Temperature effects, EP-10

DATA:
a) Single BMR; optimum conditions Tmax=675 K
isothermal at T=Tmax Cp =18 cal/mol K ;
𝑽_(𝑩𝑴𝑹−𝒐𝒑𝒕)=(𝑭_𝑨𝒐 -HA= -10 000 cal/mol;
To=Tmax T1=Tmax 𝒙_𝑨𝟏)/ 〖−𝒓〗 _𝑨𝟏 Qo=0.3 dm3/s
𝑽_𝑩𝑴𝑹=((𝟎.𝟑)(𝟎.𝟓)
(𝟎.𝟖))/((𝟎.𝟑)/𝟔𝟎) CAo=0.5 mol/dm3
CBo =2.5 mol/dm3
𝑽_𝑩𝑴𝑹=𝟐𝟒 〖𝒅𝒎〗 ^𝟑
1.0
r mol/dm3 min BMR-2 Operation Point
0.9 r0 0
b) Two BMRs in series; optimum cond. r1 0.05
To=Tmaks T1=Tmax
0.8 r2 0.3
r3 0.5
xA1=? T2=Tmax 0.7 r4 1.0
xA2=0.8 r5 1.5 BMR-1 Operation Point
0.6 r6 2.0

𝑽_(𝑩𝑴𝑹−𝟏, 𝒐𝒑𝒕)=(𝑭_𝑨𝒐 𝑽_(𝑩𝑴𝑹−𝟐, 𝒐𝒑𝒕)=(𝑭_𝑨𝒐

xA 0.5 r7 3.0

𝒙_𝑨𝟏)/ 〖−𝒓〗 _𝑨𝟏 (𝒙_𝑨𝟐−𝒙_𝑨𝟏))/ 〖−𝒓〗 _𝑨𝟐

𝑽_(𝑩𝑴𝑹−𝟏)=((𝟎.𝟑)(𝟎.𝟓) 𝑽_(𝑩𝑴𝑹−𝟐)=((𝟎.𝟑)(𝟎.𝟓) 0.4
(𝟎.𝟓))/((𝟏.𝟓)/𝟔𝟎) (𝟎.𝟑))/((𝟎.𝟑)/𝟔𝟎)

𝑽_(𝑩𝑴𝑹−𝟏)=𝟑 〖𝒅𝒎〗 𝑽_(𝑩𝑴𝑹−𝟐)=𝟗 〖𝒅𝒎〗 ^𝟑 0.3

^𝟑
0.2
trials 0.1
xA1 VBMR-1 VBMR-2 Vtotal Tmaks 700
0 450 500 550 600 650
0.5 3 9 12
T, K
0.63 5.7 5.1 10.8 P
0.37 1.7 12.9 14.6

c) Single adiabatic BMR 1.0

Single ady. BMR;
IMPOSSABLE
OPERATION POINT
 Single ady. BMR;
1.0 IMPOSSABLE
To T1 r mol/dm3 min
OPERATION POINT
Adiabatic 0.9
r0 0
Operation Line 0.8 r1 0.05
r2 0.3
0.7 r3 0.5
𝐹_𝑇𝑜 𝐶_𝑝 (𝑇_𝑜−𝑇_1 )+(−∆𝐻_𝐴)(- r4 1.0
𝑟_𝐴1)𝑉_𝐵𝑀𝑅=0 0.6
r5 1.5
𝐹_𝑇𝑜 𝐶_𝑝 (𝑇_𝑜−𝑇_1 )+(−∆𝐻_𝐴)𝐹_𝐴𝑜 𝑥_𝐴1=0 xA 0.5 r6 2.0
r7 3.0
𝑥_𝐴1=(𝐹_𝑇𝑜 𝐶_𝑝)/((−∆𝐻_𝐴 ")" 0.4
𝐹_𝐴𝑜 ) 〖 (𝑇 〗 _1−𝑇_𝑜) 0.3
𝑥_𝐴1=((3)(18))/((−10000)(0.5)) 0.2
〖 (𝑇 〗 _1−𝑇_𝑜) 0.1
Tmaks700
𝑥_𝐴1=−0.0108 〖 (𝑇 〗 _1−𝑇_𝑜) 0 450 500 550 600 650
T, K
𝑥_𝐴1=0.8; 𝑇_𝑜=675 𝐾  𝑇_1=601 𝐾
d) Two adiabatic BMRs in series 1.0
To T1 T'1 0.9 r mol/dm3 dk
xA1=? T2 r0 0
0.8 r1 0.05
xA2=0.8 r2 0.3
0.7

Ad
r3 0.5

. BM
0.6 r4 1.0
r5 1.5
𝐹_𝑇𝑜 𝐶_𝑝 (𝑇_𝑜−𝑇_1 )+(−∆𝐻_𝐴)(-𝑟_𝐴1)𝑉_𝐵𝑀𝑅=0 xA 0.5

R-2
𝐹_𝑇𝑜 𝐶_𝑝 (𝑇_𝑜−𝑇_1 )+(−∆𝐻_𝐴)𝐹_𝐴𝑜 𝑥_𝐴1=0 r6 2.0 heating
r7 3.0
𝑥_𝐴1=(𝐹_𝑇𝑜 𝐶_𝑝)/((−∆𝐻_𝐴 ")" 𝐹_𝐴𝑜 ) 〖 (𝑇 〗 _1−𝑇_𝑜) 0.4

