(84)Number of electrons present in 0.

96 g of SO2-4 ion is
(a)6 x 1023 (b) 8 x 6 x 1023
(c)3 x 1023 (d) 12 x 6 x 1023
(85)An element X exist in two isotopes X25 and X28
if their percentage abundance is 40% and 60% respecti-
vely, the average atomic mass of X is :
(a)25.2 (b)26. (c)26.8 (d)25.8
(86)The percentage of nitrogen in urea (NH2CONH2) is :
(a)38.4 (b)46.6 (c)59.1 (d)61.3.
(87)A compound of phosphorus and chlorine is composed
of 10.33 g of P for every 35.5 g of chlorine. Thesimplest
formula of the compound is :
(a)PCl (b)PCl3 (c)PCI5 (d)PCl4+.
(88)The number of atoms present in 52u of He is :
(a)26 (b)13
(c)26 x 6.02 x 1023 (d)13 x 6.02 x 1023
(89)The number of valence electrons present in 4.2 g N3-
ions is (where NA=Avogadro’s number).
(a)0.3 NA (b)0.6 NA (c)2.4 NA (d)6 NA
(90)A compound contains 0.08% sulphur. The minimum
molecular mass of the compound is ?
(a)10000 (b)20000 (c)35000 (d)40000
(91)Given that the abundances of isotopes 54A, 56A and
57
A are 5%, 90% and 5% respectively, the atomic
mass of A is ?
(a)55.35 (b)55.95 (c)55.15 (d)56.05
(92)The total number of atoms present in 1 molecule of
CuSO4.5H2O is :
(a)18 (b)19 (c)20 (d)21.
(93)Hymoglobin stores oxygen for metabolic process in
muscle. Chemical analysis shows that it contains 0.34%
Fe by mass. What should be the minimum molar mass
ofhymoglobin?
(a)16470 g/mol (b)8235 g/mol
(c)32842 g/mol (d)24362 g/mol.
(94)Which of the following has maximum number of atoms
(a)4 u He (b)2 g He
(c)22.4 L He (d)2 g atom He.
(95)Mass of 2.24 L gas at STP is 4.4 g, gas may be
(a)CO (b)SO2 (c)CO2 (d)NO2
(96)Product of atomic mass and specific heat is approxim-
-ately 6.4” is known as :
(a)Dulong and petit’s law.
(b)Law of definite proportion.
(c)Gay Lussac’s law.
(d)Law of reciprocal proportion.
(97)Number of H-atom in 1.7 g of NH3 is (NA = Avogadro’s
(82)2.2 g of CO2and 2.24 L of H2 at STP are mixed in a con-
number).
-tainer. The total number of moles in the mixture will be
(a)NA (b)0.1 x NA (c)0.3 x NA (d)3 x NA
(a)0.25 (b)2.5 (c)0.15 (d)1.5
(98)Number of electrons in 1 mol CO32- ion.
(83)Which has maximum number of gram atoms ?
(a)192 (b)32
(a)24 g of C (b)56 g of Fe
(c)32 x 6 x 1023 (d)30 x 6 x 1023.
(c)5.4 g of Al (d) 1.08 g of Ag
(99)The density of gold is 19 g/cc. If 1.9 x 10-4 g of gold
 is dispersed in one litre of water to give a sol having
spherical gold particles of radius 10 nm, the number of
gold particles per mm3 of the sol will be :
(a)1.9 x 1012 (b)2.3 x 1014
(c)6.3 x 1010 (d)2.4 x 106
(100)A compound of iron contains 69.9% Fe and 30.1%
oxygen by mass. What would be empirical formula of
the iron oxide ? [Fe=56, O=16].
(a)FeO (b)Fe2O3 (c)Fe3O4 (d)FeO2
(101)Which has maximum number of electrons ?
(a)1.6 g of CH4 (b)1.7 g NH3
(c)1.8 g H2O (d)All has equal number of electrons.
(102)What is the ratio of numbers of oxygen atoms that
are present in 2.2 g of CO2 and 2.3 g of NO2 respectively
(a)1 : 1 (b)2 : 1 (c)1 : 2 (d)2 : 3
(103)Number of molecules of H2O present in 1 ml of water
is (dH2O= 1 g/mol).
(a)NA (b) 1 NA (c) 1 N (d)2NA
18
(104)Total number of atoms present in one mole of KMnO4
is :
(a)NA (b)2NA (c)4NA (d)6NA
(105)10 ml of water contains 200 drops, then the number
of molecules in one drop of water would be :
(dH2O = 1g/ml)
(a)1.673 x 1021 (b)6.023 x 1023
21
(c)3.346 x 10 (d)1.204 x 1024
(106)Which has the maximum number of molecules among
the following ?
(a)180 g glucose (b)180 g water.
(c)180 g acetic acid (d)180 g CO2.
(107)A 400 mg iron capsule contains 100 mg of ferrous
fumerate (HC2O2)2Fe. Calculate the percentage of Fe
present in it (approx).
(a)30% (b)8% (c)20% (d)15%
(108)What will be relative atomic mass of naturally occu-
-ring Mg if the distribution of isotopes is 24 Mg =78.7%
12
25
Mg=10.1% and 26Mg =11.2% ?
12 12

(a)24.10 (b)24.32 (c)24.69 (d)24.98

(109)What is the number of Cu-atoms present in 0.200
mole of copper?
(a)1.20 x 1023 (b)1.20 x 1021
20
(c)1.20 x 10 (d)1.20 x 102
(110)The number of hydrogen atom in 39.6 g of ammo-
-nium sulphate, (NH4)2SO4is :
(a)1.44 x 1020 (b)1.44 x 1022
24
(c)1.44 x 10 (d)1.44 x 1018 .
(111)Mass of an atom of element is 1 x 10-23 g. Number
of g atoms in 6 kg sample is nearly :
(a)1000 (b)5000 (c)1500 (d)10
Chapter-(B) Calculation involving reaction
(1)0.9 g Al reacts with dil. Hcl to give H2. The volume of H2
gas evolved at 273oC and 1 atm. Pressure will be :- 10 L each of SO2 and H2S at STP is.
(a)1.12 lit (b) 2.24 lit (d) 5.6 lit (e)0.112 lit SO2 + H2S S + H 2O
(2)24.5g KClO3 is heated to give O2, which is allowed to rea- (a)42.86 g (b)21.43 g (c)18.34g (d)14.23g
-ctcompeletely with H2 to form H2O. This H2 comes from (13)Moles of H3PO4 required to completely neutralize
(Zn+H2SO4) reaction. The amount of Zn required for the 1 mole of NaOH will be :
purpose is? (a)1/3 (b)1/2 (c)2 (d)3
(a)0.39g (b)3.9g (c)39g (d)390g. (14)1 g of a mixture of NaCl and Na2CO3 is completely
(3)What volume of 1M H2SO4 is required to reactcomplet- reacted with 75 ml N HCl. The % of Na2CO3 in the
-ely with 100ml of 2M NaOH? mixture is?
(a)200 ml (b)150 ml (c)175 ml (d)100 ml. (a)53 (b)39.75 (c)26.5 (d)79.5
(4)20 ml CO burnt with 10 ml O2 gas at STP change in vol- (15)1.575 g (COOH)2 x H2O is dissolve in water and dilute
-ume is. upto 250 ml. 25 ml of this solution is completely neu-
(a)Increases by 20 ml. tralised with 25 ml N/10 NaOH. The value of x is :-
(b)Decreases by 20 ml. (a)1 (b)2 (c)5 (d)10
(c)Increases by 10 ml. (16)In ozonizer, oxygen is converted into ozone as per
(d)Decreases by 10 ml. the reaction 3O2(g) 2O3(g). 1 L O2 on passing thro-
(5)How many moles of SO3 will be produced from 1 mole –ugh ozonizer reduces to 0.8 L mixture of O2 and O3 at
Of S8 ? STP. The ratio of volume of O2 and O3 in the mixture
(a) 1 (b) 2 (c) 4 (d) 8 will be :-
(6)Chlorine is prepared in the lab by given reaction (a) 1: 1 (b) 1: 2 (c) 2 : 3 (d) 3 : 2.
4HCl(aq) + MnO2(s) 2H2O(I)+MnCl2+Cl2(g). (17)85 g calcium carbonate was produced when CO2
How many litrs of Cl2 can be prepared by the ractionof gas was passed through lime water. What volume of
1 mol HCl and 0.25 mol MnO2. (At N. T. P) CO2 at STP was used?
(a)5.6 L (b)11.2 L (c)67.3 L (d)22.4 L (a) 22.4 L (b) 19.04 L (c) 15.8 L (d) 12.32 L
(7)If 2.24 L H2 and 1.12 L Cl2 are mixed and exploded in a (18)2.0 g of a sample of Ba(OH)2 is dissolved in 50 ml of
tube, the volume of HCL formed is. 0.4 N HCl. The excess of HCl was titrated with 0.1 N
(a)1.12 L (b)2.24 L (c)3.36 L (d)4.48 L NaOH. The volume of NaOH used was 20 ml. What is
(8)When 500 ml of propane was burnt with 3000 ml of oxy- the percentage purity of Ba(OH)2. [Atomic mass:Ba=137]
-gen, the yield of the gaseous product was just 50% of (a) 67.50% (b) 89.55% (c) 76.95% (d)82.00%
expected. Find the total volume of all the gases at the (19)What volume of 0.0858 M BaCl2 will react completely
end of the reaction. with 0.486 g of Na2SO4 ?
(a)2000 ml (b)2750 ml (c) 1900 ml (d)750 ml. (a)44.6 ml (b)53.2 ml (c)49.3 ml (d)39.9 ml.
