1.advanced Technical Textile Products
1.advanced Technical Textile Products
Tatsuki Matsuo
To cite this article: Tatsuki Matsuo (2008) Advanced technical textile products, Textile Progress,
40:3, 123-181, DOI: 10.1080/00405160802386063
To link to this article: https://doi.org/10.1080/00405160802386063
1. Introduction
1.1 The content and objectives of this book in terms of advanced technical textiles
series
In the former article in this advanced technical textile series, fiber materials for advanced
technical textiles [1] have been published. In this article, advanced technical textile prod-
ucts, which are the application products of these fiber materials are introduced from the
technological point of view. The application fields in this article are classified as (1) re-
sources and environmental matters, (2) automobile, (3) medical and hygienic, (4) protection
and safety, (5) electric and information technologies, (6) construction and civil engineering,
and (7) E-textiles.
There are some application fields of advanced technical textiles to be added to the
above (1) to (7) items, such as sports, agriculture/sericulture, marine/fishery, packaging,
and textiles for production machines and systems. But they are not included in this article
to save the pages under the volume restriction. Although electronic textiles are still at an
infancy stage, they have now become one of the exciting application fields as to be treated
in an independent chapter.
Objectives in the concept for writing this article are as follows:
∗
Email: [email protected]
(c) to give them a feeling of how large the potential of advanced technical textile products
is in its technological advancement.
The topics in the article must cover quite a wide range to cope with the above objectives
within the volume restriction. Therefore, all the description must be compact. Hence, the
readers may often want to know more in detail. In addition, many cited references in this
article are written only in Japanese. In order to avoid this difficulty to some extent, a few
important books related to technical textiles written in English are especially listed at the
end of the “references” part.
In many cases of fiber-reinforced composites, functional elements (2), (3), and (4) are
fully utilized. In several kinds of membrane hollow fibers, the element (3) is highly utilized.
Optical fiber utilizes firstly the element (2) and secondly the element (1). In tyres, (1), (2),
and (3) are main functional elements.
The required performance for textile products is varied with detailed kinds of end uses.
Then their optimum structures are fully dependent on their end uses. Therefore, technical
textile products are much wider in their structural range than apparel textiles.
gradually increased. As understood by these descriptions, the heart of some strong enthu-
siasm and patience are generally needed for the manufacturer in the business of advanced
technical textiles. In contrast to conventional textile business, the life of commercial value
for the advanced technical textile product thus developed is usually much longer because
of the technological barrier grown by the development.
In the business of advanced technical textiles, the manufacturer must be sensitive to
patent management. In the early stages of the development, he must carefully check if
all the technologies in the development will not be obstructed by any existing patents and
must also apply the patents related to the development to guard the development and the
output products.
1.3.2 The market size of advanced technical textiles
The product forms of technical textiles for a specified manufacturer can be fiber, textiles
(fabrics etc.) or unit/parts using textile. Statistics of amount for technical textiles are
influenced by what product form is adopted for the statistics and how technical textiles are
defined in their range for the statistics. Hence market sizes of technical textiles in amount
and value are not so clear. But Table 1, which shows worldwide consumption statistics
of technical textiles reported from an investigation company [2], must be useful to have a
rough idea of the market size of technical textiles by application field. There are no statistics
for advanced technical textiles, which is fully dependent on the range defined as advanced
technical textiles. But roughly speaking, the author feels that their share in technical textiles
is over 50% in advanced countries in total size.
Growth Growth
2000 2005 (% per annum) 2000 2005 (% per annum)
Transport textiles (auto, train, 2,220 2,480 2.2 13,080 14,370 1.9
sea, aero)
Industrial products and 1,880 2,340 4,5 9,290 11,560 4.5
components
Medical and hygiene textiles 1,380 1,650 3.6 7,820 9,530 4.0
Home textiles, domestic 1,800 2,260 4.7 7,780 9,680 4.5
equipment
Clothing components (thread, 730 820 2.3 6,800 7,640 2.4
interlinings)
Agriculture, horticulture and 900 1,020 2.5 4,260 4,940 3.0
fishing
Construction – building and 1,030 1,270 4.3 3,390 4,320 5.0
roofing
Packaging and containment 530 660 4.5 2,320 2,920 4.7
Sport and leisure (excluding 310 390 4.7 2,030 2,510 4.3
apparel)
Geotextiles, civil engineering 400 570 7.3 1,860 2,660 7.4
Protective and safety clothing 160 220 6.6 1,640 2,230 6.3
and textiles
Total above 11,340 13,680 3.9 60,270 72,360 3.7
Ecological protection textiles 230 310 6.2 1,270 1,610 4.9
126 T. Matsuo
and energy saving at fiber plant/textile mills, (5) treatment of wastes at fiber plant/textile
mills, and (6) reuse and recycling of textile products can be classified as defensive. Offen-
sive technologies can be mentioned as follows: (1) water treatment and purification; (2) air
purification; (3) enhancement of energy resources through fibrous materials for the elec-
trode and the separator of battery/fuel cell, for reinforcement of wind turbine and through
composites for lightening transport vehicles; (4) energy saving through comfortable wears
for mild cool air conditioning in summer and for mild warm air conditioning in winter; (5)
energy saving through fibrous materials by thermal insulation; (6) recycling of polyethy-
lene terephthalate (PET) bottle into fibrous materials; and (7) water-saving systems for
plantation.
