SAFETY DATA SHEET

1442358 MDT 80C-T Screen Printing Medium

Product specification RS_FP_830081 Revision Date 20.02.2023
Version 1.0 Print Date 18.04.2024
Material number 1442358 Page Page 1 of 12

1. PRODUCT AND COMPANY IDENTIFICATION

Product name : 1442358

MDT 80C-T Screen Printing Medium

Product code : 1442358

Manufacturer or supplier's details

Company : PT Vibrantz Additives Asia

Address : Bringinbendo No. 35,

Sidoarjo 61257

Telephone : +623199204888

Emergency telephone number

CHEMTREC Global Number : +(1)-703-527-3887 (Call Collect)
Telefax : +623199204889

2. HAZARDS IDENTIFICATION

GHS Classification
Flammable liquids : Category 3

Skin corrosion/irritation : Category 3

Reproductive toxicity : Category 1B

Aspiration hazard : Category 1

GHS label elements

Hazard pictograms :

Signal word : Danger

Hazard statements : H226 Flammable liquid and vapour.

H304 May be fatal if swallowed and enters airways.
H316 Causes mild skin irritation.
H360FD May damage fertility. May damage the unborn child.

Precautionary statements :
Prevention:
P203 Obtain, read and follow all safety instructions before use.
P210 Keep away from heat, hot surfaces, sparks, open flames
and other ignition sources. No smoking.
P233 Keep container tightly closed.
SAFETY DATA SHEET

1442358 MDT 80C-T Screen Printing Medium

Product specification RS_FP_830081 Revision Date 20.02.2023
Version 1.0 Print Date 18.04.2024
Material number 1442358 Page Page 2 of 12

P240 Ground and bond container and receiving equipment.

P241 Use explosion-proof electrical/ ventilating/ lighting equip-
ment.
P242 Use non-sparking tools.
P243 Take action to prevent static discharges.
P280 Wear protective gloves/ protective clothing/ eye protec-
tion/ face protection/ hearing protection.
Response:
P301 + P316 IF SWALLOWED: Get emergency medical help
immediately.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediate-
ly all contaminated clothing. Rinse affected areas with water.
P318 IF exposed or concerned, get medical advice.
P331 Do NOT induce vomiting.
P332 + P317 If skin irritation occurs: Get medical help.
P370 + P378 In case of fire: Use dry sand, dry chemical or
alcohol-resistant foam to extinguish.
Storage:
P403 + P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste
disposal plant.

Other hazards which do not result in classification

None known.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Chemical nature : organic solvent, carbonic acid/ester/anhydride, glycol ether/-
acetate, synthetic polymer
Components
Chemical name CAS-No. Concentration (%
w/w)
solvent naphtha (petroleum), heavy, aromatic 64742-94-5 >= 30 - < 50
methyl/butyl methacrylate copolymer 25608-33-7 >= 30 - < 50
bis(2-ethylhexyl) phthalate 117-81-7 >= 1 - < 10
2-butoxyethanol 111-76-2 >= 1 - < 10

4. FIRST AID MEASURES

General advice : Do not leave the victim unattended.

Move out of dangerous area.
Show this safety data sheet to the doctor in attendance.
Symptoms of poisoning may appear several hours later.

If inhaled : If unconscious, place in recovery position and seek medical

SAFETY DATA SHEET

1442358 MDT 80C-T Screen Printing Medium

Product specification RS_FP_830081 Revision Date 20.02.2023
Version 1.0 Print Date 18.04.2024
Material number 1442358 Page Page 3 of 12

advice.
In case of skin contact : Wash off immediately with soap and plenty of water while
removing all contaminated clothes and shoes.
If skin irritation persists, call a physician.
In case of eye contact : Flush eyes with water as a precaution.
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.
If swallowed : Keep respiratory tract clear.
Do NOT induce vomiting.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
Take victim immediately to hospital.
Most important symptoms : May be fatal if swallowed and enters airways.
and effects, both acute and May damage fertility. May damage the unborn child.
delayed
Notes to physician : Treat symptomatically.