(9)The chloride of a metal (M)contains 65.5% of chorine, (20)1.6 g of sulphur was burnt in air to form SO2. The
100 ml of the vapour of the chloride of the metal at STP number of molecules of SO2 introduced into the air
weigh 0.72 g. The molecular formula of the metal chlor- will be :
-ide is ? (a) 6.02 x 1023 (b) 3.01 x 1023
(a)MCl3 (b)MCl2 (c)MCl4 (d)MCl (c) 6.02 x 1022 (d) 3.01 x 1022
(10)A sample of pure CaCo3 is used to standardize a solution (21)When 100 ml of M H2SO4 is mixed with 500 ml of M
ofHCl. Standardization of same HCl solution can be ma- 10 10
-de if mixture of MgCO3 and SrCO3 is used. It found that NaOH, then the nature of resulting solution as well as
mass of CaCO3 and mixture is identical to standardize its normality will be :
identical volume of HCl. What would be the percentage (a)Acidic, N/10 (b)Acidic, N/5
of MgCO3 in the given mixture ? (c)Basic, N/5 (d)Basic,N/20
(Atomic mass : C=12, O=16, Mg=24, Ca=40, Sr=88). (22)The crystalline salt, Na2SO4 x H2O on heating loses 56%
(a) 36% (b)45% (c)54% (d)66%. Its weight. The formula of the crystalline salt is :
(11)The maximum moles of barium phosphate that can (a) Na2SO4 . 5H2O (b) Na2SO4 . 7H2O
be obtained on complete reaction of 1 mole each of (c) Na2SO4 . 10H2O (d) Na2SO4 . 6H2O.
BaCl2 and Na3PO4is : (23)100 kg of iron oxide (Fe2O3) containing 20% impurities
BaCl2 + Na3PO4 NaCl + Ba3(PO4)2. on reduction with CO gives iron equal to :
(a) 1 mole (b) 0.1 mole (c) 1/3 mole (d) 2/3 mole (a) 122 kg (b) 40 kg (c) 160 kg (d) 56 kg.
(12)Mass of sulphur that will be produced by action of (24)When 1 mole of C reacts with 1 mole of O2 number
 of moles CO formed is : is completely oxidised by chlorine water to H2SO4 .
(a) 1 (b) 2 (c) 1.5 (d) 0.5 BaCl2 solution is then added in excess. What is the mass
(25)Oxygen produced by thermal decomposition of 50 g of of BaSO4percipitated? [Atomic mass : S=32, Ba=137].
KClO3, 2KClO3 2KCl + 3O2 (Relative atomic mass (a)63.4 g (b)79.6g (c)93.2g (d)98.0g
K=39, Cl=35.5, O=16 & molecular weight KClO3=122.5) (38)Sea water has phytoplanktons in abundance. They
(a)19.6 g (b)40 g (c)80 g (d) 50 g. absorb and fix it in the form of (C6H10O5)n. The time tak-
(26)What mass of graphite must be burnt to produce 18.46g en by 2 g of brown green algae to triple its weight if it
of CO2 ? (Relative atomic mass C=12, O=16) absorbs 10-2 mol CO2 per hour is :
(a)17.86 g (b)5.03 g (c)4.78 g (d)7.76 (a)9.2 hrs (b)10.0 hrs (c)14.8 hrs (d)16.2 hrs.
(27)How many grams of CaCl2 can be produced from 20 g (39)3 moles of KlO3, 4 moles of Kl and 5 moles of HCl are
ofCa ? (Given Ca=40, Cl=35.5). allowed to react as :
(a)111 g (b)222 g (c)55.5 g (d)555 g. KlO3 +Kl + HCl KCl +ICI +H2.O
(28)The mass of Co2 that shall be obtained by heating 10 kg The total number of moles of products formed is :
of 80% pure limestone (CaCO3) is : (a)7.5 (b)9.5 (c)12 (d)15.
(a)4.4 kg (b)6.6 kg (c)3.52 kg (d)8.8 kg. (40)6 g of hydrogen and 16 g oxygen were filled in a steel
(29)How much ethene can be obtained from the following vessel and exploded. Amount of water produced in this
process if we started with 8 kg of CaCl2 ? reaction will be :
CaC2 +H2O CaO +HC ≡ CH (a)108 g of H2O (b)144 g of H2O
HC ≡ CH +H2 H2C=CH2 2 2
(a)7 kg (b)8 kg (c)3.5 kg (d)4 kg. (c) 36 g of H2O (d) 72 g of H2O
(30)The ratio of volume of gases evolved at same conditions 2 2
when equal moles of NaNO3 and LiNO3 are heated, is : (41)2.74 g of a mixture of NaHCO3 and Na2CO3 lost 0.62 g
(a) 1 : 1 (b) 1: 2 (c) 2 : 5 (d) 1 : 3 of its weight on strong heating. The mole fraction of
(31)What volume of 1 M NaOH is required to react with 44.8 NaHCO3 in the original mixture is :{Due to H2O & CO2
L of Co2 at STP to form Na2CO3 ? Loss is calculated}
(a) 1 L (b) 2 L (c) 3 L (d) 4 L . (a)0.67 (b)0.33 (c)0.55 (d)0.40
(32)On passing 1.8 L of oxygen through ozonizer gives 1.6 (42)18 g CaCO3 is heated strongly in air. The volume of CO2
of a mixture of ozone and oxygen. What is the mole fra gas evolved at STP is 3.185 litre. What is the percentage
-ction of ozone in the resultant mixture ? purity of CaCO3 ?
(a)0.15 (b)0.25 (c)0.40 (d)0.50 (a)53% (b)79% (c)87% (d)92%.
(33)A mixture of bicarbonates of two alkali metals contain (43)250 ml of 0.2 M BaCl2 solution is mixed with 40 ml of 0.5
18% of one metal, If 5.0 g of the mixture on heating libe M Na3PO4 solution. What is the maximum amount of
-rates 1.32 g of CO2. What is the percentage of the other Ba3(PO4)2 formed in the reaction ?
metal assuming carbonates of alkali metals are (a)0.02 mol (b)0.04 mol (c)0.03 mol (d)0.01 mol.
stable ? (44)3 litre of mixture of CH4 and C3H8 on complete combust-
(a)24.2% (b)14.6% (c)8.8% (d)3.6% -ion gave 4.2 litre of CO2 at the same temperature and
(34)6.125 g of KClO3 is heated strongly. The oxygen produ- pressure. What is the percentage of C3H8 by volume in the
ced in the reaction is used to oxidise aluminium. What given mixture ?
mass of aluminium will be oxidized by the entire oxygen (a)20% (b)40% (c)60% (d)80%.
produced ? [Atomic mass : O=16, Al=27, Cl=35.5, K=39] (45)Cyclohexanol is dehydrated using conc. H2SO4 to give
(a)3.0 g (b)2.7 g (c) 2.1 g (d)1.8 g cyclohexene. If the yield of the reaction is 75%. How mu-
(35)In an auto engine with no pollution controls, about 5% -ch cyclohexene will be obtained from 100 g of cyclohex-
of the fuel (C8H18)(g) is unburnt. Molar ratio of CO(g) -anol ?
and C8H18(g) emitted in the exhaust gas is : (a)61.5 g (b)82 g (c)109.3 g (d)75 g.
(a)100 (b)152 (c)230 (d)120 (46)30 g Mg and 30 g O2 are reacted and the residual mixture
(36)Equal weights of X (atomic weight = 36) and Y (atomic contains :
weight =24) are reacted to form the compound X2Y3, (a)50 g MgO only
which of the following is/are correct ? (b)50 g MgO and 20 g O2
(a)X is the limiting reagent. (c)50 g of MgO and 15 g of O2
(b)Y is the limiting reagent. (d)50 g of MgO and 10 g of O2.
(c)No reactant is left over. (47)1.0 mol of iron reacts completely with 0.60 mol of O2 to
(d)Mass of X2Y3 formed is double the mass of X taken. give a mixture of only FeO and Fe3O4.What is the molar
(37)12.8 g of sulphur is heated in air to form SO2, which ratio of FeO to Fe3O4 ?
 (a)3 : 2 (b) 2 : 1 (c) 4 : 3 (d) 7 : 2 -wing sequence of reaction?
(48)The hydrate salt Na2CO3.xH2O undergoes 63% loss in S8(g) O2(g) So2 O2(g) SO3(g ) S3O9(s)
mass on heating and becomes anhydrous. The value of x V2O5
is ? (62)What is the number of moles of S3O9 formed?
(a)8 (b)10 (c)12 (d)16. (a)1.33 (b)2.67 (c)4.00 (d)7.98
(49)What mass of HNO3 is needed to convert 12.7 g of I2to (63)Consider the following chemical reaction.
HiO3 according to the following reaction? [Atomic mass : Fe3O4 + CO Fe + CO2
N=14, I=127]. what mass of Fe3O4 is required to obtain 2 kg of Fe if
I2 +HNO3 2HIO3 + 10NO2 + 4H2O. the process is 90% efficient ?
(a)24.8 g (b)13.5 g (c)31.5 g (d) 48.2 g (a)2.76 kg (b)2.48 kg (c)3.06 kg (d)2.22 kg.
(50)The ratio of gas evolved when 1 mole of zinc reacts com- (64)An ideal gas mixture of ethane (C2H6) and ethene (C2H4)
-pletely with H2SO4 and NaOHis : occupies 28 liter at STP. The mixture reacts completely
(a)1 : 1 (b)2 : 1 (c)1 : 2 (d)4 : 1 with 128 g of O2 to produce CO2 and H2O. Mole fraction
(51)5 g of a mixture of BaO and CaO when treated with an of C2H6 in the mixture is :
excess of H2SO4 produced 10.33 g of the mixed sulphates. (a)0.6 (b)0.4 (c)0.5 (d)0.8
percentage of CaO in the mixture is ? (65)How much gram of oxygen is produced on decomposit-
(Atomic masses : O=16, Ca=40, Ba=137). -ion of 3.14 g KClO3 ? [Atomic mass : O=16, Cl=35.5, K=39]
(a)60% (b)40% (c)35% (d)50% (a)0.54 g (b)1.91 g (c)1.23 g (d)2.46 g.
(52)4HCl +MnO2(s) MnCl2 +2H2O+Cl2 (66)Rocket motor fuel consists of butane. How much of the
How many gram of HCl react with 5 g of MnO2 fuel is burnt by each kg of oxygen ?