Regarding the items (1) and (2), some introductive explanations are given in the former
article [1] in this series. The items (1), (2), (3), (4), and (5) in offensive technologies and
item (6) as technical textiles in defensive technologies are introduced in this chapter.
2.2.1.2. Bioreaction systems. In case that the filter medium is a layer piled by large number
of fiber-mass blocks sustaining microorganism, the filter systems described in section
Figure 1. Filtration system using rotating drum covered by a microfiber woven fabric [3].
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Figure 2. Bioreactor using membrane hollow fibers. (a) reactor [4] (b) actions to a hollow fiber;
MBR indicates membrane bioreactor.
2.2.2.1 can act as not only a filtration vessel, but also as a bioreaction vessel to reduce the
biological oxygen demand of organic wastewater. Figure 2 illustrates a bioreactor using UF-
/MF-membrane hollow fiber. In the system, large numbers of the fiber module are dipped
in activated sludge aeration tank. Water suction is applied in the hollow part of the fiber.
Activated sludge filtrated on the outer surface of the fiber is removed by the bubble made
by aeration. As compared to conventional bioreactor tank, it can be much more compact
and the quality of treated water is much higher [4].
2.2.2 Reverse osmosis and UF/MF using membrane systems for the production of purified
water
2.2.2.1. Reverse osmosis. Figure 3 shows the principle of reverse osmosis (RO) hollow
fiber, whose membrane is nonporous (see Figure 6 in the former article [1]). By applying
higher pressure than the RO pressure, water permeates through the membrane into its
hollow part. Such materials as salt, virus, and pyrogen can be rejected at the surface of
2.2.2.2. UF and MF for water work. In water work, the requirement to remove pathogenic
microorganisms has been enhanced, especially in developed countries. Most of UF- and
MF-membrane hollow fibers are very feasible for the requirement (see Figure 6 in the
former article [1]).
2.2.2.3. Reuse and recycling of water. In order to efficiently utilize water, several techno-
logical systems for the reuse of wastewater or water recycling have intensively developed.
In these systems, RO-, UF- and MF-membrane hollow fibers have been utilized according
to water-quality requirements
2.2.3.2. Photocatalyst fiber. A water purification system using conical nonwoven units
made of photocatalyst fiber has been developed [6]. The constituent of the fiber is gradually
varied from silica at the core part to TiO2 (photocatalyst) at the surface. In the system, an
ultraviolet (UV) lamp is located at the axial center of the conical units line. Contaminants
in the water are oxidized and degraded by the photocatalyst under the UV light during the
passage of water through the conical units line. The system is going to be widely applied
130 T. Matsuo
for purifying several kinds of water in recycled water usages such as public bath, spring
bath, swimming pool and industrial use water.
2.2.3.3. Ion-exchangeable fibers. There are some kinds of ion-exchangeable fibers. They
can be effective to remove toxic ingredients of heavy metal from water. The fiber made of
ion-exchangeable polystyrene resin is used for purification of recycled water from atomic
power plants.
2.2.4.2. Separation and removal of oil from water. This section concerns removing small
amount of water from oily materials, or small amount of oil from water. Figure 5 is a typical
example of the system for the removal [7]. The coalescer cartridge medium is composed of
microfiber nonwoven felt having very small pore size. Small size of oil particles can quickly
coagulate by the microfiber network as schematically shown in the figure (a). The separator
cartridge is made of membrane, screen or nonwoven having surface of water repellency.
This kind of system is used for such end uses as the removal of water from aircraft fuel, the
removal of water from petroleum products, and the removal of oil from cooling water for
chemical plants.
Figure 5. Oil/water separator [7]: (a) principle of separation at coalescer medium and (b) separator
tank with coalescer and separator cartridges.
drop is also increased. Removal efficiency is the lowest at 0.05–0.1 µm of dust particle
size, because inertial collision effect for catching dusts within airflow by fiber within the
medium becomes more significant for larger particles with particle size above 0.1 µm,
and diffusion effect is more effective for small particles, below 0.05 µm. Filter medium is
Figure 7. Removal system for toxic gas using honeycomb bed made of activated carbon paper [9].
usually pleated in the filter of high removal efficiency, because pleating increases the area
of filtration and can reduce the pressure drop of the filter by lowering the velocity of air
passing through the filter medium.
Electret filter can have higher removal efficiency with comparatively low pressure drop
by making the use of electric static traction force between dust and fiber. The filter unit
whose medium is exchangeable after its pressure drop increases up to the settled value has
been developed in order to save unit frame.
Figure 8. Solvent recovery system using activated carbon fiber felt [9].
Textile Progress 133
2.4.1.2. For separator. Wet-formed nonwoven made of such fiber material as PP is used
for the separation sheet of nickel/hydrogen battery. The sheet is composed of fine fibers
and is finished by hydrophilic treatment, which enhances its working life, its electric power
and its ability to suppress self-discharge.
2.4.2 Composites for high-pressure vessel, wind turbine blade, and the rig of deep-water
oil plant
2.4.2.1. High-pressure vessel. Compressed natural gas (CNG) is more environmentally
friendly than gasoline because CNG emits less CO2 than gasoline. Its vessel can contain
the CNG of 250 atm pressure. The CNG vessel made of carbon fiber reinforced plastic
(CFRP) is 70% lighter than that of steel. The former is generally fabricated by filament
winding on Al liner.
