Enthuse All - 15-10-20 - P-2 - Combined

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JEE ADVANCED PATTERN

TEST-8 (15-10-2020)
Time: 3 Hours ENTHUSE - ALL Maximum Marks: 183

PAPER-2 WITH SOLUTION


READ THE INSTRUCTIONS CAREFULLY
GENERAL

DO NOT BREAK THE SEALS WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR.


1. This sealed booklet is your Question Paper. Do not break the seal till you are told to do so.
2. The paper CODE is printed on the right hand top corner of this sheet and the right hand top corner of the
back cover of this booklet.
3. Use the Optical Response Sheet (ORS) provided separately for answering the questions.
4. The paper CODE is printed on the left part as well as the right part of the ORS. Ensure that both these
codes are identical and same as that on the question paper booklet. If not, contact the invigilator for
change of ORS.
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7. After breaking the seal of the booklet verify that the booklet contains 26 pages and that all the
54 questions along with the options are legible. If not, contact the invigilator for replacement of the
booklet.
8. You are allowed to take away the Question Paper at the end of the examination.
OPTICAL RESPONSE SHEET
9. Darken the appropriate bubbles on the ORS by applying sufficient pressure. This will leave an impression
at the corresponding place on the Candidate’s Sheet.
10. The ORS will be collected by the invigilator at the end of the examination.
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13. Write your name, roll number and code of the examination center, and sign with pen is the space provided
for this purpose on the ORS. Do not write any of these details anywhere else on the ORS. Darken the
appropriate bubble under each digit of your roll number.
DARKENING THE BUBBLES ON THE ORS
14. Use a BLACK BALL POINT PEN to darken the bubbles on the ORS.
15. Darken the bubble COMPLETELY
Y.
16. The correct way of darkening a bubble is as:
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18. Darken the bubbles ONLY IF you are sure of the answer. There is NO WAY to erase or “un-darken” a
darkened bubble.
Please see the last page of this booklet for rest of the instructions.

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I have verified all the information filled in by the Candidate.


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Signature of the Candidate Signature of the invigilator

CHOOSE WISE TO RISE


Some Useful Data

Quantity Values
Constant of gravitation 6.67259 × 10–11 N-m2 kg–2
Speed of light in vacuum 2.99792458 × 108 m s –1
Avogadro constant 6.0221367 × 1023 mol–1
Gas constant 8.314510 JK–1-mol–1
Boltzmann constant 1.380658 × 10–23 JK–1
8.617385 × 10–5 eV K–1
Stefan-Boltzmann constant 5.67051 × 10–8 W m–2 - K–4
Wien’s displacement law constant 2.897756 × 10–3 m -K
Charge of proton 1.60217733 × 10–19 C
Mass of electron 9.1093897 × 10–31 kg
5.48579903 × 10–4 u
Mass of proton 1.6726231 × 10–27 kg
1.007276470 u
Permeability of vacuum 4 × 10–7 NA–2
Permittivity of vacuum 8.854187817 × 10–12 C2 N–1 m–2
Faraday constant 96485.3029 C mol–1
Planck constant 6.6260755 × 10–34 J-s
4.1356692 × 10–15 eV-s
JEE-ADVANCED
PART-I : PHYSICS
SECTION-I : One or More Options Correct Type
This section contains 7 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONE OR MORE THAN ONE may be correct. You will be awarded 4 marks if all the
correct option(s) is/are chosen and zero mark if none of the option is chosen. For each correct answer
+1 mark will be awarded if no incorrect option is chosen. In all other cases minus two (–2) mark will be
awarded.

1. An observer A and a charge Q are fixed in a stationary frame F1 . An observer B is fixed in a frame
F2 , which is moving with respect to F1 :

A B
F1 •Q F2

(A) both A and B will observe electric field


(B) both A and B will observe magnetic field
(C) neither A nor B will observe magnetic field
(D) B will observe magnetic field but A will not

2. Nucleus A decays to B with decay constant λ1 and B decays to C with decay constant λ2. Initially
at t = 0, number of nuclei of A and B are 2N0 and N0 respectively. At t = t0, number of nuclei of B
3N 0
stop changing. If at this instant number of nuclei of B are .
2
1 4 λ1 1 4 λ1
(A) the value of t 0 is ln (B) the value of t 0 is ln
λ1 3 λ 2 λ2 3 λ2
3N 0 λ 2 2N 0 λ 2
(C) the value of NA at t 0 is (D) the value of NA at t 0 is
2 λ1 3 λ1
Nucleus Education-(ENTHUSE ALL)_15102020

3. A sound wave of frequency ν travels horizontally to the right. It is reflected from a large vertical
plane surface moving to the left with a speed V. The speed of sound in the medium is c.
ν (c + V )
(A) the number of wave pulse striking the surface per second is
c
c (c − V )
(B) the wavelength of the reflected wave is
ν (c + V )
ν (c + V )
(C) the frequency of the reflected wave is
(c − V )
vV
(D) the number of beats heard by a stationary listener to the left of the reflecting surface is
c −V

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JEE-ADVANCED
4. Two monochromatic coherent point sources S1 and S2 are separated by a distance L. Each source
emits light of wavelength λ, where L >> λ. The line S1S2 when extended meets a screen
perpendicular to it at a point A
(A) the interference fringes on the screen are circular in shape
(B) the interference fringes on the screen are straight lines perpendicular to the line S1 S 2 A
(C) the point A is an intensity maxima if L = nλ
(D) the point A is always an intensity maxima for any separation L

5. H+, He+ and O++ ions having same kinetic energy pass through a region of space filled with
uniform magnetic field B directed perpendicular to the velocity of ions. The masses of the ions H+,
He+ and O++ are respectively in the ratio 1 : 4 : 16. As a result
(A) H+ ions will be deflected most
(B) only O++ ions will be deflected least
(C) He+ and O++ ions will suffer same deflection
(D) All ions will suffer the same deflection