(At. Wt. of Mn=55, Cl=35.5, O=16, H=1). (a)278 kg (b)480 g (c)4.8 kg (d)0.278 kg.
(a)8.39 g (b)18.9 g (c)83.9 g (d)38.9 g. (67)H3PO4 is a tribasic acid and one of its salts is NaH2PO4
(53)Volume of CO2 at NTP evolved by strong heating of what volume of 1 M NaOH solution should be added to
20 g CaCO3 : 24.2 g of NaH2PO4 to convert it into Na3PO4 ?
(a)44.8 L (b)4.48 L (c)22.4 L (d)2.24 L. (a)100 ml (b)200 ml (c)400 ml (d)300 ml.
(54)Mass of iron which will be converted into it’s oxide (68)25.2 g of ammonium dichromate on heating yields a
by the action of 18 g of steam. (At.Wt.of Fe=56). residue weighing [Atomic mass of Cr=52].
Fe + 4H2O FE3O4 + 4H2 (a)2.52 g (b)15.2 g (c)10 g (d) 20 g.
(a)4.2 g (b)8.4 g (c)42 g (d)None of these (71) Fe2O3 + C Fe +Co2.
(55)2 Lmixture of CO2 and CO was passed through red (69)94.5 kg of impure iron is obtained from 120 kg of 90%
hot charcoal. The final volume becomes 2.5 L. Volume pure Fe2O3. Find the percentage purity of Fe.
Of CO in original mixture : (a)70% (b)90% (c)80% (d)20%
(a)1.5 L (b)0.5 L (c)1 L (d)None of these. (70)When 10 gof an impure sample of CaCO3 is treated with
(56)Maximum amount of H2O that can be formed by 4g H2 excessHCl, 3.3 g of CO2 was evolved. The percentage pu-
and 40g of O2. -rity of the sample is ?
(a)44 g (b)36 g (c)18 g (d)None of these (a)25% (b)60% (c)75% (d)90%.
(57)If 30 ml of H2 and 20 ml of O2 reacts to form water (71)Consider the reaction 2A + B + 3C P+2Q starting
what is left at the end of reaction ? with 3 mol of A, 2 mol of B & 6 mol of C, number of moles
(a)10 ml H2 (b)5 ml H2 of products P and Q would be respectively be :
(c) 10 ml O2 (d)5 ml O2 (a) 2 & 4 (b) 4 & 2 (c) 3 & 1.5 (d) 1.5 & 3.
(58)Pure CaO is used to produce CaC2 as per the following (72)Mass of 50% pure NaOH required to neutralise 3.6 kg of
reaction : HCl :
CaO + 3C CaC2 + CO (a)8 kg (b)4 kg (c)0.8 kg (d)None of these.
Somehow the CaC2 is obtained to an extent of 80% to (73)5 moles of A, 6 moles of B and excess amount of C are
get 1280 kg of pure CaC2 how much CaO should be used mixed to produce a final product D, according to the re-
(a)1400 kg (b)1440 kg (c)1120 kg (d)1344 kg. -actions :
(59)20 ml of a gaseous hydrocarbon requires 100 ml of O2 A + 2B I
for complete combustion and produces 60 ml of CO 2 I+C B+D
gas. The molecular formula of hydrocarbon is : What is the maximum moles of D, which can be produced
(a)C2H4 (b)C3H8 (c)C3H6 (d)C2H6 assuming that the products formed can also reused in the
(60)If 256 g of S8(g) is consumed completely in the follo- reaction :
-wing sequence of reaction ? (a)3 moles (b)4.5 moles (c)5 moles (d)6 moles.
(61)If 256 g of S8(g) is consumed completely in the follo- (74)On combustion 0.2 g of an organic compound contain-
 -ing carbon, Hydrogen and oxygen yields 0.147 g carbon (87)The mass of CO2 obtained when 60 g of calcium carbon-
dioxide and 0.12 g water only. The percentage of C, H & -ate treated with excess of HClis :
O are respectively : (a)30.0 g (b)15.0 g (c)13.2 g (d)26.4 g
(a)22.5, 8.7 and 68.8 (b)20, 6.7, and 73.3. (88)250 ml of 0.2 M BaCl2 solution is mixed with 40 ml of 0.5
(c)18.2, 9.5 and 72.3 (d)28.9, 12.8 and 58.8 M Na3PO4 solution. What is the maximum amount of
(75)1 L solution containing 0.05 M H2SO4 and x M HCl Ba3(PO4)2 formed in the reaction ?
is completely neutralized by 500 ml of 0.4 M NaOH, (a)0.02 mol (b)0.04 mol (c)0.03 mol (d)0.01 mol
then x is : (89)12.8 g of sulphur is heated in air to form SO2 which is
(a)0.1 (b)0.2 (c)0.3 (d)0.4 completely oxidized by chlorine water to H2SO4.BaCL2
(76)14.5 g of CO2 was obtained when 5 g sample of CH4 solution is then added in excess. What is the mass of
and C2H4 was burnt in excess of oxygen. How much BaSO4 precipitated? [Atomic mass : S=32, Ba=137].
gram of CH4 was present in the mixture ? (a)63.4 g (b)79.6 g (c)93.2 g (d)98.0 g
(a)2 g (b)0.19 g (c)0.07 g (d)3.04 g (90)2 mol of CO2 is passed over red hot charcoal. Find the
(77)100 ml of NH3 gas is decomposed completely into N2 number of moles of gaseous product and reactant at
and H2 gases. The volume change in the reaction is : equilibrium if 25%, CO2 is reduced in the reaction :
(a)An increase of 2 ml (b)An increase of 100 ml (a)1.5 mole CO2 and 1 mole CO
(c)A decrease of 2 ml (d)A decrease of 100 ml. (b)1 mole CO2 and 1 mole CO
(78)One mole of potassium chlorate (KClO3) is thermally (c)1 mole CO2 and 1.5 mol CO
decomposed and excess of magnesium is burnt in the (d)1.5 mole CO2 and 1.5 mole CO.
gaseous product. Calculate the weight of magnesium (91)H3BO3 on heating decomposes in two ways :
oxide thus formed. [Atomic mass : Mg=24, O=16]. I H3BO3 HBO2 + H2O.
(a)40 g (b)80 g (c)120 g (d)200 g. II H3BO3 B2O3 + H2O.
(79)What is the mass of carbonic acid produced when From 9 moles H3BO3, some part decomposes like (i) and
67.2 litre of CO2 at STP is dissolved in water ? the remaining like (ii). If total 11 moles of water are pro-
(a)62 g (b)124 g (c)186 g (d)248 g -duced then the moles of B2O3 formed are.
(80)3 litre mixture of CH4 and C3H8 on complete combus- (a)2 (b) 3 (c)5 (d)6.
-ton gave 4.2 litre of CO2 at the same temperature & (92)Consider the reaction MnO2 + 4HCl MnCl 2 + Cl2 +
pressure. What is the percentage of C3H8 by volume in 2H2O. The mass of 60% pure MnO2 required to produce
the given mixture ? 22.4 L Cl2 at STP is (Mn=55).
(a)20% (b)40% (c)60% (d)80% (a)52.2 g (b)87 g (c)145 g (d)217.5 g.
(81)18 g CaCO3is heated strongly in air. The volume of (93)0.5 mole of magnesium nitride on reaction with an exces
CO2 gas evolved at STP is 3.185 litre. What is the per- of water gives :
–centage purity of CaCO3 ? (a)1 mole of nitric acid. (b)2 moles of ammonia
(a)53% (b)79% (c)50% (d)75% (c)1 mole of ammonia (d)2 moles of nitric acid.
(82)The volume of hydrogen gas liberated at NTP by the (94)A zinc rod weighing 25 g was kept in 100 ml of 1 M CuSO4
action of 0.65 g of pure zinc on excess of caustic soda solution. After a certain time the molarity of Cu2+ in the
Solution (atomic weight of Zn =65). solution was 0.8 M. The weight of Zn rod left is equal to
(a)22.4 ml. (b)224 ml (c)2.24 L (d)4.48 L [At. Mass of Zn=65, Cu=63.5].
(83)What volume of 0.3 M NaOHsolution is required to (a)1.308 g (b)23.692 g (c)25 g (d)26.8 g.
react completely with 10 ml of 0.1 M H3PO3 solution. (95)When 96 g C allowed to react completely with 256 g
(a)3.3 ml (b)6.6 ml (c)5 ml (d)2.0 ml. of oxygen to form CO2, then choose the correct state-
(84)When 0.4 mole of Fe2O3 was reduced with 2.2 moles -mentis :
of carbon monoxide to give FeO and CO2, the limiting (a)C is limiting reagent.
reagent is : (b)O2 is limiting reagent
(a)FeO (b)Fe2O3 (c)CO (d)CO2 (c)C completely combines with O2.
(85)In a chemical reaction, (d)400 g of CO2 will form.
4A + 3B + 7C D (96)What is the mass of potassium chlorate, KClO3 that
The initial number of moles of A, B and C are 0.7, 0.35, would contain 48 g of oxygen? [K=39, Cl=35.5, O=16].
0.25 respectively. The limiting reagent will be : (a)200 g (b)245 g (c)112.5 g (d)122.5 g
(a) A (b) B (c) C (d) Can’t be decided.. (97)A gaseous mixture of propane and butane of volume
(86)The weight of 50% H2SO4 solution required to react 3 litre on complete combustion produces 11.0 litre of
completely with 50 g pure CaCO3 is : CO2 under standard conditions of temperature and pre-
(a)49 G (b) 98 g (c)24.5 g (d)9.8 g -ssure. The ratio of volume of propane to butane is :
 (a)1 : 2 (b)2 : 1 (c)3 : 2 (d)3 : 1.
(98)20 ml CO burnt with 10 ml O2 gas at STP change in
volume :
(a)Increases by 20 ml.
(b)Decreases by 20 ml
(c)Increases by 10 ml.
