Nesrine-Unit2.Matter, Chemical Reactions, and Solutions
Nesrine-Unit2.Matter, Chemical Reactions, and Solutions
Nesrine-Unit2.Matter, Chemical Reactions, and Solutions
2 Matter,
Chemical Reactions,
and Solutions
59
Chapter 6
MATTER, PROPERTIES,
AND PHASES
MATTER and ATOMS matter
anything that
MATTER describes everything that we has mass and
can see, touch, smell, or feel. In other takes up space
words, mat ter is anything that has mass atom
and takes up space (including air and the smallest
unit of matter
almost everything else).
60
Remember that a model is a
ATOMIC MODELS way to represent something
th at we can’t easily see.
Atoms are made of smaller particles:
nucleus
the center of an
atom, formed by
protons and neutrons
Protons and neutrons stick
together to form the center The MODERN ATOMIC MODEL
of an atom, called the shows an ELECTRON CLOUD rather
than individual electrons like
NUCLEUS, which has a net
the model above. It demonstrates
positive charge. Electrons where you’re most likely to find
orbit, or circle around, the an orbiting electron. Denser
areas of the cloud mean a higher
nucleus, but too quickly to
probability of electrons.
pinpoint their exact locations.
61
Brief History of the Atomic Models
JOHN DALTON was the first scientist to propose that elements
are composed of indestructible atoms. He thought that there
were particles so small that we could not see them. He called
these particles atoms, and his theory on matter was known as
the ATOMIC THEORY OF MATTER.
ERN EST J. J.
64
Conservation of Mass conservation
While things may change of mass
The amount of mass at
appearance or composition during
the start of a reaction will
physical and chemical changes, equal the amount of mass
one thing remains consistent: after the reaction.
the amount of mat ter present.
This concept is called the CONSERVATION OF MASS. So
mass doesn’t just disappear-it still exists, but it may be in a
different form, like in the surrounding gases. The atoms have
just rearranged to form different substances.
STATES of MATTER
Matter is usually found in three STATES (or PHASES): solid,
liquid, and vapor (or gas). The arrangement and behavior
of particles is what determines the state of matter. The
attraction between particles keeps particles close together,
and the energy of their movement allows particles to
overcome these attractive forces.
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A SOLID, like ice, wood, or metal, is
matter that has a defined shape and
volume. The particles in matter are
packed closely together, and they don’t move around freely,
which is why a solid has a defined shape and volume. Still,
particles in a solid vibrate back and forth, but not enough to
overcome the attractive force between particles.
SOLID Fixed shape and volume Vibrate, but have fixed positions
Shape can change, volume is Free-moving—
LIQUID
fixed. Can flow. no fixed positions.
GAS Shape and volume not fixed and Particles move quickly and
depends on container. Can flow. are far apart.
PHASE CHANGES
A state is not permanent. Changes in pressure and temperature
alter mat ter- these are described as PHASE CHANGES.
vapor
Above 100°C, water is a vapor. 100
˚
Between 0°C and 100°C, water is a liquid. liquid
Below 0°C, water is a solid. 0
˚ ice
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VAPORIZATION is when liquid turns to vapor. When sweat
disappears and dries up, it has vaporized or evaporated.
Evaporation happens slowly and only at the surface (individual
molecules get bumped out into the air). When water boils, it has
reached the temperature at which water turns from liquid to
vapor. Heat causes liquid particles to move around quickly. When
the particles are moving around fast enough to overcome all
attractive forces between particles, the liquid turns to vapor.
VAPOR
n co
a tio nd
en
l im n va p
tio s at
s u b ep o s i o ri
zat
io n
d io n
melting
freezing
SOLID LIQUID
68
w CheckYour Knowledge
1. What is the positively charged particle in an atom?
3. I
f you turn eggs, flour, and milk into pancakes, what sort of
change have the ingredients undergone? If you make a smoothie
out of a banana, strawberries, and yogurt, what sort of change
have the ingredients undergone?
10. D
efine vaporization and condensation. Give an example of each.
answers 69
Check Your ANSWERS
1. A
proton
2. T homson thought that electrons and protons were embedded
together, sort of like raisins in oatmeal-raisin cookies.