5. FIREFIGHTING MEASURES

Suitable extinguishing media : Use extinguishing measures that are appropriate to local cir-
cumstances and the surrounding environment.
Alcohol-resistant foam
Carbon dioxide (CO2)
Dry chemical
Unsuitable extinguishing : High volume water jet
media
Specific hazards during fire- : Do not allow run-off from fire fighting to enter drains or water
fighting courses.

Hazardous combustion prod- : No hazardous combustion products are known

ucts

Specific extinguishing meth- : Use a water spray to cool fully closed containers.
ods Collect contaminated fire extinguishing water separately. This
must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
For safety reasons in case of fire, cans should be stored sepa-
rately in closed containments.
Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for firefighters

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protec- : Beware of vapours accumulating to form explosive concentra-

tive equipment and emer- tions. Vapours can accumulate in low areas.
gency procedures Material can create slippery conditions.
Use personal protective equipment.
Ensure adequate ventilation.
Remove all sources of ignition.
Evacuate personnel to safe areas.
SAFETY DATA SHEET

1442358 MDT 80C-T Screen Printing Medium

Product specification RS_FP_830081 Revision Date 20.02.2023
Version 1.0 Print Date 18.04.2024
Material number 1442358 Page Page 4 of 12

Environmental precautions : Prevent product from entering drains.

Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.

Methods and materials for : Clean contaminated floors and objects thoroughly while ob-
containment and cleaning up serving environmental regulations.
Contain spillage, and then collect with non-combustible ab-
sorbent material, (e.g. sand, earth, diatomaceous earth, ver-
miculite) and place in container for disposal according to local
/ national regulations (see section 13).

7. HANDLING AND STORAGE

Advice on protection against : Take necessary action to avoid static electricity discharge
fire and explosion (which might cause ignition of organic vapours).
Keep away from open flames, hot surfaces and sources of
ignition.
Do not spray on a naked flame or any incandescent material.

Advice on safe handling : Avoid release to the environment.

Avoid formation of aerosol.
Do not breathe vapours/dust.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the ap-
plication area.
Provide sufficient air exchange and/or exhaust in work rooms.
Open drum carefully as content may be under pressure.
Dispose of rinse water in accordance with local and national
regulations.
Conditions for safe storage : No smoking.
Keep container tightly closed in a dry and well-ventilated
place.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
Observe label precautions.
Electrical installations / working materials must comply with
the technological safety standards.
Further information on stor- : No decomposition if stored and applied as directed.
age stability

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Components CAS-No. Value type Control parame- Basis
(Form of ters / Permissible
exposure) concentration
2-butoxyethanol 111-76-2 TWA 20 ppm 2000/39/EC
98 mg/m3
Further information: Identifies the possibility of significant uptake
SAFETY DATA SHEET

1442358 MDT 80C-T Screen Printing Medium

Product specification RS_FP_830081 Revision Date 20.02.2023
Version 1.0 Print Date 18.04.2024
Material number 1442358 Page Page 5 of 12

through the skin, Indicative

STEL 50 ppm 2000/39/EC
246 mg/m3
Further information: Identifies the possibility of significant uptake
through the skin, Indicative
Engineering measures : Handle only in a place equipped with local exhaust (or other
appropriate exhaust).
Personal protective equipment
Respiratory protection : No personal respiratory protective equipment normally re-
quired.
Hand protection : Wear protective gloves, for example: polyvinyl alcohol or
nitrile-butyl-rubber gloves, or similar; Glove thickness: > 0.4
mm and Break Through time: > 480 minutes. The suitability
for a specific workplace should be discussed with the pro-
ducers of the protective gloves. Before removing gloves
clean them with soap and water.

