Chemistry - Chang 10th Edition 2

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3.

7 Chemical Reactions and Chemical Equations 95

Figure 3.7 Three ways of


representing the combustion of
hydrogen. In accordance with the
ⴙ 8n law of conservation of mass, the
number of each type of atom
must be the same on both sides
of the equation.

Two hydrogen molecules ⴙ One oxygen molecule 8n Two water molecules

2H2 ⴙ O2 8n 2H2O

ends as we did before it started. We can balance Equation (3.2) by placing the appro-
priate coefficient (2 in this case) in front of H2 and H2O:
When the coefficient is 1, as in the case of
2H2 1 O2 ¡ 2H2O O2, it is not shown.

This balanced chemical equation shows that “two hydrogen molecules can combine
or react with one oxygen molecule to form two water molecules” (Figure 3.7). Because
the ratio of the number of molecules is equal to the ratio of the number of moles, the
equation can also be read as “2 moles of hydrogen molecules react with 1 mole of
oxygen molecules to produce 2 moles of water molecules.” We know the mass of a
mole of each of these substances, so we can also interpret the equation as “4.04 g of H2
react with 32.00 g of O2 to give 36.04 g of H2O.” These three ways of reading the
equation are summarized in Table 3.1.
We refer to H2 and O2 in Equation (3.2) as reactants, which are the starting
materials in a chemical reaction. Water is the product, which is the substance formed
as a result of a chemical reaction. A chemical equation, then, is just the chemist’s
shorthand description of a reaction. In a chemical equation, the reactants are conven-
tionally written on the left and the products on the right of the arrow:

reactants ¡ products

To provide additional information, chemists often indicate the physical states of


the reactants and products by using the letters g, l, and s to denote gas, liquid, and
solid, respectively. For example,

2CO(g) 1 O2 (g) ¡ 2CO2 (g) The procedure for balancing chemical


2HgO(s) ¡ 2Hg(l) 1 O2 (g) equations is shown on p. 96.

To represent what happens when sodium chloride (NaCl) is added to water, we write
HO
NaCl(s) ¡
2
NaCl(aq)

where aq denotes the aqueous (that is, water) environment. Writing H2O above the
arrow symbolizes the physical process of dissolving a substance in water, although it
is sometimes left out for simplicity.

TABLE 3.1 Interpretation of a Chemical Equation

2H2 1 O2 ¡ 2H2O
Two molecules 1 one molecule ¡ two molecules
2 moles 1 1 mole ¡ 2 moles
2(2.02 g) 5 4.04 g 1 32.00 g ¡ 2(18.02 g) 5 36.04 g




















36.04 g reactants 36.04 g product

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