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Solutions to JEE Advanced – 2 |JEE 2023 | Paper-1 (Gen 1 & 2)

PHYSICS
1.(C) Since A moves faster than B, clearly it will cover a greater distance before they meet
3R
So, we can look at the situation as A being three-quarters of the circle, i.e. a distance behind B initially.
2
So, the particles will be at diametrically opposite points on the circle when A is a half-circle behind B. Hence,
the time instant when this happens is given by
R
s A  sB 
2
 2v  R
vt1    t1 
 3  2
3R
 t1 
2v
3R
Now, the distance travelled by the particles until t  is
2v
 3R  3R  2v   3R 
sA  v   and sB       R
 2v  2  3   2v 
3R
So, at t  , the coordinates of A and B are respectively  0, R  and  0,  R 
2v
Hence, their average velocity in the interval t1 is respectively
2R 2 2 2R  4 
 v and   v
 3R   3   3R   3 
   
 2v   2v 
2.(D) After the block has moved downwards by a distance x, the net force it on upward direction,
F  kx  mg
F k
Therefore, its acceleration, a    x g
m m

We can see that the graph must be a straight line with positive slope, and the value of a at x = 0 is –g

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3.(C)

Vsep  e Vapp

 l 
  Vcm   2  2u
 2 
  l  2Vcm  2u … (i)
Conserving angular momentum about the centre of mass of the rod B (taking clockwise positive)
 l 3l   l l   ml 2   ml 2  
 mu  mu     mu   mu      2     2      2m  Vcm  l 
 2 2  2 2  4   4  
 2mul  ml 2  2mVcm l  2u  l  2Vcm …(ii)
2u
From (i) and (ii), we get  
l
4.(B) The horizontal component of the velocity of the ball remains unchanged throughout.
2
2 h1 2 h2 L g 
So, u u L  h2    h1 
g g u 2 
5.(A) Let the acceleration of the plank relative to the ground be a0
Then, the acceleration of the man relative to the ground is a  a0
Since the external force on the system is zero, the acceleration of the CM must be zero
M  a  a0   2M  a0  a
Therefore, aCM  0  a0  
M  2M 3
Now, the man reaches the other end when his displacement relative to the plank has become L

1 2L
Therefore, srel  a t2  L  t
2 a
a 2
So, the velocity of the plank at this instant is v    t   aL
 3 3
6.(B) If F is increased beyond a limt, block D will slip over C. This is because friction force acting on D is
responsible to acceleration D + B+ A. Hence, for all the four block to move together –
Acceleration of the system produced by F  acceleration produced by friction on D in the system D + B + A

F m2 g  m  m2 
   F0  2m2 g  1 
2m1  2 m2 m1  2m2  2m2  m1 

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7.(ABCD)
Equation of trajectory of the projectile:
gx 2
y  x tan  
2u 2 cos2 
Since the particle must pass through the point 15,5 ,
2
10 15 
5  15 tan  
2 15 
2 1  tan 2 
Simplifying, we get a quadratic equation in tan  :
tan 2   3tan   2  0
So, the two solutions are:   45o and   tan 1 2
Now, the time taken for the projectile to hit the point P can be simply found by using the motion in the X-
15 1
direction:  u cos   t  15  t 
15cos  cos 
1 1
So, the time in the two cases is:  2s and  5s
cos 5 o

cos tan 1 2 
Since we are given that t1  t2 , we get
t1  2 s and t2  5 s
1  45o and 2  tan 1 2
8.(AD) Since the velocity of the bottom-most point at t  0 is towards right, kinetic friction f K  mg acts towards
left
Therefore, the acceleration of the centre of mass,
f
aCM  K  g (towards left)
m
And, the angular acceleration of the cylinder,
f R 2f 2g
 K  K  (clockwise)
1 2 mR R
mR
2
So, taking rightward positive and clockwise positive, at any general time instant t,
 2g 
vCM  v0  g t and   0   t
 R 
Pure rolling begins when vCM  R
(Note carefully that we can write this because we have taken rightward positive for vCM and clockwise positive
for  )
  2g   v  R0 1   0.1 50 
So, v0  g t  R  0   t  t 0  2s
  R   3g 3  0.110 
Therefore, at t  2 s ,
vCM  v0  g t  1   0.110  2   1 m/s
 2g   2  0.110  
So, vCM  1 m/s towards left and,   0    t  50     2   10 rad/s
 R   0.1 
So,   10 rad/s anti-clockwise
Once pure rolling begins, vCM and  remain constant at the values they had at t  2 s .

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9.(ABCD)
Let the positive X-axis be towards East and the positive Y-axis towards North

Let the velocity of the train be vT


Let the initial velocity of the cyclist be vC1  4 ˆj

Let the initial velocity of the train relative to the cyclist be vTC 1

We are given that vTC1  12iˆ  12 ˆj
  
Now, we know from the definition of relative velocity that vTC 1  vT  vC 1
 
Therefore, vT  vC 1  12iˆ  12 ˆj
 
 
So, vT  vC1  12iˆ  12 ˆj  12iˆ  16 ˆj
 12   3
Hence, the train’s actual velocity is 20 m/s, in a direction tan 1    tan 1   West of North
 16  4

Now, if the cyclist moves towards East, his velocity is vC 2  4 iˆ
  
 
Therefore, the velocity of the train as seen by him now is vTC 2  vT  vC 2  12iˆ  16 ˆj  4iˆ  16iˆ  16 ˆj
  
The velocity of the train as seen by the cyclist is vTC  vT  vC
So, it is clear that if he orients his velocity opposite to the train’s actual velocity, their vector subtraction has
the maximum magnitude
10.(BCD)
String becomes tight again when distance travelled by the two blocks becomes equal.
1
 6t  2t  gt 2  t  0.8s
2
At t = 0.8s, v1 = 6m/s
v2 = 2 + (0.8)g = 10 m/s.
As string becomes tight string applies equal impulse on the blocks in the directions shown.
 We can equate change in momentum of the blocks.
(1) (6) + (1) (10) = (1 + 1) V
 v = 8m/s  Blocks move at v = 8m/s immediately after t = 0.8s.
 