6. Figure shows three concentric thin spherical shells A, B and C of radii R, 2R, and 3R. Shells A and
C are given charges q and 2q and shell B is earthed. Then

B
C
4 4
(A) charge on inner surface of shell C is q (B) charge on outer surface of shell B is − q
3 3
2 4
(C) charge on outer surface of shell C is q (D) charge on outer surface of shell C is q
Nucleus Education-(ENTHUSE ALL)_15102020

3 3

7. The temperature drop through a two layers furnace wall is 900ºC. Each layer is of equal area of
cross-section. Which of the following actions will result in lowering the temperature θ of the
interface?
Inner Outer
layer layer
1000ºC 100ºC

θ
(A) by increasing the thermal conductivity of outer layer
(B) by increasing the thermal conductivity of inner layer
(C) by increasing thickness of outer layer
(D) by increasing thickness of inner layer

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JEE-ADVANCED
SECTION-II : Integer Value Correct Type
This section contains 5 questions. For each question, enter the correct numerical value (in decimal
notation, truncated / rounded off to the second decimal place; e.g. 6.25, 7.00, –0.33, –0.30, 30.27,
–127.30) using the mouse and the on screen virtual numeric keypad in the place designated to enter the
answer. You will be awarded 3 marks if correct numerical value is entered as answer. No negative
marks will be awarded for incorrect answers in this section.
8. In certain element the K-shell electron energy is – 18.525 keV and the L-shell electron energy is –
3 keV. When an electron jumps from the L-shell to K shell, an X-ray photon is emitted. The
wavelength(in Å) of the emitted X-rays is

9. Two identical sources P and Q emit waves in same phase and of same wavelength. Spacing between P
and Q is 3λ. The maximum distance from P along the x–axis at which a minimum intensity occurs is
given by Nλ. Value of N is
y

P x

10. Three long, straight and parallel wires C, D and G carrying currents are arranged as shown in
figure. The force experienced by a 25 cm length of wire C is α × 10-3 N. Value of α is.
D C G

30 A 10 A 20 A

3 cm 10 cm
Nucleus Education-(ENTHUSE ALL)_15102020

11. In the circuit shown in figure if switch S is closed, the charge(in µC) that flows through battery is
equal to
3µF 15µC, 3µF
S +
_
_
+
_
+

10 V

12. The frequency of a sonometer wire is 100 Hz. When the weights producing the tensions are
completely immersed in water the frequency becomes 80 Hz and on immersing the weights in a
certain liquid the frequency becomes 60 Hz. The specific gravity of the liquid is

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JEE-ADVANCED
SECTION-III : Paragraph Type
This section contains 2 Paragraphs each describing theory, experiment and data etc. Six questions relate
to two paragraphs with three questions on each paragraph. Each question of a paragraph has
ONLY ONE is correct answer among the four choices (A), (B), (C) and (D). You will be awarded
3 marks if only the correct option is chosen and zero mark if none of the option is chosen. (–1) marks
will be awarded for incorrect answers in this section.
Answer Q.13, Q.14 and Q.15 by appropriately matching the information given in the three
columns of the following table
Column-I Column-II Column-III
v

Real object & its image


always lie on the same (–f, 0)
(I) (i) Concave mirror (P) u
side of pole/optical
centre. (0, –f)

C v i

(0, f)
Image of real object is
(II) (ii) Convex mirror (Q) (f, 0) u
always virtual.

C v i

(f, 0)
Image of virtual object
(III) (iii) Diverging lens (R)
Nucleus Education-(ENTHUSE ALL)_15102020

is always real. (–f, 0) u

Image of real object is


(IV) (iv) Converging lens (S) (f, 0) u
always erect
(0, –f)

13. In which of the given case velocity of object and image is in opposite direction
(A) (IV)-(ii)-(Q) (B) (I)-(iii)-(S) (C) (II)-(iv)-(R) (D) (III)-(iv)-(R)

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JEE-ADVANCED
14. In which of the given case magnification is always greater than one.
(A) (II)-(i)-(P) (B) (IV)-(ii)-(P) (C) (IV)-(i)-(R) (D) None of these

15. In which of the given case image is always diminished ?


(A) (II)-(ii)-(P) (B) (I)-(i)-(R) (C) (IV)-(ii)-(Q) (D) None of these

Answer Q.16, Q.17 and Q.18 by appropriately matching the information given in the three
columns of the following table
Power dissipated in circuit is P
Column-I Column-II Column-III
2R

2R
V2
(I) (i) r=R (P) P=
r R

2R 4R

5R
V2
(II) 4R 8R (ii) r = 2R (Q) P=
4R

V r

R R
Nucleus Education-(ENTHUSE ALL)_15102020

2R R V2
(III) (iii) r = 3R (R) P=
6R
V r

2R

Power dissipated is
(IV) (iv) r = 4R (S)
maximum
V r

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16. Which of the following combination is correct?
(A) (I) (iv) (R) (B) (II) (ii) (R) (C) (I) (ii) (S) (D) (I) (i) (P)

17. Which of the following combination is correct?


(A) (II) (iv) (R) (B) (IV) (i) (R) (C) (III) (ii) (Q) (D) (III) (i) (P)

18. Which of the following combination is correct?


(A) (I) (iv) (Q) (B) (II) (i) (Q) (C) (I) (ii) (S) (D) (IV) (i) (S)
Nucleus Education-(ENTHUSE ALL)_15102020

