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General Organic Chemistry JEE Main 2024 January Question Bank

Questions with Answer Keys MathonGo

Q1 - 2024 (01 Feb Shift 1)

Given below are two statements:


Statement (I) : Aminobenzene and aniline are same organic compounds.

Statement (II) : Aminobenzene and aniline are different organic compounds.


In the light of the above statements, choose the most appropriate answer from the options given below:

(1) Both Statement I and Statement II are correct


(2) Statement I is correct but Statement II is incorrect
(3) Statement I is incorrect but Statement II is correct

(4) Both Statement I and Statement II are incorrect

Q2 - 2024 (01 Feb Shift 1)

Ionic reactions with organic compounds proceed through:

(A) Homolytic bond cleavage

(B) Heterolytic bond cleavage


(C) Free radical formation

(D) Primary free radical

(E) Secondary free radical


Choose the correct answer from the options given below:

(1) (A) only


(2) (C) only

(3) (B) only


(4) (D) and (E) only

Q3 - 2024 (01 Feb Shift 1)

In Kjeldahl's method for estimation of nitrogen, CuSO acts as :


4

(1) Reducing agent


(2) Catalytic agent

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General Organic Chemistry JEE Main 2024 January Question Bank

Questions with Answer Keys MathonGo

(3) Hydrolysis agent


(4) Oxidising agent

Q4 - 2024 (01 Feb Shift 1)

Number of optical isomers possible for 2 - chlorobutane _____

Q5 - 2024 (01 Feb Shift 2)

The set of meta directing functional groups from the following sets is:

(1) −CN, −NH 2, −NHR, −OCH3

(2) −NO 2, −NH2 , −COOH, −COOR

(3) −NO 2, −CHO, −SO3 H, −COR

(4) −CN, −CHO, −NHCOCH 3, −COOR

Q6 - 2024 (01 Feb Shift 2)

Lassaigne's test is used for detection of :

(1) Nitrogen and Sulphur only


(2) Nitrogen, Sulphur and Phosphorous Only

(3) Phosphorous and halogens only

(4) Nitrogen, Sulphur, phosphorous and halogens

Q7 - 2024 (01 Feb Shift 2)

Which among the following has highest boiling point?

(1) CH 3 CH2 CH2 CH3

(2) CH 3 CH2 CH2 CH2 − OH

(3) CH 3 CH2 CH2 CHO

(4) H 5 C2 − O − C2 H5

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General Organic Chemistry JEE Main 2024 January Question Bank

Questions with Answer Keys MathonGo

Q8 - 2024 (01 Feb Shift 2)

The functional group that shows negative resonance effect is:

(1) −NH 2

(2) −OH

(3) −COOH

(4) −OR

Q9 - 2024 (01 Feb Shift 2)

Following Kjeldahl's method, 1 g of organic compound released ammonia, that neutralised 10 mL of


2MH2 SO4 . The percentage of nitrogen in the compound is _______ %.

Q10 - 2024 (27 Jan Shift 1)

Highest enol content will be shown by :

(1)

(2)

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General Organic Chemistry JEE Main 2024 January Question Bank

Questions with Answer Keys MathonGo

(3)

(4)

Q11 - 2024 (27 Jan Shift 1)

Which of the following has highly acidic hydrogen?

(1)

(2)

(3)

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General Organic Chemistry JEE Main 2024 January Question Bank

Questions with Answer Keys MathonGo

(4)

Q12 - 2024 (27 Jan Shift 1)

The ascending order of acidity of −OH group in the following compounds is :


(A) Bu − OH

(B)

(C)

(D)

(E)

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General Organic Chemistry JEE Main 2024 January Question Bank

Questions with Answer Keys MathonGo

Choose the correct answer from the options given below :

(1) (A) < (D) < (C) < (B) < (E)
(2) (C) < (A) < (D) < (B) < (E)
(3) (C) < (D) < (B) < (A) < (E)

(4) (A) < (C) < (D) < (B) < (E)

Q13 - 2024 (27 Jan Shift 1)

Cyclohexene

is ______ type of an
organic compound.