So, impulse on block 2 during tightening is I 2  1 8   10   2 kg m/s

1 1 1
Heat generated = KEi  KE f   1 6 2  1102   2  182   4 J
2 2  2 
11.(BD) Initial momentum = Final momentum
2
2  v  v
Therefore, mu   mv    m   2  mv   m  cos 60o
 2  2
7v 2u
 u  v
2 7

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Now, since the common normal is along the final direction of motion of disk B, the angle between the final
direction of motion of A and the common tangent is 30o
And, the angle between the initial direction of motion of A and the common tangent is   30o
So, equating the component of A’s velocity along the common tangent before and after the collision,
 
u cos   30o  v cos 30o  
3v 3
 
cos   30o   2u

7
12.(AD)
Torque is the rate of change of angular momentum
Think of torque and angular momentum similar to how you think about force and momentum
During the flight of the particle, the only force acting on it is its weight vertically downward
Clearly, the angular momentum about P is initially zero, and since the torque on the particle (due to the
particle’s weight) about P is always clockwise, the angular momentum about P keeps increasing
About Q, the angular momentum is anti-clockwise just after projection, and clockwise just before landing. And
the torque on the particle (due to the particle’s weight) about Q is always clockwise. Hence, we can deduce
that the initially anti-clockwise angular momentum about Q must have reduced to zero and then increased in
the clockwise direction
1.(280) Let the time taken from the beginning until the crossing be t
1 a 2
Then,  a   t  300  at 2  400
2 2
at
The velocities of A and B at the instant of crossing are at and respectively
2
Therefore, the time taken by the cars to stop after the crossing is respectively
at at /2
 2t /5 and  t /2
5a /2  a
2t 7t
So, the total time for which the car A moved is t  
5 5
7t
Since  14  t  10 s
5
400
Therefore, a 2
 4 m/s2
10
So, the speed of A at the instant of crossing is  4 10   40 m/s and its deceleration afterwards
5  4
is  10 m/s2
2
2
1  40  280 m
So, the total distance moved by A is s A   4 102 
2 2 10 
t
2.(15) The total time for which B moved is t   15 s
2

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3.(2.40) 4.(1.20)
Let the duration of the collision be denoted by 
We know that F    must be zero
A
 A  B2  0  
B
Now, applying impulse momentum theorem along the horizontal direction
 
0 F  t  dt  p ( F  t  is the only force acting in the horizontal direction)

A2 B3 A3 8 A 2 8
    0.2   3   5   2
   
2 3 6B 5 6 5
8 6  2.4  104 N/s And, A 2.4  104
 A 2
B   1.2  106 N/s2
5  0.02   0.02
5.(320) 6.(40)

Normal reaction by the incline on the platform is

N 100 g cos37  800 N
 Maximum possible friction force on the platform (by incline) is
f max  N  400 N
The maximum friction by the man on the platform is downward direction can be f m  40 N . This means that
the man is experiencing friction force of 40N up the plane.
240  40
Acceleration of man in this case a   5 m/s 2
40
If f m  0 ; acceleration of man a  6 m/s 2

If acceleration of man is large than 6 m/s 2 , the friction f m reverse direction.

When a  7 m/s 2
f m  40 N
Friction on platform by incline will adjust itself to 320 N.

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CHEMISTRY
CO CO 2
x mol (1 x) mol
1.(C)
(eq) CO2  (eq) NaOH
20
(1  x)  2  1
40
3
x
4
1
CO  O 2 
 CO2
2
t=0 x mole (1– x) mol
0 x + (1– x) = 1 mol
(eq) CO2  (eq) NaOH
x
1 2  1  x  80g
40
Extra amount of NaOH = 80 – 20 = 60g = 1.5 mole
2.(C) VA  0.5, VB  1
TA  TB
dA MA 1
 2, 
dB MB 2
d
P  RT
M
PA d A M B
   2 2  4
PB d B M A
P
3.(D)  const.  polytropic process
V
PV 1  const.  x = – 1
nR
w (T2  T1 )
(x  1)
3
U  n R(T2  T1 )
2
U 3 3
 (x  1)  ( 2)  3
w 2 2
n3
4.(C) T
z2
3 2
T3 , Li 2  3 2 3

     
T2 , He  2 3 2

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2 2
T2 , He   T3 , Li 2  x s
3 3
5.(A) (B) It violates Hund’s rule
(C) It violates Aufbau principle
(D) It violates Aufbau principle
6.(C) 25  4x  y  (3x  90  110)
x  y  175
9
x y
5
9 175  5
y  y  175  y 
5 14
y  62.5 kcal.
7.(ABC)
(a) 2NaOH  CO2  Na 2 CO3  H 2 O
6 gm 4.4gm
0.15mol 0.1mol
NaOH will be limiting reagent
(b) NaOH  CO2 
 NaHCO3
0.15 mol 0.1mol