(d)Decreases by 10 ml.
(99)Consider the following reaction:
NaN3 Na +N2(g)
What weight of NaN3 will be required to produce 50 g
N2gas ?
(a)174 g (b)65.60 g (c)77.3 g (d)232 g.
(100)A metal oxide has the formula X2O3 It can be reduced
by hydrogen to give free metal and water. 0.1596 g of
metal oxide requires 6 mg of hydrogen forcomplete
reduction. The atomic mass of the metal in amuis :
(a)15.58 (b)155.8 (c)5.58 (d)55.8
(101)What is the amount of Zn required (65% pure) to get
enough hydrogen on reaction with dilute H2SO4 to obt-
-ain 3g of ethane by the hydrogenation of etheneacco-
-rding to following reaction sequence ?
Zn + H2SO4 ZnSO4 + H2
C 2H4 + H2 C 2H6
(a)6.5 g (b)10 g (c) 16.5 g (d)12 g.
(102)Consider the following chemical reaction :
Ag2CO3(s) 2Ag(s) + CO2(g) + 1/2 O2(g).
The total volume of gases released at STP when 2.76 g
of silver carbonate is completely decomposed is :
[Ag=108, C=12 & O=16].
(a)336 L (b)33.6 L (c)0.336 L (d)3.36 Lk
(103)At standard temperature and pressure, it was observe
that 22.7 L of N2reacted with 68.1 L of H2 to give 45.4 L
of NH3. This is in accordance with :
(a)Dalton’s law.
(b)Gay-Lussac’s law.
(c)Boyle’s law
(d)Law of multiple proportion.
(104)Zn reacts with sulphuric acid according to the equation
Zn(s) + H2SO4(aq) ZnSO4 + H2(g)
What mass of Zn is required to react completely with 50
ml of 1.0 M H2SO4 solution ? [Zn = 65]
(a)32.5 g (b)0.325 g (c)3.25 g (d)325 g.
(105)Consider the following chemical equation.
AgNO3(aq) + Nal (aq) Agl(s) + NaNO3(aq).
if 50 ml of 0.2 M aqueous AgNO3 is added to 250 ml of
0.04 M aqueous Nal, then mass of Agl deposited will be
[Ag=108, I=127].
(a)4.70 g (b)2.35 g (c)7.05 g (d)1.17 g
Chap-(C) Solution
(1)Which of the following is temperature dependent? (a) 10 M (b) 1 M (c)0.5 M (d) 0.1 M
(a)Molarity (b)Molality (c)Molefraction (d)All of these. (18)The mole fraction of solute in 1 m aquous solution is :
(2)The mass of (COOH)2. 2H2O needed to prepare 500 m.l (a) 0.0176 (b) 1.8 (c) 0.05 (d) 0.98
Of 0.1 M solution is ? (19)A 5 M solution of H3PO4 is diluted from 1 L to a volume
(a)12.6g (b)6.3g (c)4.5g (d)9g. of 10 L, the normality of resulting solution will be :
(3)50 ml of an aqueous solution of glucose contain 6.02 x (a)1 N (b)0.1 N (c)1.5 N (d)0.5 N
1022 molecules, the concentration of the solution is ? (20)x L of 1 M HCl is mixed with 2 L of 2 M HCl in order to
(a)0.1 M (b)1 M (c)0.2 M (d)2 M. prepare y L of 1.5 M HCl. The values of x & y are respe-
(4)25 ml of 3M HNO3 are mixed with 75 ml of 4M HNO3, ctively :
the molarity of the final mixture would be ? (a) 6, 4 (b) 2, 4 (c) 3, 4 (d) 4, 2.
(a)3.25M (b)4M (c)3.75M (d)3.5M. (21)In what ratio should a 18% aqueous solution by mass,
(5)A molal solution is one that contains 1 mole of a solute of formic acid be mixed with a 5% aqueous solution, by
in :- the same acid to prepare 12% solution by mass ?
(a)1000 g of the solvent. (b)One litre of the solution (a) 6 : 5 (b) 7 : 6 (c) 9 : 7 (d) 7 : 10.
(c)One litre of the solvent (d) 22.4 L of the solution. (22)The density (gm/ml) of a 3.60 M aqueous H2SO4 (29%
(6)Molarity of water is? by mass) solution is (H=1, S=32, O=16).
(a)1 M (b)1m (c)12 M (d)55.5 M (a)1.22 (b)1.45 (c)1.64 (d)1.88
(7)How many moles of K+ ions are in 30 ml of 0.2 M (23)x gram of an acid furnishes0.5 mole H3O+ in aqueous
K3PO4. solution. What will be ‘N’ of acid if y gram dissolve in
(a)0.06 (b)0.006 (c)0.012 (d)0.018. 500 ml solution ?
(8)15 ml of 0.5 M HCl is mixed with 30 ml of 0.3 M HCl. (a) y x 1000 (b) y
the molarity of resulting solution is ? X x 500 x
(a)0.45 M (b)0.36 M (c)0.90 M (d)0.18 M. (c) y (d) y x X
(09)The concentration term which is independent of tem- 2X x 500 5000
-perature ? (24)The specific gravity of a solution is 1.4 g/ml. It was 54%
(a)Molarity (b)Molality (c)Normality (d)w / V%. (mass/mass) of a salt. What is the weight of salt in 750 ml
(10)Density of 1.5 M solution of phosphoric acid in water of the solution?
is 1.15 gml-1. The molality of solution is? (a)537 g (b)555 g (c)567 g (d)586 g.
(a)2.99 m (b)1.495 m (c)4.486 m (d)3.339 m. (25)Calculate molarity of a solution of ethanol in water in
(11)A solution is prepared by mixing 50 g sugar (C12H22O11) which mole fraction of ethanol is 0.04. Assume the dens-
in 100 g water. The mole fraction of sugar is ? -ity of solution is 1.0 g/mol
(a)0.50 (b)0.33 (c)0.025 (d)0.66 (a)1.11 M (b)2.09 M (c)3.25 M (d)4.40 M
(12)The mole fraction of water in 20% (w/w) aqueous (26)2.98 g KCl is dissolved in some water and the volume of
solution of H2O2 is ? solution is made upto 125 ml. What is the molarity of
(a)20/80 (b)68/77 (c)77/68 (d)80/20 solution ? (Atomic mass :Cl=35.5 and K=39).
(12)The molarity of solution obtained by dissolving 3.42 g (a)0.04 M (b)0.16 M (c)0.24 M (d)0.32 M.
sugar in 50 ml solution. (mol. Mass of sugar=342 g). (27)What is the molality of a solution present in benzene, if
(a) 0.2 M (b) 0.01 M (c) 0.05 M (d) 0.06 M the mole fraction of solute is 0.2 ?
(13)An aqueous solution of NaCl is 5% by weight. What is its (a)2.8 (b)4.9 (c)5.7 (d)3.2
concentration in ppb (parts per billion)? (28)Equal moles of benzene and toluene are mixed together
(a)5 x 10-7 (b)5 x 107 (c)107 (d)109 to form a solution. The mole fraction of benzene in the
(14)The molarity of pure H2SO4 liquid is (Assume density of solution is :
pure H2SO4 liquid to be 1.25 g ml-1). (a)1/2 (b)3/4 (c)1/3 (d)1/4.
(a)10.2 (b)12.75 (c)1 (d)122.5. (29)The density of an aqueous solution of glucose is 1.8 g/ml
(15)1 Kg of NaOH solution contains 4 g of NaOH. The app- the mass percent of glucose in it being 90%. The molarity
roximate concentration of solution is : of the solution will be [mol. Mass of glucose =180].
(a) 1 M (b) 0.1 M (c) 0.001 M (d) 10 M (a)9 (b)8 (c)1/9 (d)1/8
(16)Mole fraction of solute in a aquous solution of molality (30)A container contains equal mass of CH4 and H2, mole
2 is ? fraction of CH4 in the mixture is :
(a) 1/57.5 (b) 2/57.5 (c) 55.5/57.5 (d) Non of these (a)8/9 (b)6/9 (c)1/9 (d)4/9
(17)6.023 x 1024 number of glucose molecule present in 20 (31)Mass of solution of 0.5 m which contains 0.15 mole of
L of a solution. Molarity of the solution is : CH3COOH in it’s aqueous solution is :
 (a)309 g (b)30.9 g (c)39 g (d)None of these. (a)3% (b)3 x 10-4%
4
(32)4.9 g of H2SO4 present in 500 ml of solution. Molarity (c)3 x 10 % (d) 300%.
of the solution is : (47)The mole fraction of HNO3 in an aqueous binary sol-
(a)1.0 M (b)0.1 M (c)0.01 M (d)0.5 M -ution is 0.15. The ratio of moles of HNO3 to H2O in
(33)Molarity of 98% (w/w) H2SO4, if its density is 1.8 gram/ the solution is nearly :
ml. (a)17 : 3 (b)3 : 17 (c)1 : 1 (d)15 : 100.
(a)9 M (b)15 M (c)18 M (d)20 M. (48)Find the density of an aqueous H3PO4 solution who-
(34)How much weight of H2SO4 is required to prepare 200 -se weight percent is 9.8% and molarity is 1.25.
ml of 0.1 M H2SO4. (a)1.25 g ml-1 (b)2.5 g ml-1 (c)1.5 g ml-1 (d)2 g ml.
(a)9.8 g (b)1.96 g (c)19.6 g (d)0.1 g. (49)What is molality of 93% (w/v) H3PO4solution ? [Given
(35)Normality of a solution obtained by mixing 50 ml N/10 its density is 1.84 g/ml].
H2SO4, 50 ml N/5 HNO3 and 75 ml N/5 HCl solution, is (a)10.4 (b)12.9 (c)11.7 (d)13.2
(a)0.20 N (b)0.75 N (c)0.25 N (d)0.1714 N (50) The normality of 0.4% (wt./vol.) NaOH Is :
(36)An aqueous solution of ethanol has density 1.25 g/ml (a)0.1 N (b)0.01 N (c)0.005 N (d)0.001 N.
and it is 1.5 M. What is the molality of this solution ? (51)171 g of cane sugar is dissolved in 1000 g of water at30oC.
