XI Chemistry 2015

PAK GRAMMAR COLLEGE
CHEMISTRY XI
Time: 3Hrs PRLIMINARY EXAMINATION 2015 Total marks: 85
SECTION “A” – (MCQs – Multiple Choice Questions)
Q.1. Choose the correct answer for each from the given options. (17 Marks)
i. When gaseous anions and cations are brought closer, the energy involved is
(a) Electron affinity (b) Lattice Energy (c) Ionization Energy (d) Electro Negativity
ii. The molecules which 64gm SO2 contains are
(a) 1.02 x 1023 (b) 2.04 x 1023 (c) 3.06 x 1023 (d) 6.02 x 1023
iii. Faraday’s experiment indicates, the existence of
(a) Positron (b) Electron (c) Proton (d) X-rays
iv. The Molecular mass of Na₂CO₃ is
(a) 100 a.m.u (b) 102 a.m.u (c) 104 a.m.u (d) 106 a.m.u
v. If pH of a solution is zero, the nature of solution will be
(a) Acidic (b) Amphoteric (c) Neutral (d) Basic
vi. The bonds present in one molecule of ethane (C₂H₄) are
(a) Four Sigma two pi (b) Five Sigma one pi (c) Five pi one Sigma (d) Two Sigma four pi
vii. The bond distance between Carbon-Carbon Single bond (C-C) is
(a) 1.34 A° (b) 1.54 A° (c) 1.20 A° (d) 1.24 A°
viii. The integar part of logarithm is called
(a) Characteristic (b) Base (c) Mantissa (d) Power
ix. The rate of diffusion of C₃H₈ and CO₂ are the same because
(a) They are gases (b) Both contain Carbon (c) Their Molecular (d) C₃H₈ is an Organic
Mass are same Compound
x. The colour of light depends upon its
(a) Wave length (b) Velocity (c) Source (d) None
xi. Which atomic orbital is always involved in sigma bonding?
(a) s-Orbital (b) t-Orbital (c) d-Orbital (d) p-Orbital
xii. In hydrogen halides, which of the following possess the largest ionic character?
(a) HCl (b) HBr (c) HI (d) HF
xiii. Which of the compound has Sp2 hybridization
(a) NH₃ (b) C₂H₄ (c) C₂H₂ (d) H₂O
xiv. The molecular formula of Vitamin “C” is C₆H₈O₆. Its empirical formula is
(a) C₂H₃O₂ (b) C₃H₄O₃ (c) CH₂O (d) CHO₂
xv. Bohr’s model of atom is contradicted by
(a) Rutherford’s Atomic (b) Heisenberg’s (c) Pauli’s exclusion (d) Plank’s quantum
Model Uncertainty Principle Principle Theory
xvi. Cabon dioxide (CO₂) molecule has zero dipole moment because its structure is
(a) Linear (b) Tetrahedron (c) Angular (d) Triangular
xvii. The value of “Kc” is independent of
(a) Initial concentration (b) Pressure (c) Volume (d) Catalyst
of reactants
SECTION “B” – (Short Answer Questions) (40 Marks)