CO 2 will be limiting reagent

(c) NaOH  CO 2 
 NaHCO3
0.15mol 0.1mol 0
0.05mol left 0 0.1molform

NaOH  NaHCO3 
 Na 2 CO3  H 2O
0.05mol 0.1mol O O
0.05molleft 0.05molform 0.05molform

Moles of NaHCO3 left = moles of Na 2 CO3 formed but masses are not equal.
Total mass of reaction mixture
 WH 2O  WNa 2CO3  WNaHCO3
 0.05[18  106  84]
= 10.4 gm (Law of mass conservation)
8.(ABD)
Correct order : S > O (electron affinity)
9.(ACD)
(A) Magnetic moment: Cr 2  Co3 (both have 4 unpaired electrons)
(C) I.P.  Sn < Pb
(D) Element belongs to 13th group
10.(BC)
(A) No. of angular nodes in 3s-orbital = 0
(D) d orbital has non zero electron density in XY-plane
Z2

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11.(BC)
(U rms ) A TA M B
 
(U rms )B TB M A
0.866 300 M B
 
1 400 M A
MB 4
 0.75   1
MA 3
12.(BCD)
Correct order of bond angle
NO 2  NO 2  NOΘ
2
BF3  BCl3  BBr3
OF2  H 2O  O(CH 3 )2
1.(–147)
N 2 H 4  O 2  N 2  2H 2O
 240   36  3 9
H          76   (68)  147kcal / mol
 4   4  4 4
2.(11)  N 2 H 4 ( )
N 2 (g)  2H 2 (g) 
 240   36  3 68
H        ( 76)   11kcal / mol
 4   4  4 4
3.(1)
4.(300)
PV = nRT for He gas
190 1
 V  0.01  300
760 12
V=1L
P  T  PHe at 600K  380 mm of Hg
NH 4 Cl(s) 
 NH3 (g) HCl(g)
x mm x mm

x  x  380  980
PNH3  x  300 mm of Hg = 300 Torr

5.(7) PCl6– , SF6 , XeO3 F2 , SCH 2 F4 , SF4 , XeO64 , I 2Cl6

6.(5) O2 , B2 , O 2 , O2 , H 2 are paramagnetic species

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MATHEMATICS
1.(B) Other root will be 2  3. as a, b, c  Q
 roots  2  3
b c

a
 4,
a
 
 2  3 2  3 1 
a  2b  3c 4 4
 b  4a , c  a   
a  3b  2c 9 9
2.(A) zz 3  zz 3  30
     
zz z 2  z 2  30  a 2  b 2 2 a 2  b 2  30

 a 2  b 2  5 , a 2  b2  3  a 2  4 , b2  1
1 1  1
Area of rhombus  4     1 
2 4  2
3.(C)

4.(B) x 1  0  x  1
1 x  0  x  1  x  1

5.(C) Coefficent of x9 in ( x  1)5 ( x  2)5

 (5 C0 ) (5 C1  2)  (5 C1 ) (5 C0 )
 10  5  15

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6.(B) No. of rectangles including squares

 (10 C2 ) (11 C2 )
No. of squares only
9 9  9  10  9(10)(19)
  (11  r ) (10  r )   (110  21r  r 2 )  110  9  21   330
r 1 r 1  2  6
 No. of rectangles excluding squares = 2475 – 330 = 2145
7.(ABC) Let z  x  iy then | x |  | y |  6

1 1
ar  OAB    6  6   6 2  | z |min  z min  3 2  18  z  36
2 2
3
8.(ABCD) x  x  1  0   roots : , , 
         0
        1
  1
2
  2  2   2   2      2  2
Now, 3    1  0  3    1  3    1  3
3    1  4  2    4   2    2
3    1  5  3   2   5  3   2   3  2  5
3    1  6  2  2  1  6  2  2  1  5
1 x2  x  1  x2  x  1
9.(ABC)  2  3  log 2  2   log 2 1, log 2 2,log 2 3  0,1, log 2 3
3 x  x 1  x  x  1 
log 2 3  1.5  3  21.5


10.(BC) f   x   e x  e x tan   x   sin3   x    f ( x)
 x2  x  1   x2  x  1 
g   x   ( x ) log  2   x log  2  g ( x)
 x  x 1  x  x  1 
   
h   x   sin cos   x  tan x   sin cos  x  tan x   h  x 
k   x   2 x  k ( x) for all x
11.(ABCD) AA DD II M N R V Y
Selection of 5 letters No. of ways
2 alike 2 alike 1 different (3 C2 ) (6 C1 )  18
2 alike 3 different (3 C1 ) (7 C3 )  105
8
All different C5  56
Total 179

VMC |JEE-2023 | Paper – 1 11 Solutions |JEE Advanced-2 | Gen 1 & 2

 Vidyamandir Classes

Coefficient of x5 in (1  x  x 2 )3 (1  x)5
= coefficient of x5 in (1  3 x  6 x 2  7 x3  6 x 4  3x 5  x 6 ) (1  x)5
 5C5  3  5C4  6  5C3  7  5C2  6  5C1  3  5C0  179
Coefficient of x 6 in (1  x  x 2 )3 (1  x )5
 3  5C5  6  5C4  7  5C3  6  5C2  3  5C1  5C0  179
  3  182  2  7 13  No. of divisors  8
  1  180  2 2  32  5  No. of divisors  18