Highly pressured hydrogen is one of the most realistic candidates as the fuel source
for the fuel cell of automobile. Its pressure is required to be about 700 atm. Hence CFRP
vessel using high-performance carbon fiber is indispensable to keep the weight of vessel
lighter than 50 kg/unit.
2.4.2.2. Wind turbine blade. The total amount of electric power produced by the installed
aerogenerators has been growing rapidly. Most of their turbine blades are made of glass
fiber reinforced plastic (GFRP ). But with an increase in their size in order to attain higher
efficiency, CFRP becomes a more suitable material for their blade. It is usually fabricated
by vacuum-assisted resin-transfer molding [10] method using multiaxially layered warp
knit [11].
2.4.2.3. Rig tools of deep-water oil plant. In order to cope with the growing demand of oil
and saturation tendency of its production amount, the necessity of oil digging in the area
of deep-sea water has been more serious. The tether and riser made of steel for such a rig
134 T. Matsuo
Figure 9. Comparison of weight reduction effect by panels made of several materials under the
condition of same stiffness [12]; SMC indicates Sheet molding compound; CFRP, carbon fiber-
reinforced plastic.
cannot resist their own heavy weight. Then CFRP composites have become indispensable
material for them.
Figure 11. Examples of automobile parts made of glass fiber reinforced plastic: (a) Intake-manifold
made of PA6/GF [14], (b) Mount bracket made of PA66/GF [15], and (c) Engine head cover made of
PA66/GF [15].
reduction ratio is 40% from previous aluminum part. In the case (b), the mount bracket is
fabricated by injection molding, and its weight reduction rate is 50%. On the other hand,
the use of CFRP parts to passenger cars has been fairly limited. Figure 12 is an example
of the advanced cars in which many parts are composed of CFRP. In this case, most of
the exterior panel, most of the chassis, and the shock absorber are made of CFRP. Its use
of carbon fiber is more than 110 kg/unit. In the near future, introduction of CFRP into
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automobile parts and frame will be gradually increased with an increase in the demand of
energy saving.
automobile is extremely difficult. But the dust sorted as mixture of fibrous materials and
urethane has been transformed as automobile silencer boards settled between engine, cabin,
and under-floor carpet [20].
The automobile parts made of technical textiles are necessarily reused in the reused car.
This is one of the most popular examples of reuses of technical textile products.
2.6.2 Recycling of fibrous materials into technical textile products
Recycled fibrous materials have been widely used for cushion material and wiping sheet.
In addition to these applications, several trials for recycling into technical textile products
have been conducted. We can mention such applications to man-made wood, floorboard,
substrate sheet for cultivation, reinforcement of earth, and silencer as mentioned above. An
example of a boat made of the man-made wood produced from recycled fibrous material has
been reported. One of the other examples of recycling from textile mills is the application
to substrate sheets for lawn cultivation.
2.7 Water-saving system for plantation
There is a large area of land in the world where water resource is too insufficient to make
and to keep plantation. Therefore it is thought that the efficient use of water for plantation
is very important to be developed. Nonwoven has been widely used for controlling sunlight
by covering agricultural plant. But the use of fibrous materials for irrigation and water
retention for plantation has been very limited. But there have been several remarkable
proposals of irrigation system for water saving.
3. Textiles products for automobiles
3.1 General scope of textile products in automobile sector
The automobile sector is the largest user as estimated from Table 1. The amount of fiber used
for a standard passenger car is about 25 kg. This is now increasing because the requirements
for the safety and comfort of passengers and for car weight reduction, which means an
increase of reinforcing fibers for hard composites, are being intensified. Furthermore, the
worldwide demand for automobiles is growing. Hence, the total amount of automotive fiber
is increasing. These facts indicate the industrial importance of automotive fiber in terms of
end use.
The selection criterion for automotive-use materials is “performance/cost” similar to
most other technical textile materials. But it is generally more strictly applied to automotive
use. For example, steel cord is usually used as a reinforcing material in tyre-belt plies for
passenger cars. The reason is that steel has the largest value for “tensile modulus/cost” of
the existing materials. But if car weight reduction becomes more important in the future,
the selection criterion may become “specific tensile modulus/cost” and then steel could be
replaced by a high-performance fiber such as polyketone fiber [21].
Fiber is used in the manufacture of several kinds of parts in automobiles such as (a) tyres,
driving belts, tubes, and hoses; (b) seat belts and air bags; (c) seats, roof trims, and floor
coverings; (d) noise control materials; (e) cover sheets; (f) filters; and (g) mechanical parts,
exterior body panels, and bumper beams. In the near future, optical fiber for the information
and driving-control system and reinforcing fiber for the fuel pressure vessel may also be
widely used. The percentage use of automotive fibers for main parts is summarized in
Table 2. “Hard composites” is the second largest user group, as shown in the table. They are
reinforced mostly by glass fiber through compression molding and/or injection molding.
With regard to the shares in the total amount of automotive fibers used, PET fiber takes
up about 42% and nylon 66 fiber about 26% [22].
138 T. Matsuo
Figure 13. Structures of tyres for passenger car [23]: (a) bias tyre, (b) radial tyre, and (c) the
cross-sectional structure of radial tyre.
