Question

Answer Notes Marks

number
1 (a) (i) M1 & M2 – any two from: 2
 does not melt/high melting point Ignore general physical properties of
 does not colour the flame metals, eg boiling point
 inert/unreactive / does not burn/react with
oxygen/air

(ii) to remove any substance that may affect the colour ignore references to removing 1
impurities
Allow result/flame for colour

(iii) difficult to see the colour produced by the substance Accept flame not hot enough (to 1
(under test) vaporise the sample)
Accept the temperature is not high
enough (to vaporise the sample)
Allow flame is (already) coloured

(b) (i) (X)

M1 – sodium Accept symbol in any formula 1
M2 – chloride 1

(Y)
M3 – lithium accept Li symbol and SO4 in any 1
M4 – sulfate formula 1

accept strontium for M3

(ii) iron(II) / Fe2+ / Fe+2 / Fe++ accept ferrous 1

ignore iron ion
if both name and formula given both
must be correct
(c) M1 – add (dilute) acid 1

M2 – test gas/bubbles/carbon dioxide with limewater If incorrect gas mentioned, only M1 1

can be awarded

M3 – limewater turns milky M3 DEP on mention of gas 1

 Question
Answer Accept Reject Marks
number
2 (a) magnesium chloride/MgCl2 1

oxygen/O2 carbon dioxide/CO2 1

sulfuric (acid)/H2SO4 1
IGNORE hydrogen sulfate

If name and formula given, both must be

correct

(b) Mg + H2O  MgO + H2 1

IGNORE state symbols even if incorrect

Penalise incorrect symbols and failure to

use subscripts

(Total marks for Question 2 = 4 marks)

 Question
Answer Accept Reject Marks
number
3 (a) (i) Impurities/chemicals/substances may affect the 1
colour/flame
IGNORE affect the result/test
(ii) a luminous flame may mask 1
colour can (easily) be seen (in a non-luminous the colour
flame)
IGNORE references to temperature
(iii) any combination of the 1
acceptable colours, e.g.
yellow/orange/gold(en) golden-yellow
(b) (i) Li+ and Ca2+ lithium and calcium/Li and Ca+ etc 1
Ca

(ii) M1 − ammonia/NH3 1

M2 – (water is needed) to form hydroxide 1

ions/OH— to form an alkali/an alkaline
solution/ammonium
hydroxide
to dissolve the ammonia any other
1
(iii) M1 – iron(III)/Fe 3+ ammonia needs to be oxidation
aqueous states/ferrous

ferric ammonia 1
M2 – ammonium/NH4+

If both names and formulae given both must be

correct

Total 8
Question
Answer Notes Marks
number
4 (a) (i
(i) ) hydroxide Accept ferrous in place of 1
sodium sulfate iron(II) 1
Accept in either order
Ignore formulae even if wrong
Max 1 if extra product added
Ignore oxidation state of
sulfate
(ii) green precipitate Ignore qualifiers such as pale 1
/ dark / dirty
Accept solid / suspension /
ppt(e) in place of precipitate
Ignore grey
Reject all other colours
Reject bubbles or equivalent
Ignore refs to turning brown
Ignore refs to reaction type
(eg displacement / oxidation)
Ignore refs to solution turning
colourless / clear
Ignore refs to reactants
Do not penalise wrong
identity or formula of
precipitate
4 (b) (i) ba ium sulfate / BaSO4 1

(ii) (dilute) hydrochloric acid / HCl Accept other suitable acids 1

(name or formula) such as
HNO3 / CH3COOH
Ignore hydrogen chloride
Reject sulfuric acid
Reject ‘acid’ alone
Reject extra incorrect
reagents
fizzing / bubbles / effervescence Allow gas 1
Ignore carbon dioxide
Ignore gas tests
Ignore wrongly named gas
Reject wrong observation (eg
precipitate)
M2 dep on M1 given
Allow M2 if sulfuric acid or
just ‘acid’ given in M1
4 (c) M1 ad sodium hydroxide (solution) Accept any named Group 1 or 1
(and warm) Group 2 hydroxide
Addition of any other incorrect
reagent means 0/3
If no reagent added, max 1
for correct test and result
M2 test (gas/ammonia) with (damp Accept use of universal 1
red) litmus (paper) indicator paper
Reject blue litmus for M2 and
OR M3
Ignore ‘ammonium’
test with hydrogen chloride / conc.
hydrochloric acid Accept HCl
Reject dilute hydrochloric acid
M3 turns blue Do not award M3 if clear 1
statement that litmus is
OR dipped into solution

