Block 3

BPHET-141
ELEMENTS OF
Indira Gandhi National
Open University
MODERN PHYSICS
School of Sciences
Block
3
APPLICATIONS OF QUANTUM MECHANICS TO SIMPLE
SYSTEMS
UNIT 9
Particle in a Box 7
UNIT 10
Step Potential 35
UNIT 11
Barrier Potential 51
UNIT 12
Finite Potential Well 79
Course Design Committee
Prof. A. K. Ghatak, Retd. Dr. Parthasarathy Prof. Shubha Gokhale
IIT Delhi, Dept. of Physics, School of Sciences,
New Delhi Maharaja Agrasen College, IGNOU, New Delhi
University of Delhi, Delhi
Prof. Suresh Garg, Retd. Prof. Sanjay Gupta
School of Sciences, Prof. M. S. Nathawat School of Sciences,
IGNOU, New Delhi, Former Director, IGNOU, New Delhi
Vice Chancellor, School of Sciences,
IGNOU, New Delhi Dr. Subhalakshmi Lamba
Usha Martin University
School of Sciences,
Prof. Vijayshri IGNOU, New Delhi
Prof. R. M. Mehra, Retd.
Dept. of Electronics, School of Sciences,
South Campus, IGNOU, New Delhi
University of Delhi, Delhi Prof. Sudip Ranjan Jha
School of Sciences,
Dr. Ashok Goyal, Retd. IGNOU, New Delhi
Dept. of Physics, Hansraj College,
University of Delhi, Delhi
Block Preparation Team

Dr. M. Boazbou Newmai (Unit 10) Dr. Subhalakshmi Lamba (Units 9,11,12)
School of Sciences, School of Sciences,
IGNOU, New Delhi IGNOU, New Delhi
Course Coordinators: Dr. Subhalakshmi Lamba, Dr. M Boazbou Newmai
Block Production Team

Sh. Sunil Kumar
AR (P), IGNOU
August, 2021
© Indira Gandhi National Open University, 2021
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Printed and published on behalf of Indira Gandhi National Open University, New Delhi by
Prof. Sujatha Varma, Director, School of Sciences, IGNOU.
CONTENTS
Block and Unit Titles 1
Credit page 2
Contents 3
BLOCK 3: APPLICATIONS OF QUANTUM MECHANICS TO SIMPLE
SYSTEMS 5
Unit 9 Particle in a Box 7

