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SAFETY DATA SHEET

calcium hypochlorite
According to the REACH etc. (Amendment etc.) (EU Exit) Regulations 2020 No. 1577, as amended.

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name calcium hypochlorite

CAS number 7778-54-3

EU index number 017-012-00-7

EC number 231-908-7

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Research and development.

Uses advised against Not suitable for human consumption or veterinary purposes.

1.3. Details of the supplier of the safety data sheet

Supplier Molekula Ltd.
Lingfield Way,
Darlington,
DL1 4XX,
United Kingdom
+44 (0) 3302000333
[email protected]

1.4. Emergency telephone number

+44 (0) 7769276927

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (SI 2019 No. 720)
Physical hazards Ox. Sol. 2 - H272

Health hazards Acute Tox. 4 - H302 Skin Corr. 1B - H314 Eye Dam. 1 - H318 STOT SE 3 - H335

Environmental hazards Aquatic Acute 1 - H400

2.2. Label elements

EC number 231-908-7

Hazard pictograms

Signal word Danger

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Hazard statements H272 May intensify fire; oxidiser.

H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H335 May cause respiratory irritation.
H400 Very toxic to aquatic life.

Precautionary statements P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P220 Keep away from combustible materials.
P260 Do not breathe dust.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301+P312 IF SWALLOWED: Call a POISON CENTRE/doctor if you feel unwell.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water or shower.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P370+P378 In case of fire: Use foam, carbon dioxide, dry powder or water fog to extinguish.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/ container in accordance with national regulations.

2.3. Other hazards

This substance is not classified as PBT or vPvB according to current UK criteria.

SECTION 3: Composition/information on ingredients

3.1. Substances
Product name calcium hypochlorite

EU index number 017-012-00-7

CAS number 7778-54-3

EC number 231-908-7

Chemical formula Ca(OCl)2

SECTION 4: First aid measures

4.1. Description of first aid measures

General information Get medical attention if any discomfort continues. Show this Safety Data Sheet to the medical
personnel. Chemical burns must be treated by a physician.

Inhalation Move affected person to fresh air and keep warm and at rest in a position comfortable for
breathing. Maintain an open airway. Loosen tight clothing such as collar, tie or belt. When
breathing is difficult, properly trained personnel may assist affected person by administering
oxygen. Get medical attention. Place unconscious person on their side in the recovery
position and ensure breathing can take place.

Ingestion Rinse mouth thoroughly with water. Give a few small glasses of water or milk to drink. Stop if
the affected person feels sick as vomiting may be dangerous. Never give anything by mouth
to an unconscious person. Place unconscious person on their side in the recovery position
and ensure breathing can take place. Keep affected person under observation. Get medical
attention if symptoms are severe or persist.

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Skin contact It is important to remove the substance from the skin immediately. Rinse immediately with
plenty of water. Continue to rinse for at least 15 minutes and get medical attention. Chemical
burns must be treated by a physician.

Eye contact Rinse immediately with plenty of water. Do not rub eye. Remove any contact lenses and open
eyelids wide apart. Continue to rinse for at least 15 minutes and get medical attention.

Protection of first aiders It may be dangerous for first aid personnel to carry out mouth-to-mouth resuscitation.

4.2. Most important symptoms and effects, both acute and delayed
General information The severity of the symptoms described will vary dependent on the concentration and the
length of exposure.

Inhalation A single exposure may cause the following adverse effects: Severe irritation of nose and
throat. Symptoms following overexposure may include the following: Corrosive to the
respiratory tract.

Ingestion May cause chemical burns in mouth, oesophagus and stomach. Symptoms following
overexposure may include the following: Severe stomach pain. Nausea, vomiting.

Skin contact Causes severe burns. Symptoms following overexposure may include the following: Pain or
irritation. Redness. Blistering may occur.

Eye contact Causes serious eye damage. Symptoms following overexposure may include the following:
Pain. Profuse watering of the eyes. Redness.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media Extinguish with the following media: Use dry powder, dry sand or dry earth to extinguish. Use
fire-extinguishing media suitable for the surrounding fire.

Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire. Carbon dioxide (CO2).
media

5.2. Special hazards arising from the substance or mixture

Specific hazards May cause or intensify fire; oxidiser. This product is toxic. Severe corrosive hazard. Water
used for fire extinguishing, which has been in contact with the product, may be corrosive.

Hazardous combustion Thermal decomposition or combustion products may include the following substances: Very
products toxic or corrosive gases or vapours. Chlorine. Hydrogen chloride (HCl). Oxides of: Calcium.