(1) Benzenoid aromatic


(2) Benzenoid non-aromatic
(3) Acyclic
(4) Alicyclic

Q14 - 2024 (27 Jan Shift 1)

IUPAC name of following compound (P) is:

(1) 1-Ethyl-5, 5-dimethylcyclohexane


(2) 3-Ethyl-1,1-dimethylcyclohexane
(3) 1-Ethyl-3, 3-dimethylcyclohexane

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General Organic Chemistry JEE Main 2024 January Question Bank

Questions with Answer Keys MathonGo

(4) 1,1-Dimethyl-3-ethylcyclohexane

Q15 - 2024 (27 Jan Shift 1)

Among the given organic compounds, the total number of aromatic compounds is

(A)

(B)

(C)

(D)

Q16 - 2024 (27 Jan Shift 2)

The order of relative stability of the contributing structure is

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General Organic Chemistry JEE Main 2024 January Question Bank

Questions with Answer Keys MathonGo

Choose the correct answer from the options given below:

(1) I > II > III

(2) II > I > III


(3) I = II = III
(4) III > II > I

Q17 - 2024 (27 Jan Shift 2)

The molecular formula of second homologue in the homologous series of mono carboxylic acids is

(1) C 3 H6 O2

(2) C 2 H4 O2

(3) CH 2O

(4) C 2 H2 O2

Q18 - 2024 (27 Jan Shift 2)

The technique used for purification of steam volatile water immiscible substance is:

(1) Fractional distillation

(2) Fractional distillation under reduced pressure


(3) Distillation
(4) Steam distillation

Q19 - 2024 (27 Jan Shift 2)

Bond line formula of HOCH(CN)2 is:

(1)

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General Organic Chemistry JEE Main 2024 January Question Bank

Questions with Answer Keys MathonGo

(2)

(3)

(4)

Q20 - 2024 (27 Jan Shift 2)

The incorrect statement regarding conformations of ethane is:

(1) Ethane has infinite number of conformations


(2) The dihedral angle in staggered conformation is 60 ∘

(3) Eclipsed conformation is the most stable conformation.


(4) The conformations of ethane are interconvertible to one-another.

Q21 - 2024 (27 Jan Shift 2)

Total number of compounds with Chiral carbon atoms from following is ______

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General Organic Chemistry JEE Main 2024 January Question Bank

Questions with Answer Keys MathonGo

CH3 − CH2 − CH (NO2 ) − COOH

CH3 − CH2 − CHBr − CH2 − CH3

CH3 − CH(I) − CH2 − NO2

CH3 − CH2 − CH(OH) − CH2 OH

Q22 - 2024 (29 Jan Shift 1)

The difference in energy between the actual structure and the lowest energy resonance structure for the given
compound is

(1) electromeric energy


(2) resonance energy

(3) ionization energy


(4) hyperconjugation energy

Q23 - 2024 (29 Jan Shift 1)

Appearance of blood red colour, on treatment of the sodium fusion extract of an organic compound with

FeSO4 in presence of concentrated H 2 SO4 indicates the presence of element/s

(1) Br

(2) N
(3) N and S
(4) S

Q24 - 2024 (29 Jan Shift 1)

The interaction between π bond and lone pair of electrons present on an adjacent atom is responsible for

(1) Hyperconjugation

(2) Inductive effect


(3) Electromeric effect

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General Organic Chemistry JEE Main 2024 January Question Bank

Questions with Answer Keys MathonGo

(4) Resonance effect

Q25 - 2024 (29 Jan Shift 2)

The ascending acidity order of the following H atoms is

(1) C < D < B < A


(2) A < B < C < D
(3) A < B < D < C
(4) D < C < B < A

Q26 - 2024 (29 Jan Shift 2)

