DPP - Daily Practice Problems

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Start Time : End Time :

SYLLABUS :
CHEMISTRY ( 11
Thermodynamics-2 (Laws ofThermochemistry, Entropy, Spontaneous Process) ]
Max. Marks : 120 Time : 60 min.
GENERAL INSTRUCTIONS
•
The Daily Practice Problem Sheet contains 30 MCQ's. For each question only one option is correct. Darken the correct drcle/
bubble in the Response Grid provided on each page.
•
You have to evaluate your Response Grids yourself with the help of solution booklet.
Each correct answer will get you 4 marks and 1 mark shall be deduced for each incorrect answer. No mark will be given/ deducted
if no bubble is filled. Keep a timer in front of you and stop immediately at the end of 60 min.
•

• The sheet follows a particular syllabus. Do not attempt the sheet before you have completed your preparation for that syllabus.
Refer syllabus sheet in the starting of the book for the syllabus of all the DPP sheets.
• After completing the sheet check your answers with the solution booklet and complete the Result Grid. Finally spend time to
analyse your performance and revise the areas which emerge out as weak in your evaluation.

DIRECTIONS (Q.l-Q.21) : There are 21 multiple choice Q.3 Calculate the standard free energy change for the reaction
questions. Each question has 4 choices (a), (b), (c) and (d), N2 (g) + 3H2 (g) � 2NH3 at 298K
out of which ONLY ONE choice is correct. Given L".H0 =- 92.4 kJ and t.S0 = -198.3 JK- 1
(a) - 23.106 kJ (b) - 43.506 kJ
Q.l Calculate the enthalpy change (t.H) for the following (c) - 33.306 kJ (d) - 13.306 kJ
reaction Q.4 Calculate the entropy change in melting l mole of ice at
2C2H2 (g)+ 502(g) � 4C02(g) + 2Hp (g) 273K, Mlr0 = 6.025 kJ/mole-
Given average bond energies of various bonds (a) 11.2 JK-1 moJ-1 (b) 22.1 JK-1 mol-l
i.e. C-H, C""C ,O=O,C=O, O - Has 414, 810, 499, 724and (c) 15.1 JK- 1 mol- l (d) 5.1 JK- 1 mol- l
460 kJ/mok respectively Q.S Determine the standard free energy change for the
(a) - 1861 kJ (b) - 1 361 kJ following reaction at 298 K
(c) - 1261 kJ (d) - 1 161 kJ N2 (g) + 3Hlg) � 2NH3(g)
Q.2 The gaseous endothermic reaction : P + Q � 3R Given L".G0r for Nig) , H2(g) and NH3(g) are 0, 0 and
at 327°C takes place spontaneously, because- - 16.66 kJ mol-l
(a) t.H < 0; t.S < 0 (b) t.H > 0; t..S > 0 (a) - 1 l.22kJ (b) -22.22kJ
(c) t.H<O;t.S>O (d) t.H>O;t..S < O (c) -33.32kJ (d) -44.44 kJ
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42 t---- DPP/ C (1 1 ) w
Q.6 Calculate the standard enthalpy change for a reaction Q.U One mole of an ideal diatomic gas (C" = 5 cal) was
C02(g) + Hlg) ---+ CO(g) + H20 (g) transformed from initial 25°C and 1 L to the state when
given that Lllif for C02(g), CO(g) and H20(g) as-393.5, ­ temperature is I oooc and volume l OL. Then for this process
(R = 2 cal.ories/moi/K) (take calories as unit ofenergy and
II 0.5 and-24 1 . 8 kJ/mol respectively.
kelvin for temp.). Which ofthe following is incorrect?
(a) -31.2kJ (b)-2 1 .2 kJ (c) -11.2kJ (d) +41.2kJ
(a) t.H= 525
Q.7 Determine the enthalpy change for the react ion 373
CH4(g) + Cl2(g) ---+ CH3CI(g) + HCI (g) (b) t.S = 5 ln + 2 ln 10
298
Bond energies for C-H, C - CI, CI- CI, H-CI are412, 338, (c) Lili= 525
242,431 kJ/mol. respective! y. (d) t.G of the process cannot be calculated using given
(a) -215 kJ/mol information
(b) -1 1 5 kJ/ mol
(c) -130 kJ/mol (d) -145 kJ/mol Q.12 C(graphite) + 02(g) ---+ C02(g);MI = -94.05 kcal mol-1
Q.8 Calculate the beat change in the reaction C(diamond) + 02 (g) ---+ C02 (g); Llli = -94.50 kc al mol- 1
4NH3 (g) + 302 (g) ---+ 2Nig) + 6Hp(C) therefore,
at 298 K, given that the heats offormation at 298 K for NH3 (a) C(graph.ite) ---+ C(diamond); t,H;98K = -450 cal mol - l
(g) and H20 (e) are - 46.0 and-286.0 kJ mol-l respectively. (b) C(diamond) ---+ C(graphite); Llli298K = +450 cal mol-1
(a) - 1 861 kJ (b)-1361 kJ (c)-1261 kJ (d) -1532kJ
•

