lac HYDROCARBONS BIALKYNES) i as angus 1 ee? (4), BEES B) 5 Product (B) is: en . a NAN -e ib (A Product (A) is (a) H,C =CH—CH=CH, () CH, —c =c—cH, (© CH; —CH, —C=CH (@) CH; —CH =C =CH, oa Product (K) of the above reaction is : OH Caco C=C—ert @ @)4 7: QH on = C—CH,—CcH, Cm C—CHy © @ CH, — CH, — CH, —C =CH + LiNH; —> (A) 8+ 5 (B) = Give the structural formula of compound (8) : (@) CH; — (CH), —C =C —S0,H (b) CHy — (CH), —C = C—CH, @ Oh— in ene —o-f @ CH, —cH, —c =c—cH, _-CHly ~ CH, ~ CH 4S biceps Ss 5 This conversion can be acheived by : (@) NaNH2, CHjCHO () NaNH2, CHj—CH,—CH,—Br (© KOH, CHy — CH, — Br @ KOH, Gh,— Gi Bro oBr Which alkyne will give 3-ethylhexane on catalytic hydrogenation ? Ss i @ ” © @ Allof these Reactant P gives products Q or R. 7 G)- Ge Ka obey “ The possible reagents are : (D 2Na/liq. NH (I) Hy/Pd/CaCO. (quinoline) (WD) 2H, /Pd/c ‘The correct statement with respect to the above conversion is/are : (@) Qis obtained on treatment with reagent (1) (b) Rand Q are obtained on treatment with reagent (11) (© Ris obtained on treatment with reagent (1)eT (@) Ris obtained on treatment with reagent (11) 8. Br—(CH,),2 —C = CHM (4) Het (B) ; Product (B) fs ¢ a ke © (@ Br—(CH,)—CH = CH, 9. Ph—C=CH —2—, Major product of the reaction is : Ph. H Ph. OMe Ne Neg @ © exc wen Ky wen, (© Ph—c=c—oMe (@ Ph-g =cly e OMe 10. the —cH, “2, (A) 5 Product (4) is a ee (a) Ph—CH=CH, (6) Ph—C=CH (©) Ph—CH,—CH, (d) Ph—C=CNa 11. Which combination is best for preparation of the compound (A) shown below ? Hs Him c— cHCH,CH,C = CH CH3CH3 (A) 8 cH, Hc mi, cape eet, ne’, NaC me CH MEM —cacrgcHate “= S4) (6) He — cucrycrbr ME~ M4) CHyCHy cHycH, 4 ‘cH 2 BCH,GHcHC—=eH CHCH, CHACH, 412. Which one of the following isthe intermediate in the preparation of ake tn alkyne in the presence of sulfuric aid and mercury dt) sulphate > YeraOn oF 4 © Be faa (a) (A (a) Hepp ttt ’ 2. BCH CHG, cH14. 15. 16. 17. 18. ‘oun CH cu To carry out above conversion, (A) and (B) respectively, are : (a) NaNH,Cl—CH, —CH, —CH, — Br (b) NaNH3, F—CH, —CH, —CH, — Br (© NaNH;,1—CH, —CH, —CH, —Br (@) NaNH, I—CH, —CH, —CH, —I l : H—C=C—Ph ———+—-> Product; Product obtained in this reaction is : HON, @ Ph—G—=cH—1 ) Ph—CH—CH, 1 (© Ph—c=c— ovata, . ae >= cH Omattta AH, (4) > (8) 5 Product (B) =C—CH, ae neo °C) “ort aa en @ egy Which of the following alkyne on treatment with H(2 smole)/ B gives an optically inactive I (@1—C=c—H compound ? (a) 3-Methyl-1-pentyne (b) 4-Methyl-1-hexyne (©) 3-Methyl-I-heptyne (@) None of the above CoC, H(A) —BSEASUBYE > (B), Product (B) of the reaction is : (catia tide (a) Toluene (b) Ethyl-benzene (©) Benzene @ Butyne What is the final product, C, of the following reaction sequence ? \ Naty A © CHyCHBr Ai ASANO) 5 ang, °C Br Br Br Br Br or wo LK one one Br NH, Br19, 20. 