Textile Progress 139
Table 3. Properties of nylon 66 and HMLS PET tyre cords comparing with other materials [24].
High-modulus
low-shrinkage
polyethylene Polyethylene Rayon
Nylon 66 terephthalate naphthalate (PEN) super III p-Aramid Steel
is usually used for body ply cord because of its excellent toughness. In radial tyres for
passenger cars, PET fiber is mainly used for body ply cord because its higher modulus can
contribute to improved driving comfortability by the reduction of flat spotting. Nylon 66
fiber is mainly used for cap ply cord because of its higher strength and higher toughness.
A high-modulus low-shrinkage type of PET multifilament is usually used for tyre cord
because higher modulus and higher heat resistance in shrinkage are important requirements
of tyre cord. But an important problem that needs to be improved for PET is its comparatively
low adhesiveness to matrix rubber. Regarding nylon, a high-strength type of multifilament is
required for tyre cord. The properties of tyre cords made of several materials are summarized
in Table 3 in which yarn thickness/number of plies is also shown.
There are some other methods for the fiber reinforcement of tyres than using cord. One
is a direct blend of short fiber such as p-aramid with matrix rubber. Another example is the
use of the composite made of p-aramid nonwoven and rubber, which is inserted into the
inner part of a truck/bus tyre to increase run-flat capability.
Figure 14. Structures of several kinds of driving belts [24]: (a) wrapped V-belt, (b) raw edge V-belt,
(c) V-ribbed belt, (d) block, (e) rubber belt (f) belt with cog, and (g) composite V-belt.
Figure 15. Examples of inflated airbags [26]: (a) front airbags, (b) thorax bags and curtain bag.
The base material of an air bag is nylon 66 weave because nylon fiber can be more
compactly contained and has higher resistance to small burning particles. The thickness of
nylon filament used for air bags ranges from 235 to 700 dtex. The number of monofilaments
ranges from 70 to 220. A high-strength type is needed. There are two types of base material –
coated and noncoated. The coating material is now mainly silicone resin. The advantages of
the coated type are better nongas permeation, easier bag-pressure control, and greater heat
resistance to burning particles. On the other hand, the noncoated type is lighter in weight,
thinner, more flexible, and less expensive. For noncoated cloth, some special products
have been developed by weaving with an ultra-high yarn density, with a filament of lower
monofilament thickness, and with a filament whose fiber cross section is flat.
3.4 Car interiors
The main interior components of an automobile are the seats, door trim, roof trim, and floor
covering.
3.4.1 Seats and door trim
Polyester fiber is used for most of the seat skin sheet and for some seat cushion material.
It is also used for some door trim skin material because PET fiber has a higher modulus,
higher heat stability, higher resistance to color change, and higher durability for sunlight
degradation and is less expensive.
There are several kinds of seat skin sheets such as pile weave, weave, tricot with
raising, pile double raschel knit, and pile circular knit. General trends are toward an
increase in knit fabrics (tricot, double raschel, and circular knit) that are less expensive
and have more formability than weave fabrics. Recently, a suede fabric, using a PET
microfiber nonwoven as base material, has been introduced. Skin sheets containing phase-
change material (PCM) have also been developed, which can increase the microclimate
comfortability of the seat. The essential properties of seat skin sheets can be classified as
aesthetic effect, physiological comfortability, strength/wearing durability, color fastness,
flame retardancy, heat resistance, and nonvolatile substance content. They are also often
required to have some special functions such as antibacterial, deodorizability, antistatic
and stain-resistant properties. Pile or raising of these sheet fabrics is usually related to an
increase in the values of tactile and visual aesthetic effects. An extremely high level of color
fastness in sunlight is usually required because automobiles can be used in the environment
of high temperatures and strong sunlight.
142 T. Matsuo
Urethane foam is usually used for seat cushion material under the skin sheet. But
some special PET nonwovens have recently been developed such as a fiber mass stabilized
with elastomer fiber-fused bonding, a folded web and stitch-bonded web, and a PET three-
dimensional knit fabric with super water absorbancy. One of the most important advantages
of these fibrous materials over urethane foam is their good moisture permeability, which
keeps passenger’s physiological comfort.
The material of door trim skins is usually made of plastic such as vinyl chloride and
polyolefin. But textile sheets are also used for higher-class cars. In most cases, the textile
material is the same as the seat skin fabric. However, the fabric needs to have high enough
formability to be made into the complicated shape of a door trim. Its lower end is usually
covered by the same carpet as the floor because the door often gets kicked.
3.4.2 Roof trims
PET nonwoven and tricot are used as roof trim skin sheets. The use of needle-punched
nonwoven in particular has increased, and nonwoven patterned using velour by needling
is especially common. But there are also spun-laced nonwovens and stitch-bonded
nonwovens. They are usually formed into roof trim by integration with base materials.
Pigment-dyed PET has been widely adopted. Sheets need to have color fastness for sun-
light, heat resistance, mechanical durability, light durability, formability, and nonvolatile
substance content and stain resistance in addition to lightness. Certain levels of sound-
absorbing capability and heat insulation are also needed.
The base materials for roof trim can be mainly classified as polymer foam sheets and
fiber-reinforced porous polymer sheets. Glass fiber is usually used for reinforcing these
sheets.
Figure 16. The illustration of three main types of surface patterns for needle punched carpet [27]:
(a) plain, (b) loop like, and (c) velour like.