12.(BCD) (1  x)n  nC0  nC1 x  nC2 x 2  nC3 x3  ...  n Cn x n …(1)

( x  1)n  n C0 x n  n C1 x n1  nC2 x n 2  ....  n Cn …(2)

Multiply (1) and (2) and equate coefficient of x n both sides, we get
n
2n
Cn  nC02  nC12  nC22  ....  nCn2   n Cr2
r 0
Put x  1 in (1), to get, 0  C0  C1  C2  nC3  ....  ( 1) n nCn
n n n

Put x  1 in (1) to get, 2 n  n C0  n C1  n C2  n C3  .....  nCn

Use (1  x )2 n  2 nC0  2n C1 x  2 nC2 x 2  .....  2n C2 n x 2 n
Put x  1, 22 n  2 nC0  2n C1  2 n C2  .....  2 nC2n
4n  ( 2 nC0  2n
C1  2n
C2  ....  2n
Cn 1 )
2n 2n 2n
Cn  ( Cn 1  Cn  2  ..... 2n C2 n 1  2n
C2n )
2n
C0  2 nC1  2 nC2 .... 2 nCn1 4n  2n
Cn n
2n 4n  2n
Cn
 
2
  Cr 
2
r 0

1.(2) z corresponding to point P has minimum arg.

 OP   OC 2   CP 2  3
3 1
In OCP, sin   ,cos  
2 2
 P  OP cos   i OP sin 
3 3
 P i
2 2
b 3 3
   2
a2  2   4 

2.(6) z  3  6i maximum along and QCQ '.

 z  3  6i max  QC  CQ '
 3  4i  1  6.

VMC |JEE-2023 | Paper – 1 12 Solutions |JEE Advanced-2 | Gen 1 & 2

 Vidyamandir Classes

i 2k 
 2k    2k   10 .
3.(2) Ak  cos    i sin  e
 10   10 
 Ak is 10th root of unity.
By observation
Here ar  A1 A3 A6   ar  A2 A4 A7 
 ar  A3 A5 A8   ar  A4 A6 A9 
 ar  A5 A7 A10   ar  A6 A8 A11 
6
 ar  Ak Ak 2 Ak 5 
k 1
3
2
 ar  Ak 1 Ak 3 Ak 6 
k 1
10
4.(2)   2   n    2    2     2   2  2  3  ... 2  10 
n1
since  is 11th root of unity

  
 x11  1   x  1 x    x   2 .... x  10 
x11  1
  x     x   2  x  3  .... x  10 
x 1
211  1   2     2   2  2  3  ....  2  10 

 2 11  1 
and  2     2   2  2  3  ....  2  10    2     2   2  2  3  ....  2  10 
2  1
10  10 
  2  n   211  1  2047
 2  
n
  
 n101   11   3   3   n101 2
 2 1 2049  
2   n
    2  n
 n 1
  

n 1

5.(15) No. of ways = coeff. of x3 in ( x 0  x1 ) ( x 0  x1  x 2 ) ( x 0  x1  x 2  x 3 )

( x 0  x1  x 2  x 3  x 4 )
= coefficient of x3 in (1  x ) (1  x  x 2 ) (1  x  x 2  x3 ) (1  x  x 2  x3  x 4 )
= coefficient of x3 in (1  x ) (1  x  x 2 ) (1  x  x 2  x 3 ) (1  x  x 2  x 3 )
= coefficient of x3 in (1  x ) (1  x  x 2 ) (1  x  x 2  x 3 ) 2
= coefficient of x3 in (1  2 x  2 x 2  x3 ) (1  x  x 2  x3 )2
= coefficient of x3 in (1  2 x  2 x 2  x3 ) (1  3x 2  2 x  4 x 3 )  15
6.(27) x1  x2  x3  5  No. of sol.  7C5  21
x1  x2  x3  2  No. of sol.  4C2  6
 Total no. of solutions = 27

VMC |JEE-2023 | Paper – 1 13 Solutions |JEE Advanced-2 | Gen 1 & 2

 Vidyamandir Classes

Solutions to JEE Advanced – 2 |JEE 2023 | Paper – 2 (Gen 1 & 2)

PHYSICS
1.(BCD) Moment of inertia of the rod about the pivot,
2
1 L L 1
I mL2  m     mL2
12 2 3 9
So, the initial angular acceleration of the rod is given by
  I
 L 1  3g
 mg     mL2    
6
   9  2 L
 L g
So, the initial acceleration of the CM     
6 4
Let the force applied by the pivot on the rod just after it is released be F upwards
g 3mg
Then, mg  F  m    F
4 4
The rod attains its maximum angular velocity  when it is vertical
By conservation of energy between the horizontal and vertical positions,
 L 11  3g
mg     mL2  2  
6
  2  9  L
And, in the vertical position, the angular acceleration of the rod is zero. Hence, the acceleration of its CM
 L g
is 2   
6 2
2.(AD) Let us assume that the acceleration of the centre of the pulley and the block are aC and A , directed downwards
and upwards respectively, and the angular acceleration of the pulley be  anti-clockwise
Then, since the strings are wound on the pulley and hence do not slip on it, we get the following equations
from the two points on the pulley where the strings begin contact with it:
aC  R and 2 R  aC  A
 A  R and A  aC