white smoke / solid / powder

Accept white fumes

Total 9 marks
Question
Answer Notes Marks
number
5 a burns with a pop/squeak Must be reference to test and result 1
OR Reference to splint/match with no indication of flame
use burning/lit splint/flame to see if pop/squeak is not enough
Ignore flame extinguished
Reject reference to glowing splint

Squeaky pop test on its own is not enough

b i anhydrous/white copper sulfate Ignore colourless 2

Accept correct formula
Incorrect formula (eg CuSO) counts as near miss
turns blue
OR
anhydrous/blue cobalt chloride Accept correct formula
Incorrect formula (eg CoCl) counts as near miss
turns pink

M2 DEP on M1 or near miss

ii measure boiling point / freezing point Accept boil it / freeze it 2

Ignore heat

100 (°C) / O (°C) Value must match property

Ignore units

Answers such as boils/distils at 100 °C

/ freezes at 0 °C score M2 only
Question
Answer Notes Marks
number
5 b iii cross by 2
carbon dioxide from the air reacts to cause the
cloudiness
cross by
the cloudiness is caused by the formation of a
white precipitate
If 3 boxes crossed then max 1
If 4 or more boxes crossed then 0

Total 7 marks
 Question
Answer Notes Marks
number
6 a i M1 bubbles / fizzing / effervescence Accept gas formed /given off 1
Ignore any name or formula
M2 iron/solid disappears Accept iron/solid gets smaller / 1
OR dissolves
green/colourless solution (forms)
Ignore references to heat change /
change in pH
ii iron sulfate AND hydrogen (in either order) Penalise oxidation states other than (II) 1
Accept ferrous sulfate
Reject ferric sulfate
b 2 (1) 2 Accept multiples and fractions 1
c i M1 white Ignore colourless 1
M2 blue Ignore all qualifiers such as pale / dark 1
ii D 1
iii M1 boiling point / melting/freezing point 1
M2 100 ºC / 0 ºC Accept just º or C but not just number 1
Value must match property
Accept correct values in K
Ignore other physical properties such as
pH / density

PhysicsAndMathsTutor.com
 Question
Answer Notes Marks
number
6 d i low density / less dense than air Accept lighter than air / the lightest gas 1
but not just light / lightweight
ii non-flammable Ignore unreactive 1
OR Accept does not react with oxygen/air
does not burn / explode (when ignited)
e H2(g) → H2(l) Ignore “+ heat/energy” on RHS 1
Penalise indication of endothermic
process

Tota
Total 12

PhysicsAndMathsTutor.com
Questio
n
Answer Notes Marks
numbe
r
7 a M1 NH4+ Award 1 if wrong way around 1

M2 Cl– Penalise missing charges both times 1

b i M1 (add) sodium hydroxide/NaOH (solution) Accept any identified Group 1 or Group 2 1

(and warm) hydroxide
If no reagent added, max 1 mark for correct
test AND result even if dipped into solution
If just hydroxide or OH- ions, do not award M1
but continue marking
If any other incorrect reagent added, then 0/3
M2 test (gas / ammonia) with (damp red) Accept use of universal indicator 1
litmus (paper) Accept holding litmus above tube etc
OR Reject blue litmus for M2 and M3
test with hydrogen chloride / conc HCl Do not penalise ammonium instead of
ammonia in M2 1
Do not allow (dilute) hydrochloric acid
M3 (litmus paper) turns blue Do not award M3 if litmus dipped into solution
OR (even if only implied)
white smoke/solid/powder

ii M1 (add) silver nitrate/AgNO3 (solution) If missing or incorrect reagent, 0/3 1

M2 (dilute) nitric acid Do not accept any other acid or just acidified 1
If acid missing or wrong, M3 can still be
awarded
M3 white precipitate / solid / suspension If bleaching litmus paper mentioned, only M1 1
can be awarded

