Gas Liquid Separation Technology
Gas Liquid Separation Technology
Naphtha
Kero
Diesel
They have proven their performance in more than 100’000 columns, 50’000 gas/liquid or liquid/liquid
separators and 100’000 static mixers in operations worldwide.
2
Gas/liquid separation technology
Product overview 5
Mist elimination 9
Mellachevron 15
Combined systems 19
Applications 21
Sulzer is a major player in the field of gas/liquid and liquid/ economic demands of offshore, onshore, remote and challenged
liquid separation technology, offering a full range of innovative gas processing. Compact Mass Transfer and Inline Separation
products and related services. Our commitment to development Technology (cMIST™), incorporating our patented compact HiPer
of technology, combined with application skills and consistent TwinLine™ Separator, can replace conventional TEG contactors and
fabrication standards ensures that a well-engineered solution is associated separators to meet pipeline dew point specifications. It
available for most separation problems. allows significant reductions in weight, footprint and cost. cMIST™
is an innovative dehydration system licensed from ExxonMobil to
Our expertise gained from thousands of successful installations in Sulzer.
a broad spectrum of applications ensures that the best possible
product is recommended for each individual duty. Enhanced liquid-liquid separation is provided by the Sulzer VIEC™
(Vessel Internal Electrostatic Coalescer), system that uses alternating
Our strategic alliance agreement with Shell Global Solutions high voltage electrical fields. With the ability to tolerate 100% water
International B.V. provides access to state of the art separation and 100% gas in a robust and stable process, the system is well-
technology, including the Shell VersiSwirl™ and Schoepentoeter™. suited for the separation of water dispersed in oil and the handling of
The oil and gas industry is increasingly pursuing compact and stable emulsions.
lower weight processing technology to meet the technological and
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Sulzer vessel based separator portfolio
Typical materials*
Product
PP,
Stainless Alloy Alloy Alloy Alloy Alloy Alloy FEP, Glass
facts
Type of separator Copper on page
steels C22 C276 400 625 825 20 ETFE, fibers
PTFE
KnitMesh™
5
Mist Eliminator
KnitMesh V-MISTER™ 5
KnitMesh™ 9797
High Performance 5
Mist Eliminator
** ** ** **
Mellachevron™
6
Mist Eliminator
***
Shell VersiSwirl™ 6
Shell Schoepentoeter™
and Schoepentoeter Plus™ 7
Inlet Device
Treelnlet™
7
Device
HiPer™ Cyclone
8
Inlet Device
GITV
8
Vapor Horn
4
Product overview
KnitMesh V-MISTER™
5
Mellachevron™ Mist Eliminator
Shell VersiSwirl™
6
MKS Multi Cassette™ Mist Eliminator
Treelnlet™ Device
Key characteristics
• The Treelnlet provides a superior liquid pre-separation and gas
distribution and is normally effective up to dynamic pressures of
about 10’000 Pa.
Key areas of application
• The Sulzer Treelnlet is an axial flow vane gas inlet device for vertical
feed nozzles.
• Ideal for bulk liquid disengagement in a wide range of services and
applications.
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HiPer™ Cyclone Inlet Device
8
Mist elimination
Liquid entrainment in a process gas stream can be formed by If the gas is travelling too fast to allow the liquid droplets to settle out
either dynamic processes, such as contact between gas and liquid under gravity, they become suspended (or entrained) in the gas or
phases in a mass transfer operation, or thermal processes such vapor. In most cases, the entrainment must be removed to purify the
as condensation. For example, droplets can result from bubbles gas and prevent potential process or environmental contamination.
bursting or jetting at a gas/liquid interface - typically in distillation
columns, evaporators, bubble columns and flooded packed bed Sulzer mist eliminators provide an effective solution to liquid
scrubbers. Where there is a high relative velocity between gas and entrainment problems in many types of equipment including:
liquid, droplets can be sheared from the wet surfaces. This type of • scrubbing, absorption, stripping or distillation columns
problem is likely to occur in venturi scrubbers, two-phase flow in • evaporators
pipes and packings. • falling film condensers
• knock-out vessels
Droplets can also be formed by thermodynamic changes in a • 3 phase separators
system. For example, vapor condenses when saturated gases • desalination plants
are cooled in condensers and heat exchangers and, although • refrigeration plants
most of the liquid will remain on the heat transfer surfaces, the gas • gas dehydration plants
can become supersaturated in places causing droplet formation. • compression systems
This type of condensation mist can occur during heat exchange
processes, the sudden release of pressure or by mixing hot and
cold gas streams. Similar mists can result from gas phase reactions
which yield a liquid product. Typical applications suffering from mist
contamination include sulfuric, phosphoric and nitric acid plants.