 
Since aC and A are assumed in opposite directions, we get aC   A
(This relation is independent of the masses of the bodies)
Now, let the tension in the upper and lower strings be T1 and T2 respectively
Then, T2  Mg  MA
T2  mg  T1  maC

VMC |JEE-2023 | Paper – 2 1 Solutions |JEE Advanced – 2 | Gen 1 & 2

 Vidyamandir Classes

3 
And T1R  T2  2 R    mR 2  
2 
Simplifying the equations, we get
T2  Mg  MR … (i)
T2  mg  T1  mR … (ii)
3
T1  2T2  mR … (iii)
2
Adding all three equations, we get


m  M  g
5m /2  M  R
Therefore, aC  A 
m  M  g
5m /2  M 
2g
So, if M  2m , A   , i.e. 2 g /9 downwards
9
g
And, if M  m /2 , A  , i.e. g /6 upwards
6
3.(BD) Components of velocity upon reaching the ground for the first time:
VX 0  10 VY0  2(10) (20)  20

After the first rebound, the X-component remains unchanged, and because now the velocity vector makes 45o
angle with the horizontal,

Therefore, the maximum height reached before the ball strikes the ground again,

Also, the coefficient of restitution,

Therefore, the velocity components after the second rebound are:

So, after the second rebound, the angle made by the velocity vector with the horizontal,

VMC |JEE-2023 | Paper – 2 2 Solutions |JEE Advanced – 2 | Gen 1 & 2

 Vidyamandir Classes

4.(ABD) For 0  t  2,
t 3t 2 t 3
0
 
v  t   v  0    3t  t 2 dt 
2

3
t t3 t4
x  t   x  0    v  t  dt  
0 2 12
For 2  t  4,
t 10  5 1 
2
 
v  t   v  2    4  5t  t 2 dt    
  4  t  2   t 2  4  t 3  8 
3  2 3 

5 1
 v  t   4  4t  t 2  t 3
2 3
t t4  3 8
 t  2t 2  4t 
x  t   x  2    v  t  dt  
2 12 6 3
7 11
So, v 1  and v  3 
6 2
Displacement between between t  1 and t  3 is x  3  x 1  6.66 And, x  4   13.33
5.(AC) We can understand this quite simply using the concept of pseudo force.
If we look at the point mass in the reference frame of the rotating disc, the point mass is in equilibrium. Hence,
net force on it must be zero.
We already know two forces acting on the point mass: its weight W = mg acting downwards, and the pseudo
force FC  m2 r (the centrifugal force) acting radially outward.

Then, the force F exerted by the disc on the mass m, must be such that it balances the resultant of the above
two forces (because the point mass is in equilibrium in the frame of the disc)

2
 g  mg 2
We know that W  mg and FC  m R  m   R
 2R  2
  
And we know that F   W  FC  , i.e. the force exerted by the disc on the point mass m is equal and opposite
to the resultant of the other two forces.
 
Since W always acts downward, and FC acts radially outward, the instantaneous angle between them is  itself

 mg 
2
 mg 
So, F  W 2  FC2  2 W   FC  cos    mg 2     2  mg    cos 
 2   2 
 5 
1/2
 F    cos   mg
4 

VMC |JEE-2023 | Paper – 2 3 Solutions |JEE Advanced – 2 | Gen 1 & 2

 Vidyamandir Classes

1/2
 2   5  1   3
So, F         mg  mg
 3   4  2  2
1/2
5  mg
F        1  mg 
4  2
     
 
We know that if v is the instantaneous velocity of the point mass, then P    F v   W  FC v  
   
Now, since FC is always radial and v is always tangential to the disc, FC  v  0 at all instants
   
And, since the instantaneous angle between W and v is     ,
2 
   
P     W v  mg  R cos      mgR sin 
2 
   mgR  3  mgR
So, P    and P  
4 2  4  2
6.(ABD) Before the string breaks, the acceleration of both blocks,
 2.1  1.9 
a   g  0.5 m/s 2 upward for block A and downward for block B
 2.1  1.9 
Therefore, at t  1.0 s , the velocities of the blocks are: (taking upward positive)
v A1   0.51  0.5 m/s
vB1   0.51  0.5 m/s
After the string breaks, acceleration of both blocks is g downwards
So, at t  1.1 s , the velocities of the blocks are:
vA  0.5   10  0.1  0.5 m/s
vB  0.5   10  0.1  1.5 m/s
Now, between t  0 and t  1.1 s , the total displacements of the two blocks are:
1 2  1 2
s A    0.5 1     0.5  0.1   10  0.1   0.25 m  25 cm
2   2 
1 2  1 2
sB    0.5 1     0.5 0.1   10  0.1   0.35 m  35 cm
2   2 
7.(B) Conserving angular momentum about the hinged point,
Initial angular momentum = Final angular momentum
1  3v
 mvL    2m  L2  mL2    
3  5L
8.(B) Moment of inertia of the combined system after the collision, about the pivot is
1  5
I    2m  L2  mL2   mL2
3  3

Then, conserving energy,

Loss in KE = Gain in GPE

VMC |JEE-2023 | Paper – 2 4 Solutions |JEE Advanced – 2 | Gen 1 & 2

 Vidyamandir Classes

15 2 2 L  3V 
 mL     2m  g    mgL    
23  2  5L 
20 gL
v2 
3
2
9.(C) The length of the spring at the instant the block comes to rest is L2   3L /4   5L /4
So, the elongation at this instant is x  5L /4  L  L /4
Conserving energy,
Loss in KE = Gain in elastic PE
2
1 1  L L k
Mv 2  k    v
2 2 4 4 M
10.(A) Let the angle made by the spring with the horizontal at this instant be 
Then, the acceleration a of the block is given by kx cos   Ma