(a)1.5 M (b) 1.27 M (c)1.06 M (d)2 m. if the density of solution is 1.1 g/ml, then
(37)The density of 0.5 M glucose solution is 1.09 g/ml. (a)Molarity < Molality (b)Molarity = Molality
The molality of the solution is ? (c)Molality < Molarity (d) Molarity = 2 Molality.
(a)0.1 (b)0.2 (c)0.25 (d)0.6 (52)Calculate molarity of a solution of ethanol in water in
(38 The mole fraction of benzene in a solution of benz- which mole fraction of ethanol is 0.04. Assume the densi-
-ene and toluene is 0.5. The mass % of benzene in the -ty of solution is 1.0 g/mol.
solution is ? (a)1.11 M (b)2.09 M (c)3.25 M (d)4.40 M.
(a)50% (b)25% (c)43.7% (d)45.9% (53)6.023 x 1020 molecules of glucose are present in 100 ml
(39)The volume of H2O required to prepare2/5N H2SO4 of its solution. The concentration of the solution is :
from 20 N 10 ml H2SO4 is : (a)0.1 M (b)0.01 M (c)0.02 M (d)0.001 M
(a)500 ml (b)490 ml (c)510 ml (d)400 ml. (54)What volume of 12N and 3N solutions must be mixed to
(40)1 g acetone (d= 0.6 g ml-1) is mixed with 2 g of water produce 3L of 6N solution of HCl?
(d= 1.0 g ml-1) hence volume percent of acetone (v/v) (a)2 L 12 N + 1 L 3 N (b)1 L 12 N + 2 L 3 N
is nearly : (c)1.5 L 12N + 1.5 L 3 N (d)0.5 L 12 N + 2.5 L 3 N.
(a)20% (b)40% (c)45% (d)60%. (55)On heating a litre of N/2 HCl, 1.375 g of HCl is lost and
(41)The amount of Na2CO3 . 10H2O required to prepare the volume of solution becomes 400 ml. The normality
250 ml of semi molar solution is : of resulting solution will be :
(a)107.25 g (b)35.75 g (c)53.62 g (d)71.50 g (a)0.58 (b)1.155 (c)0.057 (d)5.7
(42)When 644 g of Na2SO4 .xH2O is dissolved in 4000 ml (56)100 ml of H2SO4 solution having molarity 1 M and dens-
of aqueous solution, the molarity of the solution was -ity 1.5 g/ml is mixed with 400 g of water. Calculate the
found to be 0.5 M. The value of x is ? final molarity of H2SO4 solution if the final density is 1.25
(a) 5 (b) 10 (c) 8 (d) 2. g/ml.
(43)2.98 g KCl is dissolve in some water and the volume (a)0.227 M (b)1.25 M (c)2 M (d)1 M
of solution is made upto 125 ml. What is the molarity (57) The volume of 75% by mass alcohol solution (d=0.8 g/ml)
of solution ? required to prepare 105 ml 30% by mass alcohol solution
[Atomic mass :Cl=35.5, K=39] (d=0.9 g/ml) is.
(a)0.04 M (b)0.16 M (c)0.24 M (d)0.32 M. (a)77.25 ml (b)70 ml (c)50 ml (d)100 ml.
(44)20 g NaOH dissolved in 100 ml solution. The molarity (58)Molarity of water is :
of solution is : (a)1 M (b)1 m (c)12 M (d)55.5 M
(a)5 M (b)4 M (c) 3 M (d)2 M. (59)Calculate the density of acetic acid solution if the molar-
(45)The number of carbon atoms in 100 ml of 0.01 M ox- -ity and molality of its solution is 8 M and 3 m respectively.
-alic acid (C2H2O4) solution is : (a)3.14 g/ml (b)0.47 g/ml (c)1.368 g/ml (d)0.92 g/ml
(a)12.044 x 1020 atoms. (60)100 ml of 0.5 N solution of KCl is diluted till normality
(b)3.011 x 1023 atoms. becomes 0.2 N. Find the volume of water added for dilu-
(c)6.022 x 1020 atoms -tion.
(d) 6.022 x 1025 atoms. (a)250 (b)350 (c)50 (d)150.
(46)A solution is 3 ppm by weight. The weight percent (61)Mole fraction of solute in solution is 0.012. Molality
of this solution is : of thissolution is :
 (a)0.012 m (b)0.988 m (c)0.674 m (d)0.666 m.
(62)Find the correct statement about given aqueous sol-
-ution :
solution (A) : 1 M
solution (B) : 1 m.
(a)Solution A is more concentrated than solution V.
(b)Solution B is more concentrated than solution A.
(c)Both the solution are equally concentrated.
(d)Solution A is very dilute solution.
(63)What is the approx. mole fraction of solvent in 40%
(wt./wt.) aqueous solution of urea ?
(a)0.167 (b)0.833 (c)0.44 (d)0.66
(64)Which of the following would have minimum volume
at STP ?
(a)1 g equivalent O2 (b)1 g H2
(c)1 mole Cl2 (d)1 kg O3
(65)200 ml 0.1 M solution of HCl is prepared by mixing
V1 ml 0.07 M, V2 ml 0.12 M and V3 ml 0.15 M HCl solu-
-tions. The value of V1, V2 and V3 can be :
(a)110, 40, 50 (b)120, 30, 50
(c)100, 50, 50 (d)120,60,20.
(66)The density of 3 m aqueous solution of NaCl is 1.25
g/ml. What is the molarity of the solution ?
(a)2.0 m (b)2.8 m (c)3.2 m (d)3.8 m
(67)250 ml of an aqueous solution contains 7 g H2SO4 .
what would be the normality of the solution ?
(a)2/7 N (b)1/7 N (c)4/7 N (d)3/7 N.
(68)Molarity of 200 ml of acetic acid solution is 2 M. What
will be the molarity of 20 ml of the same solution ?
(a)0.2 M (b)20 M (c)0.02 M (d)2 M.
(69)What is the molality of 20% (wt./wt.)NaOH solution ?
(a)5 m (b)5.25 m (c)6.25 m (d)6.0 m
(70)The concentration of an aqueous solution of NaOH is
0.5 mol L-1. What volume of this solution must be added
to 250 ml of water to form a solution of concentration
0.02 mol L-1 ?
(a)5.2 ml (b)10.4 ml (c)15.6 ml (d)9.2 ml.
Chapter-(D) Equivalent wt. & no. of equivalent
(1)Equivalent Weight of Al2(So4)3 is? (15)Let molecular mass of Al2(SO4)3 = M1 and that of KCL.
(a)M/2 (b)M/3 (c)M/8 (d)M/6 MgCl2.6H2O = M2, then equivalent weight of the above
(2)Volume of one equivalent of any gas at S.T.P is given by :- compounds are respectively :
(a)22.4 lit. x n-factor (b) 22.4 lit. (a) M1 , M2 (b) M1 , M2
n-factor 3 1 6 3
(c)22.4 lit.- n-factor (d)22.4 lit. + n-factor (c) M1 , M2 (d) M1 , M2
(3)Normality of 1M H3BO3 is. 3 2 6 4
(a)3 N (b)2 N (c)1 N (d)4 N. (16)Normality of 0.1 M H3PO2 acid is :
(4)A trivalent metal has an equivalent mass of 9. The molecu- (a)0.1 (b)0.2 (c)0.3 (d)10.
-lar mass of the metal nitride is ? (17)1.0 g of metal nitrate gave 0.86 of metal carbonate.
(a)27 (b)41 (c)34 (d)23 equivalent weigh of metal is approximately.
(5)A1 g of an element gives A2 g og its oxide, the equival- (a)167 (b)83.5 (c)62 (d)30.
-ent mass of the element is : (18)1.5 g of hydroxide of a metal gave 1.0 g of its oxide on
(a) A1 x 35.5 (b) A2-A1 x 8 heating. The equivalent mass of metal is ?
A2-A1 A1 (a)5.0 (b)10.0 (c)12.0 (d)15.0
(6)The equivalent weight of H3PO4 may be (M=Molecular (19)8.4 g of a metal carbonate dissociates into 4 gram
weight of H3PO4). metal oxide. Calculate equivalent weight of metal car-
(a) M (b) M/2 (c) M/3 (d)All of these. -bonate.
(7)What volume of ammonia gas at NTP will be required (a)24 (b)84 (c)12 (d)42.
to be passed into 30 ml of 1 N H2SO4 to bring down the (20)Find the equivalent weight of acid in the given reaction
acid normality to 0.2 N? H3PO4 + B(OH)2 BHPO4 + 2H2O.
(a) 480.5 ml (b) 537.6 ml (c) 438.4 ml (d) 556.5 ml. (a)98 (b)49 (c)32.6 (d)196
(8)A mixture of MgCl2 and MgSO4 contains 0.6 moles of (21)The equivalent weight of a certain trivalent element is
chloride ions and 0.2 moles of sulphate ions. The equ- 20. Molecular weight of its oxide is :
-ivalent fraction of Mg2+ present in the mixture is : (a)168 (b)68 (c)152 (d)56.
(a) 0.3 (b) 5/13 (c) 0.5 (d) 1/3 (22)What is the number of gram equivalent of solute in 100
(9)x1 gram of an element gives x2 gram of its hydride. The ml of 5 N HCl ?
equivalent weight of the element is : (a)0.5 (b)1 (c)0.025 (d)0.05
(a) x2 (b) x2 – x1 (c) x1 (d) x2 – x1 (23)The molarity of 2 N H2SO4is :
x2-x1 x2 x1-x2 x1 (a)1 M (b)2 M (c)3 M (d)4 M.