Rain
Drop Drizzle Mist Fog
Entrainment
from water
cooling & spray
cooling towers
500 200 100 50 20 10 5 2 1 0.5
Droplet diameter (microns)
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Mist elimination
Several types of mist eliminators are available for the separation Each mechanism is critically dependent on the droplet size
of entrained liquid. To choose the appropriate equipment, the four distribution for a given application. For example, in gas drying
basic mechanisms of droplet capture should be considered. applications using glycol contactors, droplet size distributions are
often in the range of 5-25 µm and high separation efficiency is
• Diffusional Deposition is only effective in the separation of very critical. In these circumstances, direct and inertial interception are the
finely dispersed aerosols with droplets typically smaller than 1µm - most appropriate mechanisms and separation is best achieved by
that are small enough to be affected by Brownian Motion. impingement of droplets on the wires and fibers of high performance
• Direct Interception assumes that a droplet of a given diameter and mesh mist eliminators.
negligible mass follows the stream line around the ‘target’ wire or
fiber and is separated as it touches the target or collection fiber. Diffusional deposition is an important mechanism in the design of
• Inertial Interception considers the droplet mass and predicts how fiber bed mist eliminators (candle filters) used for removal of sub-
momentum will make it deviate from the gas stream. micron droplet dispersions found in applications such as acid mists.
• Gravitational Deposition works on the principle that large, slow
moving droplets may separate from a gas stream under gravity.
This is restricted to large droplet sizes and low superficial gas
velocities – making separator dimensions both unreasonably large
and uneconomical.
• Sulzer Mellachevron™
– inertial interception
Diffusion • Shell VersiSwirl™ and Swirltube Light™
– inertial interception
• Sulzer KnitMesh™
– inertial/direct interception
• Sulzer MKS Multi Cassette™
– inertial/direct interception
Flow streamlines
Direct interception
Gravity
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Mist elimination
Gravity Baffles/ Vane packs – Vane packs – Axial cyclone Knitted Candles/
separators/ louvers simple vanes with drainage separators mesh mist fiber beds
knockout channels eliminators
drums
Direct
Separation Gravitational Inertial Inertial Inertial Inertial Inertial/direct interception/
mechanism deposition interception interception interception interception interception diffusional
deposition
Gas handling
Low High High High Very high Moderate Low
capacity
30 %
Turndown capacity Very high 30 % 30 %-50 % 30 %-50 % Higher with 25 % Very high
preconditioner
Low except Low except High down High down High down Very high down Very high at
Efficiency for large for large to approx. to approx. to approx. to sub-micron
droplet sizes droplet sizes 25 µm 25 µm 10 µm 2-5 µm droplet sizes
Liquid load capacity Very high Very high Moderate High High Moderate Low
Solids
Very high Very high Moderate Low Moderate-high Low Very low
handling capability
Prone to fouling Prone to fouling
Suitable for high Suitable for high Unsuitable
Liquid Suitable for high Suitable for high with high liquid with high liquid
viscosities/ viscosities/ for high liquid
viscosity viscosity viscosity viscosities/ viscosities/
waxes waxes viscosities
waxes waxes
Pressure
Very low Very low Low Low Moderate Low High
drop
Design advice
v = K· √ ρ ρ- ρ
l
v
v
Comprehensive performance information is available v = maximum superficial gas velocity Derating factors are often applied
on a wide range of standard designs, enabling Sulzer ρl = liquid density to allow a safety margin for
engineering staff to tailor the mist eliminator design to ρv = gas density exceptional conditions such as
suit most applications. K = a constant which is specific to the liquid slugs and gas surges, and
separation equipment and is a function the K-value can be optimized to
For best performance, it is important to achieve of process parameters such as: suit specific process conditions,
uniform gas flow distribution and maximum effective • Liquid loading and challenging physical
area, and recommendation can be given on the most • Gas and liquid viscosity properties such as low surface
appropriate positioning, in terms of disengagement • Gas pressure tension systems. The selection
distances from vessel inlet, outlet and other vessel • Surface tension of K-value is therefore critical
internals. and we recommend that designs
should be checked by our
engineering team.