21. 22. 24, s compound 002» {)— atch C,H AO Preiiate ° 0 0 i tl ° a ll iL Ted HH C— CH, — CH) —C-C-H+H-C— @ CSc cca ) (cH — cr cH © € ecco ct @ Cee ccc Choose the sequence of steps that describes the best synthesis of 1-butene from ethanol : (@) () NaC = CH ; (2) Ha, Lindlar Pa (b) (1) NaC==CH ;, (2) Na, NH, (© @) HBr, heat ; (@2)NaC==CH ; () Hy, LindlarPd (@) (2) HBr, heat ; (2) KOC(CH)3 , DMSO ; (3) NaC-= CH ; (4) Ha, Lindlar catalyst Which alkyne yields butanoic acid (CH,CH,CH,CO,H) as the only organic product treatment with ozone followed by the hydrolysis? ae ae ° ° I I CHO. —0-H+H—C-O-H+/ cHO ‘Compound (X) will be : (a) 1-Butyne (b) 4-Octyne (© 1L-Pentyne (@) 2+Hexyne @) Cya, CH — ont Carlina oxide Unit of unsaturation in compound (A) ? @7 os ©9 @10 ° LC» sot (4) MOH, gy Hebets, gy Prodiict (C) of above reaction is: @ Hyc—=cH, ©) CH —c=mc—cu, (© HC=CcH @ CH; —CH=cH—cn, To convert 1-butyne to 1-D-butanal, one would carry out the following steps : (D_ Sodium amide, then D,0 (I) Disiamy Iborane, then hydrogen peroxide/sodium hydroxide (ID The transformation can not be carried out with the indicated reagents. (@) |, followed by (b) Il, followed by1 (©) IM @t26. 27. 29. ‘An unknown compound (A)has a molecular formulaC,Hs. When (A) is treated with excess of Bry a new substance (B) with formula C,HgBry is formed. (4) forms a white ppt. with ammonical silver nitrate solution. (A) may be : (@) But-1-yne (b) But-2-yne (© But-Lene @ But-2-ene One mole of 1,2-dibromopropane on treatment with X moles of NaNH, followed by treatment with ethyl bromide gave a pentyne. The value of X is : (@) One &) Two © Three @ Four i: CHy)-CH-C=CH —_ocustr ‘The product of the above reaction is: Hy Br Br @ Br (@). CH ~ CH- CH- CH (b) CH, - CH -C = CH, Is Br is ir (© cry -cH-F-cHy @ cH, - CH-CH, ~ CH Br r cotta, CH, —C = C—CH, —*40804_4¢4) Product (A) @ cue Le © on tL en HOH (© CHy—CH—CH—CH, @ 0=CH—cH, —cH,cH=0 In which reaction last product is Ph —C = CH? Br I @ Cotte —6— CH eeatanar? a, Br 2 Naty nage (b) CoHsCH = CHa ca ieatonstear? — Il ‘nate (© Cette —C—cH, Fy, te, (@) All260 30. 31. 32. ORGANIC Chemistry for ITJEE Predict the product of the following reaction sequence. te (i) ces NaN Bog ICH, aH an (@) 6-iodo-1-hexyne (@) Thexyne (© S-decyne @ Liodo-1-hexene ‘The best sequence of reactions to prepare 2-heptanone is (@) propyne Mais, x —#-Ctste , y_ Hote” () ethyne Py x Sate y ane” an, (© 1-hexyne Na, x BE, yo @) 1—pentyne BH x SBE, y_Hooi ‘The major product of the reaction of 2butene with cold alkaline KMnO, is oS © A © A @ a Ht