46.

In X number of electrons are 18, and its

atomic mass is 31. Then number of neutrons
present in X will be :

(1) 18 (2) 21
(3) 16 (4) 13
47. Which of the following are isodiaphers ?
(1) B',C (2) K, zCa
(3) H, He (4) None of these
48. Discovery of the nucleus of an atom was due to
the experiment carried out by
(1) Bohr (2) Mosley
(3) Rutherford (4) Thomson

49. Which one of the following constitutes a group

of the isoelectronic species :
(1) NO,C?,CN , N;
(2) CN ,N2, 03,c?
(3) N2, 0;, NO,Co
(4) C;,0,, Co, NO
50. Let mass of electron is half, mass of proton is two
times and mass of neutron is three fourth of original.
Then find out new atomic weight of C" atom
(1) increase by 12.5%
(2) decrease by 25%

(3) increase by 37.5%

(4) decrease by 37.5%
51. Splitting of spectral lines under the influence of
magnetic field is called :

() Zeeman effect
(2) Stark effect
(3) Photoelectric effect

(4) None of these

52. Wavelength of electromagnetic wave having
frequency 3 x 10'* sec' is :
(1) 1A (2) 10 m
(3) 10l m (4) 10-l0 A
53. The energy of second Bohr's orbit in H-atom is
-328 kJ mol, hence the energy of fourth
Bohr's orbit would be ?

(1) -82.25 kJ mol!

(2) -41 kJ mol

(3) -1312 kJ mol

(4) -164 kJ mol
54. According to Bohr's theory, the angular
momentum for an electron of 5th orbit is ?
() 2.5h Sh
(2)
25h 6h
(3) (4) 3
55. For any H-like system, the ratio of velocities of

I, II &I orbit i.e. V,:V,:V, will be :

(1) 1:2:3
(2) 1:1/2: 1/3
(3) 3:2:1
(4) 1:1l:1
56. The angular momentum of an electron in a
given stationary state can be expressed as
h
Based on this expression an
27
electron can move only in those orbits for
which its angular momentum is
(1) equal to n
h
(2) Integral multiple of 27
(3) Multiple of n
h
(4) equal to only.
57. Frequency of revolution (f) of electron is :

) r«
n
3) ra (4) f< 7
58. The radius of hydrogen atom in ground state is
0.53 Å. What will be the radius of L in the
ground state ?

(1) L.06 A (2) 0.265 A

(3) 0.17 ¢ (4) 0.53 Å
59 Velocity of electron in 2nd orbit of Be will be :
(1) 4.36 x 10 m/s
(2) 4.36 m/s
(3) 2.18 x 10° m/s
(4) 9.8 x 10 m/s

60 In a hydrogen atom, the electron is at a distance

of 4.768 Å from the nucleus. The angular
momentum of the electron is :
3h h
() (2) (3) (4)
2
61. Which Transition in H-atom gives visible
radiation ?

(1) 5’ 3 (2) 6 ’ 1

(3) 3 ’ 2 (4) 6’5

62 The wavelength of line having maximum wavelength
of paschen series in spectrum ofLi ion is ;
1 144
(1) R (2)
7R
16
(3) R (4) 7R
16
63. Calculate number of absorbed lines when
electron jumps from n= I ton=4?
(1) 1 (2) 2
(3) 4 (4) 6
64. The ratio of the frequency corresponding to the
third line in Lyman series of hydrogen atomic
spectrum to that of the first line in Balmer
series ofLi" spectrum is i
(1) 4/5 (2) 5/4 (3) 4/3 (4) 3/4
65. If electron in H-atom, fall down from 5h energy
state to first excited state how many lines are
obtain in ultraviolet region :
(1) 4 (2) 3
(3) 1 (4) zero
66 From the following transitions of hydrogen
atom the one which gives an absorption line of
lowest frequency is:
(1) n= l to n =2
(2) n= 3 to n = 8
(3) n=2 to n = 1

(4) n= 8 to n =3
67. In H-atom which of the following expressions
represents the spectrum of Balmer series. (Ifn
is the principal quantum number of higher
energy level in hydrogen atom) ?

(1) ù = R(n 1)(n +1)

n2

(2) V=
R(n - 2)(n +2)
4n2

(3) ¼ =
R(n 2)(n + 2)
n?

