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    WINSEM2022-23 CHE4001 ELA VL2022230501352 2022-12-21 Reference-Material-I

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    WINSEM2022-23 CHE4001 ELA VL2022230501352 2022-12-21 Reference-Material-I

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    WINSEM2022-23_CHE4001_ELA_VL2022230501352_2022-12-21_Reference-Material-I

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    WINSEM2022-23 CHE4001 ELA VL2022230501352 2022-12-21 Reference-Material-I

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    of 3

    Expt No: 5 Date:

    VAPOR – LIQUID EQUILIBRIA

    AIM

    To construct the equilibrium and boiling point diagrams for the given binary system.

    APPARATUS

    VLE Setup, Specific gravity bottles, Refractometers and Beakers.

    SYSTEM

    Toluene – CCl4

    CHEMICALS

    Toluene – CCl4

    INTRODUCTION

    Distillation is a technique used for separation of components of liquid mixture in a


    closed system. The vapor liberated from a liquid mixture will be in equilibrium and the
    composition depends on the concentration of liquid phase. The relation between x,
    concentration of one component in liquid phase and y, the concentrations of that component in
    vapor phase at equilibrium, is the vapor – liquid equilibrium curve which is determined at the
    boiling point corresponding to partial pressure.

    A diagram representing the boiling temperature of a mixture of liquids, completely


    miscible with each other against the composition of vapor and liquid equilibrium is called t –
    xy diagram. The boiling points are plotted as ordinate and the mole fraction of more volatile
    component in vapor and liquid as abscissa. The diagram consists of two curves, the ends of
    which coincide. One curve, representing the vapor and the other liquid composition. Any point
    below the lower curve represents entirely liquid phase points. Between the two curves,
    represent partially vapor and partially liquid state of mixture.

    PROCEDURE

    Prepare a standard plot of specific gravity / refractive index Vs. Mole Fraction of more
    volatile component by preparing different composition of components A and B and charge the
    contents in to the VLE still. Switch on the electrical energy input. As the boiling proceeds, the
    vapors collect in the vapor receiver and the samples of vapor and liquid and note the
    composition by using standard plot and record the T-x-y Values. Repeat the experiment at
    different compositions by withdrawing a known quantity from the still and add the same
    amount of pure liquid to the still. After attaining the equilibrium note down the T – x y values
    as above.

    TABLE – 1

    Standard Graph

    S.No g. moles of A g. moles of B Mole Fraction of A Rl / Sp.gr.


    TABLE – 2

    S.No Sp.gr / RI Mole fr. Of Mole fr. Of A Temp.


    . Feed A in liquid: in vapor
    Mole fr. Mole fr. Sp.gr / Liq. Vap.
    Of A Of B RI

    RESULT

    Construct the Equilibrium and boiling point diagrams for the given binary system.

    ANALYSIS OF RESULTS/CONCLUSIONS:

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