dermal LD50 Inhalation LC50

3-Aminopropyltriethoxysilane = 1780 mg/kg ( Rat ) approx. 4000 mg/kg (Rabbit)***
Ethanol 21 g/kg (Rat); 6300 mg/kg (Rabbit) 20 g/kg (Rabbit) = 124.7 mg/L ( Rat ) 4 h

Skin corrosion/irritation No information available.

_____________________________________________________________________________________________

Page 6 / 11
BRB Silanil© 919 Revision date 31-Mar-2016
_____________________________________________________________________________________________

Serious eye damage/eye irritation No information available.

Sensitisation No information available.

Germ Cell Mutagenicity No information available.

Carcinogenicity No information available.

Reproductive Toxicity No information available.

STOT - single exposure No information available.

STOT - repeated exposure No information available.

Aspiration Hazard No information available.

SECTION 12: Ecological information

12.1. Toxicity

0% of the mixture consists of components(s) of unknown hazards to the aquatic environment***

Product Information

Acute (short-term) algae toxicity

EC50 No information available

EC0 No information available

IC50 No information available

IC0 No information available

ErC50 No information available

EbC50 No information available

Acute (short-term) fish toxicity

LC50 No information available

LC0 No information available

EC50 No information available

EC0 No information available

Acute (short-term) aquatic invertebrate toxicity

EC50 No information available

EC0 No information available

Chronic (long-term) algae toxicity

NOEC No information available

_____________________________________________________________________________________________

Page 7 / 11
BRB Silanil© 919 Revision date 31-Mar-2016
_____________________________________________________________________________________________

LOEC No information available

Chronic (long-term) fish toxicity

NOEC No information available

LOEC No information available

Chronic (long-term) aquatic invertebrate toxicity

NOEC No information available

LOEC No information available

Chemical name Algae/aquatic plants Fish Crustacea

3-Aminopropyltriethoxysilane EC50: approx. 603 mg/l LC50: > 934 mg/l (Brachydanio rerio EC50: approx. 331 mg/l (Daphnia
(Pseudokirchneriella subcapitata 96h)*** magna 48h)***
72h)***
Ethanol - 12.0 - 16.0: 96 h Oncorhynchus 9268 - 14221: 48 h Daphnia magna
mykiss mL/L LC50 static 100: 96 h mg/L LC50 2: 48 h Daphnia magna
Pimephales promelas mg/L LC50 mg/L EC50 Static
static 13400 - 15100: 96 h
Pimephales promelas mg/L LC50
flow-through

12.2. Persistence and degradability

Product Information

Biodegradation No information available

BOD No information available

ThCO2 No information available

DOC No information available

12.3. Bioaccumulative potential

Product Information

Bioaccumulation (factor) No information available

Chemical name Partition coefficient

Ethanol -0.32

12.4. Mobility in soil

No information available.

12.5. Results of PBT and vPvB assessment

This substance is not considered to be persistent, bioaccumulating nor toxic (PBT). This substance is not considered to be very
persistent nor very bioaccumulating (vPvB).

12.6. Other adverse effects

No information available

_____________________________________________________________________________________________

Page 8 / 11
BRB Silanil© 919 Revision date 31-Mar-2016
_____________________________________________________________________________________________

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Waste from residues/unused Disposal should be in accordance with applicable regional, national and local laws and
products regulations.

Contaminated packaging Do not re-use container.

OTHER INFORMATION Waste codes should be assigned by the user based on the application for which the product
was used.

SECTION 14: Transport information

ADR
14.1. UN number UN3267
14.2. UN proper shipping name Corrosive liquid, basic, organic, n.o.s.
14.3. Transport hazard class(es) 8
Labels -
14.4. Packing group II
Description UN3267, Corrosive liquid, basic, organic, n.o.s.
(3-Aminopropyltriethoxysilane), 8, II, (E)
14.5. Environmental hazards Not applicable
14.6. Special precautions for user None
Classification code C7
Tunnel restriction code (E)
Limited quantity (LQ) 1L
ADR Hazard Id (Kemmler Number) 80
Note: -

RID
14.1. UN number UN3267
14.2. UN proper shipping name Corrosive liquid, basic, organic, n.o.s.
14.3. Transport hazard class(es) 8
Labels -
14.4. Packing group II
Description UN3267, Corrosive liquid, basic, organic, n.o.s.
(3-Aminopropyltriethoxysilane), 8, II
14.5. Environmental hazards Not applicable
14.6. Special precautions for user None
Classification code C7
Limited quantity (LQ) 1L
Note: -

IMDG
14.1. UN number UN3267
14.2. UN proper shipping name Corrosive liquid, basic, organic, n.o.s.
14.3. Transport hazard class(es) 8
Subsidiary hazard class -
14.4. Packing group II
Description UN3267, Corrosive liquid, basic, organic, n.o.s.
(3-Aminopropyltriethoxysilane), 8, II
14.5. Environmental hazards Not applicable
14.6. Special precautions for user None
EmS-No F-A, S-B
Limited quantity (LQ) 1L
Note: -
14.7. Transport in bulk according to Annex II of No information available
MARPOL73/78 and the IBC Code

_____________________________________________________________________________________________

Page 9 / 11
BRB Silanil© 919 Revision date 31-Mar-2016
_____________________________________________________________________________________________

IATA
14.1. UN number UN3267
14.2. UN proper shipping name Corrosive liquid, basic, organic, n.o.s.
14.3. Transport hazard class(es) 8
Subsidiary hazard class -
14.4. Packing group II
Description UN3267, Corrosive liquid, basic, organic, n.o.s.
(3-Aminopropyltriethoxysilane), 8, II
14.5. Environmental hazards Not applicable
14.6. Special precautions for user None
ERG Code 8L
Limited quantity (LQ) 0.5 L
Note: -

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

National Regulations

See section 8 for national exposure control parameters

France

Occupational Illnesses (R-463-3, France)

Chemical name French RG number
Ethanol RG 84
64-17-5

Germany

Water hazard class (WGK) slightly hazardous to water (WGK 1)

Storage class 8A

European Union

Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents
at work

International Inventories

All of the components in the product are on the following Inventory lists: TSCA (United States), Canada (DSL/NDSL),
Europe (EINECS/ELINCS/NLP), Australia (AICS), South Korea (KECL), China (IECSC), ENCS (Japan), Philippines (PICCS),
NZIoC - New Zealand Inventory of Chemicals.

15.2. Chemical safety assessment

For this substance a chemical safety assessment has not been carried out.

SECTION 16: Other information

_____________________________________________________________________________________________

Page 10 / 11
BRB Silanil© 919 Revision date 31-Mar-2016
_____________________________________________________________________________________________

Full text of H-Statements referred to under sections 2 and 3

H225 - Highly flammable liquid and vapour
H302 - Harmful if swallowed
H314 - Causes severe skin burns and eye damage
H317 - May cause an allergic skin reaction

Revision note Not applicable.

This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006

End of Safety Data Sheet

_____________________________________________________________________________________________

Page 11 / 11