3L /4
Now, cos    3/5
5L /4
kx cos  3 kL
So, a 
M 20 M
11.(C) Since there is no external force on the system in the horizontal direction, and the CM of the system (which is
initially at the mid-point of the rod) is initially at rest, it remains at rest
At t  t1 , as the rod is parallel to the Y-axis, and the CM of the system will be collinear with the rod itself, the
L
rod at this instant is along the line x 
2
L 
So, at this instant, let the coordinates of the man A (and the mid-point of the rod) be  , y
2 
L L
Then, the coordinates of the man B must be  ,y 
2 2

VMC |JEE-2023 | Paper – 2 5 Solutions |JEE Advanced – 2 | Gen 1 & 2

 Vidyamandir Classes

L 
Since the CM still must be at  ,0 ,
2 
 L
M  y  M  y  M  y  
 2 L
YCM  0  0  y
M M M 6
L L
So, at t  t1 , the mid-point of the rod has coordinates  , 
2 6
L L
Hence, at this instant, the man B has the coordinates  , 
2 3
12.(B) Now, let the angular velocity of the rod at t  t1 be 
Between t  0 and t  t1 , we can conserve the angular momentum of the system about any point in space as
there is no external force, and hence no external torque about any point in space
Let us conserve the angular momentum about the CM of the system, since that is quite convenient to work out
The moment of inertia of the system about its CM:
1   L 2  7
At t  0 I0  ML2  2  M     ML2
12   2   12
 
1 2 2 2
L  L  L L 1
At t  t1 I1   ML2  M     M    M     I1  ML2
 12  6   6 6 2 4

So, about the CM of the system,
Initial angular momentum = Final angular momentum
I 00  I11
(as at both instants, the men are at relative to the rod)
7 2 1 2 7
  ML  0   ML  1  1  0
 12  4  3
L 7
So, at t  t1 , the velocity of man A is v A  1    L 0
 6  18

1.(2) Instantaneous position of the particle, r  cos  3t  iˆ  2sin  3t  ˆj
 d 
Instantaneous velocity of the particle, v   r    3sin  3t   iˆ  6cos  3t  ˆj
dt
 d 
Instantaneous acceleration of the particle, a   v    9 cos  3t   iˆ  18sin  3t  ˆj
dt

Velocity and acceleration must be perpendicular

 
Therefore, a v  0
 27sin  3t  cos  3t   108sin  3t  cos  3t   0  sin  3t  cos  3t   0
  
 sin  6t   0  t , , ...
6 3 2

VMC |JEE-2023 | Paper – 2 6 Solutions |JEE Advanced – 2 | Gen 1 & 2

 Vidyamandir Classes

     
Position at t  , r  cos   iˆ  2sin   ˆj  2 ˆj
6 2 2
2.(20) The time instants t  1 s and t  4 s must be the solutions to the equation:
1 u h
h  ut  10 t 2 i.e. t2    t   0
2 5 5
h
Therefore, the product of the roots of the quadratic equation, i.e. must be equal to 1 4   4
5
Therefore, h  20 m
3.(4) We are given that y4 x  y 2  16 x
dy dx
Differentiating with respect to time, 2 y  16  yv y  8vx
dt dt
If x  4 , y 8  v y  vx

Now, we are also given that v x2  v 2y  4 2

Therefore, at this instant, v y  v x  4
4.(32) Let N 1 and N 2 denote the forces acting on the sphere from the supports A and B respectively

Balancing forces,
3 N1 4 N 2
 …(i)
5 5
4 N 1 3N 2
  40 …(ii)
5 5
Solving, we get
N 1  32 N
N 2  24 N

VMC |JEE-2023 | Paper – 2 7 Solutions |JEE Advanced – 2 | Gen 1 & 2

 Vidyamandir Classes

5.(1.25)
Since the force is always perpendicular to the velocity of the particle, it cannot change the speed of the
particle, and will only change its direction of motion
F 2t
The instantaneous radial acceleration of the particle is ar    2t
m 1
Now we know that if R is the instantaneous radius of curvature of the path of the particle, the radial
v2
acceleration is  2 R
R
Since we need to find the angle turned by the particle, we need to find its instantaneous angular velocity (and
we do not need the radius of curvature), we write the radial acceleration as
v
ar  2 R  2    v
 