5.3. Advice for firefighters

Protective actions during Avoid breathing fire gases or vapours. Evacuate area. Keep upwind to avoid inhalation of
firefighting gases, vapours, fumes and smoke. Ventilate closed spaces before entering them. May cause
or intensify fire; oxidiser. Cool containers exposed to heat with water spray and remove them
from the fire area if it can be done without risk. Cool containers exposed to flames with water
until well after the fire is out. Avoid discharge to the aquatic environment. Control run-off water
by containing and keeping it out of sewers and watercourses. If risk of water pollution occurs,
notify appropriate authorities.

Special protective equipment Regular protection may not be safe. Wear chemical protective suit. Wear positive-pressure
for firefighters self-contained breathing apparatus (SCBA) and appropriate protective clothing. Firefighter's
clothing will provide a basic level of protection for chemical incidents.

SECTION 6: Accidental release measures

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6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet. No action shall be
taken without appropriate training or involving any personal risk. Do not touch or walk into
spilled material. Avoid inhalation of dust. Use suitable respiratory protection if ventilation is
inadequate. Avoid contact with skin and eyes.

6.2. Environmental precautions

Environmental precautions Avoid discharge into drains or watercourses or onto the ground. Avoid discharge to the
aquatic environment.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up Wear protective clothing as described in Section 8 of this safety data sheet. Clear up spills
immediately and dispose of waste safely. Do not use sawdust or other combustible material.
This product is corrosive. Provide adequate ventilation. Collect spillage with a shovel and
broom, or similar and reuse, if possible. Collect and place in suitable waste disposal
containers and seal securely. Flush contaminated area with plenty of water. Wash thoroughly
after dealing with a spillage. Dangerous for the environment. Do not empty into drains. For
waste disposal, see Section 13.

6.4. Reference to other sections

Reference to other sections For personal protection, see Section 8. See Section 11 for additional information on health
hazards. See Section 12 for additional information on ecological hazards. For waste disposal,
see Section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Read and follow manufacturer's recommendations. Wear protective clothing as described in
Section 8 of this safety data sheet. Keep away from food, drink and animal feeding stuffs.
Keep container tightly sealed when not in use. This product is corrosive. Immediate first aid is
imperative. Avoid discharge to the aquatic environment. Do not handle until all safety
precautions have been read and understood. Do not handle broken packages without
protective equipment. Do not reuse empty containers.

Advice on general Wash promptly if skin becomes contaminated. Take off contaminated clothing. Wash
occupational hygiene contaminated clothing before reuse.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Store away from incompatible materials (see Section 10). Store locked up. Keep away from
flammable and combustible materials. Keep only in the original container. Keep container
tightly closed, in a cool, well ventilated place. Keep containers upright. Protect containers from
damage.

Storage class Oxidiser storage.

7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure controls/Personal protection

8.1. Control parameters

8.2. Exposure controls

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Protective equipment

Appropriate engineering Provide adequate general and local exhaust ventilation. Ensure the ventilation system is
controls regularly maintained and tested. Good general ventilation should be adequate to control
worker exposure to airborne contaminants. Observe any occupational exposure limits for the
product or ingredients.

Eye/face protection Wear tight-fitting, chemical splash goggles or face shield. If inhalation hazards exist, a full-
face respirator may be required instead.

Hand protection Wear protective gloves. The most suitable glove should be chosen in consultation with the
glove supplier/manufacturer, who can provide information about the breakthrough time of the
glove material. To protect hands from chemicals, wear gloves that are proven to be
impervious to the chemical and resist degradation. Considering the data specified by the
glove manufacturer, check during use that the gloves are retaining their protective properties
and change them as soon as any deterioration is detected. Frequent changes are
recommended.

Other skin and body Wear appropriate clothing to prevent any possibility of skin contact.
protection

Hygiene measures Wash after use and before eating, smoking and using the toilet. Do not eat, drink or smoke
when using this product.

Respiratory protection Ensure all respiratory protective equipment is suitable for its intended use and is ‘UKCA’-
marked. Check that the respirator fits tightly and the filter is changed regularly. Gas and
combination filter cartridges suitable for intended use should be used. Full face mask
respirators with replaceable filter cartridges suitable for intended use should be used. Half
mask and quarter mask respirators with replaceable filter cartridges suitable for intended use
should be used.