PhysicsAndMathsTutor.com
Questio
n
Answer Notes Marks
numbe
r
7 c M1 reversible / goes both ways Ignore equilibrium 1

d i M1 ammonium chloride / NH4Cl Do not accept ammonia chloride 1

If name and formula given, both must be
correct

ii M1 ammonia / NH3 / molecules / they / it Ignore descriptions such as lighter / smaller / 1

are / move / diffuse /travel faster / denser
quicker
Accept phonetic spellings including amonia /
ammonium
Do not accept hydrogen chloride / hydrochloric
acid / HCl / ammonium chloride / NH4Cl in
place of ammonia
Accept all other words with same meaning as
faster - eg speedier
Do not accept react faster or travel further

Accept reverse statements such as hydrogen

chloride slower

e M1 Corrosive / burns / damages skin or eyes Ignore harmful / irritant / toxic / poisonous 1
M2 Wear eye protection eg goggles or mask Allow tongs / tweezers if reference to cotton 1
/ gloves / place bung in the end of the wool
tube / use of fume cupboard Ignore lab coats
M1 and M2 are independent
Total 13 marks

PhysicsAndMathsTutor.com
 Question
Answer Notes Marks
number
1 a i M1 bubbles / fizzing / effervescence Allow just gas (given off) 1
OR Ignore wrongly named gas
solid/magnesium disappears/dissolves
OR
flask gets warm Allow temperature increases but not heat
produced

ii M1 magnesium chloride / MgCl2 Accept phonetic spellings 1

Accept poorly written formulae such as
MGCl2 and MgCL2

b i M1 2H2 + O2 → 2H2O correct formulae = 1 1

M2 balancing = 1 1
Ignore heat anywhere
Ignore state symbols

ii M1 condensation Accept phonetic spellings 1

c i M1 blue Do not accept any other colours even in 1

combination with blue, eg blue-green

Accept phonetic spellings

Ignore qualifiers such as pale / dark / light
Ignore mention of solution / liquid / solid
 Question
Answer Notes Marks
number
1 c ii M1 measure boiling point / Ignore heat and cool 1
melting/freezing point
OR
distil / boil / freeze
M2 100 ºC / 0 ºC Value must match property 1
Accept º or C in place of ºC
Do not award M2 if only value given
Ignore evaporates
M2 dependent on M1

Total 8 marks
 Question
Answer Notes Marks
number
2 (a) (i) ACCEPT any 1
combination of dots
and crosses
NB H does not need to be shown if
touching / overlapping circles are shown if overlapping /
touching circles used
both electrons must
be within the
overlapping/touching
area

(ii) M1 weak forces (of attraction) between ACCEPT particles 2

molecules / weak intermolecular ACCEPT bonds for
forces forces for both M1
and M2
ACCEPT correctly
named IMF

M2 (therefore) little (thermal/heat) IGNORE more easily

energy required to overcome these separated / easier to
forces / separate the molecules (into break
the gaseous state)
REJECT atoms for
both M1 and M2

NB any mention of
breaking covalent or
ionic bonds scores 0

(b) (i) M1 atoms of the same element atoms with same 2

atomic number /
atoms same number
of protons

M2 with different masses different mass

numbers / different
numbers of neutrons

IGNORE references to
electrons unless
incorrect

(ii) H
1
H
2
H
3 one mark for each 3
protons 1 1 1 correct row
neutrons 0 1 2
electrons 1 1 1
Question
Answer Notes Marks
number
(c) (i) exothermic 1

(ii) 2H2 + O2 → 2H2O ACCEPT multiples 2

and halves
M1 all formulae correct IGNORE state
symbols even if
M2 balanced incorrect

(iii) M1 (add to) anhydrous/white copper(II) turns copper(II) 2

sulfate sulfate from white
to blue scores 2
M2 turns blue
ACCEPT equivalent
M2 dep on M1 or near miss description of test
with anhydrous
cobalt(II) chloride
(blue to pink)