5
a 2t t 5 t2
  r        dt   1.25 rad
v 20 10 0 20
0
6.(0.80) Let the velocity of the CM at the end of the rough portion be v1
Conserving energy in the top half,
h 1 2 1  v12 
mg  mv1  mk 2
2 2 2
   2  … (i)
R 
Conserving energy in the bottom half,
2
h 1   14 gh   5gh
mg  m    v1
2
 v12 
2 2  9   9
 
k2 4
Using this in equation (i), we get  = 0.8
R2 5

VMC |JEE-2023 | Paper – 2 8 Solutions |JEE Advanced – 2 | Gen 1 & 2

 Vidyamandir Classes

CHEMISTRY
15
1.(BC) C6 H 5COOH(s)  O 2 (g)  7CO 2 (g)  3H 2 O()
2
 C H  7 (390)  3( 285)  (410)   3175 kJ / mol
 1  8.314  300
 C U  C H  n g RT   3175       3173.75 kJ / mol
 2 1000
2.(BD) Mass of solution = 900 + 138 = 1038 g
Volume of solution = 1 L
1038 g kg
Density of solution   1.038 3  1038 3
1000 cm m
3 3
X C2H5OH  
3  50 53
3
M   3mol / L
1
3 1000 10
m  mol / kg
900 3
3.(BCD) (B) Real gas behaves ideally at boyle’s temperature
a
(C) TB 
Rb
2a
(D) Z 1  for 2 moles of vander waal’s gas at low pressure
VRT
4.(BC) 4.25  A  TA
4.2  B  (TA  2.5)
0.05  A  B  2.5
B  A  2.45
 B  2 A
h 2h
  TA  4TB
2mTB 2mTA
TA  4 (TA  2.5)
10
3TA  10  TA  eV
3
5
TB  eV
6
10
4.25  A   A  0.92eV
3
B  3.37eV

VMC |JEE-2023 | Paper – 2 9 Solutions |JEE Advanced – 2 | Gen 1 & 2

 Vidyamandir Classes

5.(AD)

6.(BCD) (B) Ionic radius  O2   F  Na   Mg 2

(C) Li  B  Be  C (IE1 )
(D) Cl  F  Br  I (EA)
7.(B) Stability of N 2  N 2 so bond energy of N 2  N 2

8.(B) Bond order of N 2 , O 2  2.5

Bond order of F2 1

Bond order C 2 1.5

No. of ABMO e   O 2  N 2
9.(D) I.E  He > Ne > Ar > Kr
10.(B) Na   Na  Na 
H  x H  y
yx
11.(B) w  nR  T  1 8.314  72  598.6 J
= – 0.6 kJ
12.(A) U  q  w  1.6  ( 0.6)  1.0 kJ
1.(4) PCl3 F2 , CCl 4 , SF6 , C 2 H 4 have zero dipole moment.
2.(2) IE1  IE 2  IE3  IE 4  + 2 state is more stable  2 nd group
3.(15) G    RT n K P
H  TS   RT n K P
(10.5 103 )  300 S   2  300( 10)
4500
S   15
300
4.(5) Radial Probability density  R 2 (r)
3
21 1 
at r  0  R (r)   
  a0 
3
1 1 
at r  2a 0  R (r)    e 4
2
  a0 
R 2 (2a 0 ) 4
2
 e  xe y
R (0)
x = 1, y = 4  x + y = 5

VMC |JEE-2023 | Paper – 2 10 Solutions |JEE Advanced – 2 | Gen 1 & 2

 Vidyamandir Classes

5.(2.5) HNF (g)  Cl (g)  KF(s) 

 ClNF2 (g)  KF  HCl(s)
2 2
a mmol a mmol
2a 2a a
mmol mmol mmol
3 3 3
a/3
Volume percent of ClNF2 in gaseous mixture   100  20%
5a / 3
6.(0.96)
NH3 H2
xml (100  x) ml

2NH3   N 2  3H 2
3x
xml ml
2
3x x
Volume of H 2   100  x  100 
2 2
2H 2  O 2   2H 2 O
 x
Volume of O2 used   50   ml
 4
 x
80   50    6
 4
x
24   x  96
4
fraction of NH 3 in original mixture = 0.96

VMC |JEE-2023 | Paper – 2 11 Solutions |JEE Advanced – 2 | Gen 1 & 2

 Vidyamandir Classes

MATHEMATICS
P

1.(ABD) Given expression  3  5  72  1  2P  P   0
 p  3n  1, 3n  2, n  I
1  z2 1  ei 2 
2.(ABC) Let arg z   then z  ei    ei 2 
1 z 2 1  e i 2 
 1 z2    2 
arg   2   , 
 1  z 2  3 3 
 
3.(AC) By observation, x  1 gives same relation in both equation.
 common root  x  1 when 1  a  b  c  0 or a  b  c  1
2 50 2 3 100
4.(ABD) (1  2 x  3 x )  a0  a1 x  a2 x  a3 x  ....  a100 x …(1)
Put x  0 in (1), we get a0  1
Also, put x  1 in (1) to get 650  a0  a1  a2  ......  a100
Differentiate (1) w.r.t. x, we get
50 (1  2 x  3x 2 ) 49 (2  6 x)  a1  a2 (2 x)  a3 (3 x 2 )  .....  a100 (100 x99 ) …(2)
Put x  0 in (2) to get, a1  100
Differentiate (2) w.r.t x, to get
50  49 (1  2 x  3 x 2 ) 48 (2  6 x)2  300 (1  2 x  3x 2 )49
 2  a2  a3 (6 x)  a4 (12 x 2 )  ....  a100 (9900 x98 )
Put x  0 to get, a2  5050

5.(ABCD) (A) Fundamental period =
2
(B) Fundamental period = 

(C) Fundamental period =
2
(D) Not periodic
6.(ABD) No. of ways to invite one or more friends
 3C1  3C2  3C3  7
 31   31 
No. of zeroes at the end of 31 = exponent of 5 in 31    2 7
 5  5 
7.(C) 1  x 101  101C0  101C1 x  101C2 x 2  101C3 x3  101C4 x4
 101C5 x5  101C6 x6  ....  101C101 x101 …(1)
Differentiate (1) w.r.t x to get
1011  x 
100
   
 101C1 101 C2  2 x  101 C3 3 x2 101 C4 4 x3  101C5 5 x 4  .......  