Sizing
Equipment type K-Value ft/s
For equipment based on direct and/or inertial
m/s
interception, gas stream velocity affects all three
principles involved in separation (impingement, Gravity *) 0.07 0.23
coalescence and drainage). Flooding, or re- Sulzer Mellachevron – simple profiles 0.13 – 0.17 0.42 – 0.56
entrainment of liquid, can occur if the flow of gas Sulzer Mellachevron –
0.15 – 0.45 0.49 – 1.46
prevents drainage, and the effective area of the mist high capacity profiles with drainage channels
eliminator is therefore established by determining an Sulzer KnitMesh mist eliminator 0.08 – 0.12 0.26 – 0.4
appropriate superficial velocity for the equipment.
Sulzer KnitMesh V-MISTER 0.08 – 0.13 0.26 – 0.43
The overall performance of the mist eliminator is then
Sulzer MKS Multi Cassette *) 0.10 – 0.30 0.33 – 1
a balance between efficiency and pressure drop.
Shell VersiSwirl *) 0.15 – 0.30 0.5 – 1
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KnitMesh mist eliminators
Metal Designs
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KnitMesh mist eliminators
3
Liquid load: 1.1 m3/m2 hr
2
2.5 3 3.5 4 4.5 5
Velocity (m/s)
The advantage of longer service time of the Sulzer KnitMesh XCOAT mist eliminator
compared to common wire mesh pads using Teflon filaments or higher alloyed and Sulzer KnitMesh XCOAT mist eliminator for
acid-resistant steel wires has been demonstrated in several industrial applications. a sulfuric acid drying column
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KnitMesh mist eliminators
Fig. 3 illustrates one layer of mesh within the mist eliminator and
stages of separation considered by the performance model:
• D1 avoids capture and moves in to the next layer of mesh.
• D2 is captured by the mesh.
• D3 and D4 coalesce to form a bigger droplet or film.
• D5 drains from the mesh surface. Fig. 3: The stages of droplet separation on a wire mesh.
An extensive range of mesh styles have been analyzed for a variety Existing applications for Sulzer KnitMesh 9797 Mist Eliminators
of process systems ranging from air/water to more challenging include:
hydrocarbon conditions. The performance of the mist eliminator is • glycol contactors – minimization of TEG entrainment from natural
established by calculating the cumulative effect of combined mesh gas dehydration columns (see p 21).
layers and their characteristics. The model allows a high degree • gas sweetening – installation in amine absorbers
of optimization so that layer specifications can be varied to meet • dew-point separators – 9797 designs have helped reduce water
specific process challenges. For example, high free volume/low liquid and hydrocarbon dew-points in natural gas processing (see p 23).
hold-up may be an important feature of the inlet region of the mist • rotary screw compressors – reduction of entrainment of synthetic
eliminator with a gradual increase in separation efficiency towards oil from compressor system knock-out drums
the outlet. • steam drums – guaranteed steam dryness can be achieved using
Sulzer KnitMesh 9797 mist eliminators
i=n
VN is the volume of droplets leaving layer N
i = n-1 Ei is the individual layer efficiency,
Fig. 4
i=1
VN = V0 ∏ (1 – Ei )
i=1
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Mellachevron
Sulzer Mellachevron™
mist eliminators
Sulzer Mellachevron vane mist eliminators are
high capacity inertial separators constructed as
banks of parallel, chevron profiles which cause
the gas to change direction several times from
inlet to outlet. Momentum forces entrained liquid
droplets to impinge on the vane surfaces where
they form a liquid film and drain.
