DH LP BTD 2018 19
DH LP BTD 2018 19
DH LP BTD 2018 19
MODULE – 2
First Law of Thermodynamics: Joules experiments, equivalence of heat and 10 Hours
11 work. Statement of the First law of thermodynamics, extension of the First law
to non - cyclic processes
energy, energy as a property, modes of energy,Extension of the First law to
12 control volume; steady flow energy equation(SFEE), important applications.
Second Law of Thermodynamics: limitations of first law of thermodynamics
13 Devices converting heat to work; (a) in a thermodynamic cycle, (b) in a
mechanical cycle
Thermal reservoir, Direct heat engine; schematic representation and
14 efficiency.
Devices converting work to heat in a thermodynamic cycle; reversed heat
15 engine, schematic representation,coefficients of performance.
Kelvin - Planck statement of the Second law of Thermodynamics; PMM I and
16 PMM II,
Clausius statement of Second law of Thermodynamics
17 Equivalence of the two statements; Carnot cycle, Carnot principles.
18 Numericals
19 Numericals
20 Numericals
MODULE – 3
21 Entropy: Clasius inequality, Statement- proof, Entropy- definition, a property
change of entropy, entropy as a quantitative test for irreversibility, principle of
22 increase in entropy,
23 calculation of entropy using Tds relations, entropy as a coordinate.
24 Numericals
25 Numericals
Reversibility: Definitions of a reversible process, reversible heat engine,
26 importance and superiority of a reversible heat engine and irreversible 10 Hours
processes;
27 factors that make a process irreversible, reversible heat engines.
Unresisted expansion, remarks on Carnot’s engine, internal and external
28 reversibility, Definition of the thermodynamic temperature scale.
29 Numericals
30 Numericals
MODULE –4
Pure Substances: P-T and P-V diagrams, triple point and critical points. Sub-
31 cooled liquid, saturated liquid, mixture of saturated liquid and vapor, saturated
vapor and superheated vapor states of pure substance with water as example
Enthalpy of change of phase (Latent heat). Dryness fraction (quality), T-S and
32 H-S diagrams, representation of various processes on these diagrams
Steam tables and its use. Throttling calorimeter, separating and throttling
33 calorimeter.
34 Numericals
35 Numericals
Availability, Irreversibility and General Thermodynamic relations. 10 Hours
36 Introduction, Availability (Exergy), Unavailable energy (anergy), Relation
between increase in unavailable energy and increase in entropy. Gibbs
Maximum work, maximum useful work for a system and control volume,
37 irreversibility, second law efficiency (effectiveness). Gibbs and Helmholtz
functions, Maxwell relations, Clapeyron equation
Joule Thomson coefficient, general relations for change in entropy,enthalpy ,
38 internal energy and specific heats.
39 Numericals
40 Numericals
MODULE –5
Ideal gases: Ideal gas mixtures, Daltons law of partial pressures, Amagat’s law 10 Hours
41 of additive volumes,
evaluation of properties of perfect and ideal gases, Air- Water mixtures and
42 related properties, Psychrometric properties, Construction and use of
Psychrometric chart.
43 Numericals
44 Numericals
45 Real gases – Introduction , Air water mixture and related properties, Van-der
Waal's Equation of state,
46 Van-der Waal's constants in terms of critical properties,
Redlich and Kwong equation of state Beattie-Bridgeman equation , Law of
47 corresponding states,
compressibility factor; compressibility chart. Difference between Ideal and real
48 gases.
49 Numericals
50 Numericals
TEXT BOOKS:
2. Basic and Applied Thermodynamics, P.K.Nag, 2nd Ed., Tata McGraw Hill Pub. 2002
REFERENCE BOOKS:
5. B.K Venkanna, Swati B. Wadavadagi “Basic Thermodynamics, PHI, New Delhi, 2010