(10)An excess of NaOH was added to 125 ml of a ferric chl- (24)5.6 L of oxygen at NTP is equivalent to :
-oride solution. This caused the precipitation of 1.78 g (a)1 mole (b)1/2 mole (c)1/4 mole (d)1/8 mole
of Fe(OH)3. Calculate the normality of the ferric chlor- (25)A metal (M) when heated in air shows 24% increase in
-ide solution. Its weight due to the formation of its oxide (MO). What
(a) 0.28 N (b) 0.34 N (c) 0.40 N (d)0.48 N Is the equivalent weight of the metal ?
(11)0.70 g mixture of (NH4)2SO4 was boiled with 100 ml of (a)12 (b)24 (c)33.33 (d)42.11
0.2 N NaOH solution till all NH3 evolved and got dissolve (26)In the reaction
in solution itself. The remaining solution was diluted to H3PO4 + 2 NaOH Na2HPO4 + 2H2O
250 ml. 25 ml of this solution was neutralize using 10 ml The equivalent mass of H3PO4(molecular mass =M) is ?
of 0.1 N H2SO4 solution. The percentage purity of the (a)M (b)M/2 (c)M/3 (d)2M
(NH4)2SO4 sample is : (27)Find the incorrect match.
(a) 50.8 (b) 98 (c) 79.8 (d)94.28 Compound Equivalent mass
(12)2.32 g of metal oxide produces 0.16 gram of O2 at 298 (a)Al2O3 M/3
K then equivalent weight of metal is : (b)H3BO3 M
(a)108 (b)216 (c)232 (d)Unpredictable. (c)KCl.MgCl2 M/3
(13)0.16 g of a dibasic acid required 25 ml of N/10 NaOH (d)Ca(OH)2 M/2
for complete neutralisation. What is the molecular wei- (M= molar mass).
–ght of the acid ? (28)2 g metal displaces all hydrogen present in 0.05 mole
(a)128 (b)93 (c)64 (d)46. H2SO4. Equivalent mass of metal oxide is :
(14)n- factor of H2SO4 in the following reaction is : (a)14 (b)28 (c)42 (d)56.
Pb +PbO2+H2SO4 PbSO4 +H2O.
(a)2 (b)3 (c)1/2 (d)1.
(E) Miscellaneous question (12)A sample of clay contains 40% silica and is 15% H2O.
the sample is partially dried by which it loses 5g water.
(1)One lit. hard water contains 2mg mgCl2 and 3mg CaCl2.
if the percentage of water in the partially dried clay is 8
find the total hardness in terms of parts of CaCo3 per
calculate the %age of silica in the partially dried clay :
106 parts of water by mass.
(a)43.29% (b)17.6% (c)28.24% (d)84.21%
(a)4.8 ppm (b)1.95 ppm (c)2.75 ppm (d)3.5ppm
(13)1 g of fuming H2SO4 (oleum) is diluted with water. This
(2)The percentage of hydrogen in water and hydrogen
solution is completely neutralized by 53.4 ml of 0.4 N
peroxide is 11.1% and 5.9% respectively. These figures
KOH. The percentage of free SO3 in the sample is :
iustrate :-
(a)20.6% (b)30.6% (c)50% (d)40.6%
(a)Law of constant proportion.
(14)2.00 g of a mixture of NaHCO3 and KClO3 requires 10 ml
(b)Law of conservation of mass.
of 1 N HCl for complete neutralization. The weight of
(c)Law of combining volume.
KClO3 present in the mixture is :
(d)Law of multiple proportion.
(a)0.84 g (b)1.84 g (c)1.16 g (d)0.16 g.
(3)5 g of hydrocarbon on combustion with 15.5 g of oxygen
(15)Excess of Kl and dil H2SO4 were mixed in 50 ml of H2O2.
produce 12.2 g of CO2 and 8.3 g of H2O. The data illu-
the I2 liberated requires 20 ml of 0.1 N Na2S2O3. The
-strate the law of.
strength of H2O2 is.
(a)Multiple proportion. (b)Constant proportion
(a)0.68 g/litre (b)0.58 g/litre
(4)Different proportion of oxygen in the various oxides of
(c)0.48 g/litre (d)0.38 g/litre.
nitrogen, prove the law of :
(16)25 ml of a solution containing HCl and H2SO4 required
(a)Reciprocal proportion.
10 ml of 2.0 N NaOHsolution for neutralization. 10 ml
(b)Multiple proportion.
of the same acid mixtureon being treated with an excess
(c)Constant proportion.
of BaCl2 gave 0.699 g of BaSO4. The normality of HCl and
(d)All of these.
the normality of H2SO4 are respectively. (Atomic mass :
(5)The temperature of a place was recorded as 149oF.
Cl=35.5, Ba=137).
what is the temperature reading in Kelvin ?
(a)0.15 N and 0.35 N (b)0.20 N and 0.60 N
(a)65 (b)412.15 (c)338.15 (d)573.35
(c)0.25 N and 0.40 N (d)0.50 N and 0.40 N
(6)In which of the following type of reaction total mass is
(17)An excess of NaOH was added to 100 ml of a FeCl3 sol-
not conserved?
-ution. This caused the precipitation of 1.425 g of Fe(OH)3
(a)Sublimation reactions.
calculate the normality of ferric chloride solution. (Atom-
(b)Salt-Hydrolysis reactions.
-icmass : Fe=56).
(c)Nuclear reactions.
(a)0.24 N (b)0.48 N (c)0.40 N (d)0.62 N
(d)Isomerisation reactions.
(18)A mixture of 2 g each of the sulphates of two metals
(7)The number of significant figures in 6.2 x 1023is ?
whose equivalent weights are 12 & 32 respectively was
(a) 23 (b)3 (c)4 (d)26.
dissolved in water. To this solution , an axcess of BaCl 2
(8)A gas is found to have the formula (CO)Xits vapour
was added, the weight of BaSO4 precipitated is :
density is 84. The value of x must be :
(Atomic mass : O=16, S=32, Ba=137).
(a)7 (b)6 (c)5 (d)3.
(a)3.4 g (b)6.8 g (c)13.6 g (d)27.2 g.
(9)For 118% H2SO4 labelled oleum, if the number of mo-
(19)A mixture contains equimolar quantities of carbonates
-les of free SO3, number of moles of H2SO4 present in
of two bivalent metals. One metal is present to an extent
oleum and number of moles of H2O required for com-
of 13.5% by weight in the mixture and 2.50 g of the mix-
plete reaction of SO3 are x, y, and z respectively, then
-ture on heating leaves a residue of 1.18 g. Calculate the
What will be value of x + y + z ?
percentage by weight of the other metal :
(a) 3.4 (b) 3.2 (c) 4.2 (d) 2.2
(a)28 (b)14.5 (c)30 (d)29.
(10)If excess of water is added to 100 g oleum sample
(20)2.00 g of a mixture of NaHCO3 and KClO3 requires 100ml
labeled as 112% H2SO4 and is reacted with 5.3 g
of 0.1 N HCl for complete neutralization. The weight of
Na2CO3, then find the volume of CO2 evolved at 1 atm
KClO3 present in the mixture is :
pressure and 300 K temperature after the reaction is
(a)0.84 g (b)1.84 g (c)1.16 g (d)0.16 g.
complete.
(21)An oleum sample is labeled as 104.5%. To 10 g of this
(a)11.2 L (b)12.3 L (c)1.23 L (d)2.46 L
sample 180 mg water is added then which of the followi-
(11)A clay was partially dried and was found to contain 50%
-ing statement (s) about the resulting solution is/are
silica and 7% water. The original clay contained 12%
correct ?
water. Find the percentage of silica in original sample ?
(a)Solution contains 11.79% free SO3
(a) 47% (b) 50% (c) 53% (d) 62%
(b)Solution contains 10.18 g H2SO4
 (c)Solution contains 19.65% free SO3 (a)Acidic (b)Highly basic
(d)Solution contains 8.98 g H2SO4. (c)Neutral (d)Weakly basic.
(22)A sample containing H3PO4 and P4O10 is labeled in the (35)Which of the following pair shows law of multiple
analogous manner as oleum. The mass of P4O10 in a proportion ?
sample labelled as 127%, Would be (Atomic mass : O=16, (a) CO2 and CS2 (b)CH4 and H2O
P=31). (c)HCl and HBr (d)SO2 and SO3.
(a)24 g (b)37 g (c)53 g (d)71 g. (36)How many ml of 0.2 N H2SO4 are needed to dissolve
(23)A metal oxide contains 53% metal and carbon dioxide 6.175 g copper(II) carbonate ?[Atomic mass : Cu =63.5].
contains 27% carbon. Assuming the law of reciprocal (a)1/2 L (b)5 L (c)1L (d)2 L.
proportions, the approximate percentage of metal in the (37)The molarity of HCl formed on mixing equal volumes
metal carbide is : of 1 M BaCl2 and 0.4 M H2SO4 is :
(a)75 (b)25 (c)37 (d)66. (a)0.4 M (b)1 M (c)0.5 M (d)0.2 M
(24)A gaseous mixture of NH3 gas and H2S gas contains 20% (38)When a metal is burnt in air, its weight increased by
(by mole) of NH3.The vapour density of the mixture is : 50%. The equivalent weight of metal will be :
(a)20.4 (b)3.06 (c)10.2 (d)15.3 (a)25 (b)24 (c)13.2 (d)16.
(25)If excess of water is added to 100 g oleum sample labe- (39)100 ml sample of tap water contains 800 mg of Ca2+ ions
-lled as 112% H2SO4 and is reacted with 5.3 g Na2CO3, th- to this sample, 100 ml, M/10 solution of Na2CO3 is added
-en find the volume of CO2 evolved at 1 atm pressure and the concentration of residual calcium ions in mol per litre
300 K temperature after the reaction is complete . in the solution, is :
(a)11.2 L (b)12.3 L (c)1.23 L (d)2.46 L. (a)0.05 M (b)0.10 M (c)0.15 M (d)0.50 M
(26)0.70 gm of (NH4)2SO4 was boiled with 100 ml 0.2 M (40)0.16 g of a dibasic acid required 25 ml of N/10 NaOH for
ution was neutralized by 10 ml of 0.1 NH2SO4. The Perc- complete neutralization. What is the molecular weight
-entage purity of (NH4)2SO4is : of the acid ?