(c) Graphite is the stable allotrope

Q.9 The heat of hydration of solutions of anhydrous CuS04 (d) Diamond is harder than graphite
and hydrated CuS04. 5H20 are - 66.5 and I I . 7 kJ mol-1 Q.13 Consider the reactions
respectively Calculate the heat of hydration of CuS04 to C(s)+ 2H2(g) ---+ CH4(g),�H = -x kcal
CuS04. 5H20.
C(g) +4H(g) -+ CH4(g),�H =-x1 kcal
(a) -78.2kJ (b)-8 1 . 2 kJ (c)-68.2kJ (d)-60.1kJ
CH4 (g) ---+ CH3(g) + H(g),�H = +y kcal
Q.10 Calculate the entropy change (t.S) per mole for the following
The bond energy of C - H bond is
reactions:
(a) y kcal mol- l (b) x1 kcal mol- l
(i) Combustion ofhydrogen in a fhel cell at 298 K (c) x /4 kcal mol 1- (d) x1 /4 kcal mol- 1
H2(g) + Y2 02(g) ---+ H20 (g) Q.14 Iffor a given substance, melting point is T8 and freezing
t.H = -241.6 kJ, t.G = - 228.4 kJ point is TA• then correct variation shown by graph
(ii) Vaporisation ofmethanol at its normal boiling point. between entropy change and temperature is

(iii)
CH,OH (e) ---+ CH,OH (g)
LlHv,'P = 23.9 kJ, boiling point = 338 K
Fusion ofice at its normal melting point,
lee ---+ Water
(a) Ilk
S fl�
S
TB