Q.2. Answer any TEN questions from this Section. All questions carry equal marks.
i. Derive an expression for the energy of an electron in nth orbit.
ii. Define Coordinate Covalent bond and explain it with the formation of (NH⁺₄)
iii. Define the following terms
 Significant Figures  Avogadro’s Number
 Mole  Stoichiometry
iv. An organic compound producing air pollution contains 8.73% carbon 77.45% chlorine and 13.82% fluorine; find the
molecular formula of the compound if its molecular mass is 137.5. (Atomic Masses: C = 12, Cl = 35.5, F = 19)
v. Give the main postulates of Kinetic Molecular Theory of Gases.
Page 1 of 2
vi. Write the electronic configuration for the ground state Na (Z = 11) and Mg+2 (Z = 12).
vii. Give scientific reasons for the following
A falling drop of a liquid is always spherical.
Ionization potential of oxygen is smaller than that of Nitrogen.
Honey is more viscous than water.
Zinc dust when reacted with HCl produces hydrogen at a faster rate than a big piece of Zinc.
viii. Find the equilibrium constant for the reaction N₂(g) + O₂(g) ↔ 2NO(g) at 2000°C is the initial concentration of N₂ and
O₂ are 10 moles/dm3.
ix. Calculate the mass of ZnSO₄, the volume of H₂ and the number of molecules of H₂ which will be produced by reacting
163.5gm of Zn with H₂SO₄, at S.T.P. (Atomic Masses: Zn = 65.4, S = 32, O = 16, H = 1).
x. Differentiate between Isomorphism and polymorphism.
xi. Write down five properties of each Alpha (α), Beta (β), Gamma (γ) rays.
xii. Will PbCrO₄ precipitate from a solution mixing 200cm(3) of 2.5 x 10⁻⁴ M Pb(NO₃) and 600cm(3) of 1.5 x 10⁻⁸ M
K₂CrO₄?
xiii. State and explain Gram’s Law of diffusion.
xiv. What do you understand the term Hybridization? Discuss Sp3, Sp2 and Sp hybridization with examples.
xv. Write short notes on following (Any Two)
 Viscosity  Surface Tension
 Electron Affinity  Hydration
 Common Ion Effect  Buffer Solution
xvi. Find the molarity of 0.5gm of NaOH in 250cm3 of aqueous solution.
SECTION “C” – (Detailed Answer Questions) (28 Marks)

Q.3. (a) Write short notes on the following. (Any two)
 Hydrogen Bonding  Arrhenius Theory of Ionization
 pH  Molarity
Q.3. (b) Define Rate of Reaction, describe the methods to determine the rate of reaction and also describe the factors on which the
rate of reaction depends?
Q.3. (c) Describe the following rules of electronic configuration.
 Pauli’s Exclusion Principle  (n + 1) Rule
 Aufbau Principle  Hund’s Rule of Maximum Multiplicity
Q.4. (a) For the Chemical reaction F₂ + 2CIO₂ → 2FCIO₂, Calculate the rate constant when initial concentration of F₂ is 0.1
mol/dm3, of ClO₂ is 0.01 mol/dm3 and the rate of reaction is 1.2 x 10-3 mol/dm3 sec.
Q.4. (b) What do you understand by the term Electrode Potential? How is the Electrode Potential of Zinc and Copper discovered?
Q.4. (c) Write down the points of Electron Pair Repulsion Theory and Hybrid Orbital anode. Describe the shapes and structures of
CH₃, BeCl₂, H₂O and NH₃ on the basis of Electron Pair Repulsion Theory.
Q.5. (a) State Le-Chatlier’s Principles. Apply the Principle on Haber’s Process in terms of pressure and temperature for the
maximum yield of NH₃.
N₂(g) + 3H₂(g) ↔ 2NH₃(g) + Heat
Q.5. (b) State the Law of Mass Action. Derive the equilibrium. Constant Kc for reaction nA + nB ↔ nC = yD. Apply the Law of
Mass Action on Contact Process to derive its equilibrium expression.
2SO₂(g) + O₂(g) ↔ 2SO₃(g)
Q.5. (c) Differentiate between the following. (Any two)
 Sp3Hybridization and Sp2Hybridization  Polar Covalent Bond and Non-Polar Covalent
Bond
 Valence Bond Theory and Molecular  Exothermic Reactions and Endothermic
Orbital Theory Reactions.
--------END-------
----------------------------------------------------------BEST OF LUCK-------------------------------- ------------------------
Page 2 of 2

XI Chemistry 2015

Uploaded by

Copyright:

Available Formats

XI Chemistry 2015

Uploaded by

Document Information

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

XI Chemistry 2015

Uploaded by

Copyright:

Available Formats

PAK GRAMMAR COLLEGE

SECTION “B” – (Short Answer Questions) (40 Marks)

SECTION “C” – (Detailed Answer Questions) (28 Marks)

You might also like