Jee Chemistry
Jee Chemistry
Jee Chemistry
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The set of meta directing functional groups from the following sets is:
(4) H 5 C2 − O − C2 H5
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(1) −NH 2
(2) −OH
(3) −COOH
(4) −OR
(1)
(2)
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(3)
(4)
(1)
(2)
(3)
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(4)
(B)
(C)
(D)
(E)
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(1) (A) < (D) < (C) < (B) < (E)
(2) (C) < (A) < (D) < (B) < (E)
(3) (C) < (D) < (B) < (A) < (E)
(4) (A) < (C) < (D) < (B) < (E)
Cyclohexene
is ______ type of an
organic compound.
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(4) 1,1-Dimethyl-3-ethylcyclohexane
Among the given organic compounds, the total number of aromatic compounds is
(A)
(B)
(C)
(D)
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The molecular formula of second homologue in the homologous series of mono carboxylic acids is
(1) C 3 H6 O2
(2) C 2 H4 O2
(3) CH 2O
(4) C 2 H2 O2
The technique used for purification of steam volatile water immiscible substance is:
(1)
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(2)
(3)
(4)
Total number of compounds with Chiral carbon atoms from following is ______
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The difference in energy between the actual structure and the lowest energy resonance structure for the given
compound is
Appearance of blood red colour, on treatment of the sodium fusion extract of an organic compound with
(1) Br
(2) N
(3) N and S
(4) S
The interaction between π bond and lone pair of electrons present on an adjacent atom is responsible for
(1) Hyperconjugation
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is named as
(1) Cyclohex-1-en-2-ol
(2) 1-Hydroxyhex-2-ene
(3) Cyclohex-1-en-3-ol
(4) Cyclohex-2-en-1-ol
(1) B only
(2) A only
(3) A \& B only
(4) C only
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(1)
(2)
(3)
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(4)
(1)
(2)
(3)
(4)
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(1)
(2)
(3)
(4)
Structure of 4-Methylpent-2-enal is
(1)
(2)
(3)
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(4)
Given below are two statement one is labeled as Assertion (A) and the other is labeled as Reason (R).
Assertion (A): CH 2 = CH − CH2 − Cl is an example of allyl halide
Reason (R): Allyl halides are the compounds in which the halogen atom is attached to sp hybridised carbon
2
atom.
In the light of the two above statements, choose the most appropriate answer from the options given below:
(4) Both (A) and (R) are true and (R) is the correct explanation of (A)
On a thin layer chromatographic plate, an organic compound moved by 3.5 cm, while the solvent moved by
Which among the following purification methods is based on the principle of "Solubility" in two different
solvents?
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(1) 2-Aminopentanenitrile
(2) 2-Aminobutanenitrile
(3) 3-Aminobutanenitrile
(4) 3-Aminopropanenitrile
(1) (CH 3
) C
3
+
> CH3 − C H2 > (CH3 )
2
C H >C H3
+ + + +
(2) C H 3
> (CH3 )
2
C H > CH3 − C H2 > (CH3 )
3
C
+ + + +
(3) (CH 3)
3
C> (CH3 )
2
C H > CH3 − C H2 >C H3
(4)
Number of geometrical isomers possible for the given structure is/are _______
A species having carbon with sextet of electrons and can act as electrophile is called
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(1) Extraction
(2) Chromatography
(3) Distillation
(4) Sublimation
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Separation of
spent-lye
Distillation
Chloroform-
D. under reduced IV.
Aniline
pressure
(1)
(2)
(3)
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(4)
The fragrance of flowers is due to the presence of some steam volatile organic compounds called essential oils.
These are generally insoluble in water at room temperature but are miscible with water vapour in vapour
phase. A suitable method for the extraction of these oils from the flowers is _______
(1) crystallisation
(2) distillation under reduced pressure
(3) distillation
(4) steam distillation
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Answer Key
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Solutions MathonGo
Q1
Q2
Q3
Kjeldahl's method is used for estimation of Nitrogen where CuSO acts as a catalyst.
4
Q4
and
Q5
Q6
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Solutions MathonGo
Q7
Q8
shows −R effect, while rest 3 groups shows +R effect via lone pair.
Q9
Millimole of H 2 SO4 → 10 × 2
So Millimole of NH 3 = 20 × 2 = 40
Organic → NH3
Compound 40 Millimole
∴ Mole of N =
40
1000
wt. of N = 40
1000
× 14
= 56%
Q10
Q11
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Solutions MathonGo
Q12
Q13
So;.
is Alicyclic
Q14
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Solutions MathonGo
Q15
Q16
I > II > III, since neutral resonating structures are more stable than charged resonating structure. II > III,
since stability of structure with −ve charge on more electronegative atom is higher.
Q17
Q18
Steam distillation is used for those liquids which are insoluble in water, containing non-volatile impurities and
are steam volatile.
Q19
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Solutions MathonGo
CH(OH)(CN)2 is
Q20
Q21
Q22
The difference in energy between the actual structure and the lowest energy resonance structure for the given
compound is known as resonance energy.
Q23
+
H
2+ +3
Fe −−−−−−−−→ Fe
Conc. H2 SO4
−
SCN
Fe
+3
−−−→ Fe(SCN)3 ( blood red colour )
Appearance of blood red colour indicates presence of both nitrogen and sulphur.
Q24
Q25
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Solutions MathonGo
Q26
Ethanol → 15.9
Phenol → 10
M-Nitrophenol → 8.3
P-Nitrophenol → 7.1
Q27
Cyclohex-2-en-1-ol
Q28
Memory Based
Q29
Due to unsymmetrical.
Q30
it is aromatic species
Q31
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Solutions MathonGo
Q32
Q33
CH2 = CH − CH2 − Cl
3
It is allyl carbon and sp hybridized
Q34
Distance travelled by sample/organic compound
etardation factor =
3.5 −1
= = 7 × 10
Distance travelled by solvent 5
Q35
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Solutions MathonGo
Different Extraction
Different layers are formed which can be separated in funnel. (Theory based).
Q36
Q37
Q38
3 stereocenteres, symmetrical
Q39
Q40
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Solutions MathonGo
Q41
Q42
Fact (NCERT)
Q43
2,3-dibromo-1-phenylpentane
Q44
Steam distillation technique is applied to separate substances which are steam volatile and are immiscible with
water.
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