IGNORE any
references to
testing with
indicators

(iv) M1 measure/determine the boiling point ACCEPT boil the 2

water / heat until it
boils

M2 100 ºC it boils at 100 ºC

ALLOW “heat it and

OR
it boils at 100 ºC “
for 2

M1 measure/determine the ACCEPT freeze the

melting/freezing point water / cool until it
freezes

M2 0 ºC it freezes at 0 ºC

ALLOW “cool it and

it freezes at 0 ºC “
OR for 2

M1 measure/determine the density

M2 1 g/cm3
Question
Answer Notes Marks
number

3 a CaCl2(aq) + H2SO4(aq) → CaSO4(s) + 2HCl(aq) All four must be correct to score 1

Do not penalise upper case letters

b M1 filter paper in filter funnel 2

Do not penalise inappropriate size

M2 everything else correct

Not essential that funnel touches flask
Reject beaker/tube for M2
Ignore labels
Ignore relative sizes

c i Ca2+ / calcium (ion) Reject Ca with incorrect or missing charge 1

Mark (i) and (ii) independently
ii calcium sulfate/CaSO4 is partially/slightly soluble 1

OR

contains unreacted/excess calcium chloride/CaCl2 Accept unreacted/excess calcium ions

(solution)
Question
Answer Notes Marks
number

3 d i white precipitate Accept solid / ppt / ppte / suspension in place 1

of precipitate
Reject other colours
Reject other observations eg fizzing
Ignore cloudy/milky/grey

ii silver chloride Accept correct formula 1

Ignore incorrect formula
Award both marks if both answers in either (i)
or (ii)

iii (hydrochloric/sulfuric) acid / H+ there Accept because there are no other ions that 1
OR could form a precipitate
solution acidic Accept no carbonate/hydroxide (ions)

Reject methods that refer to filtrate /solution

/crystallisation
e M1 wash/rinse (with water) Ignore other named solvents 2

M2 leave it (to dry) / leave in a warm place / Accept leave on a window ledge
place in an oven / place in desiccator / heat it / Ignore evaporate it / boil it
dry with absorbent paper (eg
kitchen/filter/blotting)
Award 1 mark for both M1 and M2 correct but
in wrong order

Total 10 marks
 Question
Answer Notes Marks
number
4 a bromine: (red-)brown Accept red 1
Reject orange / yellow
fluorine: gas 1
AND
astatine: solid

2+
4 b i Mg Accept H+ / H3O+ 1
Cl– Ignore OH– 1
Award 1 for both ions correct but in
wrong order

ii hydrogen / H2 Ignore H 1
burns with a pop / squeak Must be reference to test and result 1
OR Reference to splint/match with no
use burning/lit splint/flame to see if pop/squeak indication of flame is not enough
Reject reference to glowing splint
Ignore flame extinguished
'Squeaky pop test' alone is not sufficient
No ECF from wrong gas
M2 DEP on M1 correct or missing

iii white precipitate Accept white solid / ppt / ppte / 1

suspension
silver chloride Accept AgCl 1
to prevent other precipitates forming Accept to react with carbonate (ions) 1
Accept to react with hydroxide (ions)
Accept carbonates/hydroxides (also)
form (white) precipitates
Questio
n Answer Notes Marks
number

4 b iv hydrogen chloride/HCl does not dissociate Accept hydrogen chloride covalent bonds 1
/ does not form/produce ions do not break
OR Ignore there is no water
hydrochloric acid is not formed (in Ignore there are no ions (unspecifiied)
methylbenzene) Ignore all references to not reacting with
/HCl is not an acid (in methylbenzene) methylbenzene
/ no H+ ions (present/formed)
OR
only dissociates/forms H+ ions in water

(Total for Question 4 = 10 marks)

 Question
Answer Notes Marks
number
5 (a) (i) electrolysis 1

(ii) carbon / graphite 1

(iii) negative 1

(iv) cryolite Accept Na3AlF6 1

solvent (for alumina) Reject to lower melting or 1
boiling point of alumina /
OR aluminium oxide / aluminium
Ignore refs to boiling point of
to lower operating temperature / mixture / electrolyte
to lower melting point of mixture / Accept to reduce (heat)
electrolyte energy requirement
Accept to increase
conductivity of electrolyte
Ignore references to boiling
point
Reject acts as catalyst
M2 indep of M1