TA
(b)
T,

TA

mfusion = 6.025 kJ, melting point = 0°C T --+ T --+

Jl J I K
(a) -44.3 JK-1, ?O JK-1 , 22 JK-1
(o) T.
(b) -24.3 JK-1, 60 JK-1 , 1 1 JK-1

�
(d)
(c) - l 4.3 JK-1, 50JK-1 , 3 2 JK-1
1 1
(d) -54.3JK- ,40JK- 1 , 2 ! JK-
T-

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DPP/ C ( 1 1 ) ------� 43
Q.15 When a solid melts reversibly Q.20 The H20(g) molecule dissociates as
(a) H decreases (b) G increases
(i) Hp(g) H(g) + OH(g);6H = 490 k.T
�
(c) E decreases (d) S increases
Q.16 The enthalpies of formation of A1203 and Cr203 are (ii) OH(g) � H(g) + O(g); Ml = 424 kJ
-1596 kJ and -1134 kJ respectively, �H for the reaction The average bond energy (in kJ) for water is
(a) 490 (b) 424 (c) 914 (d) 914/2
2Al + Cr203 � 2Cr + Al203 is
Q.21 Following reaction occurring in an automobile
(a) -2730 kJ (b) ---462 kJ �
2C8H18(g) + 2502(g) 16C02(g)+ 18H20(g). The sign of
(c) -1365kJ (d) +2730kJ
Ml, �s and 60 would be
Q.17 "The quantity ofheat which must be supplied to decompose
a compound into its element is equal to the heat evolved (a) +, -, + (b) -, +, - (c) -, +, + (d) +, +, -
during the fonnation of that compound from the elements." DIRECTIONS (Q.22-Q.24) : In the following questions,
This statement is known as more than one of the answers given are correct. Select the
(a) Hess's law correct answers and mark it according to the following
(b) Joule's law codes:
(c) Le-chatelier 's principle Codes :
(d) Lavoisier and Laplace law (a) 1 , 2 and 3 are correct (b) 1 and 2 are correct
Q.18For the reaction (c) 2 and 4 are correct (d) 1 and 3 are correct
Q.22 In which of the following entropy increases ?
H2(g) +.!_02(g
2
) � H20(1), Ml = -285.8 kJ mol -1 ( 1 ) Rusting of iron
(2) Melting of ice
6S = -0.163 kJ mol- IK-1 . (3) Vaporization of camphor
What is the value of free energy change at 27°C for the (4) Crystallization of sucrose from solution
reaction ?
(a) -236.9 kJ mol- l (b) -281.4 kJ mol-l Q.23 For a reaction tili = 9.08kJ mol-1 and �S = 35.7 JK-1 mol- l
(c) -334.7 kJ mol-l (d) +334.7 kJ mol-l which of the following statements is incorrect for the
reaction?
Q.19The direct conversion of A to B is difficult, hence it is
(I) Reversible and isothermal
carried oul by the following shown path :
C D (2) Reversible and exothermic
(3) Spontaneous and exothermic
t +
A B (4) Spontaneous and endothermic
Given Q.24 Which of the following are correct statements ?
6S(A->C) =SO e.u. , 6S(C- >D) = 30 e.u., �Sea�D) = 20 e.u. , (1) When �G is negative, the process is spontaneous
(2) When �G is zero, the process is in a state ofequilibrium
where e.u. is the entropy unit, then 6S(A�B) is (3) When �G is positive. the process is non-spontaneous
(a) +60e.u (b) +lOO e.u (c) -60e.u. (d) -lOO e.u. (4) When �G is positive, the process is spontaneous

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44 t---- DPP/ C (1 1 ) w
DIRECTIONS (Q.25-Q.27) : Read the passage given below and Q.27 Internal energy change at 25°C is LlE 1 while at 35°C it is Ll�
answer the questions that follows : then -
(a) L'lE1 = L'lE2 (b) L'l� > L'lE1
(c) L'..E 1 > L'..E2
J. W. Gibbs and H.Von Helmholtz: had given two equations which
are known as Gibbs-Helmholtz equation. One equation can be (d) None of these
expressed in terms of change in free energy (LlG) and enthalpy DIRECIIONS (Q. 28-Q.30) : Each ofthese questions contains two
(M-1) while other can be expressed in terms ofchange in internal statements: Statement-! (Assertion)andStatement-2(Reason). Each
energy (L'..E) and work function (L\.W)
ofthese questions has four alternative choices, only one ofwhich is
LlG = LlH + T . d (��)P ............. (!)
the correct answer. You have to select the correct choice.
(a) Statement-! is True, Statement-2 is True; Statement-2 is a

= L'lE+ T . ct( �)
Ll correct explanation for Statement-!.
LlW ............. (2) (b) Statement-! isTrue, Statement-2 is True; Statement-2 is NOT
d v
a correct explanation for Statement-!.
Where T is temperature

,
(c) Statement - 1 is False, Statement-2 is True.
Equation ( I ) is obtained at constant pressure while equation (2) is
obtained at constant volume. I t is observed that for the reaction (d) Statement - I is True Statement-2 is False.
N2(g) + 3Hig) 2NH3(g) Q.28 Statement 1 : Entropy ofice is less than water.
Free energy change at 25°C is -33 kJ while at 35°C it is -28 kJ Statement 2 : Ice has cage like structure.
which are at a constant pressure. Q.29 Statement 1 : There is no reaction known for which LlG is
Q.25 What would be the difference between enthalpy change at positive, yet it is spontaneous.
25°C and 35°C for a given reaction ? Statement 2 : For photochemical reactions LlG is positive.
(a) 4 kJ (b) 5 kJ (c) 3 kJ (d) zero Q.30 Statement 1 : Enthalpy and entropy of any elementary
Q.26 What would be the free energy change at 30°C ? substance in the standard state are taken as zero.
(a) 30.5 kJ (b) 33 kJ Statement 2 : Even at zero degree absolute, the constituent
� �8 � � �0.5 kJ particles are not complete!y motionless.