(4) ù R(n 1(n+ 1)

4n2
68. If the De-Broglie wavelength of 3 Bohr orbit
of H-atom is 3Å, the circumference of the orbit
will be :
(1) 9A (2) 16 A (3) 3A (4) 6A
69 What is the maximum wavelength for the line
in the Lyman series of He* ion?
(1) 3R (2) 1/3R
(3) 1/R (4) None of these
70. The wavelength of electron wave in two orbit is 3 :5.
The ratio of kinetic energy of electrons will be?
(1) 25:9 (2) 5:3 (3) 9:25 (4) 3:5
71 What will be the mass of a particle if
uncertainty in its position is 10* m and
uncertainty in velocity is 5.26 x 105 ms?
(1) 0.01 kg (2) 100 kg
(3) 1 kg (4) 10 kg

72. If the uncertainty in the position of an electron is

zero, the uncertainty in its momentum will be :
h
(1) 4
(2) (3) Zero (4) Infinite
4n
73. In an atom an electron is moving with a speed
of 600 m/s with uncertainty of 0.05%. Then
uncertainty in position of electron can be
located as : (h = 6.6 x 10-34 Kg m's, mass of
electron = 9.1 x 10 Kg)
(1) 5.10 x 10- m (2) 1.92 x 10 m

(3) 3.84 x 10 m (4) 2.52 x 10 m

74 Which of the following pairs of orbitals possess
two nodal planes ?
() P,d,-y? (2) day, d
(3) Px, dzx (4) d,zi, d,-y?
75. For sodium atom number of electrons with m =0
will be

(1) 2 (2) 7 (3) 9 (4) 8

76. Which of the following subshell can accomodate
as many as 10 electrons ?

(1) 2d (2) 3d (3) 3d,y (4) 3d,:

77. Which of the following has non spherical shell
of electron ?

(1) He (2) B (3) Be (4) Li

78 In argon atom how many electrons have mË = 1?
(1) 4 (2) 2 (3) I (4) 6
79 Which two orbitals are located along the axis,
and not between the axis ?

(1) d,, d,? (2) dy, P.

3 (3) dz P (4) p,, dy?
80 Which statement is not corect for n=5, m=2:
(1) (=4 (2) =0, 1, 2, 3
(3) (=3 (4) (=2, 3, 4
31 Which of the following statements are not incorrect
(a) Energy of e in 2d orbit of He* is same as
energy ofe in 4th orbit of Be ion
(b) Velocity of e increases when we move away
from the nucleus

(c) Difference of energy of successive orbits

decreases when we move away from the nucleus
(d) Wavelength of any moving particle is
proportional to its momentum
() b, c, d (2) b and d
(3) a and c (4) a, c and d

82, The correct order of energy is -

(1) E,, (H) > E, (Li) > E,, (Na) > E, (K)
(2) E, (H) < E, (Li) < E,, (Na) < E, (K)
(3) E, (H) = E,, (Li) = E,, (Na) = E, (K)
(4) None
83 Which of the following orbitals hydrogen
atom is closer to the nucleus?

(1) Sf (2) 6d (3) 7s (4) 7p

84. Group oforbitals having identical values of(n +() is :
(1) 3p, 3d, 4f (2) 3d, 4p, 5s
(3) 4s, 3d, 5p (4) 3d, 3p, 4s
85 Degenerate orbitals :
(1) have exactly equal energy
(2) belongs to same subshell
(3) both (1) and (2)
(4) none of the these
86. Energy of subshell in H-atom depend upon
(1) n value (2) (n+ () value
(3) value only (4) n, l and m value
 Maximum electron in nh orbit
87.
2
represents :

() Number of subshells in an orbit

(2) Number of orbitals in an orbit
(3) Number of orbitals in a subshell
(4) Number of electrons in an orbital
88. The mass of aparticle is 10g and its radius
is 2 x 10 cm. If its velocity is 10 cm sec
with 0.0001% uncertainty in measurement, the
uncertainty in its position is : -
(1) 5.2 x 10m
(2) 5.2 x 10 m
(3) 5.2 x 10 ° m
(4) 5.2 x 10 m

89. The orbital angular momentum of an e in 2S

orbital is :
h
(1) 4T (2) Zero

h
(3) 2T
(4)

90. The set of quantum number not applicable for

an e in an atom is :

(1) n=1, l= 1, m= 1,s=+

(2) n=1, ( =0, m= 0, s = +

(3) n=1, (=0, m=0, s=-

(4) n=2, ( - 0, m=0, s =+