(b) (i) oxygen / O2 Ignore O 1

(ii) decreases capacity of blood to Accept correct reference to 1

carry oxygen haemoglobin /
oxyhaemoglobin /
carboxyhaemoglobin
Accept ref to CO bonding to
red blood cells but not to
white blood cells

(iii) (pass through) limewater / Ignore incorrect formulae eg 1

calcium hydroxide solution CaOH
Accept Ca(OH)2 solution /
Ca(OH)2(aq) but not just
Ca(OH)2
turns milky / cloudy / white Accept chalky / white ppte etc 1
Ignore refs to later going
clear
M2 dep on M1
5 (c) (i) (positive) ions / cations / Al3+ Do not accept atoms / 1
negative ions / anions as
alternative
(delocalised) electrons 1

(ii) layers of ions/particles Accept planes / sheets / rows 1

Do not penalise atoms instead
of ions here
Reject molecules / protons /
electrons

slide over each other Accept explanation in terms of 1

non-directional bonding
Do not award mark if wrong
particles named, eg protons /
electrons

(iii) delocalised / sea of electrons Accept free 1

move (through structure) / mobile “ions free to move” scores 0 1

(iv) low density / high strength to Ignore light 1

weight ratio Accept lightweight / not dense

Total 16 marks
Question
Answer Notes Marks
number
1 a Any two of: 2
 (same) volume of acid Reject volume(s) of solutions
 (same) concentration of acid Accept amount of acid as alternative to
 (same) concentration of alkali either of first two bullet points
 (same) rate of stirring / stir for the same time
 (same) starting temperature
/ temperature of acid/alkali/solutions/room

b M1 correct reference to accuracy / temperature rise eg accuracy improved or increased 2

/ temperature rise greater or more
accurate or closer to correct value(s)
/ final temperatures higher
Accept temperatures more accurate
Ignore just higher temperatures
Ignore results more reliable / valid

M2 correct reference to insulation / heat loss eg polystyrene is a (better) insulator

/ poorer conductor (than glass)
/ reduces heat loss
/ more heat trapped
Ignore no heat loss
Accept reverse argument for glass
Question
Answer Notes Marks
number
1 c i M1 (final) 39(.0) Both values correct but in wrong order 3
scores 1 mark (of M1 and M2)
M2 (initial) 17(.0)

M3(change) (+)22(.0) M3 CQ on final and initial values

ii exothermic 1
AND
temperature has increased Accept heat / thermal energy given out or
/ temperature change is positive transferred to the surroundings
/ final temperature higher than initial temperature
Reject just energy has been given out
Question
Answer Notes Marks
number
1 d Any two of: 2
 correct statement about first part of graph, identified as eg reaction continuing
positive gradient / positive correlation or acid being neutralised
/ temperature increase / temperatures up to 30 or 32.5 °C or some acid still unreacted
/ volumes up to 20 or 22 cm3 / experiments 1-4 or heat being produced

 correct statement about top of graph, identified as eg reaction complete

where lines cross / intersection / peak / maximum or all acid neutralised
or neutralisation point reached
or shows volume of alkali needed to
neutralise acid

 correct statement about second part of graph, identified as eg further alkali causes cooling
negative gradient / negative correlation or sodium hydroxide absorbs heat
/ temperature decrease / temperatures after 30 or 32.5 °C or no reaction occurs
/ volumes after 20 or 22 cm3 or up to 40 cm3 or no acid left
/ experiments 5-8 or alkali in excess
Reject reaction becomes endothermic

Ignore references to direct

proportion / particle collisions /
limiting reagents / rate of reaction

Total 10 marks
Question
Answer Notes Marks
number

2 a sulfur/precipitate forms Accept usual precipitate alternatives 1

Ignore precipitate colour
Accept cloudy / opaque
Reject wrongly identified precipitate (eg
sodium chloride)

b to keep the depth/height/shallowness of liquid Accept reverse argument 1

(in the conical flask) the same / OWTTE Reject to keep the concentration the same
OR
the same mass of sulfur (needed to obscure the
cross)

c reaction would start before the correct depth Ignore references to keeping the total 1
/concentration of liquid was obtained volume constant
OR Ignore references to fair test / accuracy
the reaction starts when the acid is added / safety
/ straight away/ before the water is added
 Question
Answer Notes Marks
number
2 d fume cupboard / well-ventilated room 1
/open windows / extractor fan
OR
wear eye protection / safety goggles / OWTTE
OR
(gas) mask / respirator