9.1 Introduction 8
9.2 A Free Particle 8
9.3 Particle in a Box 14
9.3.1 Solving the Schrödinger Equation 14
9.3.2 Eigen Functions and Eigen Values 15
9.3.3 Time Dependent Wave Function 20
9.3.4 Probability Density 21
9.4 Quantum Dot 24
9.5 Summary 26
9.6 Terminal Questions 28
9.7 Solutions and Answers 29
Unit 10 Step Potential 35
10.1 Introduction 36
10.2 Step Potential and Schrödinger Equation 36
10.3 Energy (E) of the particle is less than V0 39
10.3.1 Reflection and Transmission Coefficients 41
10.4 Energy (E) of the particle is greater than V0 44
10.4.1 Reflection and Transmission Coefficients 46
10.5 Summary 47
Unit 11 Barrier Potential 51
11.2 One-Dimensional Barrier Potential 53
11.2.2 Reflection and Transmission Coefficient for E<V0 59
11.2.3 Reflection and Transmission Coefficient for E>V0 64
11.3 Applications of Quantum Tunnelling 66
11.3.1 Alpha Decay 66
11.3.2 Scanning Tunnelling Microscope 68
11.4 Summary 69
Appendix 11A: Calculating the Reflection and Transmission
Coefficients 76
3
Unit 12 Finite Potential Well 79
12.2 One-dimensional Finite Potential Well 80
12.2.2 Parity of the Eigen Functions 84
12.2.3 Energy Eigen Values 87
12.2.4 Symmetric Infinite Potential Well 91
12.3 Summary 94
Further Readings 99
Table of Physical Constants 100
List of Blocks and Units: BPHET-141 101
Syllabus: Elements of Modern Physics (BPHET-141) 102
4
BLOCK 3 : APPLICATIONS OF QUANTUM MECHANICS TO
SIMPLE SYSTEMS
In Block 2 of this course we have introduced you to the basic concepts of quantum
mechanics. Quantum mechanics has forced us to reconsider our deepest convictions about
the reality of nature. For example, the idea that wave-particle duality is an inherent property of
all the elements that make up the physical universe does away with the distinction between
matter and radiation (which is at the root of classical physics). Then you have seen how
classical determinism and causality are called into question by quantum mechanics through
the uncertainty principle and the probabilistic description. You learnt that our inability to
measure certain pairs of variables with arbitrary accuracy is not a limitation of the
experimental apparatus. Quantum mechanics tells us that uncertainty is not a matter of our
inability to do better, rather it is inherent to the nature of the quantum world. That a particle
may not have a well-defined position and momentum at the same time is a fundamentally new
notion which many physicists including Einstein found hard to accept. It is indeed in the
nature of things - either we define the particle’s position and lose all information about its
momentum, or we pinpoint its momentum and do not know where in space it is. This is surely
a far cry from the deterministic depiction of classical mechanics. These fundamental ideas
were built into a mathematical framework which you studied in Units 7 and 8.
The Schrödinger equation for the time evolution of matter waves led us to the probabilistic
description of the quantum world. Quantum mechanics tells us that the probabilistic
description is also the fundamental description; there is no deeper level. It gives us only the
probability amplitude from which a probability can be computed. For example, we can
compute the probability that an electron would have a certain velocity. But quantum
mechanics does not give the velocity of a specific particle. Instead it claims that no such
detailed information even exists.
The first idea of the energy quantum was introduced by Planck in 1900; it took about another
thirty years to develop into a full-fledged theory. We can say that it is one of the most
successful theories in the history of science. In the subsequent years since its birth, the
fundamental ideas of quantum mechanics have been tested and verified with increasingly
accurate experiments. It has continued to evolve into other important areas of research like
quantum field theory, quantum electrodynamics and the quantum description of gravity. The
methods of quantum mechanics become important when we talk of microscopic systems, far
removed from our daily experiences. Yet it affects our lives in many different ways, because
in today’s world, a lot of the technology we take for granted owes its origins to quantum
mechanics: shrinking transistor sizes to power laptops and mobiles, medical technology like
MRI and PET and so on. This has become possible, in part, because of one important aspect
of quantum mechanics: its ability to predict. You will discover its power in this block when you
study its applications to some simple one-dimensional systems.
In Unit 9 of this block, entitled Particle in a Box, you will solve the one-dimensional
Schrödinger equation for the free particle and for a particle confined to a rigid one-
dimensional box. You will study an important distinction between classical and quantum
physics: that when a quantum particle is confined to a tiny region, its energies cannot be
continuous. Rather the particle’s energy can have only specified discrete values, which
depend on the parameters of the system. This idea has important applications in
semiconductor technology and in this context, you will study about the quantum dot.
5
In Unit 10 entitled Step Potential you will study the properties of a quantum particle moving
in a one-dimensional step potential. You will learn that it is possible for quantum particles to
be found in regions that are classically forbidden.
In Unit 11 entitled Barrier Potential, we solve the Schrödinger equation for the one-
dimensional potential barrier. You will find that it is possible for a particle to be transmitted
across a potential barrier even when its kinetic energy is less that the barrier potential. This
phenomenon of barrier penetration is called “quantum tunnelling” because it has no