Eye protection : Ensure that eyewash stations and safety showers are close to
the workstation location.
Tightly fitting safety goggles
Skin and body protection : Impervious clothing
Protective measures : Wear suitable protective equipment.
Hygiene measures : Wash hands before breaks and at the end of workday.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : viscous liquid

Colour : colourless

Odour : characteristic

Odour Threshold : No data available

pH : No data available

Melting point/freezing point : No data available

Boiling point/boiling range : No data available

Flash point : 53 °C

Method: Pensky-Martens closed cup

Evaporation rate : No data available

Upper explosion limit / Upper : 10.6 %(V)

flammability limit
SAFETY DATA SHEET

1442358 MDT 80C-T Screen Printing Medium

Product specification RS_FP_830081 Revision Date 20.02.2023
Version 1.0 Print Date 18.04.2024
Material number 1442358 Page Page 6 of 12

Lower explosion limit / Lower : 0.6 %(V)

flammability limit

Vapour pressure : No data available

Relative vapour density : No data available

Relative density : No data available

Density : No data available

Solubility(ies)
Water solubility : insoluble

Partition coefficient: n- : No data available

octanol/water

Viscosity
Viscosity, dynamic : 300 mPa.s

Flow time : No data available

Oxidizing properties : No data available

Refractive index : No data available

10. STABILITY AND REACTIVITY

Reactivity : No decomposition if stored and applied as directed.

Chemical stability : Stable under normal conditions.
Possibility of hazardous reac- : No decomposition if stored and applied as directed.
tions Vapours may form explosive mixture with air.

Conditions to avoid : Heat, flames and sparks.

Incompatible materials : Not applicable
Hazardous decomposition : Stable under normal conditions.
products

11. TOXICOLOGICAL INFORMATION

Acute toxicity
Not classified based on available information.
Product:
Acute oral toxicity : Acute toxicity estimate: > 2,000 mg/kg
Method: Calculation method

Acute inhalation toxicity : Acute toxicity estimate: > 20 mg/l

Exposure time: 4 h
SAFETY DATA SHEET

1442358 MDT 80C-T Screen Printing Medium

Product specification RS_FP_830081 Revision Date 20.02.2023
Version 1.0 Print Date 18.04.2024
Material number 1442358 Page Page 7 of 12

Test atmosphere: vapour

Method: Calculation method

Components:

methyl/butyl methacrylate copolymer:

Acute oral toxicity : LD50 Oral (Rat): 5,000 mg/kg

2-butoxyethanol:
Acute oral toxicity : Acute toxicity estimate: 1,200 mg/kg
Method: Acute toxicity estimate according to Regulation (EC)
No. 1272/2008

LD50 Oral (Rat, male and female): 1,746 mg/kg

Method: OECD Test Guideline 401
GLP: no

Acute dermal toxicity : LD50 Dermal (Rabbit, male and female): > 2,000 mg/kg
Method: OECD Test Guideline 402
GLP: yes

Skin corrosion/irritation
Not classified based on available information.
Components:

2-butoxyethanol:
Species : Rabbit
Exposure time : 72 h
Method : OECD Test Guideline 404
Result : Irritating to skin.
GLP : yes

Serious eye damage/eye irritation

Not classified based on available information.
Components:

2-butoxyethanol:
Result : Eye irritation

Respiratory or skin sensitisation

Skin sensitisation
Not classified based on available information.
Respiratory sensitisation
Not classified based on available information.
Germ cell mutagenicity
Not classified based on available information.
SAFETY DATA SHEET

1442358 MDT 80C-T Screen Printing Medium

Product specification RS_FP_830081 Revision Date 20.02.2023
Version 1.0 Print Date 18.04.2024
Material number 1442358 Page Page 8 of 12

Carcinogenicity
Not classified based on available information.
Reproductive toxicity
May damage fertility. May damage the unborn child.
STOT - single exposure
Not classified based on available information.
STOT - repeated exposure
Not classified based on available information.
Aspiration toxicity
May be fatal if swallowed and enters airways.
Further information

Product:
Remarks : Solvents may degrease the skin.