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JEE-ADVANCED
PART-II : MATHEMATICS
SECTION-I : One or More Options Correct Type
This section contains 7 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONE OR MORE THAN ONE may be correct. You will be awarded 4 marks if all the
correct option(s) is/are chosen and zero mark if none of the option is chosen. For each correct answer
+1 mark will be awarded if no incorrect option is chosen. In all other cases minus two (–2) mark will be
awarded.
  −1  x 
  tan x + 2sgn  2 
, x≥0
19. Let f(x) =    1 + x  and g(x) = |x + 2| – tan 1 ∀ x ∈ R
{[x]}, x < 0

If h(x) = min. (f(x), g(x)), then
(A) minimum value of h(x) is – tan1.
(B) maximum value of h(x) is 3
(C) number of points where h(x) is discontinuous is 2
(D) number of points where h(x) is non-derivable is 5.
[Note : [y], {y} and sgn(y) denote greatest integer, fractional part and signum function
respectively ]

 −1 + x 2 + 1 
20. If g(x) = sin −1   then
 2 1 + x 
2

g(x)  π
(A) g'(–1) = lim− (B) range of g(x) is 0, 
x →0 2x  4
g(x) 1
(C) lim = (D) g'(x) is an even function
x →0 x 2
Nucleus Education-(ENTHUSE ALL)_15102020

 x2 
21. If g(x) =   + ƒ(3 – x2) ∀ x ∈ (–3, 4), where ƒ"(x) > 0 ∀ x ∈ (–3, 4), then g(x) is –

 3 
3   3 
(A) increasing in  , 4  (B) increasing in  − ,0 
2   2 
 3  3
(C) decreasing in  −3, −  (D) decreasing  0, 
 2  2

 x 
22. Given =
x →−∞
( )
L1 lim x + x 2 − 8x + 4 & L 2= lim  x − x 2 −   
x →∞ 
  2  
(where [.] → G.I.F.) then
(A) L1 = 4 (B) L1L2 = 1 (C) L1L2 = 4 (D) L2 = 1

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JEE-ADVANCED
23. Which of the following statement(s) is/are correct ?
Where sgn(k) and [k] denotes signum function and greatest integer function respectively.
(A) If f(x) = x2 + 10 sin x, –∞ < x < ∞ then ∃ some c ∈ R such that f(c) = 2015.
(B) Suppose f is continuous function on [1, 5] and the only solutions of the equation f(x) = 6
are x = 1 and x = 4. If f(2) = 8, then f(3) > 6.
(C) The functions f(x) = sgn (tan–1 e–x) and g(x) = cos(2[cot–1 x]π) are identical functions,
(D) If the function g(x) = sgn (kx) is continuous for every x ∈ R ,then number of real values of
k is one.

24. Let circle is drawn on chords of xy = 4 as diameter, which are parallel to transverse axis of
hyperbola xy = 4 with eccentricity eH. If these circles always passes through extremities of major
axis of ellipse with eccentricity e such that e.eH = 1, then
(A) equation of ellipse is 3x2 + 3y2 + 2xy – 16 = 0
(B) equation of director circle of ellipse is x2 + y2 = 12
(C) equation of common tangents of ellipse and hyperbola are x + y = ± 4
(D) transverse axis of hyperbola coincides with major axis of ellipse.

25. Let x + y = 2 and 2x + y = 4 are tangents to a parabola such that P(–2, 4) and Q(1, 2) are foot of
perpendicular from focus respectively, then –
(A) equation of axis of parabola is 3x – 2y + 21 = 0
(B) equation of latus rectum is 2x + 3y + 27 = 0
65
(C) length of latus rectum =
13
(D) coordinates of focus is (–9, 3)

SECTION-II : Integer Value Correct Type


This section contains 5 questions. For each question, enter the correct numerical value (in decimal
notation, truncated / rounded off to the second decimal place; e.g. 6.25, 7.00, –0.33, –0.30, 30.27,
–127.30) using the mouse and the on screen virtual numeric keypad in the place designated to enter the
Nucleus Education-(ENTHUSE ALL)_15102020

answer. You will be awarded 3 marks if correct numerical value is entered as answer. No negative
marks will be awarded for incorrect answers in this section.
26. There are 7 distinguishable rings. The number of possible five-ring arrangements on the four
fingers (except the thumb) of one hand (the order of the rings on each finger is to be counted and it
N
is not required that each finger has a ring) is N, then is equal to
120

27. Let a cubic polynomial be f(x) = x3 – 3x2 + ax + 4. If all the values of a for which f(x) has a
positive point of maxima also satisfy the inequality x2 – x – kx + k2 – 2k < 0, then the sum of all
the integral values of k is

28. If the slope of the tangent to the curve 2(x – y3)4 = x2 (1 + x3)5 at the point (1, –1) is t,
then the value of [| t |].
[Note : [k] denotes the largest integer less than or equal to k.]

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2 − x + a 2 − 9a − 9, for x < 2
29. Let f (x) = 
2x − 3, for x ≥ 2
where a is a positive constant. If f(x) has local minima at x = 2, then the smallest integral value
of a is

100
aπ a−c
30. If ∑ tan −1
(n 2 + n + 1) = – tan–1 c, then find the value of where a, b, c ∈ N and a & b
n =1 b b
are relatively prime.

SECTION-III : Paragraph Type


This section contains 2 Paragraphs each describing theory, experiment and data etc. Six questions relate
to two paragraphs with three questions on each paragraph. Each question of a paragraph has
ONLY ONE is correct answer among the four choices (A), (B), (C) and (D). You will be awarded
3 marks if only the correct option is chosen and zero mark if none of the option is chosen. (–1) marks
will be awarded for incorrect answers in this section.
Answer Q.31, Q.32 and Q.33 by appropriately matching the information given in the three
columns of the following table
Match the condition of column-1 with corresponding number of real roots of f(x) = 0 in column-II
and number of points of non-derivability of y = |f( | x | ) | in column-III, where f(x) = ax2 + bx + c.

