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Chemistry
Standard level
Paper 1
11 May 2023
45 minutes
Instructions to candidates
2223 – 6110
12 pages © International Baccalaureate Organization 2023
The Periodic Table
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
1 2
1 H He
1.01 4.00
3 4 Atomic number 5 6 7 8 9 10
2 Li Be Element B C N O F Ne
6.94 9.01 Relative atomic mass 10.81 12.01 14.01 16.00 19.00 20.18
11 12 13 14 15 16 17 18
3 Na Mg Al Si P S Cl Ar
22.99 24.31 26.98 28.09 30.97 32.07 35.45 39.95
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
4 K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
39.10 40.08 44.96 47.87 50.94 52.00 54.94 55.85 58.93 58.69 63.55 65.38 69.72 72.63 74.92 78.96 79.90 83.90
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
–2–
5 Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
85.47 87.62 88.91 91.22 92.91 95.96 (98) 101.07 102.91 106.42 107.87 112.41 114.82 118.71 121.76 127.60 126.90 131.29
55 56 57 † 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
6 Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
132.91 137.33 138.91 178.49 180.95 183.84 186.21 190.23 192.22 195.08 196.97 200.59 204.38 207.2 208.98 (209) (210) (222)
87 88 89 ‡ 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118
7 Fr Ra Ac Rf Db Sg Bh Hs Mt Ds Rg Cn Unt Uug Uup Uuh Uus Uuo
(223) (226) (227) (267) (268) (269) (270) (269) (278) (281) (281) (285) (286) (289) (288) (293) (294) (294)
† 58 59 60 61 62 63 64 65 66 67 68 69 70 71
Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
140.12 140.91 144.24 (145) 150.36 151.96 157.25 158.93 162.50 164.93 167.26 168.93 173.05 174.97
A. amu
B. g
C. mol g-1
D. g mol-1
3. A student heated a known mass of zinc powder in an open crucible until there was no further
mass change and recorded the final mass.
A. I and II only
D. I, II and III
Turn over
–4– 2223 – 6110
4. What is the molar mass of a gas according to the following experimental data?
Temperature 17 °C
Pressure 98 kPa
98 0.220
B.
40.0 8.31 290
40.0 8.31 17
C.
98 0.220
98 220
D.
40.0 8.31 17
A. 8
B. 18
C. 32
D. 50
2-
6. What are the numbers of neutrons and electrons in 32
16S ?
Neutrons Electrons
A. 32 18
B. 16 18
C. 16 16
D. 16 14
–5– 2223 – 6110
s p
A. f
p s
B. d
d p
C. f
s p
D. d
A. I and II only
D. I, II and III
Turn over
–6– 2223 – 6110
9. How many electrons will be gained or lost when the element with electron configuration 1s22s22p3
forms an ionic bond?
10. Which substance is likely to have an ionic lattice structure at 298 K and 100 kPa?
A. low yes
B. low no
C. high no
D. high yes
11. Why does the melting point of the elements decrease down group 1?
12. In which molecule does the central atom have an incomplete octet of electrons?
A. H2Se
B. PH3
C. OF2
D. BF3
–7– 2223 – 6110
13. Which allotrope, oxygen or ozone, has the stronger bond between O atoms, and which absorbs
higher frequency UV radiation in the atmosphere?
A. ozone ozone
B. ozone oxygen
C. oxygen oxygen
D. oxygen ozone
14. What is the enthalpy of combustion of propan-1-ol, in kJ mol-1, according to the following
calorimetry data?
Temperature rise 24 °C
−0.015 4.2 24
A.
0.075
−75 4.2 24
B.
0.015
C.
−0.015 4.2 24
75
−75 4.2 24
D.
0.015 1000
Turn over
–8– 2223 – 6110
15. Which diagram shows the enthalpy change for dissolving solid, X, in water, if the temperature of
the solution decreases?
X (s)
Enthalpy
Endothermic change
A.
X (aq)
Progress of reaction
X (aq)
Enthalpy
Endothermic change
B. X (s)
Progress of reaction
X (aq)
Enthalpy
Exothermic change
C. X (s)
Progress of reaction
X (s)
Enthalpy
Exothermic change
D.
X (aq)
Progress of reaction
–9– 2223 – 6110
Reactants
Enthalpy Products
B. Reaction is reversible
C. A catalyst is used
17. What happens to the average kinetic energy, KE, of the particles in a gas when the absolute
temperature is doubled?
1
KE = mv2
2
A. Increases by a factor of 2
B. Decreases by a factor of 2
C. Increases by a factor of 4
D. Decreases by a factor of 4
18. Which value of the reaction quotient, Q, shows the lowest relative amount of products at
a particular point in time?
A. 4.9 × 10-3
B. 8.2 × 10-3
C. 4.9 × 102
D. 8.2 × 102
Turn over
– 10 – 2223 – 6110
19. Which products are formed from the neutralization of nitric acid by calcium hydroxide?
A. good strong
B. good weak
C. poor strong
D. poor weak
A. NH3 to N2
B. NO2 to NO
C. N2 to AlN
D. NO2 to N2O4
A. CuS
B. Cu2S
C. CuSO3
D. Cu2SO3
– 11 – 2223 – 6110
A. C6H5OH
B. CH3CHO
C. CH3COCH3
D. CH3OCH3
25. Which statement explains the increase in boiling point for the homologous series of the
primary alcohols?
26. Why does benzene undergo substitution more readily than addition?
A. Benzene is unsaturated.
Turn over
– 12 – 2223 – 6110
27. The orange colour disappears when bromine water is added to compound X in the dark.
Which compound is X?
A. Ethene
B. Ethane
C. Ethanol
D. Ethanoic acid
28. What is the percentage error if the enthalpy of combustion of a substance is determined
experimentally to be -2100 kJ mol-1, but the literature value is -3500 kJ mol-1?
A. 80 %
B. 60 %
C. 40 %
D. 20 %
30. Which technique is most likely to be used for identification of functional groups?
A. Combustion analysis
References: