SORG 0010 AQUAPANEL® Fugenkleber (PUR) 12993 0010 SDS 4.0 EU en
SORG 0010 AQUAPANEL® Fugenkleber (PUR) 12993 0010 SDS 4.0 EU en
SORG 0010 AQUAPANEL® Fugenkleber (PUR) 12993 0010 SDS 4.0 EU en
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Main use category : Industrial use. Professional use.
Use of the substance/mixture : adhesives
Supplier
Knauf Gips KG
Am Bahnhof, 7
DE– 97346 Iphofen – Bayern
Germany
T +49 9323/31-0 - F +49 9323/31-277
[email protected] - www.knauf.de
E-mail address of competent person responsible for the SDS : sds-
[email protected]
Carc. 2 H351
STOT SE 3 H335
STOT RE 2 H373
GHS07 GHS08
Signal word (CLP) : Danger
Contains : polymethylene polyphenyl isocyanate, methylenediphenyl diisocyanate
Hazard statements (CLP) : H315 - Causes skin irritation.
H317 - May cause an allergic skin reaction.
H319 - Causes serious eye irritation.
H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 - May cause respiratory irritation.
H351 - Suspected of causing cancer.
H373 - May cause damage to organs through prolonged or repeated exposure.
H412 - Harmful to aquatic life with long lasting effects.
Precautionary statements (CLP) : P102 - Keep out of reach of children.
P260 - Do not breathe vapours.
P271 - Use only outdoors or in a well-ventilated area.
P273 - Avoid release to the environment.
P280 - Wear protective gloves/protective clothing/eye protection/face protection/hearing
protection.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P313 - IF exposed or concerned: Get medical advice/attention.
P405 - Store locked up.
P501 - Dispose of contents/container to hazardous or special waste collection point, in
accordance with local, regional, national and/or international regulation.
EUH-statements : EUH204 - Contains isocyanates. May produce an allergic reaction.
Extra phrases : Persons suffering from asthma, eczema or skin problems should avoid contact, including
dermal contact, with this product.
Component
polymethylene polyphenyl isocyanate (9016-87-9) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII
diethylmethylbenzenediamine, mixture of isomers This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
(68479-98-1) This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII
The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting
properties, or is not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation
(EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %
3.1. Substances
Not applicable
3.2. Mixtures
diethylmethylbenzenediamine, mixture of isomers CAS-No.: 68479-98-1 0,1 - 0,5 Acute Tox. 4 (Dermal), H312
EC-No.: 270-877-4 Acute Tox. 4 (Oral), H302
EC Index-No.: 612-130-00-0 STOT RE 2, H373
REACH-no: 01-2119486805- Eye Irrit. 2, H319
25 Aquatic Acute 1, H400
Aquatic Chronic 1, H410
methylenediphenyl diisocyanate CAS-No.: 26447-40-5 ( 0,1 ≤C < 100) Resp. Sens. 1, H334
EC-No.: 247-714-0 ( 5 ≤C < 100) STOT SE 3, H335
EC Index-No.: 615-005-00-9 ( 5 ≤C < 100) Skin Irrit. 2, H315
REACH-no: 01-2119457015- ( 5 ≤C < 100) Eye Irrit. 2, H319
45
Full text of H- and EUH-statements: see section 16
4.2. Most important symptoms and effects, both acute and delayed
No additional information available
4.3. Indication of any immediate medical attention and special treatment needed
No additional information available
Eye protection:
Safety glasses with side shields
Hand protection:
Observe skin protection plan. Apply skin care products, in particular after work. Chemically resistant protective gloves
Respiratory protection:
In case of insufficient ventilation, wear suitable respiratory equipment. Type A - High-boiling (>65 °C) organic compounds
10.1. Reactivity
Reacts with water.
LD50 dermal rabbit > 5000 mg/kg (Rabbit, Literature study, Dermal)
LD50 dermal rabbit > 9400 mg/kg bodyweight (Equivalent or similar to OECD 402, 24 h, Rabbit, Male /
female, Read-across, Skin)
LC50 Inhalation - Rat 0,49 mg/l air (Equivalent or similar to OECD 403, 4 h, Rat, Male / female, Read-across,
Inhalation (aerosol))
LD50 dermal rat > 2000 mg/kg bodyweight (OECD 402: Acute Dermal Toxicity, 24 h, Rat, Male / female,
Experimental value, Dermal, 14 day(s))
LC50 Inhalation - Rat > 2,45 mg/l (1 h, Rat, Male / female, Experimental value, Inhalation (aerosol), 14 day(s))
12.1. Toxicity
Hazardous to the aquatic environment, short–term : Not classified
(acute)
Hazardous to the aquatic environment, long–term : Harmful to aquatic life with long lasting effects.
(chronic)
EC50 - Crustacea [1] > 1000 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 24 h, Daphnia magna,
Static system, Fresh water, Read-across)
EC50 72h - Algae [1] > 1640 mg/l (OECD 201: Alga, Growth Inhibition Test, Scenedesmus subspicatus, Static
system, Fresh water, Read-across, Growth rate)
EC50 - Crustacea [1] 0,5 mg/l (EU Method C.2, 48 h, Daphnia magna, Static system, Fresh water, Experimental
value, Nominal concentration)
ErC50 algae 104 mg/l (OECD 201: Alga, Growth Inhibition Test, 72 h, Desmodesmus subspicatus,
Static system, Fresh water, Experimental value, GLP)
Partition coefficient n-octanol/water (Log Pow) 4,51 (Experimental value, OECD 117: Partition Coefficient (n-octanol/water), HPLC
method, 22 °C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
Organic Carbon Normalized Adsorption Coefficient 2,12 – 2,23 (log Koc, SRC PCKOCWIN v1.66, QSAR)
(Log Koc)
ADR
Transport hazard class(es) (ADR) : Not applicable
IMDG
Transport hazard class(es) (IMDG) : Not applicable
IATA
Transport hazard class(es) (IATA) : Not applicable
ADN
Transport hazard class(es) (ADN) : Not applicable
RID
Transport hazard class(es) (RID) : Not applicable
Overland transport
Not applicable
Transport by sea
Not applicable
Air transport
Not applicable
Rail transport
Not applicable
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
Indication of changes
Section Changed item Change Comments
Supersedes Modified
STOT SE 3 Specific target organ toxicity – Single exposure, Category 3, Respiratory tract irritation
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental
requirements only. It should not therefore be construed as guaranteeing any specific property of the product.