Date: 2014/08/27 – Review: 02

In accordance to NBR 14725-4:2012

MSDS (Material Safety Data Sheet)

BIOEXTRACT ARNICA HG
1 – IDENTIFICATION

Product name : BIOEXTRACT ARNICA HG

Product code : XF6495
Recommended use of the product : Ingredient for cosmetic formulations.
Supplier name : AQIA Química Industrial Ltda.
Address : Rua Rosa Mafei, 563-Bonsucesso- Guarulhos-SP
Contact phone number : 55 11 2436-3133 (Monday to Friday, 8 AM to 5.30 PM
Emergency phone number : 55 11 2436-3133 (Monday to Friday, 8 AM to 5.30 PM
Fax number : 55 11 2436-2145
E-mail : [email protected]

2 – COMPOSITION / INFORMATION ON INGREDIENTS

MIXTURE
 Chemical name: Arnica Hydroglycolic Extract

 INCI name:
(1)
Arnica Montana Flower Extract [EU]
(2)
Arnica Montana Flower Extract [US]

 CAS number:
(1)
68990-11-4 [EU]
(2)
68990-11-4 [US]

 EINCES number:
(1)
273-579-2 [EU]
(2)
273-579-2 [US]

3 – HAZARD IDENTIFICATION

HEALTH HAZARD DATA

 Swallowing: Harmful effects are not expected.
 Skin absorption: In a short period, it is not expected a harmful effect.
 Inhalation: Avoid inhalation. In a short period of time it is not expected a harmful effect.
 Eye Contact: Avoid eye contact. It may cause discomfort and redness.

OTHER EFFECTS OF OVEREXPOSURE: There is no reference.

4 – FIRST-AID MEASURES

FIRST-AID MEASURES
 Swallowing: Normally it is not necessary emergency cares. If accidentally ingested, do not induce
vomit. If some discomfort occurs and persists consult a doctor.
 Inhalation: If some discomfort or irritation occurs and persists consult a doctor.
 Eye contact: Wash with plenty of water for several minutes (more or less 15). If some irritation
persists, consult an ophthalmologist.
 Skin Contact (pure): Wash with plenty of water and soap or detergent.

Bioextract Arnica HG - Page 1 of 5

AQIA QUÍMICA INDUSTRIAL LTDA.
Production plant: R. Rosa Mafei, 563 - Bonsucesso - Cep: 07177-110 - Guarulhos/SP - Tel.: 55 11 2436 3133
Office: Av. Vereador José Diniz, 3651 – 7º andar - Cep: 04603-003 - Campo Belo - São Paulo/SP - Tel.: 55 11 5094 9911
WWW.AQIA.NET
 Date: 2014/08/27 – Review: 02
In accordance to NBR 14725-4:2012

MSDS (Material Safety Data Sheet)

5 – FIRE-FIGHTING MEASURES

FLASH POINT (Open Glass): 70°C

INFLAMMABILITY: It is not inflammable.
INFLAMMABILITY LIMIT IN AIR: It is not inflammable.
EXTINCTION OF FIRE: In case of fire, use: water, foam extinguisher, CO2 extinguisher, chemical powder.
SPECIAL FIRE-FIGHTING PROCEDURES: Use autonomous respiratory equipment, protective clothes
and gloves.

6 – ACCIDENTAL RELEASE MEASURES

STEPS TO BE TAKEN IF THE MATERIAL IS RELEASED OR SPILLED: Absorb the product in with
absorbent material. Wash the contaminated area with detergent or soap and plenty of water.
WASTE DISPOSAL METHOD: Observe government regulations. Follow local regulation.

7 – HANDLING AND STORAGE

HANDLING
a) Technical Advice: ----------
b) Precautionary measures: Avoid eye contact.
c) Security and specific manipulation measures: Wear protective gloves and safety glasses.

STORAGE
a) Storage condition: Store in dry area. Keep in original container, tightly closed. Protect from humidity,
light and heat (under 35ºC).
b) Shelf life: Product valid for 24 months starting from the manufactured date.
NOTE: DURING STORAGE IT MAY GET TURBID, BUT THIS WILL NOT INVALIDATE THE PRODUCT.

8 – EXPOSURE CONTROLS / PERSONAL PROTECTION

STEPS IN ORDER TO REDUCE THE POSSIBILITY OF EXPOSITION: Wear Industrial Uniform.

CONTROL MEASURE: It is not necessary control and special protection.
PRUDENT PERMISSION LIMIT (PPL) AND ABSOLUTE (APL): There is no reference.

INDIVIDUAL PROTECTION MEASURES

a) Respiratory protection: Normal.
b) Protection gloves: Rubber or other impermeable material.
c) Eyes protection: Safety glasses.
d) Other equipment of protection: Emergency shower and eye-washer.
e) Ventilation: Normal.