Environmental exposure Keep container tightly sealed when not in use. Emissions from ventilation or work process
controls equipment should be checked to ensure they comply with the requirements of environmental
protection legislation. In some cases, fume scrubbers, filters or engineering modifications to
the process equipment will be necessary to reduce emissions to acceptable levels.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance Crystalline powder.

Colour White/off-white.

Odour Not known.

Odour threshold No information available.

pH No information available.

Melting point 100°C/212°F

Initial boiling point and range No information available.

Flash point No information available.

Evaporation rate No information available.

Flammability (solid, gas) No information available.

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Upper/lower flammability or No information available.

explosive limits

Vapour pressure No information available.

Vapour density No information available.

Relative density 2.35 @ 20°C/68°F

Solubility(ies) No information available.

Partition coefficient No information available.

Auto-ignition temperature No information available.

Decomposition Temperature No information available.

9.2. Other information

Molecular weight 142.98

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity See the other subsections of this section for further details.

10.2. Chemical stability

Stability Stable at normal ambient temperatures and when used as recommended. Stable under the
prescribed storage conditions.

10.3. Possibility of hazardous reactions

Possibility of hazardous Contact with acids liberates toxic gas.
reactions

10.4. Conditions to avoid

Conditions to avoid Avoid excessive heat for prolonged periods of time.

10.5. Incompatible materials

Materials to avoid Reducing agents. Flammable/combustible materials. Hydrocarbons. Organic cyanides
(nitriles). Esters. Some metals. Acids.

10.6. Hazardous decomposition products

Hazardous decomposition Does not decompose when used and stored as recommended. Thermal decomposition or
products combustion products may include the following substances: Corrosive gases or vapours.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity - oral
Summary Harmful if swallowed.

ATE oral (mg/kg) 500.0

Acute toxicity - dermal

Summary Based on available data the classification criteria are not met.

Acute toxicity - inhalation

Summary Based on available data the classification criteria are not met.

Skin corrosion/irritation
Summary Causes severe skin burns and eye damage.

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Serious eye damage/irritation

Summary Causes serious eye damage.

Respiratory sensitisation
Summary Based on available data the classification criteria are not met.

Skin sensitisation
Summary Based on available data the classification criteria are not met.

Germ cell mutagenicity

Summary Based on available data the classification criteria are not met.

Carcinogenicity
Summary Based on available data the classification criteria are not met.

IARC carcinogenicity None of the ingredients are listed or exempt.

Reproductive toxicity
Summary Based on available data the classification criteria are not met.

Specific target organ toxicity - single exposure

Summary May cause respiratory irritation.

Target organs Respiratory system, lungs

Specific target organ toxicity - repeated exposure

Summary Based on available data the classification criteria are not met.

Aspiration hazard
Summary Not relevant. Solid.

General information The severity of the symptoms described will vary dependent on the concentration and the
length of exposure.

Inhalation Corrosive to the respiratory tract. Symptoms following overexposure may include the
following: Severe irritation of nose and throat.

Ingestion May cause chemical burns in mouth, oesophagus and stomach. Symptoms following
overexposure may include the following: Severe stomach pain. Nausea, vomiting.

Skin contact Causes severe burns. Symptoms following overexposure may include the following: Pain or
irritation. Redness. Blistering may occur.

Eye contact Causes serious eye damage. Symptoms following overexposure may include the following:
Pain. Profuse watering of the eyes. Redness.

Route of exposure Ingestion Inhalation Skin and/or eye contact

Target organs Respiratory system, lungs

SECTION 12: Ecological information

12.1. Toxicity
Acute aquatic toxicity
Summary Very toxic to aquatic life.

M factor (Acute) 10

Acute toxicity - fish LC₅₀, 96 hours: 0.049 - 0.16 mg/l, Lepomis macrochirus (Bluegill)

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Acute toxicity - aquatic EC₅₀, 48 hours: 0.067 mg/l, Daphnia magna

invertebrates

Acute toxicity - aquatic plants IC₅₀, 72 hours: 2 mg/l, Algae

Chronic aquatic toxicity

Summary Based on available data the classification criteria are not met.

12.2. Persistence and degradability

Persistence and degradability The degradability of the product is not known.

12.3. Bioaccumulative potential

Bioaccumulative potential No data available on bioaccumulation.

Partition coefficient No information available.

12.4. Mobility in soil

Mobility No data available.