Column-1 Column-2 Column-3

(I) a2 + b2 + c2 – ab – bc – ca ≤ 0, a ≠ 0 (i) 0 (P) 0

(II) a2 + b2 + c2 + ab + bc + ca ≤ 0 (ii) 1 (Q) 1


Nucleus Education-(ENTHUSE ALL)_15102020

(III) 3(a2 + b2 + c2 + 1) ≤ 2 (a + b + c + ab + bc + ca) (iii) 2 (R) 3

(IV) a2 + b2 + c2 ≤ 2a + 6b + 4c – 14 (iv) ∞ (S) 5

31. Which of the following is CORRECT combination ?


(A) (I) (i) (P) (B) (I) (iii) (Q) (C) (II) (iv) (P) (D) (II) (ii) (Q)

32. Which of the following option is INCORRECT combination ?


(A) (III) (i) (Q) (B) (II) (i) (P) (C) (I) (i) (Q) (D) (II) (iv) (P)

33. Which of the following is CORRECT combination ?


(A) (III) (i) (P) (B) (II) (i) (R) (C) (IV) (iii) (R) (D) (IV) (iii) (Q)

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Answer Q.34, Q.35 and Q.36 by appropriately matching the information given in the three
columns of the following table
Column-1 : contains conics : Column-2 : number of common tangents ; Column-3: number of
common normals

Column-1 Column-2 Column-3

(I) 2y2 = 2x – 1 and 2x2 = 2y –1 (i) 0 (P) 0


2
 3
 x + 
(II) 2 4  3  4  (y − 1) 2 (ii) 1 (Q) 1
(y – 1) =  x +  and + =
1
3 4  9 3

(III) x2 = y – 2 and y + x2 – 2x + 3 = 0 (iii) 2 (R) 2

(IV) y2 = –4x and x2 = –4y (iv) 3 (S) 3

34. Which of the following is CORRECT combination ?


(A) (I) (iv) (Q) (B) (I) (iv) (S) (C) (II) (i) (S) (D) (II) (ii) (S)

35. Which of the following option is CORRECT combination ?


(A) (IV) (i) (Q) (B) (IV) (i) (P) (C) (IV) (ii) (Q) (D) (I) (iv) (P)

36. Which of the following is INCORRECT combination ?


(A) (III) (iii) (Q) (B) (II) (i) (S) (C) (II) (iii) (S) (D) (IV) (ii) (Q)
Nucleus Education-(ENTHUSE ALL)_15102020

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JEE-ADVANCED
PART-III : CHEMISTRY
SECTION-I : One or More Options Correct Type
This section contains 7 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONE OR MORE THAN ONE may be correct. You will be awarded 4 marks if all the
correct option(s) is/are chosen and zero mark if none of the option is chosen. For each correct answer
+1 mark will be awarded if no incorrect option is chosen. In all other cases minus two (–2) mark will be
awarded.
37. Which of the following on heating produce oxygen gas?
(A) (NH4)2Cr2O7 (B) K2Cr2O7 (C) KMnO4 (D) KNO3

38. Which is/are CORRECT graph for given reaction ? [A: concentration at time t, A0 : initial
concentration, T0.5 : half life time]
lnA

(A) First order kinetics (A → B)

t
A

(B) Zero order kinetics (A → B)

t
T0.5

(C) Radioactive decay (A → B)

temp.

T0.5
(D) 2nd order kinetics (A → B)
Nucleus Education-(ENTHUSE ALL)_15102020

A0
39. An alkene 'P' (C5 H10) on ozonolysis gives a mixture of two compounds R & S. On the basis of
following obsenates.
Select the CORRECT option :

Compound/Test Fehling Iodoform


R  
S × 


(A) PH3P = CH–CH3 + (R) 
→ (P) (B) + H2SO4  → (P)
OH
Quindine 2 (i)SnCl /HCl
(C) CH3–COCl + H2/Pd  → (S) (D) CH3–CN 
(ii)H O
→ (R)
2

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40. Which of the following metal sulphide dissolved in hot and dil. HNO3
(A) HgS (B) ZnS (C) CuS (D) PbS

41. Which of the following arrangement will produce oxygen at anode during electrolysis ?
(A) Dilute H2SO4 solution with Cu electrodes
(B) Dilute H2SO4 solution with inert electrodes.
(C) Fused NaOH with inert electrodes.
(D) Dilute NaCl solution with inert electrodes.

42. A compound (P) (C3H6O), produces cyanohydrim (Q) with HCN/NaCN. (Q) reaction with 95%
H2SO4 produces (R) which can show stereoisomerism. Then select the CORRECT option.
O OH OH
(A) P ⇒ (B) Q ⇒ (C) R ⇒ (D) R ⇒
CN COOH COOH

43. Nitrogen dioxide can be obtained by heating :


(A) KNO3 (B) Pb(NO3)2 (C) Cu(NO3)2 (D) AgNO3

SECTION-II : Integer Value Correct Type


This section contains 5 questions. For each question, enter the correct numerical value (in decimal
notation, truncated / rounded off to the second decimal place; e.g. 6.25, 7.00, –0.33, –0.30, 30.27,
–127.30) using the mouse and the on screen virtual numeric keypad in the place designated to enter the
answer. You will be awarded 3 marks if correct numerical value is entered as answer. No negative
marks will be awarded for incorrect answers in this section.
44. The number of element which can be identified by flame test :
Li , Be , Mg , K , Ba , Ca , Na

45. Isotopes of oxygen with mass number less than 16 undergo β+ emission. Assuming an equimolar
mixture of O14 and O15, determine time (in sec.) required for nuclei ratio O14/O15 to become equal
Nucleus Education-(ENTHUSE ALL)_15102020

to 0.25. t1/2 for O14 and O15 are 62 and 124 second respectively.

