Top Practice Problem (Atomic Structure)

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Rutherford experiment
Bohr’s model of atom
Bohr’s model of atom
Bohr’s model of atom
Hydrogen spectrum
De Broglie’s Hypothesis
Heisenberg Uncertainty Principle
Photoelectric effect
Quantum model of atom
Nodes
What is the wavelength emitted during the transition of electron in
between two levels of Li2+ ion whose sum is 4 and difference is 2.

A 2.14 x 10-6 cm

B 1.14 x 10-6 cm

C 3 x 10-8 cm

D None
What is the wavelength emitted during the transition of electron in
between two levels of Li2+ ion whose sum is 4 and difference is 2.

A 2.14 x 10-6 cm

B 1.14 x 10-6 cm

C 3 x 10-8 cm

D None
Solution:
The shortest wavelength in H spectrum of Lyman series when
RH = 109678 cm is

A 1002.7 Å

B 1215.67 Å

C 1127.30 Å

D 911.7 Å
The shortest wavelength in H spectrum of Lyman series when
RH = 109678 cm is

A 1002.7 Å

B 1215.67 Å

C 1127.30 Å

D 911.7 Å
Solution:
For shortest wavelength n1= 1 n2=∞

=911.7 Å
Q:The ratio of the difference in energy between the first and the
second Bohr orbit to that between second and third Bohr orbit is

A 1/2

B 1/3

C 27/5

D 4/9
Q:The ratio of the difference in energy between the first and the
second Bohr orbit to that between second and third Bohr orbit is

A 1/2

B 1/3

C 27/5

D 4/9
Q:The ratio of the difference in energy between the first and the
second Bohr orbit to that between second and third Bohr orbit is

Solution :
Q:-The distance between 3rd and 2nd orbit of hydrogen atom is

A 2.646 x 10–8 cm

B 2.116 x 10–8 cm

C 1.058 x 10–8 cm

D 0.529 x 10–8 cm
Q:-The distance between 3rd and 2nd orbit of hydrogen atom is

A 2.646 x 10–8 cm

B 2.116 x 10–8 cm

C 1.058 x 10–8 cm

D 0.529 x 10–8 cm
Solutions:
A hydrogen atom in the ground state is excited by monochromatic radiation
of wavelength λ Å. The resulting spectrum consists of maximum 15 different
lines. What is the wavelength λ ? (RH = 109737 cm-1)

A 937.3 Å

B 1025 Å

C 1236 Å

D None
A hydrogen atom in the ground state is excited by monochromatic radiation
of wavelength λ Å. The resulting spectrum consists of maximum 15 different
lines. What is the wavelength λ ? (RH = 109737 cm-1)

A 937.3 Å

B 1025 Å

C 1236 Å

D None
Solution:
What is the ratio of the velocities of CH4 and O2
molecules so that they are associated with de Broglie
waves of equal wavelength?

A 1:6

B 7:9

C 2:1

D 1:4
What is the ratio of the velocities of CH4 and O2
molecules so that they are associated with de Broglie
waves of equal wavelength?

A 1:6

B 7:9

C 2:1

D 1:4
Solution :

= 2:1
A golf ball has a mass of 4.0 g and a speed of 45 ms-1 .
If the speed can be measured with an accuracy of 2%,
calculate the uncertainty in the position.

A 1.46 x 10-33 m

B 8.46 x 10-33 m

C 21.46 x 10-33 m

D 1.46 x 10-38 m
A golf ball has a mass of 4.0 g and a speed of 45 ms-1 .
If the speed can be measured with an accuracy of 2%,
calculate the uncertainty in the position.

A 1.46 x 10-33 m

B 8.46 x 10-33 m

C 21.46 x 10-33 m

D 1.46 x 10-38 m
Solution :
Which hydrogen like ionic species has wavelength difference between the
first line of Balmer and first line of Lyman series equal to 59.3 x 10–9 m?
Neglect the reduced mass effect.

A Li2+

B He+

C Be3+

D None
Which hydrogen like ionic species has wavelength difference between the
first line of Balmer and first line of Lyman series equal to 59.3 x 10–9 m?
Neglect the reduced mass effect.

A Li2+

B He+

C Be3+

D None
Solution:
Two fast moving particles X and Y are associated with de Broglie wavelength
1 nm and 4 nm respectively. If mass of X is nine times the mass of Y, the
ratio of kinetic energies of X and Y would

A 3:1

B 9:1

C 5:12

D 16:9
Two fast moving particles X and Y are associated with de Broglie wavelength
1 nm and 4 nm respectively. If mass of X is nine times the mass of Y, the
ratio of kinetic energies of X and Y would

A 3:1

B 9:1

C 5:12

D 16:9
Solution:
Two particles A and B are in motion. If the wavelength associated with
particle A is 5 x 10–8 m, calculate the wavelength associated with particle
B if its momentum is half of A.

A 107 m

B 10-7 m

C 10-8 m

D 10-9 m
Two particles A and B are in motion. If the wavelength associated with
particle A is 5 x 10–8 m, calculate the wavelength associated with particle
B if its momentum is half of A.

A 107 m

B 10-7 m

C 10-8 m

D 10-9 m
Solution:
Which of the following statement is true in the context of photoelectric
effect

A The kinetic energy of ejected electrons is dependent on the intensity of


radiation.
B The threshold frequency is same for all metals.

C The number of photoelectrons ejected depends on the frequency of


the incident radiation
D The kinetic energy of the emitted electrons depends on the
frequency of the incident radiation
Which of the following statement is true in the context of photoelectric
effect

A The kinetic energy of ejected electrons is dependent on the intensity of


radiation.
B The threshold frequency is same for all metals.

C The number of photoelectrons ejected depends on the frequency of


the incident radiation
D The kinetic energy of the emitted electrons depends on the
frequency of the incident radiation
Which of the following is the correct representation of plot radial
probability (4π r2 R2 )in Y-axis vs distance from the nucleus in X-axis for
an electron of 4d-atomic orbital?

A B

C D
Which of the following is the correct representation of plot radial
probability (4π r2 R2 )in Y-axis vs distance from the nucleus in X-axis for
an electron of 4d-atomic orbital?

A B

C D
The number of local maxima in the Radial distribution curve of 5d
orbital is

A Zero

B 3

C 2

D 1
The number of local maxima in the Radial distribution curve of 5d
orbital is

A Zero

B 3

C 2

D 1
The number of local maxima in the Radial distribution curve of 5d
orbital is

Solution:
No. of maxima is one more than number of radial nodes.
Hence = n-l = 5-2 = 3
If λ0 and λ be the threshold wavelength and the wavelength of incident
light, the velocity of photoelectrons ejected from the metal surface is

A B

C D
If λ0 and λ be the threshold wavelength and the wavelength of incident
light, the velocity of photoelectrons ejected from the metal surface is

A B

C D
Solution:
For a 3s-orbital

What is the maximum radial distance of node from nucleus

A B

C D
For a 3s-orbital

What is the maximum radial distance of node from nucleus

A B

C D
For a 3s-orbital

What is the maximum radial distance of node from nucleus

Solution:
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