classical analogue. You will study applications of quantum tunnelling in alpha decay and
scanning tunnelling microscopy.
Finally in Unit 12 entitled Finite Potential Well you will study the motion of a particle in a
finite potential well. This is important because an infinite well in which particles can be strictly
confined is actually an idealization, rarely found in nature. Once again, you will see that a
bound particle has discrete energy levels.
With this we end our study of the concepts of quantum mechanics and their applications. In
higher courses at the Master’s level, you will solve the Schrödinger equation for more
complex potentials. However, in this block you will learn the methods of solving the
Schrödinger equation and how the properties of eigen functions and energy eigen values
change with the parameters of the system.
As far as studying the material is concerned, follow the advice given in Block 2  learn to think
and calculate quantum mechanically! You may find the going tough initially as there are a lot
of mathematical steps in this material. Our advice to you is to solve each and every step on
your own. Do not try to rush through the material if you wish to really understand it for
assimilating the ideas. And at the end of it all, we hope that you experience a genuine sense
of achievement and exhilaration at having understood one of the greatest and most beautiful
intellectual creations of twentieth century science. Our best wishes are with you!
6
Unit 9 Particle in a Box
UNIT 9
Colloidal quantum dots of
different sizes emit different
colours of light when
illuminated by ultraviolet
radiation. [Walkman16, CC BY- PARTICLE
SA 3.0
<https://creativecommons.org/lic
enses/by-sa/3.0>, via Wikimedia
IN A BOX
Commons]
Structure
9.1 Introduction 9.4 Quantum Dot
Expected Learning Outcomes 9.5 Summary
9.2 A Free Particle 9.6 Terminal Questions
9.3 Particle in a Box 9.7 Solutions and Answers
Solving the Schrödinger Equation
Eigen Functions and Eigen Values
Time Dependent Wave Function
Probability Density
Discoveries in physics are made when the time for making them is ripe, and
STUDY GUIDE
In this unit you will apply the Schrödinger equation to simple systems. You will be solving second
order ordinary differential equations, obtaining normalized wave functions and calculating expectation
values of dynamical variables. You should be familiar with ordinary differential and integral calculus
which you have studied in school and the techniques of solving ODEs which you have studied in Unit
4 of BPHCT 131. Please be thorough with the concepts of Units 7 and 8 of Block 2 of this course
before you start studying these units. You must work through all the examples, SAQs and TQs to get
good practise in the methods taught here.
“A method is more important than a discovery, since the right Lev Landau
method will lead to new and even more important discoveries.”
”
7
Block 3 Applications of Quantum Mechanics to Simple Systems
9.1 INTRODUCTION
The Schrödinger equation
In Unit 7 of Block 2 you have studied the time independent Schrödinger
cannot be derived, and
equation. In this unit, you will how to solve Schrödinger equation in one
like the other postulates of
quantum mechanics, its dimension. Although the real world is three-dimensional, these one-
validity lies in its dimensional systems are of great interest. This is not only because several
agreement with physical situations are effectively one-dimensional, but also because a
experimental results. number of more complicated physical problems can be reduced to the solution
Schrödinger himself of equations similar to the one- dimensional Schrödinger equation.
applied his equation to the
hydrogen atom and in In Sec. 9.2, you will first study a quantum mechanical free particle, that is one
fact, it is in the field of on which no force is being exerted. This is a particle that cannot be confined
atomic physics that this
(bound) within a defined region of space by a potential, like a proton in a
equation has been most
successful. You should nucleus. You will see that a quantum mechanical free particle has a
also know that one cannot continuous spectrum of energy eigen values In Sec. 9.3 we solve the quantum
obtain an exact solution mechanical problem of a particle moving within a limited space like in a rigid
for neutral atoms more box. You will find that the energy eigen values of this system are different.
complex than the Finally in Sec. 9.4 we discuss a quantum dot which is a practical realization of
hydrogen atom and one
a particle in a box. A quantum dot is typically a nano sized semiconductor
has to use approximation
particle. The optical and electrical properties of the quantum dot change with
methods, which you study
about in higher classes. size and material, and they have many applications in nano scale devices.
Note also that the In the next unit you will solve the time independent Schrödinger equation for a
Schrödinger equation is one dimensional step potential function and study its applications.
not a relativistic wave
equation. So it is used
only to study the
nonrelativistic behaviour Expected Learning Outcomes
of atoms and molecules.
Just like Newton’s second After studying this unit, you should be able to:
law which gives way to
the relativistic force law to  solve the time independent one-dimensional Schrödinger equation and
study relativistic obtain the eigen functions and energy eigen values for a free particle;
phenomena, there is also
a relativistic wave  solve the time independent one-dimensional Schrödinger equation and
equation which was obtain the eigen functions and energy eigen values for a particle in a
developed by Dirac in one dimensional box; and
1928.
 explain the properties of the quantum dot on the basis of the particle in
a box model.
9.2. A FREE PARTICLE