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DAILY P RACTICE PROBLEM SH E ET 11 - CHEMISTRY

Tota l Questions 30 Tota l Marks 120
Attempted Correct
Incorrect Net Score
Cut-off Score 32 Qual ifying Score 52
Success Gap = Net Score - Qual ifying Score
N et Score = (Correct x 4} - (Incorrect x 1}

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DPP/ C ( ll ) ------� 25

(11)
DAILY PRACTICE CHEMISTRY
PROBLEMS SOLUT IONS
(1) (a) 2 [H - C = C -H]+ 5 (0 = 0) (9) (a) The required equation is :
= = + 2(
� 4 (0 c 0) H - 0 -H) +
CuSOis) 5�0 (f) � CuS04.5�0(s) =? �H
The reaction involves the breaking of4 C- H bonds, Gi e +
v n that
2CC C bonds, 5 = o s and formation of
= 0 0 b nd CuSOis) (aq.) � C S04. (aq) ; u =- 66.5 kJ �H1
8 = 0 bonds and 4 0 - H bonds. CuS04 . 5�0(s) aq. �euso4.(aq) ; � = + 1 1.7 kJ
+
�H =[Total energy required to break bonds] The process of hydration may be expressed as
6H, CuS04(aq)
= [4�Hc--[Energy given out�inHforming the bonds]
�CHC= C=+O + �oHo=7o + 60
+ 2 �H 5 ]
u
C S04 (s)

4
H
- [8 HJ
t.H2
= (4 X 414+2 X 8 1 0 + 5 X 499)-(8 X 24 4 X 4
-
CuS04. 5�0(s)
) According Hess's law
to
=5771-7632=-1861
�G=�H-T�S kJ �H1 =�H+��
(2) (b)
For an endothermic reaction �H = ve
+
�H �� �
= - �
=- 66.5- 1 1.7 =- 78.2 kJ
[less molecules � more molecules], (10) (a) (i) According to th eact o
er i n
�S =+ve
:. T S > H, and G =- ve
� � � �G=�H-T�Sof�S=
� - �G
T
Hence, the reaction occurs spontaneously. Given that �G=-228.4kJ, �=- 241.6kJ
and T 298 K
(3) {c) �G"= �H0- T�S0
=-92. 4-298 X (-198.3) X w-3 =-33.306kJ.
=
Substituting the values, we get
22 1
-
�Sr= �HrT = 273K l 1 = . (-241 .6kJ)- (-228.41<1 )
6025 1 mo
(4) (b) JK-I mol-l
�S= 298K
(5) (c) �G"=2x �Go NH3 -�G" N -(�G0 H x3) 2 2 =-0.0443 kJK -1 =-44.3JK- I
=2X (ii) Vaporisation
(6) (d) =
(-J6.66)-0-0=-33.32kJ
�H" L.�Hf" - L.� Hr"
(products) (reactants) between the liquidstandate, the�Ga state
represents

substance. At this
o state of
vapour
0 so =
f equilibrium
the

= [�H�(H20) + �?-(CO)]-[�H�(C02) + �H�(H2) ] �=T �So �S r =

�H
�H0 =[-24 1.8- 1 10.5] - [-393.5+0] -

T
=-352.3+ 393.5 =+41.2kJ Here�H=23.9 kJ. T=338 K
H

(7) (b) H - -
I
C C H + l - Cl � H -C-
H
I
CI+H-CI :. �s = 23.9KkJ = .010kJK-1 = JK-1
3 38
o 10

I I (ii ) Fusi
H H ice on represent
andwater. Atsthisa statestate,ofequi
�G l=ib0risoum between

(L. - (L. B.E.)products

�S= ­
�H = B.E.) reactants

= (4(B .E.)e-H+ l(B.E.)ci-CI- {3(B.E.)e-H � = T�S or

�H
T
+ I (B.E. )C - CI + l (B.E.)H- CI }] Here �H =
=41 2 + 242 -33 8 - 43 1 =-115 kJ/ mol
6.025 kJ and T= 273 K
(8) (d) �H" for the reaction
4NHig) + g) 30i �- 6�0 (e) + 2N2(g)
�s 6·273K
=
025k1 kJK-1 JK-1
= 0. 0220 = 22

(d) �S nCv n ( r ) ( Vr )
�H" = �H0r (products) - �H"r (reactants)
+ nR 1n
T 373
(11)
T:I vI
1 51n + 2 lnl0
{6Wr �O(e) ]+ 2�H0f[N2(g)]}
=
= =