Textile Progress 143
carpets consists mainly of pigmented PET fiber and/or pigmented PET recovered from
bottles. Its fiber thickness is reduced from 11 to 6 dtex to increase its covering factor. Quite
attractive aesthetic effects can be achieved with needle-punched carpet by the specific
patterning described above. The main performance requirements are mechanical durability,
sunlight durability, heat resistance, sunlight color fastness, sound absorbability, sound
insulation, antifogging, nonvolatile substance content, flame retardancy, stain resistance,
and formability. With an increased requirement for weight reduction, sound absorbability
has become more important than sound insulation.
Tufted carpet has usually been used for optional carpets, where its aesthetic effect and
appearance of high quality to the customer is of greater importance. Its weight ranges from
350 to 2000 g/m2 on the basis of the wide variety of customer requirements. Its surface
material fiber is nylon, PET, or PP. PP is now increasing its usage share.
Figure 17. System for removal of particles exhausted from automotive diesel engine [32]; ACG
indicates alternating current generator.
Figure 19. Several kinds of separation functional fibrous products for medical use in terms of pore
size [35].
There are many kinds of fibers and textiles that have their own separating functions
for medical use, as shown in Figure 19. These functions are originated from the action
of sieving molecular/particle through the pore or molecular spacing of their own specified
size.
In the first part of this section, membrane hollow fibers for artificial kidney, artificial
lung, and some other medical treatments are introduced. Then a system using fibrous
material for leukocyte reduction, which is also medically used, and some applications of
fiber/textiles to tissue/biological engineering will be introduced. Finally, miscellaneous
applications of fibrous materials to medical and paramedical uses are described.
4.1.2 Membrane hollow fibers for artificial kidney, artificial lung, virus removal and others
4.1.2.1. Artificial kidney. With a fall in the functional ability of kidney, water and the
waste substances such as urea that should be discharged as urine gets accumulated in
blood, causing uremia.
Artificial kidney is the system that artificially purifies the blood on the basis of dial-
ysis. Its module is consisted of a large number of hollow membrane fibers, as shown in
146 T. Matsuo
Figure 20. Water and waste substances contained in blood are introduced into the hollow
part and diffuse through fiber membrane on the basis of their concentration gradient. The
typical example of inner diameter and membrane thickness of the fiber is 200 and 10
µm, respectively. Several kinds of materials for the membrane have been developed such
as regenerated cellulose, triacetate, polyacrylonitrile, polymethylmethacylate, polyvinyl
alcohol, and polysulfone. The material is selected and/or modified in order to avoid
bioincompatibility troubles such as complement activation and/or leukocyte reduction.
Several kinds of countermeasures to realize the uniform contact of dialyzing liquid with
membrane fibers have been taken. They include uniform fiber crimping, spiral winding of
thin yarn on fiber, and the introduction of a certain projection to fiber.
Human kidneys have sharp sieving characteristics, as shown in Figure 21. Sieving
characteristics of previous conventional artificial kidneys was so much different from that
of a human kidney that the accumulation of β2-microglobulin has caused the problem of
serious symptom. Thereafter, the improvement of artificial kidneys in sieving characteristics
toward human ones has been carried out.
4.1.2.2. Artificial lung. Artificial lung is used for backing up heart surgery. Hollow fibers
whose pore size is less than 1 µm are a key component in the lung system. Pressured oxygen
and carbon dioxide-rich blood are introduced into the inside and the outside space of the
hollow fiber, respectively. Gas exchange between oxygen and carbon dioxide is carried out
Figure 21. Sieving characteristics of artificial kidney and human kidney [36].
Textile Progress 147
Figure 22. Enlarged view of membrane hollow fiber used for artificial lung [37]: (a) the cross-
sectional view of the membrane where an active layer is located in the center and (b) the view of the
outer surface.
by diffusion through the membrane. Figure 22 shows an example of hollow fiber used for
the system, whose gas exchange rate is extremely high because of a very thin active layer
in the middle. The active layer consists of amorphous polyurethane and is supported by the
two outer porous layers made of high-density polyethylene (PE).
4.1.2.3. Virus removal filter. The filter must have both sufficient permeability for plasma
protein whose range is from about 1 to 10 nm and sufficient removal rate for virus including
HIV whose size ranges from about 10 to 100 nm. The material of this UF membrane hollow
fiber is cellulose. A kind of specific capillary-void structure is extended within the membrane
in its thickness direction, whose size is strictly controlled to satisfy the above condition.
Figure 23 shows an enlarged cross section of the membrane, which is capturing HIV.
It is said that this method is excellent in easy use, nondegradation of blood and removal
reliability than the other method of virus removal methods such as heating and low-PH
treatment.
Figure 23. Cross-section view of virus removal filter and captured HIV [35].
148 T. Matsuo
4.1.2.4. Artificial liver. Artificial liver is expected to substitute the human liver up to the
time when it will restore its functionality. The liver is a kind of bioreactor in which many
biochemical reactions take place, making it almost impossible to artificially realize its
function on the basis of these biological reactions. Hence, in the artificial liver that has
been recently developed, a liver taken from an animal such as a pig is introduced into the
hollow part of fibers to make a cylindrical cell organ. The blood or plasma of the patient is
circulated in the outside space of the fibers.
