Chapter 1
Chapter 1
Course description
Fundamentals of Thermodynamics, First and Second Laws of Thermodynamics, Various power and
refrigeration cycles, Heat transfer modes including steady and unsteady conduction, convection and
radiation, Flow statics and buoyancy, Mass, momentum and energy conservation, Bernoulli equations,
Internal and external flow.
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No. of Contact
List of Topics
Weeks Hours
Introduction and Basic Concepts 1 5
3
Assessment methods
Home work : 10%
Quizzes : 10%
Project/Reports/Labs/Others : 20%
Major Exam : 20%
Final Exam : 40%
Text book(s):
Yunus A. Cengle and Michael A. Boles, Thermodynamics An Engineering Approach,
Mc Graw Hill 7th Edition, 2008.
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Chapter 1
Introduction and Basic Definitions
Objectives
The objectives of Chapter 1 are to:
• Identify the unique vocabulary associated w ith
thermodynamics through the precise definition of basic
concepts to form a sound foundation for the
development of the principles of thermodynamics.
• Explain the basic concepts of thermodynamics such as
system, state, state postulate, equilibrium, process, and
cycle.
• Review concepts of temperature, temperature scales,
pressure, and absolute and gage pressure.
The name thermodynamics stems from the G reek
w ords therme (heat)and dynamis (pow er), w hich is
most descriptive of the early efforts to convert
heat into pow er.
• Thermodynamics:The sci
ence of
energy.
• Energy:The abi
li
tyto cause changes.
• Conservation of energy principle:
During an interacti
on,energycan change
from one form to anotherbutthe total
amountofenergyremai nsconstant.
• Energycannotbe created ordestroyed.
• The first law of thermodynamics:An
expression ofthe conservati
on ofenergy
pri
nciple.
• The fi
rstl
aw assertsthatenergy i
sa
thermodynamicproperty.
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Application Areas of Thermodynamics
• Anyphysi
calquanti
tycan be characteri
zed bydimensions.
• The magni
tudesassi
gned to the di
mensi
onsare cal
led units.
• Some basi cdimensionssuch asmassm,l ength L,time t,and temperature T
are selected asprimary orfundamental dimensions,whi le otherssuch as
velocityV,energyE,and vol ume V are expressed i
n termsofthe primary
dimensi onsand are cal
led secondary dimensions,orderived
dimensions.
• Metric SI system:A si mple and l
ogi
calsystem based on a deci
mal
rel
ati
onshi p between the vari
ousunits.
• English system:Ithasno apparentsystemati cnumeri calbase,and vari
ous
uni
tsin thi
ssystem are rel
ated to each otherratherarbi
trari
ly.
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Importance of Dimensions and Units
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1-3 SYSTEMS AND CO NTRO L VO LU MES
•System:A quanti
tyofmatterora regi
on i
n space chosen forstudy.
•Surroundings:The massorregi
on outsi
de the system
•Boundary:The realori
magi
narysurface thatseparatesthe system from i
ts
surroundi
ngs.
•The boundaryofa system can be fixed ormovable.
•Systemsmaybe consi
dered to be closed oropen.
•Closed system (Control mass): A fi
xed amountofmass,and no masscan
crossi
tsboundary
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Open system (control volume)
Isolated system
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• Open system (control volume):A properly
selected regi
on i
n space.
• Itusuall
yencl osesa devi
ce thatinvol
vesmass
fl
ow such asa compressor,turbine,ornozzle.
• Both massand energycan crossthe boundary
ofa controlvolume.
• Control surface:The boundariesofa control
volume.Itcan be realorimaginary.
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O pen Systems
1-4 Properties of a System
• Property: Anycharacteri
sti
cofa
system.
• Some fami l
iarproperti
esare
pressure P,temperature T,vol
ume V,
and massm.
• Properti
esare considered to be
ei
therintensive orextensive.
• Intensive properties: Those thatare
independentofthe massofa system,
such astemperature,pressure,and
density.
• Extensive properties: Those whose
valuesdepend on the size— orextent
— ofthe system.
• Specific properties: Extensi
ve
properti
esperuni tmass.
Density and specific gravity
The w ieght of a unit volume is called specific w eight
Specific weight:
State and Equilibrium
Thermodynamics deals w ith equilibrium states.
Thermodynamic state:
•Specified by state variables: T, P, V, n (n=composition)
•State equation = relation betw een state variables T,P,V,n (ex:
PV=nRT)
•State function: system property that is only dependent on its
state.
State functions vs.Path functions :
•State functions:
Ex: E(T,V,n), P, V, n, H(P,T,n), S(T,V,n)
• Extensive sate functions: depend on n
• Intensive state functions: independent of n
W hen the variation of density with elevation is known, the pressure difference
between points 1 and 2 can be determined by integration to be:
Pascal’s law: The pressure is the same at all points on a horizontal
plane in a given fluid regardless of geometry, provided that the
points are interconnected by the same fluid.
Noting that P1 = P2 since both pistons are at the same level (the effect of small height differences is
negligible, especially at high pressures), the ratio of output force to input force is determined to be:
1–10 THE■
MANOMETER
Consider the manometer shown in Fig. 1–45 that is used to
measure the pressure in the tank.
PRESSURE
Atmospheric pressure is measured by a device called a barometer;thus, the atmospheric pressure is often
referred to as the barometric pressure.
Problem
Problems
A large fraction of the thermal energy generated in the engine of a car is rej
ected to the air by the radiator
through the circulating water. Should the radiator be analysed as a closed system or as an open system?Explain.
Answer:
A can of soft drinkat room temperature is put into the refrigerator so that it will cool. Would you model the can
of soft drinkas a closed system or as an open system?Explain.
Answer:
For a system to be in thermodynamic equilibrium, do the temperature and the pressure have to be the same
everywhere?
Answer: For a system to be inthermodynamic equilibrium,the temperature has to be the same throughout but the pressure does
not.However,there should be no unbalanced pressure forces present.The increasing pressure with depth ina fluid,for example,
should be balanced byincreasing weight.
Answer: A process during which the temperature remains constant is called isothermal;a process during which the pressure
remains constant is called isobaric;and a process during which the volume remains constant is called isochoric.
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Problems
W hat is a steady-flow process?
Answer: A process is said to be steady-flow if it involves no changes with time anywhere withinthe system or at the system
boundaries.
A gas is contained in a vertical, frictionless piston–cylinder device. The piston has a mass of 4kg and a cross-
sectional area of 35 cm2. A compressed spring above the piston exerts a force of 60 N on the piston. If the
atmospheric pressure is 95 kPa, determine the pressure inside the cylinder.
Answer:
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