Match List I with List II

Choose the correct answer from the options given below :-

(1) A-I, B-II, C-III, D-IV


(2) A-IV, B-I, C-II, D-III
(3) A-III, B-IV, C-I, D-II
(4) A-II, B-I, C-IV, D-III

Q27 - 2024 (29 Jan Shift 2)

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General Organic Chemistry JEE Main 2024 January Question Bank

Questions with Answer Keys MathonGo

According to IUPAC system, the compound

is named as

(1) Cyclohex-1-en-2-ol

(2) 1-Hydroxyhex-2-ene
(3) Cyclohex-1-en-3-ol
(4) Cyclohex-2-en-1-ol

Q28 - 2024 (29 Jan Shift 2)

Chromatographic technique/s based on the principle of differential adsorption is/are


A. Column chromatography
B. Thin layer chromatography
C. Paper chromatography
Choose the most appropriate answer from the options given below:

(1) B only
(2) A only
(3) A \& B only

(4) C only

Q29 - 2024 (29 Jan Shift 2)

Which one of the following will show geometrical isomerism?

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General Organic Chemistry JEE Main 2024 January Question Bank

Questions with Answer Keys MathonGo

(1)

(2)

(3)

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General Organic Chemistry JEE Main 2024 January Question Bank

Questions with Answer Keys MathonGo

(4)

Q30 - 2024 (30 Jan Shift 1)

Which of the following molecule/species is most stable?

(1)

(2)

(3)

(4)

Q31 - 2024 (30 Jan Shift 1)

Example of vinylic halide is

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General Organic Chemistry JEE Main 2024 January Question Bank

Questions with Answer Keys MathonGo

(1)

(2)

(3)

(4)

Q32 - 2024 (30 Jan Shift 1)

Structure of 4-Methylpent-2-enal is

(1)

(2)

(3)

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General Organic Chemistry JEE Main 2024 January Question Bank

Questions with Answer Keys MathonGo

(4)

Q33 - 2024 (30 Jan Shift 1)

Given below are two statement one is labeled as Assertion (A) and the other is labeled as Reason (R).
Assertion (A): CH 2 = CH − CH2 − Cl is an example of allyl halide
Reason (R): Allyl halides are the compounds in which the halogen atom is attached to sp hybridised carbon
2

atom.
In the light of the two above statements, choose the most appropriate answer from the options given below:

(1) (A) is true but (R) is false


(2) Both (A) and (R) are true but (R) is not the correct explanation of (A)
(3) (A) is false but (R) is true

(4) Both (A) and (R) are true and (R) is the correct explanation of (A)

Q34 - 2024 (30 Jan Shift 1)

On a thin layer chromatographic plate, an organic compound moved by 3.5 cm, while the solvent moved by

5 cm . The retardation factor of the organic compound is _______ ×10 −1

Q35 - 2024 (30 Jan Shift 2)

Which among the following purification methods is based on the principle of "Solubility" in two different
solvents?

(1) Column Chromatography


(2) Sublimation
(3) Distillation
(4) Differential Extraction

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General Organic Chemistry JEE Main 2024 January Question Bank

Questions with Answer Keys MathonGo

Q36 - 2024 (30 Jan Shift 2)

IUPAC name of following compound is

(1) 2-Aminopentanenitrile

(2) 2-Aminobutanenitrile
(3) 3-Aminobutanenitrile
(4) 3-Aminopropanenitrile

Q37 - 2024 (30 Jan Shift 2)

The correct stability order of carbocations is


+ + +

(1) (CH 3
) C
3
+
> CH3 − C H2 > (CH3 )
2
C H >C H3

+ + + +

(2) C H 3
> (CH3 )
2
C H > CH3 − C H2 > (CH3 )
3
C

+ + + +

(3) (CH 3)
3
C> (CH3 )
2
C H > CH3 − C H2 >C H3

(4)

Q38 - 2024 (30 Jan Shift 2)

Number of geometrical isomers possible for the given structure is/are _______

Q39 - 2024 (31 Jan Shift 1)

A species having carbon with sextet of electrons and can act as electrophile is called

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General Organic Chemistry JEE Main 2024 January Question Bank

Questions with Answer Keys MathonGo

(1) carbon free radical


(2) carbanion
(3) carbocation

(4) pentavalent carbon

Q40 - 2024 (31 Jan Shift 1)

'Adsorption' principle is used for which of the following purification method?