4.1.5.1. Fibrous absorbent for the treatment of septicemia. The absorbent fiber can selec-
tively remove the endotoxin from blood, which is the cause material of septicemia. It is a
bicomponent fiber of sea-and-island type whose sheath material is polystyrene. Polymyxin
B, which is a polypeptide antibionic, is chemically fixed to the porous styrene sheath of the
fiber, as shown in Figure 24. The removal is carried out on the basis of the chemical affinity
Textile Progress 149
between the endotoxin and polymyxin B. The knitted fabric made of the adsorbent fiber is
wound on a tube and contained in the module, as shown in Figure 25. The circulating blood
in the treatment system is purified while passing through the module.
4.1.5.2. Products for wound dressing. Several kinds of materials for wound dressing have
been developed. But in this part, the following three examples are introduced as their
representatives.
Chitin fiber made from crab shell is widely used for wound covering/artificial skin
carrier in the form of nonwoven/paper and sponge. It is dissolved into human body by
human enzyme and effectively enhances the healing of wounds. These wounds include
burns/scalds, bedsores, ulcers, and several kinds of external injuries. It is also used as the
carrier for cultured skin [40].
Partially carboxymethylated cellulose fiber has high absorbencies of both water and
saline. Then cotton gauze modified with the carboxymethylation used for wound dressing
can take up wound exudates. Cohesive gel sheet obtained by carboxymethyl treatment on
solvent-spun cellulose fiber has been widely used in wound management [41].
Combined sheet called as Biobrane, in which perforated silicone rubber and nylon fabric
are bonded by collagen-peptide gelatin, has been developed. The gelatin is biocompatible
Figure 25. Module containing adsorbent fiber knit for sepsis [39].
150 T. Matsuo
and can ease the pain of the patient. Rapid cell proliferation and migration into nylon fabric
occur. It can lead to faster healing of a variety of wounds including full-thickness burns
[42].
4.1.5.3. Fiber material for reusable paramedical goods. Disposal of surgical goods
through incineration causes an environmental problem. PET fabrics are rather inferior in
reusability because PET tends to be easily degraded by hydrolysis by autoclave treatment
for sterilization. Higher temperature treatment is required for higher sterilization efficiency.
A partially aromatic polyamide fiber that is feasible to such high-temperature treatment has
been developed as fiber material for reusable paramedical goods [43].
4.2.2 Diaper
Diapers can be classified as pant type and pad type according to their form, and as baby use
and aged person use according to user. But the layer components are almost the same among
all these diapers and are similar to those of sanitary napkins. In some cases, nonwovens
having fairly high stretchability are used.
the damage caused by external threats. But the performances required from these goods
and their product structures to realize the performances are fully dependent on their own
objective of protection.
In this section, textiles protective from bullet/stab disaster, danger of fire fighting, and
several harmful environmental offenses, etc., are introduced.
5.2.2 Stabproof
In the stab resistance, the key for its countermeasure is how effectively it makes the apex
point round by hard material. One example of panel structures is composed of woven fabric
with high yarn density, which is made of UHNW-PE fiber and glass fiber. Another example
is composed of p-aramid-fiber-woven fabric covered by ground-stone particles [44].
Figure 26. Manufacturing method and partial structure of a panel for bulletproof [44].
152 T. Matsuo
Figure 28. Flexible fibrous material protective from impact damage [53].
154 T. Matsuo
Composites can be useful as rigid-type material protective from impact damage. Helmet,
the toe part of safety shoes, and some protectors for sports are representative examples based
on rigid-type protection. There are two types of helmet by its material – fiber-reinforced
plastic and thermoplastic (acrylonitrile/butadiene/styrene terpolymer resin etc.). The former
can resist higher impact loading. As reinforcing fiber, glass fiber is usually used. But organic
super fiber such as p-aramid is also used for reducing its weight. Safety shoe has a toe
part that can resist high impact loading. Some examples of toe parts are made of fiber-
reinforced plastics. The part of a commercial shoe, which is made of long fiber-reinforced
thermoplastic, can sustain even the weight of standard passenger car [54].
6.3.2 Cables
Cables are used for several applications such as electric power transmission, telecommu-
nication, and wiring for electric devices. According to the object of use, their structures
are much varied. Relationships among the function of fibrous material, the kind of fiber
material in cable, and its applied cable are summarized in Table 4. Figure 31 shows the
cross-sectional structure of optical fiber cable used for main line.
Table 4. Relationships among the function of fibrous material, used fiber material, and cable
applied [58].
fibers coated with electric conductive material, organic fibers in which electric conductive
particles are dispersed, and bicomponent fibers having electric conductive part in which
electric conductive particles are dispersed.
Fibrous materials having electric conductivity are applied to such uses as antielectro-
static goods such as carpet, working wear, air filtration, conveyer belt, and clean room
clothing, and to grounding within electric equipments, shielding of electromagnetic wave,
circuit wire for electronic textiles, and the blush of electrostatic charging and discharging
for copy machine and laser printer using electrophotograph.
Figure 31. Optical fiber cable of slot type used for main line [59]; FRP indicates fiber-reinforced
plastic; PE, polyethylene.