Ad.
1
𝑥_𝐴1=((3)(18))/((−10000)(0.5)) 〖 (𝑇 〗 _1−𝑇_𝑜) 0.3

BM
𝑥_𝐴1=−0.0108 〖 (𝑇 〗 _1−𝑇_𝑜) 0.2

R-
𝑥_𝐴1=0.55; 𝑻_𝒐=𝟔𝟕𝟓 𝑲 𝑻_𝟏=𝟔𝟐𝟒 𝑲 0.1
𝐹_𝑇𝑜 𝐶_𝑝 (𝑇_1−𝑇_2 )+(−∆𝐻_𝐴)𝐹_𝐴𝑜 〖 (𝑥 〗 _𝐴2−𝑥_𝐴1)=0 0 450 Tmaks
(𝑥_𝐴2 〖−𝑥〗 _𝐴1)=−0.0108 〖 (𝑇 〗 _2−𝑇_1) 500 550 600 650 700
𝑥_𝐴2=0.8; 〖𝑻′〗 _𝟏=𝟔𝟕𝟓 𝑲  𝑻_𝟐=𝟔𝟓𝟐 𝑲 T, K
𝑽_(𝑩𝑴𝑹−𝟏)=𝟗.𝟗 〖𝒅𝒎〗 ^𝟑 𝑽_(𝑩𝑴𝑹−𝟐)=𝟒𝟓
〖𝒅𝒎〗 ^𝟑

e) Two adiabatic PFRs in series 1.0

r mol/dm3 min
0.9 r0 0
r 0.05
 r mol/dm3 min
0.9 r0 0
r1 0.05
To T1 T'1 T2 0.8

Ad
r2 0.3

. PF
xA1=? xA2=0.8 0.7 r3 0.5
r4 1.0

R-2
0.6 r5 1.5
xA 0.5 r6 2.0
xA -rA 1/-rA Area Σ Area 𝑽_(𝑷𝑭𝑹−𝟏)
r7 3.0
0.4
0.00 0.00

Ad.
0 3 0.33
〖 =𝑭 〗 _𝑨𝒐

PFR
0.3
0.2 2 0.50 0.08 0.08 ∫1_𝟎^(𝒙_𝑨𝟏)▒(𝒅𝒙_𝑨)/(

1 -
0.2
0.3 1.5 0.67 0.06 0.14
0.4 1 1.00 0.08 0.22
〖−𝒓〗 _𝑨 ) 0.1
0
0.55 0.5 2 0.225 0.45 𝑽_(𝑷𝑭𝑹−𝟏) 〖 =𝑭 〗 _𝑨𝒐 450 500 550 600 650
Tmaks
700
∑▒𝑨𝒓𝒆𝒂 T, K
xA -rA 1/-rA Area 𝑽_(𝑷𝑭𝑹−𝟐) 〖 =𝑭 〗 _𝑨𝒐
Σ Area 𝑽_(𝑷𝑭𝑹−𝟏)=(𝟎.𝟑)(𝟎.𝟓)(𝟔𝟎) 𝑽_(𝑷𝑭𝑹−𝑶𝑻𝑷) 〖 =𝑭 〗 _𝑨𝒐
0.55 1.5 0.67 0.00 0.00 (𝟎.𝟒𝟓)
∫1_(𝟎.𝟓𝟓)^(𝟎.𝟖)▒(𝒅𝒙_𝑨)/ ∫1_𝟎^(𝒙_𝑨𝟏)▒(𝒅𝒙_𝑨)/( 〖−𝒓〗 _𝑨 )
0.6 1 1.00 0.04 0.04 =𝟒.𝟏 〖𝒅𝒎〗 ^𝟑
0.7 0.5 2.00 0.15 0.19
( 〖−𝒓〗 _𝑨 ) 𝑽_(𝑷𝑭𝑹−𝑶𝑻𝑷) 〖 =𝑭 〗 _𝑨𝒐 ∑▒𝑨𝒓𝒆𝒂
𝑽_(𝑷𝑭𝑹−𝑶𝑻𝑷)=(𝟎.𝟑)(𝟎.𝟓)(𝟔𝟎)(𝟎.𝟔𝟒)=𝟓.𝟖 〖𝒅
0.75 0.3 3.33 0.13 0.33 𝑽_(𝑷𝑭𝑹−𝟐) 〖 =𝑭 〗 _𝑨𝒐 𝒎〗 ^𝟑
(−∆𝑯)( 〖−𝒓〗 _𝑨)𝒅𝑽 +U 〖𝒅𝑨〗 _(𝑰 )(𝑻_𝒔
0.8 0.05 20 0.58 0.91 ∑▒𝑨𝒓𝒆𝒂 - 𝑻)=𝟎
𝑽_(𝑷𝑭𝑹−𝟐)=(𝟎.𝟑)(𝟎.𝟓)(𝟔𝟎) (−∆𝑯)(−𝒓_𝑨) +U 𝟒/𝑫 (𝑻_𝒔 - 𝑻)=𝟎

f) PFR at OTP (𝟎.𝟗𝟏) 𝑻_𝒔=T - ((−∆𝑯) 〖 (−𝒓 〗 _𝑨)𝑫)/𝟒𝑼

=𝟖.𝟐 〖𝒅𝒎〗 ^𝟑
xA -rA 1/-rA Area Σ Area z,dm Ts, K
0 3 0.33 0.00 0.00 0.0 698 700
695
0.35 2 0.50 0.15 0.15 4.6 690 690
685
T, Ts; K

0.5 1.5 0.67 0.09 0.23 7.4 686 680

0.65 1 1.00 0.13 0.36 11.4 683 675
670
0.75 0.5 2.00 0.15 0.51 16.2 679 665
0.0 5.0 10.0 15.0 20.0
0.8 0.3 3.33 0.13 0.64 20.4 677 z, dm