3. T
he ingredients in pancakes undergo a chemical change-the
ingredients have transformed into something else with new
chemical properties. For the smoothie, the ingredients have
undergone a physical change (the ingredients are the same, they
are just cut up into small pieces and blended together).
4. T
he same. Mass is conserved.
5. T
houghts, light, a vacuum
6. W
hile both can flow freely, the particles in a liquid stick together
and don’t completely separate. So the volume of a liquid is fixed
while the volume of a vapor is not fixed.
7. A
t the boiling point, a substance changes from a liquid to a gas.
8. M
olecules vibrate in a solid, but have fixed positions. Molecules in
a liquid flow freely, but they don’t completely separate because
they don't have enough energy to completely overcome the
attractive forces between molecules. Molecules in a gas move
freely and so quickly they can overcome all attractive forces
between molecules.
9. V
iscosity is the resistance to flow. Peanut butter resists flow more.
10. V
aporization is when liquid turns to vapor, like when sweat dries
up. Condensation is the opposite--when vapor turns to liquid, like
when water droplets form on the surface of a glass holding a
cold drink.
70
Chapter 7
PERIODIC TABLE,
ATOMIC STRUCTURE,
AND COMPOUNDS
The PERIODIC TABLE element
one type of atom
Different atoms have different numbers of
protons and electrons-accounting
periodic table
for all the differences in the physical a table of all of the elements
properties of matter. Different types
of atoms are called ELEMENTS, and there are around 118
known elements. Each element is made of unique atoms.
3 Na M g
Sodium Ma g nesium
Average Atomic Mass
22.990 24.305 3 4 5 6 7 8 9
19 20 21 22 23 24 25 26 27
4 K
Potassium
Ca Sc
Calcium Scandium
Ti
Titanium
V
Vanadium
Cr Mn Fe
Chromium Man g anese Iron
Co
Cobalt
39.098 40.078 44.956 47.867 50.942 51.996 54.938 55.845 58.933
37 38 39 40 41 42 43 44 45
5 Rb Sr
Rubidium Strontium
Y
Yttrium
Zr Nb Mo Tc
Zirconium Niobium Moly bdenum Technetium
Ru
Ruthenium
Rh
Rhodium
85.468 87.62 88.906 91.224 92.906 95.95 98.9062 101.07 102.91
55 56 72 73 74 75 76 77
6 Cs Ba
Caesium Barium
Hf
Hafnium
Ta W Re
Tantalum Tungsten Rhenium
Os
Osmium
Ir
Iridium
132.91 137.33 178.49 180.95 183.84 186.21 190.23 192.22
57 58 59 60 61 62
← group →
La Ce
Lanthanum Cerium
Pr Nd Pm Sm
Praseody mium Neody mium Promethium Samarium
138.91 140.12 140.91 144.24 ( 145 ) 150.36
89 90 91 92 93 94
Ac Th
Actinium Thorium
Pa
Protactinium
U
Uranium
Np Pu
Neptunium Plutonium
( 226 ) 232.04 231.04 238.03 ( 237 ) ( 244 )
72
→ ALKALI METALS → HALOGENS 18
→ ALKALINE EARTH METALS → NOBLE GASES 2
→ LANTHANIDES
→ ACTINIDES
→ NEW AN D PEN DING DISCOVERIES
He
Helium
→ TRANSITION METALS 13 14 15 16 17 4.0026
→ UNKNOWN PROPERTIES 5 6 7 8 9 10
→ POST-TRANSITION METALS
→ METALLOIDS
B
Boron
C
Carbon
N
Nitrog en
O
Ox yg en
F
Fluorine
Ne
Neon
→ OTHER NONMETALS 10.806 12.009 14.006 15.999 18.998 20.180
13 14 15 16 17 18
Al
Aluminum
Si
Silicon
P
Phos phorus
S
Sulfur
Cl Ar
Chlorine Arg on
10 11 12 26.982 28.084 30.974 32.059 35.446 39.948
28 29 30 31 32 33 34 35 36
Ni Cu Zn Ga Ge As
Nickel Co pp er Zinc Gallium Germanium Arsenic
Se
Selenium
Br
Bromine
Kr
Kr ypton
58.693 63.546 65.38 69.723 72.63 74.922 78.96 79.904 83.798
46 47 48 49 50 51 52 53 54
Pd A g Cd In
Palladium Silver Cadmium Indium
Sn Sb
Tin Antimony
Te
Tellurium