46. The number of compound(s) which given a gas on heating which turns lime water milky.
Ag2CO3 , HgCO3 , ZnCO3 , (NH4)2CO3 , K2CO3 , BaCO3

47. How many of following reactions will produce carbonyl compound?


Hg2+
(1) CH3–C≡CH 
H SO
→ (2) (C6H5CH2)2 Cd + 2CH3COCl 

2 4

Anhydrous
(3) Hexan-1-ol 
CrO
→ (4) Cynclohexanol + C5 H 5 NH.CrO3ClΘ 

3

CH3

(i)Cl /hν
2 PhMgBr (i)
(5) 
(ii)H O,100° C
→ (6) CH3–C≡N 
(ii)H O

2 2

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48. How many of the following anions will give a brown colour gas (or liquid) on treatment with
dilute HCl.
HCO3– , S2O3–2 , NO2– , NO3– , Br– , I– , SO4–2

SECTION-III : Paragraph Type


This section contains 2 Paragraphs each describing theory, experiment and data etc. Six questions relate
to two paragraphs with three questions on each paragraph. Each question of a paragraph has
ONLY ONE is correct answer among the four choices (A), (B), (C) and (D). You will be awarded
3 marks if only the correct option is chosen and zero mark if none of the option is chosen. (–1) marks
will be awarded for incorrect answers in this section.
 Answer Q.49, Q.50 and Q.51 by appropriately matching the information given in the three
columns of the following table
Given are titration graphs for HA v/s BOH.

Column-1 Column-2 Column-3

8
At equivalent point pH
At equivalent point pH 4
(I) (i) (P) depends upon
pH > 7
concentration of salt
Vbase

10
At equivalent point
At equivalent point 6
(II) (ii) pH (Q) does not depends upon
pH < 7
concentration of salt
Vbase
Nucleus Education-(ENTHUSE ALL)_15102020

10
At equivalent point pH 4 Phenolphthalein
(III) (iii) (R)
pH = 7 indicator can be used
Vbase

8
At half equivalent
6 Methyl orange
(IV) point pH = ionization (iv) pH (S)
indicator can be used
constant
Vbase

49. For titration of weak acid with strong base INCORRECT set is :
(A) (I), (ii), (P) (B) (IV), (ii), (P) (C) (I), (ii), (R) (D) (II), (i), (Q)

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50. For titration of strong acid with strong base CORRECT set is :
(A) (III), (i), (Q) (B) (II), (i), (R) (C) (III), (iii), (R) (D) (III), (iii), (P)

51. For titration of weak base with strong acid CORRECT set is :
(A) (II), (iv), (S) (B) (IV), (iv), (Q) (C) (III), (i), (Q) (D) (II), (i), (P)

 Answer Q.52, Q.53 and Q.54 by appropriately matching the information given in the three
columns of the following table

Column-1 Column-2 Column-3


(Reaction) (Involves) (Major product)
(i)
NaOH,∆
(I) CH3–CHO →
(ii) CrO , H SO (i) Self aldol (P) Ph–CH=CH–COOH
3 2 4

3(i)(CH CO) ,∆
2 HVZ
(II) Ph–CHO 
(ii)CH COONa,∆
→ (ii) (Q) CH3–CH=CH–COOH
3 reaction
COOH 2 (i)Red/Cl Perkin
(III) 
Θ →
(iii) (R) CH3COOH
(ii)EtO ,∆ reaction
O Haloform
(IV) (i) NaOH, ∆ (iv) (S) CH2CH2OH
Ph–CHO + 
(ii) NaOI
→ reaction

52. Which of the following set is CORRECT ?


(A) (I), (i), (Q) (B) (II), (iii), (P) (C) (I), (i), (R) (D) (II), (iii), (R)

53. Which of the following set is INCORRECT ?


(A) (III), (ii), (Q,S) (B) (II), (iii), (P,R) (C) (IV), (i,iv), (P,S) (D) (IV), (iv), (P,S)
Nucleus Education-(ENTHUSE ALL)_15102020

54. Which of the following set is CORRECT For given reaction ?


(i)Drydistillation
(CH3COO)2Ca 
(ii)I / NaOH

2

(A) (iv), (S) (B) (ii), (Q) (C) (iv), (Q) (D) (iv), (R)

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ANSWER KEY & SOLUTION


PART-I : PHYSICS
1. AD 2. AC 3. ABC 4. AC 5. AC 6. ABC 7. AD
8. 0.80 9. 8.75 10. 0.40 11. 7.50 12. 1.77 13. A 14. A
15. C 16. B 17. C 18. D

PART-II : MATHEMATICS
19. ABD 20. AB 21. ABCD 22. AB 23. ABCD
24. BCD 25. AB 26. 1176.00 27. 2.00 28. 1.00
29. 10.00 30. 25.00 31. C 32. B 33. D
34. A 35. C 36. B

PART-III : CHEMISTRY
37. BCD 38. ABCD 39. BD 40. BCD 41. BCD 42. C 43. BCD
44. 5.00 45. 248.00 46. 5.00 47. 6.00 48. 1.00 49. D 50. C
51. D 52. A 53. C 54. D

SOLUTION | PART-I : PHYSICS | ENTHUSE ALL


1. (A,D)
Sol. For frame F1, the charge Q is at rest and for frame F2, the charge Q is in motion. Charge at rest or
in motion produces electric field. So both A and B will observe electric field.
Hence, choice (a) is correct.
Only moving charges produces magnetic field. So B will observe magnetic field but A will not
observe any magnetic field.
Hence, choice (d) is correct and choices (b) and (c) are wrong.
Nucleus Education-(ENTHUSE ALL)_15102020

