5

SULFUR AND SULFURIC ACID

Pressure
Filter Contaminants) Insulated
Barges
Tark
and
Cars
(Optional
for Storagel
MOlten Shipment
Rernoving Sulfur

Separator
Phase

100000-500,000T
Capacity
Sump proces
Vats
Solidification
and
Rail
Water
Shiprment Frasch
by
mining
Steam
sulfur
melted
by hot
water Eleme
Sulfur

r60-18C
atms to Bearing
25 Stringer
Pipe
Bleed
water
Deposit for
to
well IlA-l
Fig.
Water Sulfur recovery

Air Aerators
Fuel
(Contains
scale
Water
Wastesalt
forming
and
HS)
Treated
Water
 †INVÐAONI TVOINEH† SETALSnINI

Waste Scrubber Scrubber

Condenser to
S
Moten
26oC
Reactor 2nd
Surme
150C
H,S.
90-95% of
Yield oxidatio
HoCondenser
ACatalyst
15C
-Secondary Sulfur
to
Solidification
Sutfur
by
Air Bauxite Corversion Molten productio
Shipnent
70-80%
400c
sOiHs,
Air Reoctor or Sulfur
1st Vats
300C IA-2.

Fig.
Furnace

Steam
4
Process
 Dearserator
Wastecayty0
Gases
Stack Moten to
shipping
SULFUR to
steel
plart
Tower HWash IRON
ORE
HO
HsO
Plant
to
SULFUR
DIOXIDE
ELECTRICITY
Molten
S (O.7atms
ProcesS
Steam

Condenser Waste
Arsenic Fe203
Turbo-Generator pyrites.

15c from
45atmsSteam dioxide
60atms
Steam
HoRor sulfur
70ams
Steam 60dC H20 Air
and
Sulfur

Roaster IlA-3.
FUIdized
Superheater Fig.
200meshAir
Air Plant
HzSQ
Shipped
to
Fuel SeparatorSmelter FeS H20
Molten FeS
ollector
Iron
Pyrites Fese Granulator
ositior OWer

Limestone
Fyel
Oil
62
-97%t4,SQ INORGANIC CHEMICAL INDUSTRIES

98%
H2So4 process.
Storage
Spent
Gases
contact
os %B
HChillers
Cooled
Water
Pipe by
oleum
Storage
Oleum
and
JCooler acid
Air sulfuric

Stean of
manufacture
Soot
500-6od
zznz 4oo40c|
for
Steam Cataytic
Two
Sagel sheet
Converter flow
Ho
engineering

Burner Simplified
Dryer
Air
IIA-4.
Storage Fig.
Molten
Sulfur
Air
 180
CHLOR-ALKALI INDUSTRY
Rotary
Fiter
Ash
Soda Press
Gas
Fue
Hy0 Fuel"Airt
Calciner Water
Cooler impurities
CaCh
Waste

-Cooling
Water
J•SU•PUCD
Co2
OHN process.

Solvay

by
ash
f)
purifier soda
J•mOL
6upauoeSDE) of
Manufacture
brine NH3
Recycle Lime
ofMilk

to (t)
IH-1.
cO.N Make-up
NH3 Fig.
recycle
NH3 Saker
0.5
kg/
kg d)
Product
Kiln (b)
Lime (C)

Purified
Solution Limestone
Brine Coke
Air
 ITVINNOTHD KALSOTNI 66

and/or
Purification
for
Caustic
50l%
Concentration

Effect
Multiple Surry
Evaporators Salt production.
Centrifuge Depleted
4Steam Salurotor Brine
Salt soda
chlorine-caustic
Filter
SeeFgIH Cell
Meren
H-3A
Diaphragm
Cel! 3B Chlorine
Wet Constant
for
Tank
Feed
Head
See
OWe
H0 process
Denuding
Steam
Fiter Electrolytic
Filter Concentration
H0 70%Caustic
direct IIH-2.
sale
or

Prfier
Brine
Sudge
Dryer -30°cLgidCl2
for Fig.

Storage
Brine
from
Wells
Refrigeránito
Freon
 Fig. IIH-3. Various caustic/chlorine cell configurations.

pure brne chlorine

depleled
brine anode

Na

Na-amalgam
NaHg

A. Schematic representation of the eléctrolysis of aqueous salt solutions by the mercury

Cl, 4 H,

pure brine
H cell ligUor
Na

Na'i
OH

asbesi0s diaphragm

B. Schematic representation of the electrolysis of aqueous salt solutions by the diaphragm

Scanned by CamScanner

202 INORGANIC CHEMICAL INDUSTRIES

CI, | H,
depleted
brine NaOH
|C
Na'
Na
CI
Qure brine H,0
OH

membrane

C.
Schematic epresentation of the electrolysis of aqueous salt solutions by the membrane
process.
 CEMENT AND LIME 221

Beneficiaied
SurrY
Rotary
to
Kilns

Froth+Float
Water
Reagent
Recovered

Fines
Hydroseparator
beneficiatio

Agent
Frothing Air Air Recirculated
Process
WNater

Homogenizet Limestone

IIK-l.
Mineral
Rejects
Fig.
Classifier
Rake Cells
Enriching
2 Cells
Stripping
3.
SEPERATOR
Cells
Beater
Roclone Pulverizer HYDRO Cells
Flotation

Make-up 1.
Lime Water
Raw
Staçt
 CEMENT AND LIME 223
-Flue
Gases

Shippng
and
Bagging

Mill
TWo Cement
Tube
to
with
Compartment
Stack
To Cooler Circuit
Classifiers
Air
Kiln
manufacture.
Closed
Four
Heat in cement
Waste
Air Tails
Boiler Portland

Tails
Fines
IIK-2.
Circuit
Closed
Beneficiated.
Rock
SluryRotary Wet-grind Screen>
Perpheral
Fig.
Filter

Pulverizer
Limestone
Grade
High
Tube
Mill Storage
Clinker
"Clay

Start