 101C101 101x100 …(2) 
Put x  1, , 2 respectively in (2) and add to get,
100
 
101 2100  1011  
100

 101 1  2 

VMC |JEE-2023 | Paper – 2 12 Solutions |JEE Advanced – 2 | Gen 1 & 2

 Vidyamandir Classes

  
 101C1  3  101C2 2 1    2  101C3 (3  32  34 ) 101 C4 (4  43  46 ) 101 C5 5  54  58  .... 
 
 101C100 100  10099  100198  101C101 101  101100  101200  
  
101 2100  101.200  101100

 101C1  3  101C2 2  0   101C3 3  0   101C4  4   101C5  0   ......  101C100 100  3.100 

 
101.2100  101 2    3 
  101
C1  4 101C4  7. 101C7 ....  100. 101C100 




101 2100  1   101C  4. 101C
101
C7  ....  100. 101C100
1 4  7.
3
8.(A) Put x  i and  i respectively in (2) and add to get,
100 100
1011  i   1011  i    
 101C1  2   101C2  2i  2i   101C3 3i 2  3i 2  101C4 4i 3  4i 3 

 101C5 5i 4  5i 4   ....  101C101 101 i100  101i100
  
50 50
 101  2i    2i    2  101 C1  3. 101C3  5. 101C5  7. 101C7  ...  101. 101C101 
   
 250.101  101C1  3. 101C3  5. 101C5  7. 101C7  ...101. 101C101.
9.(D) f  x   2 f 1  x   x 2  2 x ..(1)
2
Replace x by 1  x in (1) to get f 1  x   2 f  x   1  x   2 …(2)
1 2
Operate 2   2   1 to get f  x    2  2 1  x   x 2 
3 
1
 f  x  x  2 2 …(3)
3
1 
Similarly, 2 g  x  1  g   1  x …(4)
x 
1 1  1
Replace x by in (4) to get 2 g   1  g  x  1  …(5)
x  x  x
1 1
Operate 2  (4)  (5) to get g  x  1   2 x  
3 x
2
1  2  x  1  1  1  2 x 2  4 x  3 
 g x      …(6)
3 x 1  3  x 1 
 
From (3), f  1  3, f  5   3
3
From (6), g(0) = 1 g 1 
2
 2 f  1  3 g  0   4 g 1  15  5 f (5)
1
10.(B) f  x   x  22  0
3
 f  x  is minimum at x = 2.

VMC |JEE-2023 | Paper – 2 13 Solutions |JEE Advanced – 2 | Gen 1 & 2

 Vidyamandir Classes

b  1
11.(D)  ab
2a 2

f  0  x 2  f 1 x  f  1  0
 x 2   a  b  1 x   a  b  1  0
 x2   2a  1 x  1  0  g  x   0
g  0  g 1  0

3
 2a  3  0 a  But a  0
2
12.(B) ax2  ax  1  0
For real and distinct roots, D > 0  a2  4a  0  a   ,0    4,  
But a > 0
 a   4,  

1.(8)
| x | 1| x  1| 1  0
e x  1 | x  2 | 3

| x | 1| x  1| 1  0 as
 ex  1  0  x   0, 1  [2, 5)
| x  2 | 3
abcd 8
2.(2)  
x4  x3  2 x  4   x  2  x3  x 2  2 x  2   x  2  x  1 x 2  2  0  
 x  2,  1,  2 i
3.(1) 11111  11112  11113  11114  11115  11116
11 12 13 14 15 16
 110  1  110  1  110  1  110  1  110  1  110  1
 11 11 10 9
C0 110   11C1 110   11C2 110   ...  11C10 110  11C11 
 12 12 11
C0 110   12C1 110   .... 12 C11 110   12C12 
 
13 13 12
C0 110   13C1 110   .... 13 C12 110   13C13

 14 14
C0 110   14C1 110  13 ......  14C13 110   14C14 
VMC |JEE-2023 | Paper – 2 14 Solutions |JEE Advanced – 2 | Gen 1 & 2
 Vidyamandir Classes

 15 15 14
C0 110  15C1 110  ....  15C14 110   15C15 
 
16 16 15
C0 110   16 C0 110   .....  16 C15 110   16C16

 100 N   11C10  12C11  13C12  14C13  15C14  16C15 110

  11 C11  12C12  13C13  14 C14  15C15  16 C16  where N is Natural number
 100 N  11  12  13  14  15  16 110  6
 100 N  8916
 digit at tenth place = 1.
2
4.(9) 
55  4 221i  2 17  13i 
ALTHOUGH we can direct use the property: z  z and thus find modulus without determining the
square roots.
1 
5.(2) Area bounded = 4 ×   1  1   2 sq. units.
 2 

6.(2164) Letters in alphabetical order A C C E I N V

6
No. of words starting with A   360
2
No. of words starting with C  6  720
6
No. of words starting with E   360
2
6
No. of words starting with I   360
2
6
No. of words starting with N   360
2
Now words starting with V
No. of words starting with V A C C E  2
No. of words starting with V A C C I E N  1
No. of words starting with V A C C I N E  1
Rank = 2164

VMC |JEE-2023 | Paper – 2 15 Solutions |JEE Advanced – 2 | Gen 1 & 2