2. (A,C)
dN B
Sol. = λ1 N A − λ 2 N B
dt
dN B 3N 0 3N 0
at, t = t0, = 0 , NB = ⇒ 2 N 0 λ1e −λ1t0 − λ 0 =0
dt 2 2
1 4 λ1
t0 = ln
λ1 3 λ 2

3. (A,B,C)
Sol. No. of wave pulse encountered by the moving plane per unit time is given by
distance travelled c + V c  V   V
ν' = = =  1 +  = v 1 + 
wavelength λ λ c  c

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The stationary observer meets the frequency v of the incident wave and receives the reflects wave
of frequency v' ' emitted by the moving plane as
 V
v1 + 
v'  c  v (c + V ) c c  c −V 
v' ' = = = wavelength λ' ' = =  
V  V (c − V ) v' ' v  c + V 
1− 1 − 
c  c
 V  V 
v1 +  1+
c   2vV
Beat frequency v' '−v =  − v = v  c − 1 =
V
 V
1 −  1 −  c −V
 c  c 

4. (A,C)
Sol. If screen is perpendicular to the line joining the sources the fringes will be circular and central
fringe will be bright if S1S2 = nλ.

5. (A,C)
m 1 4 16
Sol. r∝ ⇒ rH : rHe : r0 = : : = 1: 2 : 2
q 1 1 2
Radius is smallest for H+, so it is deflected most

6. (A,B,C)
Sol. Whole charge q given to shell A will appear on its outer surface. If a Gaussian surface is drawn
within material or shell B, net charge enclosed by it should be zero. Therefore, charge on its inner
surface will be –q. Let q′ be the charge on its outer surface then charge on inner surface of C will
be –q′ and its outer surface will be 2q + q′ as total charge on outer shell must be 2q.
Since shell B is earthed, its potential should be zero.
Nucleus Education-(ENTHUSE ALL)_15102020

1
VB = 0 2q + q
1
1  q q q′ q′ 2q + q′  q′ –q
0=  − + − +
4πε 0  2 R 2 R 2 R 3R 3R  q –q
4
Solving we get q′ = − q
3
A
So choice (a) and (b) is correct.
B
Charge on outer surface of outer shell is 2q + q′ C
4q 2q
= 2q − =
3 3
So choice (c) is correct.
Choice (d) is wrong obvious from above explanation.

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7. (A,D)
900
Sol. H = rate of heat flow = …(1)
li l
+ 0
Ki A K0 A
Hli
Now, 1000 − θ = …(2)
Ki A
 
 900  l 900
or θ = 1000 −   i = 1000 −
 li + l0  K i A l K
1+ 0 i
 K i A K 0 A  K 0 li
Now, we can see that θ can be decreased by increasing thermal conductivity of outer layer ( K 0 )
and thickness of inner layer (li ) .

8. (0.80)
Sol. E L − E K = −3 − (−18.525) = 15.525 keV
hc 6.63 × 10 −34 × 3 × 10 8
λ= = = 0.8Å
15.525 keV 15.525 × 10 3 × 1.6 × 10 −19

9. (8.75)
Sol. On the horizontal, the path difference is decreasing so at the maximum distance from P where
λ
minima occurs, path difference is .
2
λ
Hence 9λ2 + x 2 − x = ⇒ x = 8.75 λ
2

10. (0.40)
Nucleus Education-(ENTHUSE ALL)_15102020

 µ  2 I 10 −7 × 2 × 30
Sol. BD=  0  = = 2 × 10 − 4 T
4
  π r 0 . 03
10 −7 × 2 × 20
BG = = 0.4 × 10 − 4 T
0.1
B = BD – BG = 2 × 10-4 – 0.4 × 10-4 = 1.6 × 10-4T
F = B I l sin 90° = 1.6 × 10-4 × 10 × 0.25 = 4 × 10-4 N

11. (7.50)
Sol. ∴ Ceq = 3/2 µF
15 3
Charge flow ∆q = Ceq (10 – ) = × 5 = 7.5 µC
3 2

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12. (1.77)
Sol. f ∝ g
g′
In water f w = 0.8 f air ∴ = (0.8) 2 = 0.64
g
ρw
or = 0.36 …(i)
ρm
g′ ρL
In liquid , = (0.6) 2 = 0.36 or = 0.64
g ρm
ρ L 0.64
From equations (i) and (ii) = ∴ SL = ρL/ρw = 1.77
ρ w 0.36
13. (A)

14. (A)

15. (C)

16. (B)

17. (C)

18. (D)
Nucleus Education-(ENTHUSE ALL)_15102020

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PART-II : MATHEMATICS
19. [A,B,D]
0 x≤0
Sol. 
f(x) = 2 0 < x < tan1

 3 x ≥ tan1
g(x) = |x + 2| – tan 1

Now, verify the options.

20. [A,B]
 1
 − tan −1 x if x < 0

Sol. Put x = tanθ ⇒ g(x) =  2
 1 tan −1 x if x ≥ 0

 2
Now verify alternatives.

21. [A,B,C,D]
 x2 
Sol. g(x) = 3ƒ   + ƒ(3 – x2)
 3 
  x2  
g'(x) = 2x  ƒ '   − ƒ '(3 − x 2 ) 
Nucleus Education-(ENTHUSE ALL)_15102020

  3  
x2 2 4x 2 3 3
Now – (3 – x ) = –3>0 ⇒x<– or x >
3 3 2 2
4x 2 3 3  x2   3 3 
–3<0 ⇒– <x< ⇒ ƒ '   – ƒ'(3 – x2) > 0 in  −3, −  ∪  , 4 
3 2 2  3   2 2 
 x2   3 3
and ƒ '   – ƒ'(3 – x2) < 0 in  − ,  as ƒ'(x) increasing ( ƒ"(x) > 0)
 3   2 2
 3  3
⇒ g'(x) < 0 in  −3, −  ∪  0, 
 2  2
3   3 
g'(x) > 0 in  , 4  ∪  − , 0 
2   2 

