Project Report
Project Report
RELATIONSHIP
Stress
● One of the most basic test is Tension test in which specimen is subjected to an axial
load P and its deflection δ is noted.
● Stress - Depends on axial force and Cross sectional area of the specimen.
● σ =P/ A
Where σ is the engineering stress and A is the initial area.
● We did this to make it independent of the Cross Sectional Area.
Strain
● Hooke’s Law:
P=kδ
Where k is the stiffness of the material.
● ε =δ / L
Where ε is the engineering strain and L is the initial length.
● We did this to make it independent of the length of the specimen..
● So by Hooke’s Law, we get:
σ =Eε
Where E is the Young’s Modulus.
E=kL/ A
Poisson Effect
● A positive Strain in one direction will induce a negative Strain in other
directions.
● So the Poisson’s ratio is defined as :
Poisson’s Ratio,
⋎ =−ε lateral /ε longitudanal
True Stress
● Although we see that the engineering stress achieves a maximum but in
case of true stress it keeps on increasing as engineering stress is
Load/Initial Area while true stress is Load/Actual Area.
● The Area which we assumed to be constant for smaller loads becomes
significantly smaller which can not be ignored. So while we decrease the
load only engineering stress decreases while true stress keeps on
increasing thus increasing the value of strain.
● Due to some defects in the specimen the true stress have higher value at
some places on body than the other which causes the decreasing area of
that part more vigorously than the other part causing Necking.
Enthalpic Response
● Assuming, the changes we brought doesn’t contribute to the entropic
changes, we get
dU =dW =fdx
● We know that there are two types of forces at intramolecular level :
attractive and repulsive. So
2
U attractive =−AC e /r
and
n
U repulsive =B /r
● We can get value of ro, bond length by solving dU /dr=0
● On further simplification we get the value of Elastic Modulus varies as 1/ro4.
● On addition of heat the system oscillates increasing the average
separation, to some approximation the relative thermal expansion is
linearly related to △T.
Entropic Response
● There are a lot of conformational structure possibles for a molecule such
that the internal energy of all the conformers is same. So, more the no. of
conformers more will be the Entropy.
● dW =−TdS or Δ W V =△ S V
● We use “random walk” Gaussian distribution function which helps us to
tells us the probability that the other end of the chain is at a distance r as
Ω(r)=¿
Where
β=√ ❑
Where n is the number of bonds in the segment and a is the bond length.
● Let Ω1 be the probability function at the initial stage and Ω2 be the probability function
at the final stage and λX, λY and λZ be the stretches in the corresponding direction then
2 2 2
△ S=k ln (Ω2 /Ω1)=−k ( λ X + λY + λ Z −3)/2
So, we get
2 2 2
W V =NkT ( λ X + λY + λ Z −3)/2
● Now for ΔV=0 we get
❑ ❑ ❑
λ X λ Y λ Z =1
❑ ❑ ❑ ❑
So taking λ X = λ❑we get λ Y =λ Z =1/ √ ❑
And
❑ ❑2
F=dW / dL= A 0 NkT (2 λ❑ −2/ λ❑ )/ 2
❑
Or
2❑
σ =NkT ( λ−1 /λ ❑ )
Hooke’s Law
Co - Bar Velocity
INITIAL CONDITIONS
Prescribed displacement u(x , 0)=h(x )
Zero velocity - =0
This gives
Also
[ ] represents discontinuities
The above equation is or wavefront propagating in the positive x direction.
An arbitrary stress wave distribution f (x−C t )emanating from x=0 has following general
solution
If the stress pulse is reflected from free end, then the solution will be
So finally,
Axial Stress
If we split the cylinder along the
length there is force along its walls .
r 2
ρπ D
F=∫ 2 ρπrdr =
0 4
A=πDt
(Area approx rectangle , thickness t )
F ρD
(Axial stress ) σ b= =
A 4t
Buckling
A process by which structure cannot withstand loads with original shape,
so it changes shape in order to find new equilibrium .
VISCOELASTICITY
Some materials exhibit a combination of enthalpic and entropic mechanical
response.This kind of behaviour is called viscoelasticity.As not all polymers are
viscoelastic to any practical extent,the linear theory provides a suitable approximation
for many applications in polymer and composites engineering.
Rate of Conformational Change
● When stress is applied to polymers may deform by both entropic and enthalpic
response
● The lengths and angles may deform to higher internal energy very quickly
● Depending on the mobility, a polymer molecule can extend itself in the direction
of the applied stress, which decreases its entropy.
● The conformational are processes whose rates are sensitive to the local
molecular mobility.
In the range near Tg, the material is midway between the glassy and rubbery regimes.
Its response is a combination of viscous fluidity and elastic solidity.
Consider the strain at time t due to the application of a small stress ∆σ1 applied at a time
ξ previous to t .