(1) Extraction
(2) Chromatography
(3) Distillation
(4) Sublimation

Q41 - 2024 (31 Jan Shift 1)

Given below are two statements:


Statement I: IUPAC name of HO − CH 2 − (CH2 ) − CH2 − COCH3
3
is 7-hydroxyheptan-2-one.
Statement II: 2-oxoheptan-7-ol is the correct IUPAC name for above compound.
In the light of the above statements. choose the most appropriate answer from the options given below:

(1) Statement I is correct but Statement II is incorrect.


(2) Both Statement I and Statement II are incorrect.
(3) Both Statement I and Statement II are correct.
(4) Statement I is incorrect but Statement II is correct.

Q42 - 2024 (31 Jan Shift 1)

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General Organic Chemistry JEE Main 2024 January Question Bank

Questions with Answer Keys MathonGo

Match List I with List II


LIST I (Technique) LIST II (Application)

Separation of

A. Distillation I. glycerol from

spent-lye

Fractional Aniline - Water


B. II.
distillation mixture

Steam Separation of crude


C. III.
distillation oil fractions

Distillation
Chloroform-
D. under reduced IV.
Aniline
pressure

Choose the correct answer from the options given below:

(1) A-IV, B-I, C-II, D-III


(2) A-IV, B-III, C-II. D-I
(3) A-I. B-II, C-IV, D-III

(4) A-II, B-III. C-I, D-IV

Q43 - 2024 (31 Jan Shift 2)

Identify structure of 2,3-dibromo-1-phenylpentane.

(1)

(2)

(3)

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General Organic Chemistry JEE Main 2024 January Question Bank

Questions with Answer Keys MathonGo

(4)

Q44 - 2024 (31 Jan Shift 2)

The fragrance of flowers is due to the presence of some steam volatile organic compounds called essential oils.
These are generally insoluble in water at room temperature but are miscible with water vapour in vapour
phase. A suitable method for the extraction of these oils from the flowers is _______

(1) crystallisation
(2) distillation under reduced pressure
(3) distillation
(4) steam distillation

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General Organic Chemistry JEE Main 2024 January Question Bank

Questions with Answer Keys MathonGo

Answer Key

Q1 (2) Q2 (3) Q3 (2) Q4 (2)

Q5 (3) Q6 (4) Q7 (2) Q8 (3)

Q9 (56) Q10 (2) Q11 (4) Q12 (4)

Q13 (4) Q14 (2) Q15 (3) Q16 (1)

Q17 (2) Q18 (4) Q19 (4) Q20 (3)

Q21 (5) Q22 (2) Q23 (3) Q24 (4)

Q25 (1) Q26 (4) Q27 (4) Q28 (3)

Q29 (3) Q30 (1) Q31 (1) Q32 (4)

Q33 (1) Q34 (7) Q35 (4) Q36 (3)

Q37 (3) Q38 (4) Q39 (3) Q40 (2)

Q41 (1) Q42 (2) Q43 (3) Q44 (4)

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General Organic Chemistry JEE Main 2024 January Question Bank

Solutions MathonGo

Q1

Aniline is also known as amino benzene.

Q2

Heterolytic cleavage of Bond lead to formation of ions.

Q3

Kjeldahl's method is used for estimation of Nitrogen where CuSO acts as a catalyst.
4

Q4

There is one chiral centre present in given compound.