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22. [A,B]
Sol. For L1 : Put x = –t
8t + 4
∴ Given limit = lim( t 2 + 8t + 4 − t) = lim
t →∞ t →∞
t 2 + 8t + 4 + t
 4
t 8 + 
 t 8
= lim 1/2
= = 4 ⇒ L1 = 4
t →∞   2
 8 4
1 + + 2  + 1
 t t  
x
 x   2  x x x
& L2 = lim  x − x 2 −    = lim  −1 <   ≤
x →∞   2
 2  x →∞
x 2 2
x + x2 −  
2
x  x x
 − 1  
 2   2 2
⇒ lim 1/2
≤ lim 1/2
≤ lim
x →∞   x   x →∞   x   x →∞    x  1/2 
              
 2   2 
x 1 + 1 −  2   x 1 + 1 −  2    2 
x 1 + 1 −  2  
  x     x   x  
     
            
 
    

(i) (ii) (iii)

x x x 
 2  − 
2 2
 lim 2 = lim =0
x →∞ x x →∞ x2
1
So (i) and (iii) limits becomes
4
1
Hence by sandwich theorem original limit L2 =
4
Nucleus Education-(ENTHUSE ALL)_15102020

23. [A,B,C,D]
Sol. (A) Intermediate value theorem.
(B) Intermediate value theorem.
(C) f(x) = 1 ∀ x∈R & g(x) = 1 ∀ x∈R
⇒ f(x) = g(x) ∀ x∈R
(D) Only k = 0

24. [B, C, D]
 2  2
Sol. Let A  2t1 ,  , B  2t 2 , 
 t1   t2 
and MAB = 1 ⇒ t1t2 = –1
Equation of circle
⇒ (x2 + y2 – 8) – (t1 + t2) (x – y) = 0

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⇒ circles pass through point of intersection of x2 + y2 – 8 = 0 and line x = y point of intersection
are (2, 2), (–2, –2)
1
 eH = 2 , e =
2
lmajor axis = 4 2 = 2a
lminor axis = 4 = 2b

x=y

(2, 2)

(–2, –2)

x+y=0

(x − y) 2 (x + y) 2
Equation of ellipse + =
1
16 8
⇒ 3x2 + 3y2 – 2xy – 16 = 0

25. [A,B]
Sol. Foot of perpendicular from focus on tangents to parabola lie on tangent at vertex.

x+y=2
Nucleus Education-(ENTHUSE ALL)_15102020

(–2, 4) P
(–9, 3)
axis
S

(1,2) Q
L,R

2x + y = 4

Equation of SP = x – y + 6 = 0
Equation of SQ = x – 2y + 3 = 0
Point S = (–9, –3)

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26. [1176.00]
Sol. There are 7C5 ways of selecting the rings to be worn. If a, b, c, d are the numbers of rings on the
fingers, we need to find the number of quadruples (a, b, c, d) of non-negative integers such that
a + b + c + d = 5. The number of such quadruples is
(5+4–1)
C(4–1) = (8C3)
For each set of 5 rings, there are 5! assignments. Therefore, the total number of required
arrangements is
7
C5 × 8C3 × 5! = 141120

27. [2.00]
Sol. ƒ'(x) = 3x2 – 6x + a
B
D > 0, f'(0) > 0, – >0
2A

+
f '(x) = 0 and distinct
+
36 − 12a > 0 6
a<0 > 0 ⇒ a ∈ (0, 3)
a<3 6

g(x) = x2 – x – kx + k2 – 2k
g(0) ≤ k(k – 2) ≤ 0 k ∈ [0, 2]

g(3) ≤ 0 as 9 – 3 – 3k + k2 – 2k ≤ 0
k2 – 5k + 6 ≤ 0
k ∈ [2, 3]
k=2
Nucleus Education-(ENTHUSE ALL)_15102020

28. [1.00]
Sol. Point (1, –1) lie on the curve
Differentiable with side and put x = 1, y = –1
 dy  5
we get   =– =t
dx (1, −1) 4
∴ [| t |] = 1. Ans.

29. [10.00]
Sol. f(2) ≤ f(2–) ⇒ 1 ≤ a2 – 9a – 9
⇒ a2 – 9a – 10 ≥ 0 ⇒ (a – 10) (a + 1) ≥ 0
⇒a∈ (– ∞, – 1] ∪ [10, ∞)
But a is positive. hence, a ∈ [10, ∞).

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30. [25.00]
 n(n + 1) + 1 π  (n + 1) − n 
Sol. tan–1 (n2 + n + 1) = tan–1   = – tan–1 
 (n + 1) − n  2  1 + n(n + 1) 
π
= – ( tan −1 (n + 1) − tan −1 n )
2
100
π
∴ ∑ tan −1 (n 2 + n + 1) = 100 – (tan–1 101 – tan–1 1)
n =1 2
π 201π
= 50π + – tan–1 101 = –tan–1 (101)
4 4
 a − c  201 − 101
∴  = = 25. Ans.
b  4
31. [C]
32. [B]
33. [D]
Sol. (I)  a2 + b2 + c2 – ab – bc – ca ≤ 0
⇒ (a – b)2 + (b – c)2 + (c – a)2 ≤ 0 ⇒ a = b = c
∴ f(x) = ax2 + ax + a
∴D<0
∴ no real root
∴ | f ( | x | ) | is always derivable except one point
∴ (I) (i)(Q)