(SO2/it is) poisonous/toxic Ignore references to pollution / acid rain / 1

OR greenhouse effect
reference to specific harmful effect on humans Ignore just harmful
(eg affects breathing/respiratory irritant /eye
irritant/triggers asthma attack/makes
bronchitis or emphysema worse)
OR
to prevent gas reaching eyes/lungs/OWTTE
Mark independently
To score M1 and M2, explanation must
match precaution:
 fume cupboard etc can link with all
explanations
 eye protection etc. can link with all
explanations except those involving
breathing etc.
 mask etc. can link with all
explanations except those involving
eyes etc.
 Question
Answer Notes Marks
number
2 e i all points correctly plotted to nearest gridline Deduct 1 mark for each incorrect plot

suitable curve of best fit based on plotted points Do not penalise continuation of line 1
above 255 s unless incorrect (eg
straight line to 300 s)

ii curve completely below original curve Do not award mark if curve starts from 1
(10,255)
starts at vol = 10 cm3, finishes at vol = 50 cm3 DEP on point plotted for experiment 1 1

(Total for Question 2 = 10 marks)

Question
Answer Notes Marks
number

3 a brown precipitate Accept usual alternatives for precipitate 1

Ignore qualifiers such as dark / light
Ignore red(dish) / orange / rust(y)
Reject other colours
Ignore all names and formulae

b i ammonium / NH4+ If name and formula given, both must be 1

correct
gas given off is ammonia / NH3 Accept gas given off is alkaline 1
If name and formula given, both must be
correct
M2 DEP on M1 or near miss

ii sulfate / SO42– If name and formula given, both must be 1

correct

c Zn / zinc (atom) 1
(it) loses (2) electrons / gives electron(s) to Accept Fe3+ gains electron(s)/is 1
Fe3+ reduced/oxidation number decreases
/zinc is oxidised / zinc increases its oxidation Ignore Fe3+ converted to Fe2+
number / Zn converted to Zn2+
Reject iron/Fe gains electrons
M2 DEP on M1

(Total for Question 3 = 6 marks)

Question
Answer Notes Marks
number
4 (a) hydrogen / H2 Ignore H 1
burns with a pop/squeak Must be reference to test and result 1
OR Reference to splint/match with no
use burning/lit splint/flame to see if indication of flame is not enough
pop/squeak Reject reference to glowing splint
Ignore flame extinguished
‘Squeaky pop test’ on its own is not
sufficient
(b) i AgCl Ignore names even if wrong 1
Accept sufuric acid / H2SO4 1
(dilute) nitric acid / HNO3 Reject hydrochloric acid / HCl
Ignore conc(entrated) acid
Ignore acid(ified) without a named
acid
Reject other named acids

ii iron nitrate Accept ferrous nitrate and ferric 1

nitrate
Ignore oxidation states (II) and (III)
Reject other oxidation states
Question
Answer Notes Marks
number
4 (c) (add) sodium Any group I hydroxide / ammonium hydroxide / barium or calcium 1
hydroxide hydroxide / ammonia solution (names or formulae)
(solution) / NaOH If reagent incorrect, then 0/3
If reagent missing , then then M2 and M3 can be awarded
If near miss (eg ammonia hydroxide) then M2 and M3 can be awarded

green precipitate Ignore qualifiers such as light / pale / dark 1

Accept solid / suspension / ppt(e) in place of precipitate
Reject all other colours
Ignore names and formulae even if incorrect

brown precipitate Ignore qualifiers such as light / pale / dark / rusty / foxy / orange
Accept red-brown
Accept solid / suspension / ppt(e) in place of precipitate 1
Reject all other colours
Ignore names and formulae even if incorrect

If both colours correct, penalise missing precipitate once only

Do not award M2 or M3 for two correct observations in the wrong order
Ignore references to bubbles etc
Total
o 8
 Question
Answer Accept Reject Marks
number
5 (a) M1 - bubbles (of gas) / fizzing / effervescence gas/carbon dioxide 1
given off