So, Total optical isomers = 2

and

Q5

All are −M, Hence meta directing groups.

Q6

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General Organic Chemistry JEE Main 2024 January Question Bank

Solutions MathonGo

Lassaigne's test is used for detection of all element N, S, P, X.

Q7

Due to H-bonding boiling point of alcohol is High.

Q8

shows −R effect, while rest 3 groups shows +R effect via lone pair.

Q9

H2 SO4 + 2NH3 → (NH4 ) SO4


2

Millimole of H 2 SO4 → 10 × 2

So Millimole of NH 3 = 20 × 2 = 40

Organic → NH3

Compound 40 Millimole

∴ Mole of N =
40

1000

wt. of N = 40

1000
× 14

% composition of N in organic compound


40 × 14
= × 100
1000 × 1

= 56%

Q10

Q11

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General Organic Chemistry JEE Main 2024 January Question Bank

Solutions MathonGo

Conjugate base is more stable due to more resonance of negative charge.

Q12

Q13

So;.

is Alicyclic

Q14

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General Organic Chemistry JEE Main 2024 January Question Bank

Solutions MathonGo

Q15

B,C and D are Aromatic

Q16

I > II > III, since neutral resonating structures are more stable than charged resonating structure. II > III,
since stability of structure with −ve charge on more electronegative atom is higher.

Q17

Q18

Steam distillation is used for those liquids which are insoluble in water, containing non-volatile impurities and
are steam volatile.

Q19

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General Organic Chemistry JEE Main 2024 January Question Bank

Solutions MathonGo

CH(OH)(CN)2 is

Q20

Eclipsed conformation is the least stable conformation of ethane.

Q21

Chiral carbons are marked by.

Q22

The difference in energy between the actual structure and the lowest energy resonance structure for the given
compound is known as resonance energy.

Q23
+
H
2+ +3
Fe −−−−−−−−→ Fe
Conc. H2 SO4

SCN

Fe
+3
−−−→ Fe(SCN)3 ( blood red colour )
Appearance of blood red colour indicates presence of both nitrogen and sulphur.

Q24

It is a type of conjugation responsible for resonance.

Q25

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General Organic Chemistry JEE Main 2024 January Question Bank

Solutions MathonGo

Stability of conjugate base α acidic strength C < D < B < A

Q26

Ethanol → 15.9

Phenol → 10
M-Nitrophenol → 8.3
P-Nitrophenol → 7.1

Q27

Cyclohex-2-en-1-ol

Q28

Memory Based

Q29

Due to unsymmetrical.

Q30

it is aromatic species

Q31

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General Organic Chemistry JEE Main 2024 January Question Bank

Solutions MathonGo

Vinyl carbon is sp hybridized aliphatic carbon


2

is vinyl halide while

is aryl halide and

are allyl halide

Q32

Q33

CH2 = CH − CH2 − Cl

3
It is allyl carbon and sp hybridized

Q34
Distance travelled by sample/organic compound
etardation factor =
3.5 −1
= = 7 × 10
Distance travelled by solvent 5

Q35

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General Organic Chemistry JEE Main 2024 January Question Bank

Solutions MathonGo

Different Extraction
Different layers are formed which can be separated in funnel. (Theory based).

Q36

Q37

More no. of hyperconjugable Hydrogens, more stable is the carbocations.

Q38

3 stereocenteres, symmetrical

Total Geometrical isomers → 4. EE, ZZ, EZ (two isomers)

Q39

Six electron species

Q40

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General Organic Chemistry JEE Main 2024 January Question Bank

Solutions MathonGo

Principle used in chromotography is adsorption.

Q41

7-Hydroxyheptan-2-one is correct IUPAC name

Q42

Fact (NCERT)

Q43

2,3-dibromo-1-phenylpentane

Q44

Steam distillation technique is applied to separate substances which are steam volatile and are immiscible with
water.

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