(a)43.4% (b)52.6% (c)81.7% (d)94.3%. (a)128 (b)93 (c)64 (d)46.
(27)Find percentage composition of free SO3 in 118% (41)25 ml of a solution of barium hydroxide on titration with
oleum is ? 0.1 M solution of HCl gave a titre value of 35 ml. The mol-
(a)109 (b)80 (c)60 (d)40 -arity of barium hydroxide solution is :
(28)The NH3 evolved due to complete conversion of N (a)0.28 M (b)0.35 M (c)0.07 M (d)0.14 M
from 1.12 g sample of protein was absorbed in 44 ml (42)A metal of equivalent mass ‘E’ forms an oxide MxOy. The
of 0.4 N HNO3. The excess acid required 20 ml of 0.1 N atomic mass of the metal is :-
NaOH. The % N in the sample is ? (a)2Ey/x (b)xyE (c)E/y (d)Ex/2y
(a)8 (b)16 (c) 20 (d)25 (43)50 ml of 0.1 M H2SO4 is mixed with 150 ml of 0.2 M
(29)A sample containing H3PO4 and P4O10 is labelled in the NaOH solution. The resultant solution is :
analogous manner as oleum. The mass of P4O10 in a sa- (a)Acidic, N (b)Basic, N (c)Basic, 0.075 N (d) Basic, N
-mple labelled as 127%, would be (Atomic mass : O=16, 5 5 10
P=31). (44)4.16 g of BaCl2 (Ba=137) is added to 30 ml 2M solution
(a)24 g (b)37 g (c)53 g (d)71 g. of H2SO4.How much BaSO4 will be precipitated?
(30)Two metal oxide contain 50% and 40% of metal ‘M’ (a)0.2 mol (b)0.04 mol (c)0.06 mol (d)0.01 mol.
by mass respectively. If the formula of the first oxide (45)34 g of H2O2 is present in 1120 mL of solution, this solut-
is MO, then the formula of other metal oxide will be ? -ion is called ?
(a)M2O3 (b)MO2 (c)M2O5 (d) (a)20 volume (b)10 volume
(31)Which one of the following quantity has dimension ? (c)30 volume (d)32 volume.
(a) Molality (b) Mass fraction (46)Equivalent mass of a metal is 12, What will be the equi-
(c) Vapour Density (d) Specific gravity. -valent mass of the metal carbonate ?
(32)Two oxides of a metal M contain 40% & 50% of the (a)20 (b)42 (c)50 (d)28
metal respectively. If the formula of the first oxide is (47)If mA gram of a metal A displaces mB gram of another
M2O3, then the formula of the second oxide is ? metal B from its salt solution and if their equivalent wei-
(a)MO (b)MO2 (c)M3O4 (d)M2O5. -ghts are EA and EB respectively, then equivalent weight of
(33)The law of conservation of mass was proposed by A can be expressed as :
(a) John Dalton (b)J.J Thomson (a)EA=mA x EB (b)EA = mA x mB
(c)Joseph Proust (d)Lavoisier. mB EB
(34)Nature of the solution left after the reaction of 2.5 (c)EA = mB x EB (d)EA = √mA x EB
litre of 1.5 M NaOH with 1.5 M of 1.25 L H2SO4 will be mA mB
(48)A gram of metal forms b gram of metal chloride, equiva- but the molarity of solution depends on temperat-
-lent mass of metal is : -ure.
(a) a – b (b) b – a (c) a (35.5) (d) b – a x 35.5 (57)Find the correct statement(s).
b–a a (a)In all chemical reactions, the total moles of atoms
(49)1 g of fuming H2SO4 (oleum) is diluted with water. of each element remains conserved.
this solution is completely neutralized by 53.4 ml of (b)The number of atoms in one mole of any substa-
0.4 N KOH the percentage of free SO3 in the sample is : -nce is always the same.
(a)20.6% (b)30.6% (c)50% (d)40.6% (c)For very dilute solutions, the strength of solution
(50)XeFnis a white solid which reacts with H2 to give 81 ml in W/W percent and in W/V percent have nearly
ofXe at STP. The HF formed required 68.5 ml of 0.32 M equal value.
NaOH for complete neutralization. The number of lone (d)For very dilute solution, the mass of solution bec-
pair electrons in XeFn is/are -omes almost equal to the mass of the solvent.
(a)4 (b)1 (c)2 (d)3. (58)Find the correct statement(s).
(51)0.70 g mixture of (NH4)2SO4 was boiled with 100 ml of (a)The volume strength of 1.5N H2O2 solution is 8.4
0.2 N NaOH solution till all NH3 evolved and got (b)Maximum labeling of oleum is 122.5%.
dissolve in solution itself. The remaining solution was di- (c)Molality of a solution changes with temperature.
-luted to 250 ml. 25 mL of this solution was neutralized (d)Molarity of a solution is independent of temperature
using 10 ml of 0.1 N H2SO4 solution. The percentage pur- change.
-ity of the (NH4)2SO4 sample is : (59)Which relation given below is correct?
(a)50.8 (b)94.3 (c)79.8 (d)94.28. (a)For H2O2 volume strength = 5.6 x normality.
(52)which one of the following has maximum normality (b)20 volume H2O2 sample will have 6.07% strength.
of resulting solution ? (c)One molar solution of H2O2 has volume strength 11.2.
(a)100 ml of 0.2 M H2SO4 + 100 ml of 0.2 M NaOH. (d)1.5 N solution of H2O2 has volume strength 8.4.
(b)50 ml of 0.2 M H2SO4 + 50 ml of 0.2 M NaOH (60)What amount of O2 is/are required to completely oxi-
(c)1 equivalent of Ba(OH)2 + 100 ml of 0.1 N HCl. -dise 2.6 gram CH ≡ CH?
(d)25 ml of 0.4 N H2SO4 + 25 ml of 0.2 M NaOH (a)0.25 mole (b)1 gram equivalent.
(53)50 L of gaseous mixture of C2H4, CO and N2 gases (c)5.6 L at STP (d)32 gram O2.
having mass ratio 1 : 2 : 2 is taken in a eudiometric tube (61)28 g of N2 reacts with 8 g of H2 to produce NH3. The
and exploded with 60 L of O2. The incorrect statement true statement regarding this reaction is :
under NTP conditions is : (a)H2 is limiting reagent.
(a)Volume contraction after reaction is 30 L. (b)N2 is limiting regent.
(b)Volume of resulting gaseous mixture after passing (c)Product contains 8NA H atom.
through aqueous KOH is 50 L. (d)Product contains 8NA total atoms.
(c)Average molar mass of original gas mixture is 28. (62)What is/are the oxidation number of carbons in H –
(d)original mixture will decolourize baeyers regent COOCH3?
(54)30 ml of a dibasic acid is neutralized by 15 ml of 0.2 N (a)+2 (b)-2 (c)-4 (d)4
NaOH. The molarity of acid is ? (63)Same number of atoms are present in :
(a)0.05 M (b)0.1 M (c)0.2 M (d)0.4 M. (a)48 gran O (b)48 gram O2.
(55)A set of compounds and a corresponding law of chemi- (c)48 gram O3 (d)34 gram H2O2.
-cal combination which the compounds can illustrate is (64)Which of the following is/are correct for 17g/L of H2O2
given against each option. Find the incorrect one(s). solution?
(a)SO2, SO3 –Law of multiple proportion. (a)Volume strength is 5.6 at 273K and 1 atm.
(b)MgO, Cl2O7,MgCl –Law of reciprocal proportion. (b)Molarity of solution is 0.5M.
(c)NH3,N2O5,NO2 –Law of reciprocal proportion. (c)1 ml of this solution gives 5.6 ml O2 at 273K and 1 atm.
(d)H2O,D2O –Law of multiple proportion. (d)The normality of solution is 2N.
(56)Find the correct relation(s). (65)1 M HCl solution was slowly added into one litre of
(a)Molarity and molality for very dilute aqueous solution 0.37 kg of impure lime[Ca(OH)2] solution and the fol-
are approximately equal. -lowing plot was obtained.
(b)For very dilute solution, the mass of the solution beco-
-mes almost equal to the mass of solvent.
(c)Concentration of any solution has same magnitude in
any unit to express concentration.
(d)Molality of any solution is independent of temperature
 ofmilli eq. of NH4Cl.
(c)No. of milli. Eq. of NaCl = 0.0376.
(d)Percentage composition of NH4Cl = 46.5%
4 (Graph not to scale) (71)10 mol of He is equal to :
[HO-] (a)10 g of He (b)40 g of He
(mol/litre) 3 (c)40 g of atom of He (d)10 f atom of He.
(72)Which of the following represent the correct match?
2 (a)1.06 g of Na2CO3 - 10-2 g-molecule.
(b)4.9 g of H2SO4 - 0.15 g ion.
1 (c)0.15 g of CH3COOH - 2.5 x 10-3 mole.
(d)2 gH2 at STP - 22.4 mL.
(73)In which of the following ‘s’ character of underlined
1 2 3 4 atom decreases?
Volume of HCl added (a)nBeH2 (BeH2)n
(litres) (b)nBeCl2 (BeCl2)n
Now, select the correct statement among the following (c)3SO3 (SO3)3
(Assume that impurities in the lime sample do not react (d)PCl3 + Cl2 PCl 5.
withHCl). (74)Which of the following has/have same percentage of
(a)Lime sample is 50% pure. nitrogen?
(b)Mass of pure Ca(OH)2 in the original sample is 148 g. (a)NO (b)NO2 (c)N2O3 (d)N2O4.
(c)The above sample contains 1.204 x 1024 calcium ions. (75)Which of the following concentration term is/are indep-
(d)The slope of the curve is (-1). -endent of temperature?
(66)1 g molecule of Mn2O7contain. (a)Molarity (b)Molality
(a)7 mole of oxygen atom. (c)Mole fraction (d)Normality.
(b)2 mole of manganese atom. Paragraph for question Nos. 34 to 35.