M2- lump/calcium carbonate/solid disappears/gets dissolves 1

smaller forms a colourless
solution

(b) M1 - (bubble through) limewater/calcium hydroxide 1

solution
M2 - (goes) milky/cloudy/chalky white precipitate/ 1
suspension/solid
M2 dependent on M1 or near miss, e.g. Ca(OH)2(s) (formed)
IGNORE references to lighted spill goes out
(c) time increases, mass decreases reverse statement mass goes down 1
mass decreases with with no reference to
IGNORE references to mass eventually stops time time
decreasing (they have a) negative
correlation
(d) (i) 3.3 to 3.5 3 min 18s to 3 min 30s 1

(ii) lump/calcium carbonate/solid completely reacted used up/has gone has dissolved 1
(both) reactants
used up
 Question Answer
nswer A Reject Marks
Number
5 (e) (i) calcium chloride AND hydrochloric acid hydrogen chloride for 1
hydrochloric acid
correct formulae
IGNORE carbon dioxide / carbonic acid / calcium
carbonate
(ii) calcium chloride AND hydrochloric acid hydrogen chloride for calcium 1
hydrochloric acid carbonate
IGNORE carbon dioxide / carbonic acid correct formula
(f) M1 - steeper curve to left of original starting at, or close 1
to (100,0)
M2 - levels at 98.4 g curves that 'dip' 1
below 98.4 by
more than ½
small square

Total 11
Question
Answer Accept Reject Marks
number
6 (a) Cu( 2 Formula showing 1
penalise incorrect use of cases and subscript correct charges on
ignore names the ions
(b) to remove carbonate (ions) / to avoid precipitating to remove 1
any other (named) insoluble (barium) compounds compounds that
/ to remove ions that would form (white) would form (white)
precipitates precipitates
1
(c) CuSO4.5H2O / CuSO4 5H2O (i.e. no dot) formula showing
correct charges on
the ions
(d) (use a clean) wire / glass rod / silica rod any method of copper rod / any metal 1
introducing the solid that will burn or melt in
ignore references to hydrochloric acid / solution into the a flame (eg magnesium,
flame. e.g. (wet) aluminium)
wooden spill / tip or
sprinkle in

(to put) solid in non-luminous / Bunsen flame Bunsen/non- 1

luminous anywhere
No marks if solid is in container eg test tube / tray in answer
/ crucible Burner in place of
flame
Blue for non-
luminous
Total
Tot 5
Question
Answer Accept Reject Marks
number

7(a)(i) fermentation 1

(ii) (to provide the) catalyst/enzyme/zymase to increase the rate of the 1

reaction

(b)(i) M1 (test) – flame test suitable description of flame test 2

M2 (observation) – brick red / orange-red red

(ii) copper(II) ions: accept other suitable alkalis 5

M1 (test) – (aqueous) sodium hydroxide / suitable alternatives to

NaOH precipitate
all other colours
M2 (observation) – blue precipitate
ignore shades of blue

M2 dep on M1 or near miss of formula, eg

Na(OH)2

sulfate ions: (dilute) nitric acid / HNO3 Reject sulfuric

M1 (test) – (dilute) hydrochloric acid / HCl (aqueous) barium nitrate / acid for M1 only
Ba(NO3)2
M2 (test) - (aqueous) barium chloride /
BaCl2

M3 (observation) – white precipitate

M3 dep on M2 or near miss

Question Mark
Answer Accept Reject
number s

7 (c) M1 (pressure) – 60-70 atm any pressure or range within this 2

range
M2 (catalyst) – phosphoric acid / any other oxidation
H3PO4 phosphoric(V) acid state
ignore references to concentration

(d) M1 (Ʃ bonds broken) 348 + 412 + 3231

4
360 (= 1120)
3186
M2 (Ʃ bonds made) 612 + 463 (=
1075)

M3 M1 – M2 / Ʃ bonds broken − Ʃ
bonds made

M4 (+)45 (kJ/mol)

Correct answer with no working scores

4

− 5 (kJ/mol) scores 3

Total 15 marks