I
Iodine
Xe
Xenon
106.42 107.87 112.41 114.82 118.71 121.76 127.60 126.90 131.29
78 79 80 81 82 83 84 85 86
Pt Au Hg
Platinum Gold Mercur y
Tl
Thallium
Pb Bi
Lead Bismuth
Po At Rn
Polonium Astatine Radon
195.08 196.97 200.59 204.38 207.2 208.98 ( 209 ) ( 210 ) ( 222 )
63 64 65 66 67 68 69 70 71
Eu Gd Tb Dy Ho Er Tm Yb
Euro p ium Gadolinium Terbium Dys p rosium Holmium Erbium Thulium Ytterbium
Lu
Lutetium
151.96 157.25 158.93 162.50 164.93 167.26 168.93 173.04 174.97
73
3 Atomic Number
Each square has
information about the
Li
Lithium
Chemical Symbol
6.941 Element Name
element. The top number is
Average Atomic Mass
its ATOMIC NUMBER,
also the number of electrons
and the bot tom one is
its ATOMIC MASS.
atomic number
the number of protons an atom contains.
The periodic table is Elements are differentiated by their
organized by row and atomic numbers because each element
has a different number of protons.
column. Each horizontal
row is called a PERIOD,
while each vertical column is atomic mass
called a GROUP or FAMILY. the average mass of a
typical atom of that element
The elements are arranged in
order of their atomic numbers-
so as you go across, each element period
a row of elements across
has one more electron and has one the periodic table
more proton. Hydrogen has 1,
helium has 2, and so on.
group or family
Elements in the same group a column of elements in the
(column) share similar periodic table. Groups of
chemical and physical elements have similar physical
and chemical properties.
properties.
74
Atomic Structure Dmitri Ivanovich
and Energy Levels Mendeleev,
a Russian scientist,
The nucleus of the atom invented the
contains the positively periodic table
charged protons, in 1869.
Li
Lithium
Also, number of electrons.
I LOST AN
ELECTRON! ARE YOU
SURE?
I’M
POSITIVE!
77
MOLECULES and COMPOUNDS
When two or more atoms combine, they form MOLECULES.
O O O O
O + O = O2
n n N N
N + N = N2
78
Compounds have different properties from those
the individual elements have on their own-water
wouldn’t seem anything like water if it were a
bunch of separate hydrogen and oxygen atoms.
Oxygen = 8 electrons
6 valence electrons
79
How to Write a Chemical Formula
Every compound contains a specific ratio of elements. A
CHEMICAL FORMULA is sort of like the compound’s recipe-it
describes the ingredients and their quantities. In a chemical
formula, each element is writ ten using its chemical symbol,
which is a one- or two-letter symbol, with a subscript beneath
the symbol defining the number of atoms.
80
w CheckYour Knowledge
1. H
ow many known elements are there?
3. W
hat is the name of a column of elements in the periodic
table? What do these elements have in common?
4. W
hat do two or more atoms combine to form?
5. W
hat is the atomic mass of an atom?
6. I
f the atomic number of an element is 6 and the atomic mass
is 15, how many neutrons are present?
7. W
hat is an isotope?
8. W
hat is a chemical bond?
answers 81
1. 1 18
2. A
tomic numbers
3. A
group is a column of elements in the periodic table.
Groups of elements have similar physical and chemical
properties.
4. A
molecular compound
5. T
he atomic mass is the average mass of a typical atom of
that element. It’s also the combined number of protons and
neutrons.
ine neutrons are present ( 15 - 6 = 9).
6. N
7. A
toms of the same element that have a different number of
neutrons are isotopes.