(II) a2 + b2 + c2 + ab + bc + ca ≤ 0
⇒ (a + b)2 + (b + c)2 + (c + a)2 ≤ 0 ⇒ a + b = 0, b + c = 0, c + a = 0
∴a=b=c=0
∴ f(x) = ax2 + bx + c is an identity
∴ f(x) = 0 has infinite roots
∴ f(x) is always derivable.
∴ (ΙΙ) (iv) (P)
Nucleus Education-(ENTHUSE ALL)_15102020

(III) (a – 1)2 + (b – 1)2 + (c – 1)2 + (a – b)2 + (b – c)2 + (c – a)2 ≤ 0


∴a=b=c=1
∴ f(x) = 0 has no real root and | f ( | x | ) | is
non - derivable at exactly one point.
∴ (III) (i) (Q)

(IV)  (a – 1)2 + (b – 3)2 + (c – 2)2 ≤ 0


⇒ a = 1, b = 3, c = 2
∴ f(x) = x2 + 3x + 2
∴ f(x) = 0 has two distinct real roots
and y = | f ( | x | ) | is non-derivable at exactly one point.
∴ (IV) (iii) (Q).

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34. [A]

35. [C]

36. [B]
Sol. (I) 2y2 = 2x – 1 and 2x2 = 2y –1

 1 1
Equation of tangents are y= m  x −  +
 2  4m
2
1 m
and y − = mx − respectively
2 4
m 1 1 m2
So, − + = − ; m2 – 2m2 – 2m + 1 = 0
2 4m 2 4
This equation has 3 real and distinct roots i.e., 3 common tangents
For common normals they are symmetric about y = x
So, only one common normal
2 4 x 2 y3
(II) After shifting at origin, we get y = x and + = 1
3 9 3
2 1 3 m(a 2 − b 2 )
Equation of normals are y = mx − m− m and= y mx ±
3 3 a 2 + b2 m2
2 1 3 6m
So, m+ m = ; m = 0, ±1. Hence, 3 common normals
3 3 9 + 3m 2
m2
(III) y = x2 and y = –(x – 1)2 equation of tangents are y = mx –
4
2
m
and y = m(x – 1) + respectively
4
Nucleus Education-(ENTHUSE ALL)_15102020

So, we get m = 0, 2; 2 common tangents


1 1 1 1
Common normals : equation are y = mx + + 2
and y = mx – m – 2

2 4m 4m 2
3 2
So, we get 2m + 2m + 1 = 0 only one real root is 1 common normals
(IV) y2 = –4x and x2 = –4y
Number of common tangents will be same
For y2 = 4x and x2 = 4y only one common tangents
1
Common normals : 2m + m3 = –2 – 2
m
f(m) = m5 + 2m3 + 2m2 + 1 only one root negative
So, only one common normals.

C.O.: NAIVEDHYAM, Plot No. SP-11, Old INOX, Indira Vihar, Kota (Raj.) 324005 Ph. 0744-2799900 www.nucleuseducation.in 24
JEE-ADVANCED
PART-III : CHEMISTRY
37. (B,C,D)

Sol. (NH4)2 Cr2O7 Cr2O3 + N2 + H2O

K2Cr2O7 Cr2O3 + O2 + K2CrO4

KMnO4 Mn2O2 + O2 + K2MnO4

KNO3 KNO3 + O2
38. (A,B,C,D)
39. (B,D)
40. (B,C,D)
Sol. ZnS, CuS, PbS are soluble in hot & dil. HNO3
41. (B,C,D)
42. (C)
43. (B,C,D)
Sol. KNO3 → X
Pb(NO3)2 → PbO + NO2 ↑ + O2 ↑
Cu(NO3)2 → CuO + NO2 ↑ + O2 ↑
2AgNO3 → 2 Ag + 2 NO2 ↑ + O2 ↑
44. (5.00)
Sol. Alkali metals & Alkaline earth metals (except Be & Mg) can be identified by flame test.
45. (248.00)
Nucleus Education-(ENTHUSE ALL)_15102020

Sol. Let initially O14 & O15 have no nuclei.


Then after times t
ln 2
– ×t
62
N O14 = No e …(1)
ln 2
– ×t
124
N O15 = No e …(2)
ln 2
– ×t
N O14 e 62
 = 0.25 = ln 2
N O15 –
124
×t
e
 ln 2 ln 2 
1 –t – 
∴ = e  64 124 
4

C.O.: NAIVEDHYAM, Plot No. SP-11, Old INOX, Indira Vihar, Kota (Raj.) 324005 Ph. 0744-2799900 www.nucleuseducation.in 25
JEE-ADVANCED
 ln 2 
1 –t 
= e 124 
4
ln 2
∴ ln4 = t
124
∴ t = 2 × 124 = 248 sec.

46. (5.00)
Sol. All the given compounds gives CO2 except K2CO3. It is thermally stable CO2 turns lime water
milky.
47. (6.00)
48. (1.00)
Sol. Class A, subgroup-I radicals give test with dilute Acid
NO −2 + dil HCl → NO2 ↑ (Brown gas)

49. (D)
50. (C)
51. (D)
52. (A)
53. (C)
54. (D)
Nucleus Education-(ENTHUSE ALL)_15102020

C.O.: NAIVEDHYAM, Plot No. SP-11, Old INOX, Indira Vihar, Kota (Raj.) 324005 Ph. 0744-2799900 www.nucleuseducation.in 26
QUESTION PAPER FORMAT AND MARKING SCHEME
19. The question paper has three parts: Physics, Mathematics and Chemistry.
20. Each part has three sections as detailed in the following table:

NAME OF THE CANDIDATE :_____________________________________________

ROLL NO. :_______________________

I have read all the instructions I have verified the identity, name and roll number

and shall abide by them of the candidate.

_______________________ ____________________________
Signature of the Candidate Signature of the invigilator

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