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

12.6. Other adverse effects

Other adverse effects None known.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

General information The generation of waste should be minimised or avoided wherever possible. Reuse or recycle
products wherever possible. This material and its container must be disposed of in a safe
way. When handling waste, the safety precautions applying to handling of the product should
be considered. Care should be taken when handling emptied containers that have not been
thoroughly cleaned or rinsed out. Empty containers or liners may retain some product
residues and hence be potentially hazardous.

Disposal methods Do not empty into drains. Dispose of surplus products and those that cannot be recycled via a
licensed waste disposal contractor. Waste, residues, empty containers, discarded work
clothes and contaminated cleaning materials should be collected in designated containers,
labelled with their contents. Incineration or landfill should only be considered when recycling is
not feasible.

SECTION 14: Transport information

General For limited quantity packaging/limited load information, consult the relevant modal
documentation using the data shown in this section.

14.1. UN number
UN No. (ADR/RID) 1748

UN No. (IMDG) 1748

UN No. (ICAO) 1748

UN No. (ADN) 1748

14.2. UN proper shipping name

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Proper shipping name CALCIUM HYPOCHLORITE, DRY or CALCIUM HYPOCHLORITE MIXTURE, DRY
(ADR/RID)

Proper shipping name (IMDG) CALCIUM HYPOCHLORITE, DRY or CALCIUM HYPOCHLORITE MIXTURE, DRY

Proper shipping name (ICAO) CALCIUM HYPOCHLORITE, DRY or CALCIUM HYPOCHLORITE MIXTURE, DRY

Proper shipping name (ADN) CALCIUM HYPOCHLORITE, DRY or CALCIUM HYPOCHLORITE MIXTURE, DRY

14.3. Transport hazard class(es)

ADR/RID class 5.1

ADR/RID classification code O2

ADR/RID label 5.1

IMDG class 5.1

ICAO class/division 5.1

ADN class 5.1

Transport labels

14.4. Packing group

ADR/RID packing group II

IMDG packing group II

ICAO packing group II

ADN packing group II

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

14.6. Special precautions for user

Always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to
do in the event of an accident or spillage.

IMDG Code segregation 8. Hypochlorites

group

EmS F-H, S-Q

ADR transport category 2

Emergency Action Code 1W

Hazard Identification Number 50

(ADR/RID)

Tunnel restriction code (E)

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code

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Transport in bulk according to Not applicable.

Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations Health and Safety at Work etc. Act 1974 (as amended).
The Carriage of Dangerous Goods and Use of Transportable Pressure Equipment
Regulations 2009 (SI 2009 No. 1348) (as amended) ["CDG 2009"].
EH40/2005 Workplace exposure limits.

15.2. Chemical safety assessment

No chemical safety assessment has been carried out.

Inventories
EU - EINECS/ELINCS
None of the ingredients are listed or exempt.

SECTION 16: Other information

Abbreviations and acronyms ADR: European Agreement concerning the International Carriage of Dangerous Goods by
used in the safety data sheet Road.
ADN: European Agreement concerning the International Carriage of Dangerous Goods by
Inland Waterways.
RID: European Agreement concerning the International Carriage of Dangerous Goods by Rail.
IATA: International Air Transport Association.
ICAO: Technical Instructions for the Safe Transport of Dangerous Goods by Air.
IMDG: International Maritime Dangerous Goods.
CAS: Chemical Abstracts Service.
ATE: Acute Toxicity Estimate.
LC50: Lethal Concentration to 50 % of a test population.
LD50: Lethal Dose to 50% of a test population (Median Lethal Dose).
EC₅₀: 50% of maximal Effective Concentration.
PBT: Persistent, Bioaccumulative and Toxic substance.
vPvB: Very Persistent and Very Bioaccumulative.

Classification abbreviations Ox. Sol. = Oxidising solid

and acronyms Acute Tox. = Acute toxicity
Eye Dam. = Serious eye damage
Skin Corr. = Skin corrosion
STOT SE = Specific target organ toxicity-single exposure
Aquatic Acute = Hazardous to the aquatic environment (acute)

Classification procedures Acute Tox. 4 - H302: Eye Dam. 1 - H318: Skin Corr. 1B - H314: STOT SE 3 - H335: : Expert
according to SI 2019 No. 720 judgement. Aquatic Acute 1 - H400: : Expert judgement. Ox. Sol. 2 - H272: : Expert
judgement.

Training advice Only trained personnel should use this material.

Revision date 31/08/2022

Revision 1

SDS number 1418

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Hazard statements in full H272 May intensify fire; oxidiser.

H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H335 May cause respiratory irritation.
H400 Very toxic to aquatic life.

This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or
completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

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