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Mellachevron
Mellachevron designs are available for installation in either vertical or Typical housing arrangement for cross-flow Mellachevron. Sectional
horizontal gas flow. When gas flow is horizontal, the liquid film on the installation allows installation and removal through manway and vane
surface of the vane drains vertically downwards into a liquid sump. profiles can be dismantled individually for cleaning if necessary.
Complex Mellachevron profiles are used with hooks or drainage
channels which help to disengage the liquid from the gas stream and Liquid is collected in the sump and drained through the downcomer
prevent re-entrainment from the downstream face. pipe connection.
Gas
Mellachevron – Mellachevron –
simple vanes complex profiles with drainage channels
Type C – profile Z - profile C or Z - profile Complex profile - Z-profile with Z-profile with
with large vane integral drainage drainage hooks large vane spacing
spacing channel
Profile
Pressure drop Very low Low Very low Moderate Low Low
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Mellachevron
Sulzer Mellachevrons can be installed H45D and V35D high performance vane
in a variety of vessel configurations and packs provide significant advantages
as arrangement of multiple vane boxes over conventional vane mist eliminators,
to provide optimum flow and drainage including:
characteristics within the space available. • reduced pressure drop at high gas load
Typical box and vessel arrangements are factors
illustrated below in Fig. 5a and 5b. • improved liquid drainage and gas
streamlining based on hollow blade
The sophisticated vane profile with integral concept
drainage channels of our Mellachevron • up to 40 % higher gas load capacity
1. Vertical flow
1
2. Cross flow – horizontal vessel
1
3. Cross flow – two-stage separator
4. V-bank
5. Cross flow – in-line separator
3
5
2
4
Fig. 5b
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Axial cyclonic devices
Shell VersiSwirl™
Shell VersiSwirl axial cyclone represents an evolution of the long
established SMS, SVS, SMSM and SMMSM family of separators.
In comparison with the previous generations of technologies, Shell
VersiSwirl gives a step-change in performance in terms of efficiency
and capacity allowing for either smaller vessel or greater capacity.
The numerous technological improvements incorporated in the Shell
VersiSwirl include a new aerodynamic swirler, optimized secondary
gas handling and liquid film drainage. In the Shell VersiSwirl, liquid is
separated from the gas stream by impact of liquid droplets on axial
cyclone tube wall which are then drained via slits into a collection
chamber. The droplets are forced to the wall by centrifugal forces
induced by the gas vortex generated by the swirler.
Primary
For the most demanding duties, the Shell VersiSwirl can be gas outlet
combined with other technologies which provide an Edge over Secondary gas
its already impressive performance. For non-critical duties, a outlets with
Shell Schoepentoeter™ is used as standard, but in challenging decreased gas
throughput
applications, a Schoepentoeter Plus™ will greatly reduce
Top plate
entrainment from the inlet zone.
Improved
secondary gas
management
Improved
separation part
Liquids
Recommended use:
• comparable efficiency but higher capacity compared to vane
packs
• operation possible at higher pressures/ lower surface tensions
than vane packs
• compact design makes it suitable for offshore industry or in
general for high pressure conditions
• for debottlenecking of existing separators
• for high turndowns with pre-conditioner (up to factor 10)
• application for slightly fouling service and may be used where
complex vanes or wire mesh mist eliminators may become
plugged
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Combined systems
Selection of the appropriate primary separator is key to the system’s Shell VersiSwirl/Drainable KnitMesh, SLR + Schoepentoeter Plus:
overall performance, whether the intention is to optimize the droplet extra drainage capacity reduces the overall load in the vessel
size reaching the Shell VersiSwirl or reduce liquid from the internals internals where critical guaranteed performance is a must.
and prevent re-entrainment. Shell VersiSwirl gives high performance for demanding applications
and when combined with optimized technologies from Sulzer’s
New combinations portfolio a tailored solution can be provided to meet the needs of the
• Shell VersiSwirl/Schoepentoeter Plus: customer. For example, Shell VersiSwirl followed by a Sulzer MKS
optimized inlet device performance Multi Cassette deck to meet extra high separation efficiencies.