12. ECOLOGICAL INFORMATION

Ecotoxicity

Components:

2-butoxyethanol:
Toxicity to fish : LC50 (Lepomis macrochirus (Bluegill sunfish)): 1,490 mg/l
Exposure time: 96 h
Test Type: static test
Method: OECD Test Guideline 203
GLP: no

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 1,800 mg/l
aquatic invertebrates Exposure time: 48 h

Persistence and degradability

No data available
Bioaccumulative potential

Components:

solvent naphtha (petroleum), heavy, aromatic:

Partition coefficient: n- : log Pow: 3.7 - 4.2
octanol/water

2-butoxyethanol:
Partition coefficient: n- : log Pow: 0.77 (20 °C)
octanol/water pH: 7
SAFETY DATA SHEET

1442358 MDT 80C-T Screen Printing Medium

Product specification RS_FP_830081 Revision Date 20.02.2023
Version 1.0 Print Date 18.04.2024
Material number 1442358 Page Page 9 of 12

Mobility in soil
No data available
Other adverse effects

Product:
Results of PBT and vPvB : This substance/mixture contains no components considered
assessment to be either persistent, bioaccumulative and toxic (PBT), or
very persistent and very bioaccumulative (vPvB) at levels of
0.1% or higher.

Endocrine disrupting poten- : This substance/mixture contains components considered to

tial have endocrine disrupting properties for environment , accord-
ing to REACH Article 57(f), Commission Regulation (EU)
2018/605 or Commission Delegated Regulation (EU)
2017/2100.

Additional ecological infor- : None known.

mation

Components:

bis(2-ethylhexyl) phthalate:
Endocrine disrupting poten- : The substance is considered to have endocrine disrupting
tial properties according to REACH Article 57(f) for the environ-
ment.

13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : Send to a licensed waste management company.
Dispose of wastes in an approved waste disposal facility.
Do not dispose of waste into sewer.
Do not contaminate ponds, waterways or ditches with chemi-
cal or used container.
Contaminated packaging : Empty remaining contents.
Dispose of as unused product.
Empty containers should be taken to an approved waste han-
dling site for recycling or disposal.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty drum.

14. TRANSPORT INFORMATION

ADR
UN number : UN 1993
Proper shipping name : FLAMMABLE LIQUID, N.O.S.
(cyclohexanone)
Class : 3
Packing group : III
Labels : 3
SAFETY DATA SHEET

1442358 MDT 80C-T Screen Printing Medium

Product specification RS_FP_830081 Revision Date 20.02.2023
Version 1.0 Print Date 18.04.2024
Material number 1442358 Page Page 10 of 12

Hazard Identification Number : 30

Tunnel restriction code : (D/E)
IATA-DGR
UN/ID No. : UN 1993
Proper shipping name : Flammable liquid, n.o.s.
(cyclohexanone)
Class : 3
Packing group : III
Labels : Flammable Liquids
Packing instruction (cargo : 366
aircraft)
Packing instruction (passen- : 355
ger aircraft)
IMDG-Code
UN number : UN 1993
Proper shipping name : FLAMMABLE LIQUID, N.O.S.
(cyclohexanone)
Class : 3
Packing group : III
Labels : 3
EmS Code : F-E, S-E
Marine pollutant : no
Transport in bulk according to IMO instruments
Not applicable for product as supplied.
Special precautions for user
The transport classification(s) provided herein are for informational purposes only, and solely
based upon the properties of the unpackaged material as it is described within this Safety Data
Sheet. Transportation classifications may vary by mode of transportation, package sizes, and var-
iations in regional or country regulations.

15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mix-
ture
Take note of Directive 92/85/EEC regarding maternity protection or stricter national regulations,
where applicable.
Take note of Directive 94/33/EC on the protection of young people at work or stricter national
regulations, where applicable.
International Chemical Weapons Convention (CWC) : Neither banned nor restricted
Schedules of Toxic Chemicals and Precursors

REACH - Candidate List of Substances of Very High : bis(2-ethylhexyl) phthalate

Concern for Authorisation (Article 59).