8. A
chemical bond is when atoms share electrons.
9. A
toms make chemical bonds so that their electrons can pair up
and become more stable.
82
Chapter 8
SOLUTIONS
AND
FLUIDS
SUBSTANCES, MIXTURES,
and SOLUTIONS
A SUBSTANCE is something that can’t be broken down
into simpler parts and physical changes won’t alter its
composition. A substance is made of a single compound.
For example, water (H 2O) is a substance. No matter what
physical processes you put water through (like freezing or
boiling), water will remain H 2O.
83
A MIXTURE, on the other hand,
A SALAD IS ALSO
is made of different substances AN EXAMPLE OF
A MIXTURE.
mixed together that aren’t
chemically bonded. Salad dressing
is a mixture of different things,
like oil, herbs, and lemon juice.
1. H
ETEROGENEOUS MIXTURE: a mixture where
the substances aren’t evenly mixed. A salad is an
example of a heterogeneous mixture; every bite of
a salad is different no mat ter how many times you
mix the salad.
2. H
OMOGENOUS MIXTURE: a mixture where
the molecules of each substance are equally mixed,
and you can’t see the different parts of the
mixture. Sugar that is dissolved in water creates a
homogenous mixture--you can’t see the sugar and
the water, just a liquid that contains molecules of both.
SOLUTE
solvent
the substance into
which the solute
dissolves
SOLV ENT
85
SOLUBILITY
SOLUBILITY is the ability of a substance to dissolve in
another substance. Lots of things affect solubility:
Temperature
is one factor:
Usually solid solutes are
more soluble in water at
higher temperatures, which GASES CAN
BE DISSOLVED
is why it is easier to IN LIQUID,
TOO!
dissolve sugar in
hot water.
Gas solutes,
like carbonation,
are the opposite of solid
solutes. Gases are more soluble
in liquids at colder temperatures.
Carbonated beverages remain
fizzy longer when they are cold
because gas is more soluble
in cold liquids.
PRESSURE
and the
CONCENTRATION
of other solvents in a
solution also affect
solubility.
86
CONCENTRATION
The CONCENTRATION of a solution is the amount of solute
contained in a solution. A CONCENTRATED SOLUTION has a lot
of solute, while a DILUTED SOLUTION has very little solute.
For a lemon sports drink solution, a concentrated solution
would be really sour and sweet, and a diluted solution would
taste watery.
The side of a juice box will usually tell you the concentration
of fruit juice. If the concentration of fruit in a fruit punch is
7 percent, that means 7 percent of the drink is made of juice,
and the rest is stuff like water and sugar.
PRESSURE
A FLUID is anything that can flow, like liquids and vapors.
A fluid, like all other forms of matter, exerts PRESSURE,
or pushes, on its surroundings. For example, air that fills a
balloon exerts pressure on the sides of the balloon to keep it
inflated. Meanwhile, pressure from the atmosphere pushes
on the outside of the balloon. As long as the pressure from
the inside is greater, the balloon stays inflated. Pressure is
proportional to both the force of the push and the area on
which it pushes. More force means more pressure, and more
area means less pressure:
pressure = __
force
area
87
The units most commonly used for pressure are a
PASCAL (Pa), or an ATMOSPHERE (atm). One atmosphere
is the pressure the atmosphere exerts on Earth at sea level.
As you go higher up, there are fewer
air molecules above you-so there’s LITTLE WEIGHT
ABOVE YOU
less pressure. The change in
LOTS OF WEIGHT
pressure between low and high ABOVE YOU
altitudes is what causes your
ears to pop when you go
over a high mountain pass
in a car. It’s also why water boils at a lower temperature in
the mountains: There’s less pressure holding the molecules, so
they can escape more easily.
88
w
1. D
efine “substance.”
2. A
bowl of beef-barley soup is a _ _ _ _ _ _ _ _ _ _ _ _ _
mixture.
answers 89
Check Your ANSWERS
1. A
substance is something that can’t be broken down
into simpler parts, and physical changes won’t alter its
composition.
2. H
eterogeneous
3. D
ecreases
4. H
igher
6. F luid
90