• Shell VersiSwirl/V-MISTER:
improved performance over the widest range of operation
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Combined systems
Combined systems
Increasing gas capacities and higher performance requirements The liquid dispersion re-entrained from the mesh mist eliminator has
in mass transfer equipment are challenging the capabilities of a larger mean diameter (see Fig. 6) and is suitable for subsequent
conventional mist eliminator equipment. separation by secondary, high capacity equipment.
To solve this, Sulzer offers combined systems which optimize By analysis of the inlet fluid conditions, Sulzer can design optimized
the benefits of individual types of equipment and improve overall mesh structures to provide the best possible outlet conditions for the
performance. downstream separator.
For example, KnitMesh mist eliminators can be used in combination Additional benefits of combined systems include:
with Sulzer Mellachevron vane packs or Shell VersiSwirl to produce • The ability to design the equipment to provide very high turndown
very high separation efficiencies at high gas loadings. By using the capabilities.
KnitMesh mist eliminator as a pre-conditioner for the Mellachevron, • At low gas velocities, where high capacity separators tend to be
it is operated above its normal re-entrainment or flooding point and ineffective, the mesh pre-conditioners behave as conventional
consequently liquid is stripped away from the downstream surface. mist eliminators.
Frequency
KnitMesh as primary Coalesced
preconditioner large droplets
operates beyond efficiently
flooding point removed by
0 10 20 30 40 50
Mellachevron Drop size (µm)
Fig. 6
Coalesced large Separated
droplets fed liquid drains
to secondary
Mellachevron mist
eliminator
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Applications
TEG TEG
TEG
NG
NG NG
167% column diameter 131% column diameter 100% column diameter 21% column diameter
100% weight of column 73% weight of column 51% weight of column 35% weight of column
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Applications
Vapor is free of mist
Using Sulzer’s MKS 4 Cassettes
equipped with
Multi Cassette™ technology in structured
eliminators were installed in the contactor wire demisting
glycol contactors packing
top section. The application has shown to
The first application for Sulzer MKS meet measured glycol losses of < 0.1US
Collector tray
Multi Cassette mist eliminators was for gallons per MMSCF gas.
installation in Glycol Contactors in Russia.
The contactors were revamped from trays The patented Sulzer MKS Multi Cassette
to Sulzer MellapakPlus and were operated mist eliminator combines the useful
at very high gas loading factors. In order to centrifugal forces in cyclones with the high Swirl tube
keep the glycol loss low at this high column separation efficiency of wire mesh packings
Swirling
gas throughput the MKS Multi Cassette mist to give a new superior demisting device. elements
Drain pipe
Glycol
contactor
Glycol
regenerator
Feed Inlet
Scrubber Flash drum
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Applications
Low Temperature Separation (LTS) Process
The performance of the gas separators in LTS Processes is crucial in order to meet the
hydrocarbon and water dew point specifications. The dew point separator is especially
essential for the overall performance of the plant. Even small amounts of entrained liquids
will rapidly appear as increased dew point in the sales gas. To obtain the best from Compressor
the LTS Process, the high performance Shell VersiSwirl SMMSM or Sulzer MKS Multi suction drum
Cassette or the combination of both is used in the Dew Point Control Separator and in
the Separators upstream of it. To compression
Compressor
From slug
Expander
Catcher
JT valve
Glycol injection
Dried gas
Compressor Mol sieve driers to LNG unit
suction drum
KnitMesh
separator
Compressor
Flash gas to
fuel gas system
Water/HC
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Applications
Feed
pump
KnitMesh or Mellachevron
Condensate mist eliminator Brine Product
pump pump pump
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Comprehensive engineering services markets
Capabilities
Manufacturing according to PED 97/23/EC, ASME VIII Div.1, and
ASME B31.3/U-Stamp, Gost (TR), China Stamp, Norsok, or NACE
CFD Analysis
CFD calculations done in advance of fabrication can support the
decision to go for a particular technology, and can save on the
time required for commissioning and testing later. Sulzer uses CFD
technology both for the modeling of existing and the development of
new products.
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