Textile Progress 157
Figure 32. An example of electric conductive fiber and its woven fabric [60]; PET indicates polyethy-
lene terephthalate.
making its color black, as shown in Figure 32(a). The fabrics (Figure 32(b)) made of
the fiber have the shielding efficiency of about 80 dB. Some of them are transformed to
adhesive tape, which can be easily applied to cover plate, and the box to be shielded. The
sheet composed of its knitted fabric, electric conductive urethane foam, and its nonwoven
are used for electric grounding by inserting between circuit boards. The screen made of
the fine monofilament fiber is laminated to plasma display panel to cut the excessive wave
emitted from plasma display, as shown in Figure 33.
Figure 33. Electromagnetic shielding of plasma display by mesh cloth [61]; RBG indicates red, blue,
and green.
158 T. Matsuo
is transformed by E/O transformer and then is transmitted by optical fiber cable through
some relays. Optical information received is transformed again to electronic information
by O/E transformer.
For the long-distance transmission, single-mode quartz fiber whose core diameter is
about 10 µm is usually used. For middle-distance transmission, quartz fiber whose core
diameter is 200 µm is usually used. Plastic optical fiber is used for short-distance trans-
mission. Its main end uses are expected to be the LANs of automobiles, buildings such as
offices, hospitals, universities, and apartments.
Figure 35. The deformation behaviors of concrete board reinforced by high tenacity PVA short fiber
[67]: (a) bending test of the concrete board and (b) microcracks of the concrete board grown by tensile
load.
7.2.2.3. Reinforcement of concrete board. There are concrete boards reinforced by woven
fabrics. They are used for such applications as internal wall, external wall, floor, ceiling,
and formwork board. Their thickness can be less than that of the nonreinforced board.
7.3 Geotextiles
In this section, geotextiles are defined as materials for civil engineering in which fibrous
materials are used at least as one of its key materials.
162 T. Matsuo
Figure 38. Pillar reinforced by making use of board and wire [71].
Textile Progress 163
several earthquakes that recently happened in Japan, it was proved that reinforcements
using geotextiles are far better than other kinds of reinforcements. Figure 41 illustrates a
typical reinforcement of soft ground by geotextile sheet. By laying the sheet, bulldozer can
operate on even muddy ground.
Spun-laying nonwoven and geo-grid are usually used as a geotextile sheet for this kind
of reinforcement. The geo-grid belonging to geotextiles is usually fabric of mesh structure.
There are still other kinds of reinforcements using geotextiles. The following are some
of their examples: (a) short-fiber reinforcement of earth by blending; (b) blending short-fiber
material and absorbent particles with mud; (c) filling earth into textile bag; (d) reinforcement
of slope by bump jacket anchor composed of textile circular rugged tube, steel rod, and
grout intruded into the tube, as illustrated in Figure 42; and (e) reinforcement of slope and
muddy ground by specific sheet combined with jacket filled with grout. The features of the
specific sheet are that it can be very rigid after the filling of grout and that its setting work
is fairly simple.
7.3.2 Materials for drainage, separation, filtration, protection, and water barrier
7.3.2.1. Drainage. There are several kinds of geotextile material for drainage, as shown in
Figure 43. Some examples of their materials are as follows: spun-laid nonwoven and gravels,
in Figure 43(a), tube made of monofilament in (b), monofilament nonwoven board covered
by spun-laid nonwoven in (c), and plastic-corrugated board laminated with nonwoven
in (d).
Figure 40. Sharp filled earth using geotextiles and concrete [71].
164 T. Matsuo
There are vertical drainage and horizontal drainage in the earth. There are also drainages
on the slope and on the wall. Figure 44 is an example of vertical drainage system making
use of vacuuming.
7.3.2.2. Separation. The function of separation is to separate two different layers such
as (a) two kinds of earth layers, (b) earth layer and small stone layer, or (c) water, silt,
etc. In many cases, a geotextile has separation function and the other function such as
reinforcement, protection, and filtration at the same time. In the example of Figure 41, the
geotextiles sheet has the roles of both reinforcement and separation. But we can mention
silt protection membrane and pumping protection as typical application examples related
to separation function. Figure 45 shows an example of railway cross section using four
kinds of geotextile sheets: for pumping protection, for ballast net, for reinforcement, and
for grass control.
7.3.2.3. Filtration. In the case of drainage, water flows along the sheet surface. But in the
case of filtration, water flows out across the sheet through which earth particles are filtrated.
A typical example of geotextile related to filtration function is the prevention of the sand
flowing out by suction at shore protecting work, as illustrated in Figure 46. Nonwoven or
fiber-reinforced nonwoven is usually used for these kinds of sheets.
7.3.2.4. Protection. Geotextiles belonging to this category are mainly used for protecting
water-barrier membranes of such uses as pond, tunnel, and landfill place. Figure 47 is an
example of use for landfilling in which two protective layers made of thick nonwoven are
Figure 42. Reinforcement by expandable anchor bolt using textile jacket [73].
Textile Progress 165
used. Protections from mechanical damage and light degradation are the main functions of
the surface layer.
7.3.2.5. Water barrier. Some water-barrier sheets are made of fiber-reinforced rubber. They
are often used in double layers with protective fibrous sheets for landfill place, as shown
in Figure 47. Another structural example for water barrier is composed of two protective
nonwoven sheets, two water-barrier rubber sheets, and a porous drainage layer in which
sensors to watch water leakage are installed.
Figure 46. An example of protection for sand flow out at sea shore work [77].