298
- {4�H [NH3 (g)] + 3� 02(g)] } 1 R�
= 0�H moi-1 [
�H"r[�O(e)] - 2 86. kJ
For mol, CP-Cv= CP =2+ 5= 7Cal
�H= � = x 7 x 75 =525 1
f N
] nC T
(g)] = 0 and
�H" [ Hconvention) " r[N2 (g) P
= 0 (by
3 �E =nCv�T= x 5 x 75 =375I
(0)} -
�H" = 6(-286) + 2 {4 ( + 3 (0)}
{ -46.0) But �G= �H-T�S
=- 1716+ 184=- 15 32 kJ So, we cannot calculate �G from the given data.
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26 DPP/ C (ll)
(12) (c) Hea( energy is also involved when one
oftheanstableleement is converted into alloGraphi
another. tropic ftoermis
r allotrope because ofheat oftransformation (25)
�G I =�H I
(d) d (��l
+II

of C (diamond) --7 C(graphite)·

�G2 = � T2 d ( ��l +
(i) C(dia) + 02 C 0 (g
(g) = 2 ), �H = kcal -94.5

(ii) c(graphite) + 02(g) = co2(g)• � = -94.0 kca l �G2 -�Gl =(�� -�Hl)+(T2 -Tl ) (��)P
�transfonnation = -94. 5 - (-94.0) = -0.5 kcal. (� -��)=(�G2-�Gl)-(T l -T2) [ �G2T2 -�G
-TI 1 ] =0
(13) (a) The bond energy of C -H bond will be the energy
CH4 (g) CH3 (g)+H(g), �H =+ y kcal mo -1 ( �G ) [�G2 - �G1 ]
required to break one C - H in CH4 i.e.
--7 l
(d) �S--d dT -- p
_ _

(26)
T2 - T1
[ -28308-298
- (-33) ]
(14) (a) For a pure substance TA and T represent the same
B
temperature. Hence (a) is a correct choice.
(15) (d) When a solid mel ts, it changes in to liquid and hence, =- =-0.5kJ/K
entropy (s) increases.
(16) (b) --7
2AI �2 2 Al203, -1596 . ..(i)
+ 0 m = k:J �G 1 =�H1 +T 1 d (��)P
-33 = �1
2 r+ - - �H -1 134 kJ
+298 x0.5
. . .(ti)
C
3
0? --7 Cr?03 , �H 1 =-33- 149=-182 kJ/mole
(
=

2 -
By(i)-(ii) Now�G=�+T. d ��l
+ --7
2AI Cr203 2Cr + �H -462 kJ. Al203, =

(17) (d) It is Lavoisier and Laplace law. This is another law of

�G =-182 + 303 0.5 =-30.5 kJ X

thermochemi stry whi c h was put forward before Hess' s This is average of�Gat 25°C and 35°C
�H1 =�E1 �n�T +

�G = �H- T� , T 2 3 300 K
law. (27) (c)

(18) (a) S = 27 + 7 =
�.� = �E + �n�T2 2
�� -�H 1 = 0 (as calculated in Ans. 25)
�G = (-285.8) -(300)(-D.l63)=-236.9 kJmol - 1 So, M.J2 =�H1
(19) +
(a) �S(A-+B) �S(A-+C) �S (C-+D) - �S(B-+D)
=
So, �£ 1 + M� T1 = �E2+ �n�T2
=50+ 30-20 = 60 e.u.
(�E1 -�E2) = �n�(T2 -T1 )
eq.
(20) (d) (i) eq. (ii) find the required result and divide by 2.
+
But�E1 -�2>0
(21) (b) For combustion reaction. �His negative, So, �E1 > �2
(b) Entropy of ice is less than water because water
(28)
+
�nis spontaneous,
= (16 18) -(25 +7,
hence+ 2)�G= is -ve.so�S is +ve. Reaction molecules in solid state lose kinetic ernergy and hence
their tendency ofmovement minimises. Hence entropy
(22) (a) On crystallization, randomness of the system decreases in solid state. The statement that ice has
decreases and hence, entropy increases. cage likeexplstructure is alasserti
so correct but reason is not
(23) (a) � n
= +ve a d �S = +ve (given) correct anatio n for on.
:. Process will be spontaneous ifT is high. (c) Photochemical reactions may have +ve �G
(29)
Also, as �H =+ve, thus, it is endothermic process. (30)
an
Enthalpy
(c) is zero but entropy is not zero. Vibrational
motion exists even at absolute ero.z
(24) (a)