9 – PHYSICAL AND CHEMICAL PROPERTIES

- Aspect (25ºC) : Liquid

- Color : Pale amber
- Density (25ºC) : 1.015 – 1.050
- Refractive Index (25ºC) : 1.318 – 1.478
- pH sol. 100 % (25º C) : 5.0 – 6.0
- Microbial limits bacteria : Max. 100 col/ g
- Microbial limits molds : Max. 100 col/ g

- Boiling point : 90°C

- Volatile contents : Max. 99%
- Odor : Characteristic

Bioextract Arnica HG - Page 2 of 5

AQIA QUÍMICA INDUSTRIAL LTDA.
Production plant: R. Rosa Mafei, 563 - Bonsucesso - Cep: 07177-110 - Guarulhos/SP - Tel.: 55 11 2436 3133
Office: Av. Vereador José Diniz, 3651 – 7º andar - Cep: 04603-003 - Campo Belo - São Paulo/SP - Tel.: 55 11 5094 9911
WWW.AQIA.NET
 Date: 2014/08/27 – Review: 02
In accordance to NBR 14725-4:2012

MSDS (Material Safety Data Sheet)

10 – STABILITY AND REACTIVITY

CHEMICAL STABILITY: Stable if kept at room temperature and in the original closed packing.

CONDITIONS TO AVOID: High temperatures.

HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS: Burning may produce carbon

monoxide and/or carbon dioxide. NOTE: The carbon monoxide is highly toxic if inhaled. The carbon
dioxide in high concentration may be asphyxiating. Overexposure to the combustion products may cause
irritation on respiratory organs.

HYDROLYSIS: It is not applicable.

11 – TOXICOLOGICAL INFORMATION

a) Acute toxicity: Low toxicity. No harmful effects are expected.

b) Chronic toxicity or long time: There is no reference.
c) Local effects: There is no reference.
d) Allergenic sensibility: There is no reference.

12 – ECOLOGICAL INFORMATION

a) Ecotoxicity: There is no reference.

b) Persistence and degradability: It is biodegradable.
c) Bioaccumulative potential: It does not occur.
d) Environmental effects: There is no reference.

13 – DISPOSAL CONSIDERATIONS

Recommended methods for treatment and disposal:

a) Waste disposal method: Incineration.
b) Contaminated packaging disposal: The packing must not be reused. The plastic material can be
recycled or incinerated.

14 – TRANSPORT INFORMATION

NATIONAL AND INTERNATIONAL REGULATIONS

a) Land
Decreto nº 96.044:1988 – Aprova o Regulamento para o Transporte Rodoviário de Produtos
Perigosos e dá outras providências (Decree nº 96.044:1988 - the Regulation for the Road Transport of
Dangerous Products and the other steps Approves).
Resoluções ANTT nº 420:2004, 701:2004, 1644:2006, 2657:98, 2975:08 e 3383:2010 (Resolutions
ANTT nº 420:2004, 701:2004, 1644:2006, 2657:98, 2975:08 and 3383:2010).
b) Waterways
DPC – Diretoria de Portos e Costas - Transporte em Águas Brasileiras ( DPC - Direction of Ports and
Coasts - Transport in Brazilian Waters).
Normas de Autoridade Marítima – NORMAM (Norms of Maritime authorities).
NORMAM 01/DPC: Embarcações Empregadas na Navegação em Mar Aberto (Boats Used in the
Navigation in Open Sea).
NORMAM 02/DPC: Embarcações Empregadas na Navegação Interior (Boats Used in the Inland
navegation).
IMO – “International Maritime Organization” (Organização Marítima Internacional)
International Maritime Dangerous Goods Code (IMDG Code).
c) Air

Bioextract Arnica HG - Page 3 of 5

AQIA QUÍMICA INDUSTRIAL LTDA.
Production plant: R. Rosa Mafei, 563 - Bonsucesso - Cep: 07177-110 - Guarulhos/SP - Tel.: 55 11 2436 3133
Office: Av. Vereador José Diniz, 3651 – 7º andar - Cep: 04603-003 - Campo Belo - São Paulo/SP - Tel.: 55 11 5094 9911
WWW.AQIA.NET
 Date: 2014/08/27 – Review: 02
In accordance to NBR 14725-4:2012

MSDS (Material Safety Data Sheet)

DAC – Departamento de Aviação Civil: IAC 153–1001. Instrução de Aviação Civil – Normas para o
transporte de artigos perigosos em aeronaves civis (DAC - Department of Civil Aviation: IAC 153-
1001. Instruction of Civil Aviation - Norms for the dangerous article transport in civil aircraft).
IATA – “International Air Transport Association” (Associação Internacional de Transporte Aéreo)

CLASSIFICATION OF DANGEROUS GOODS FOR TRANSPORTATION

 Classification: It is not classified in RID/AD – ADNR – IMDG – ICAO/IATA DGR.
 UN number: Not classified as hazardous for transport.