REACH - List of substances subject to authorisation : bis(2-ethylhexyl) phthalate

(Annex XIV)

Regulation (EC) No 1005/2009 on substances that : Neither banned nor restricted

deplete the ozone layer
SAFETY DATA SHEET

1442358 MDT 80C-T Screen Printing Medium

Product specification RS_FP_830081 Revision Date 20.02.2023
Version 1.0 Print Date 18.04.2024
Material number 1442358 Page Page 11 of 12

Regulation (EU) 2019/1021 on persistent organic pollu- : Neither banned nor restricted
tants (recast)

Regulation (EC) No 649/2012 of the European Parlia- : Not applicable

ment and the Council concerning the export and import
of dangerous chemicals

REACH - Restrictions on the manufacture, placing on : See Annex XVII to Regulation (EC)
the market and use of certain dangerous substances, no 1907/2006 and amendments for
mixtures and articles (Annex XVII) Conditions of restriction

REACH - Restrictions on the manufacture, placing on : bis(2-ethylhexyl) phthalate

the market and use of certain dangerous substances,
mixtures and articles (Annex XVII)

The components of this product are reported in the following inventories:

TCSI (Taiwan) : On the inventory, or in compliance with the inventory

TSCA (United States) : All substances listed as active on the TSCA inventory

AIIC (Australia) : All components are listed on the inventory, regulatory obliga-
tions/restrictions apply

DSL/NDSL (Canada) : All components of this product are on the Canadian DSL

ENCS (Japan) : On the inventory, or in compliance with the inventory

ISHL (Japan) : Not in compliance with the inventory

KECI (Korea) : On the inventory, or in compliance with the inventory

PICCS (Philippines) : On the inventory, or in compliance with the inventory

IECSC (China) : On the inventory, or in compliance with the inventory

NZioC (New Zealand) : Not in compliance with the inventory

SWISS (Switzerland) : The formulation contains substances listed on the Swiss In-
ventory, On the inventory, or in compliance with the inventory

EINECS (European Union) : On the inventory, or in compliance with the inventory

CICR (Turkey) : On the inventory, or in compliance with the inventory

TECI (Thailand) : Not in compliance with the inventory

16. OTHER INFORMATION

Date format : dd.mm.yyyy

SAFETY DATA SHEET

1442358 MDT 80C-T Screen Printing Medium

Product specification RS_FP_830081 Revision Date 20.02.2023
Version 1.0 Print Date 18.04.2024
Material number 1442358 Page Page 12 of 12

Full text of other abbreviations

2000/39/EC : Europe. Commission Directive 2000/39/EC establishing a first
list of indicative occupational exposure limit values

2000/39/EC / TWA : Limit Value - eight hours

2000/39/EC / STEL : Short term exposure limit

AIIC - Australian Inventory of Industrial Chemicals; ANTT - National Agency for Transport by
Land of Brazil; ASTM - American Society for the Testing of Materials; bw - Body weight; CMR -
Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for
Standardisation; DSL - Domestic Substances List (Canada); ECx - Concentration associated with
x% response; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with
x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized Sys-
tem; GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer; IATA
- International Air Transport Association; IBC - International Code for the Construction and
Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory con-
centration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemi-
cal Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International
Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Or-
ganisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Con-
centration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median
Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships;
n.o.s. - Not Otherwise Specified; Nch - Chilean Norm; NO(A)EC - No Observed (Adverse) Effect
Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect
Loading Rate; NOM - Official Mexican Norm; NTP - National Toxicology Program; NZIoC - New
Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Develop-
ment; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumu-
lative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substanc-
es; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH - Regulation (EC) No
1907/2006 of the European Parliament and of the Council concerning the Registration, Evalua-
tion, Authorisation and Restriction of Chemicals; SADT - Self-Accelerating Decomposition Tem-
perature; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TDG - Trans-
portation of Dangerous Goods; TECI - Thailand Existing Chemicals Inventory; TSCA - Toxic Sub-
stances Control Act (United States); UN - United Nations; UNRTDG - United Nations Recom-
mendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumu-
lative; WHMIS - Workplace Hazardous Materials Information System

The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor-
mation and belief at the date of its publication. The information given is designed only as a guid-
ance for safe handling, use, processing, storage, transportation, disposal and release and is not
to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.

BD / EN