Textile Progress 167
Figure 49. Sheet for greening to protect riverbank from erosion caused by water flow [80].
168 T. Matsuo
along the construction is strained, the light frequency of Brillouin backscattering is shifted.
Thus, such events in the range of 10 km as the crack of tunnel and the microslip of earth at
slope can be monitored.
7.4.1.2. Waterproof in construction. The waterproof materials for roof of building can be
classified into asphalt, resin-coated sheet, and thick paint coating. But the most popular
method is asphalt roofing. In this method, the nonwoven made of synthetic fiber is used for
reinforcing and stabilizing the asphalt layer.
Recently, the paper sheet that can be breathable and nailed with keeping high water
tightness by using super water absorbable fiber has been developed for waterproof roofing
of woody house [82]. It is used by laying under-roof tiles.
Figure 52. Insertion of hose into pipe by inversing using pressured air [84].
170 T. Matsuo
Figure 53. Definition of E-textile and its differences from wearable computer and smart textiles;
PCM indicates phase-change material.
8. Electronic textiles
8.1 General scope of electronic textiles
It must be reasonable to define “electronic textiles (E-textiles)” as system products in
which electronic devices are integrated with textile products for information exchangeable
functions. We can mention “wearable computer” and “smart textiles” as concepts similar to
E-textiles. But it must be noted that there are some differences among them, as schematically
shown in Figure 53. E-Textiles are also a kind of computer network system product close
to the human body along ubiquitous environment.
In the former part of this chapter, materials, parts, and circuit systems for E-textiles are
introduced. In the latter part, several application systems of E-textiles are overviewed.
Figure 54. Examples of fabric parts for switching and controlling [91]: (a) a controller part for
portable audio player and (b) a flexible keyboard made of fabric.
8.2.3 Transmitting and receiver devices and interfacing technologies for E-textiles
Microslit antenna for satellite communication and transmitter using fabric substrate have
been developed. Recently, the technologies of communication through the human body
have been developed. Its features are no disturbance by external interference and easy
communication by only human touching action. One of the technologies utilizes the changes
of electric field at the surface of the human body by a specific photonic electric field sensor
[89]. This kind of technology seems to be one of the hopeful communicating and interfacing
tools for E-textiles.
There can be such input tools for E-textiles as touch panel, keyboard, and audio instruc-
tion. Figures 54(a) and (b) are examples of input tools that have been commercialized.
Visual output tools are ranged from an indicating lamp to image display panel for
visual. Audio output is more desirable for some useful purposes. For wearable computer,
head-mount display is conventionally used for image display. Figure 55 illustrates a sleeve
display integrated into a working wear and a watch-type controller.
172 T. Matsuo
Recently, a robot suit system utilizing an innovative interfacing technology has been
developed by Sankai [92]. In the technology, the signal of very small amount of bio-ion
current from his brain to move the muscle is detected by sensors attached to his muscle. On
the basis of the signal, a small-sized computer settled on his back instantly orders to start
the movement of the suit part related to his muscle. The fact must be noted that the wearer
and the suit are intimately integrated in this system.
Figure 56. An example of simultaneous observation results on heart rate, electrocardiogram (ECG)
and motional acceleration [101].
Figure 57. The structure and working principle on McKibben type man-made muscle [104].
of the motive-power sources such as man-made muscles and motor have been utilized.
Figure 57 shows the working mechanism of a typical man-made muscle, which is called
a McKibben type driven by pressurized air. Another example of a wearable robot driven
by a motor, which is previously introduced in section 8.2.3, is shown in Figure 58. The
procedure for lifting work using the muscle system includes (a) thinking to lift up the
object by hand, (b) electric signal is transmitted from brain to human muscle, (c) sensors on
human arm surface detect biovoltage, (d) computer forecasts to do lifting up motion with
the biovoltage, (e) computer orders to operate the motor of power unit, and (f) just before
the human lifting up motion, the motor starts to assist the human lifting up motion. It is
expected that these systems are useful for care working, rehabilitation, military use, and
rescue working. But strictly speaking, this robot suit cannot be classified as an E-textile
because any textile is not used as a key material in the suit.
Recently, a robot suit system assisting the rehabilitation of patients who have half
their body paralyzed has been developed. Man-made rubber muscle driven by pressured
air is integrated into the arm part of the suit. The muscle is actuated to move the par-
alyzed arm in the same manner as a normal arm by detecting the motion, as shown in
Figure 59.
Figure 58. Wearable robot for assisting human power in working [105].
Figure 59. Robot suit assisting rehabilitation of patients who have half their body paralyzed [106].
176 T. Matsuo
Figure 60. Examples of decorative uses based on light-emitting pattern by an E-textile system [110].
Figure 61. Principle of thermoregulation using Peltier cell embedded in textiles [50].
9. Concluding remarks
While writing this article, the author took special care of the following: (a) systematic
introduction by setting the general scope for each chapter or some sections, (b) system-
atic constitution of contents, (c) orientation to only applied products, (d) introduction of
advanced technologies, but not too advanced technologies from a practical point of view,
(e) orientation to technologies, but to be based on scientific knowledge, and (f) the use of
many figures and tables for easier understanding for readers. One section in this article is
dedicated to E-textiles, which are now rapidly progressing. Hence, the author is afraid that
this section might be outdated in a few years.
178 T. Matsuo
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Textile Progress 181
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