15 – REGULATORY INFORMATION

Product is not classified as hazardous material by legislation of hazardous products.

 Hommel Diamond
Health = 0
Fire = 2 2
Reactivity = 0
Specific Risks = 0 0
0
0

16 – OTHER INFORMATION

AQIA Química Industrial Ltda. recommends the user to read carefully this Material Safety Data Sheet
(MSDS) in order to know the hazards associated to the product. The MSDS presents safety information in
product handling. The information herein is given in good faith, without thereby incurring any liability,
express or implied. It is the user's responsibility to ensure that their activities comply with local, federal,
state, and municipal regulations. The information presented here pertains only to the product in its original
container. It is obligation of the user to use or determine that the product is handled safely.

REFERENCES
1. CosIng, Europe (http://ec.europa.eu/consumers/cosmetics/cosing/index.cfm?fuseaction=search.simple)
th
2. International Cosmetic Ingredient Dictionary and Handbook, 15 edition, 2014, USA.

ABBREVIATIONS

 ABNT (Associação Brasileira de Normas Técnicas) – Brazilian Association of Technical Norms

 ACGIH (American Conference of Governmental Industrial Hygienists) - Conferência Americana de
Higienistas Industriais Governamentais
 ANTT (Agência Nacional de Transportes Terrestres) – National Agency of Land Transport
 CAS – Chemical Abstract Service
 DAC (Departamento de Aviação Civil) – Civil Aviation Department
 DL0 – It is the maximum dosage tested that does not cause death in a test population.
 DL50 (Dose Letal Mediana): Lethal Dose 50% - It is the necessary dosage of a determined
substance to kill 50 % of the testing population.
 DPC (Diretoria de Portos e Costas) – Directorate of Ports and Coasts
 EINECS (European Inventory of Existing Chemical Substances) – Inventário Europeu de
Substâncias Químicas Existentes
 FISPQ (Ficha de Informações de Segurança de Produtos Químicos) – MSDS
 GHS (Global Harmonized System) – Sistema Globalmente Harmonizado para a Classificação e
Rotulagem de Produtos Químicos.
 IATA (International Air Transport Association) – Associação Internacional de Transporte Aéreo
Bioextract Arnica HG - Page 4 of 5
AQIA QUÍMICA INDUSTRIAL LTDA.
Production plant: R. Rosa Mafei, 563 - Bonsucesso - Cep: 07177-110 - Guarulhos/SP - Tel.: 55 11 2436 3133
Office: Av. Vereador José Diniz, 3651 – 7º andar - Cep: 04603-003 - Campo Belo - São Paulo/SP - Tel.: 55 11 5094 9911
WWW.AQIA.NET
 Date: 2014/08/27 – Review: 02
In accordance to NBR 14725-4:2012

MSDS (Material Safety Data Sheet)

 IMDG (International Maritime Dangerous Goods Code) – Código Internacional Marítimo para
Materiais Perigosos
 IMO (International Maritime Organization) – Organização Internacional Marítima
 INCI (International Nomenclature of Cosmetic Ingredients) – Nomenclatura Interncional para
Ingredientes Cosméticos
 LD0 (Lethal Dose 0) – É a dose máxima testada que não provoca mortalidade em uma população
em teste. / It is the maximum dosage tested that does not cause death in a test population.
 LD50 (Lethal Dose 50%) - It is the necessary dosage of a determined substance to kill 50 % of the
testing population.
 MTE (Ministério do Trabalho e Emprego) – Ministry of Work and Employment
 NBR (Norma Brasileira) – Brazilian Norm
 NIOSH (National Institute for Occupational Safety and Health) – Instituto Nacional para Segurança
Ocupacional e de Saúde
 NORMAM (Normas de Autoridade Marítima) – Maritime Authority Norms
 NR – Normas Regulamentadoras (do Ministério do Trabalho e Emprego) – Regulatory Norms (of
Ministry of Work and Employment)
 OIT (Organização Internacional do Trabalho) – International Work Organization
 ONU (Organização das Nações Unidas) – United Nations Organization
 OSHA (Occupational Safety & Health Administration) – Segurança Ocupacional e Administração
de Saúde
 ppb – Partes Por Bilhão / Parts-per-bilion
 ppm – Partes Por Milhão / Parts-per-milion

Bioextract Arnica HG - Page 5 of 5

AQIA QUÍMICA INDUSTRIAL LTDA.
Production plant: R. Rosa Mafei, 563 - Bonsucesso - Cep: 07177-110 - Guarulhos/SP - Tel.: 55 11 2436 3133
Office: Av. Vereador José Diniz, 3651 – 7º andar - Cep: 04603-003 - Campo Belo - São Paulo/SP - Tel.: 55 11 5094 9911
WWW.AQIA.NET