(c)112 g of oxygen Sometimes, Oleum (H2SO4 + SO3) sample is reported as
(d)50 g manganese. more than 100% by weight. Eg. If oleum sample is 109%
(67)40 ml of 8.4 volume H2O2 is titrated with 0.12 M KMnO4 it means 100 g of this oleum reacts with H2O to form
in acidic medium. Which of the following statement is true H2SO4. From this, mass % of free SO3 can be calculated.
about the above titration? (85)The % of free SO3 in an oleum, that is labelled 118% is :
(a)Molarity of H2O2 solution is 0.75 M (a)20% (b)40% (c)60% (d)80%
(b)Volume of KMnO4 solution used at end point in 500 ml. (86)If 100 g of 118% oleum sample is dissolved in excess of
(c)Molarity of H2O2 solution is 1.50 M. water, then what volume of 0.2 M NaOH is required to
(d)Volume of KMnO4 solution used at end point is 100 ml. neutralize the solution?
(68)A solution containing 0.1 M CuSO4 and 0.1 M Al2(SO4)3 . (a)12 l (b)14 l (c)2 l (d)8 l.
Which of the following is/are correct? Paragraph for question Nos. 33 to 34
(a)Normality of total ions = 16. The strength of H2O2 can be expressed in terms of
(b)Molarity of total ions = 0.7 volume strength. The strength of ‘10V’ means 1 volume
-2
(c)Total number of moles of SO4 ions in solution = 0.4. of H2O2 on decomposition gives 10 volumes of oxygen
(d)Total number of moles of CU+2 and Al+3 ions in solut- at STP. Also, volume strength = 11.2 x molarity.
-ion = 0.3 (87)What is the percentage strength (% w/v) of 11.2 V H2O2?
(69)Which of the following concentration term(s) is/are (a)1.7 (b)3.4 (c)34 (d)11.2
independent of temperature? (88)20 ml of H2O2 solution is reacted with 80 ml of 0.05 M
(a)Molarity (b)Molality KMnO4 in acidic medium, then what is the volume stren-
(c)Mole fraction (d)Formality. -gth of H2O2?
(70)3.76 g of a mixture of NaCl and NH4Cl were boild with (a)2.8 (b)5.6 (c)11.2 (d)22.4
an excess of a strong soda and liberated gas was comp-
-letely absorbed by 100 mL of 1.01 N H2SO4. The solution (91)Mass of KCl in the solution is :
thus obtained was made upto 500 mL. 25 mL of this sol- (a)7.45 g (b)3.725 g (c)0.745 g (d)5.225 g.
-ution required 31.7 ml of n/10–Na2CO3 solution. Find the (92)The amount of Na2CO3 present in the sample would req-
correct statement(s) about the above set of data. -uire how many grams of H2SO4 for complete reaction?
(a)NH4Cl releases NH3 when treated with alkali. (a)9.8 g (b)4.9 g (c)2.45 g (d)14.7 g.
(b)Total milli eq. of acid = No. of milli eq. of Na2CO3 + No. Paragraph for question NOS. 93 to 95
(93)Eudiometric is technique to determine the molecular (101)If the density of final solution is 1.6 gm/ml, the perce-
formula and gases composition by studying volume of -ntage (weight/volume) of KBr in the final solution is
gases at same condition in eudiometer tube and elec- (a)74 (b)37 (c)148 (d)49.3
-tric spark is passed or explosion in made to oxidise com- Paragraph for question NOS. 104 to 105.
-bustible material the volume of different gases absorbed 5 g of a mixture of lead nitrate and sodium nitrate conta-
by different reagent. -ins 3.32 g of lead nitrate and the rest is sodium nitrate.
O turpentile oil. The mixture is heated below 873 K till a constant weight
O2 Pyrogallol residue is obtained. Given that atomic mass of Na = 23
N2 heated Mg. andPb = 207.
(94)A gas mixture of 3 L of propane and butane of on comp- 2NaNO3(5) 2NaNO2(5) + O2(g)
-lete combustion at 25oC produce 10 L of CO2, the gas 2Pb(NO3)2(5) 2PbO(5) + 2NO2(g) +O2.
mixture contains. (104)Total loss in weight is :
(a)1 L C3H8 + 2 L C4H10 (b)1.5 L C3H8 + 1.5 L C4H10. (a)72% (b)28% (c)64% (d)36%
(c)2 L C3H8 + 1 L C4H10 (d)0.5 L C3H8 + 2.5 L C4H10. (105)The gaseous mixture evolved during decomposition is
(95)10 ml of a mixture of CH4, C2H4 and CO2 was exploded (a)O2 + N2O (b)NO2 + N2O
with excess of air after explosion there was a contraction (c)NO2 + O2 (d)NO2 + N2O + O2.
of 10 ml and after treatment with KOH there was a furt- Paragraphfor question NOS. 106 to 107
-her reduction of 14 ml. What was the volume of CO2in A+B C
mixture? (meq)A = (meq)B = (meq)C
(a)1.5 ml (b)4.5 ml (c)5 ml (d)2.5 ml. (106)1.42 g of a mixture of CaCO3 and MgCO3 was dissolved
Paragraph for question NOS. 96 to 97. in 200 ml of 0.2 N HCl solution which was then diluted in
3.6 g of pure Mg is burnt in limited supply of oxygen. The 250 ml. 10 ml of this solution was neutralized by 12 ml of
residue was treated with 100 mL of H2SO4 (35% by mass, (N/30) Na2CO3. Find the % of CaCO3 in this mixture.
1.26 g/mL density), 2.24 litres of H2 at 760 mm Hg at 0oC (a)70.4% (b)29.6% (c)40% (d)50%
was evolved. After the reaction, H2SO4 was found to have (107)2.7 g of Al heated with 75 ml of H2SO4 (Specific gravity
density of 1.05 g/mL. Assuming no volume change of 1.18) 24.7% by wt. After the metal is carefully dissolved
solution. the solution is diluted to 400 ml. Calculate molarity of free
(96)The approximate, % by mass of final H2SO4. H2SO4 in resulting solution.
(a)25% (b)14% (c)28% (d)32%. (a)0.183 M (b)1.83 M (c)1.4 M (d)1.73 M.
(97)Volume of O2 taken initially at STP will be : Paragraph for question NOS. 108 to 109
(a)1.12 litre (b)0.56 litre Consider the reaction Mg + 2HCl MgCl 2 +H2.
(c)11.2 litre (d)5.6 litre. In this reaction magnesium is oxidized to Mg2+ by loosing
Paragraph for question NOS. 98 to 99. 2 electrons and H+ is reduced by gaining one electron. The
A mixture of Na2CO3 and NaHCO3 is treated with excess overall reaction involves transfer of two electrons
of CaCl2 which results in the formation of 1 g of white250 ml [Atomic mass : H = 1, Mg = 24, Cl = 35.5]
precipitate. The precipitate is filtered off. The filtrate is (108)3.696 g magnesium is treated with 80.3 g of an aque-
then treated with excess of NaOH, a further 2 g of white -ous solution of HCl (4% by mass). What is the volume of
precipitate is formed.(Ignore precipitate of Ca(OH)2, if any) hydrogen gas evolved in NTP?
(98)The percentage of NaHCO3 in the mixture is approxima- (a)1.97 L (b)985.6 ml (c)492.8 ml (d)1.478 L.
-tely. (109)In the above reaction (given in Q. No. 32), What is the
(a)44% (b)56% (c)39% (d)61% amount of unreacted substance?
(99)The same mixture is heated and the gases evolved are (a)1.58 g magnesium (b)0.803 g HCl
dissolved in 500 ml of water. Assuming the gases dissolve (c)1.606 g HCl (d)2.64 g magnesium.
completely to form a solution, this is then titrated with 1 Paragraph for question NOS. 110 to 111
M NaOH solution. The volume of NaOH needed at phenol- A 500 ml of a solution containing nitrate ion was treated
-phthalein end point would be : with just sufficient magnesium metal and NaOH to give
(a)2 ml (b)10 ml (c)20 ml (d)100 ml. Mg(OH)2 and NH3. The volume of NH3 gas evolved at 300K
Paragraph for question NOS. 100 to 101 and 1 atm pressure was found to be 4.9 litres. When the
120 gm of solution of KBr (40% by mass) is mixed with same mass of magnesium was treated with dil. HCl, mag--
200 gm of a solution of KBr (50% by mass). Answer the nesium was completely converted to MgCl2 and a certain
following questions. volume of H2 gas was collected. [Use R=0.082 L atm
(100)The mass percentage of KBr in the final solution is : Mol-1K-1].
(a)92.5 (b)46.25 (c)50 (d)23.25 (110)What is the molarity of NO3- ion in the given solution?
 (a)0.4 M (b)0.2 M (c)0.15 M (d)0.35 M
(111)What is the volume of H2 gas evolved at 300 K and 6
atm pressure?
(a)4.92 litre (b)3.28 litre (c)2.46 litre (d)14.76 litre.
Paragraph for question NOS. 112 to 113
Hydrates are the compounds containing water molecules
loosely bound to other compounds. H2O can be removed
just by heating such compounds and may then be replac-
-ed by wetting.
In copper sulphate salt, five water molecules are attached
as water of hydration. Anhydrous copper sulphate salt is
white in colour while hydrated copper sulphate in blue
coloured salt.
(112)Fe(SCN)3 is found to contain 19% H2O in hydrate of
iron(III)thiocyanate. What is formula of the compound ?
[Use atomic masses : C=12, N=14, S=32, Fe=56].
(a)Fe(SCN)3.3H2O (b)Fe(SCN)3.2H2O.
(c)Fe(SCN)3.H2O (d)Fe(SCN)3.4H2O.
(113)A hydrated sulphate of metal has 8.1% metal and 43.2%
SO42- by weight. If the atomic weight of metal is 27, iden-
-tify hydrated sulphate.
(a)Al2(SO4)3.18H2O (b)Al2SO4.6H2O
(c)MgSO4.10H2O (d)MgSO4.7H2O.