Recall the time independent Schrödinger equation for the stationary state
wave function (x ) for a quantum particle of mass m from Unit 7 (Eq.7.47):
 2 d 2( x )
  V ( x )( x )  E( x )  Hˆ ( x )  E( x ) (9.1)
2m dx 2
8
You know that this is the eigen value equation for the Hamiltonian operator Ĥ .
Any solution, (x ) , of this equation is the eigen function of Ĥ . And the energy,
E, is the eigen value of Ĥ corresponding to the eigen function (x ) .
 2 ( x )
Note that in Eq. (9.1), the partial derivative has been replaced by
x 2
d 2 ( x )
because (x ) is only a function of x. Now, you know that a free
dx 2
particle is one on which no force is being exerted. You have studied in
BPHCT-131, that for a conservative system, force is related to the potential as
follows:
dV ( x )
F(x)   (9.2)
dx
So, for a system on which no force is exerted, we will have:
dV ( x )
F(x)  0   0  V ( x )  V0 (9.3)
dx
where V0 is a constant potential.
Without loss of generality, we can take the constant V0 to be zero. So now we

have a particle of mass m moving freely in space. Putting V ( x )  0 in Eq. (9.1)
we can write the time independent Schrödinger equation for a free
particle as follows:
 2 d 2( x )
  E( x ) (9.4)
2m dx 2
In the classical picture, since the particle is not subjected to any force, its
linear momentum p does not change with time. E, the total energy of the
particle (which is equal to its kinetic energy) also does not change with time. E
and p are related by the equation:
p2
E (9.5)
2m
 
From Eq. (5.3) you know that the linear momentum p  k . Since we are
considering only one-dimensional motion, we can assume that both the
momentum p and the wave vector k lie along the x-axis. So we write
p  px  k . Then the expression for the energy of the particle is:
 2k 2
E (9.6)
2m
Let us now solve Eq. (9.1). Rearranging the terms we get:
d 2( x ) 2mE
2
  2 ( x ) (9.7)
dx 
2mE
Making the substitution k 2  we get the following second order ODE:
2
9
d 2( x )
 k 2( x ) (9.8)
From Sec.4.3.3 of dx 2
BPHCT-131 you can
write the general solution For any given value of E and hence of k, there are two possible solutions to
of this equation, which are also linearly independent (read the margin remark):
d 2( x )
 k 2( x )  0
dx 2 1 ( x )  e ikx ;  2 ( x )  e ikx (9.9)
As
Thus for one value of E, we have two possible eigen functions, 1( x ) and
( x )  Aem1x  Bem2 x
Where m1 and m2 are the 2 ( x ) .
solutions of the indicial
equation Recall from Sec. 8.3.4 that such eigen functions which have the same
eigenvalue for a given eigenvalue equation are called degenerate eigen
m2  k 2  0
functions (otherwise they are non-degenerate). Thus, 1( x ) and 2 ( x ) are
Here
m1  ik; m2  ik degenerate eigen functions. The general solution of Eq. (9.4) is the linear
combination:
e m1x and e m 2 x are the
two linearly independent ( x )  Ae ikx  Be ikx (9.10)
solutions
You can check for yourself by solving SAQ 1, that (x ) is also an eigen
 2k 2
function of Eq.(9.4) with the same eigenvalue E  .
2m
The functions sin kx and
cos kx , as well as SAQ 1 - Free Particle in One Dimension
linear combinations of
Show that ( x )  Ae ikx  Be ikx is an eigen function of the time independent
these functions are also
solutions of the time
independent Schrödinger Schrödinger equation for the quantum mechanical free particle with an
equation for the free  2k 2
eigenvalue E  .
particle. You will see this 2m
for yourself when you
work out SAQ 2
For the solution (x ) to be physically acceptable, k cannot have an imaginary
part. Can you say why?
To understand, let us take k to be complex: k    i . In that case,
1 ( x )  ei ( i) x  eix ex (9.11)
Now, if  is positive, you can see that the term ex would increase
exponentially as x   . If  is negative, the term ex would increase
exponentially as x   . So this would not be an acceptable wave function, as
you have studied in Sec. 7.5. You can also check for yourself that 2 ( x )
would also would increase exponentially either as x   or as x   , if k
had an imaginary part.
So, k should be a real number and therefore k 2  0 . Therefore a quantum

mechanical free particle can have any non negative value of energy:
 2k 2
E 0 (9.12)
2m
Since any non-negative value of E is allowed, the energy spectrum of a free

10 particle is continuous, extending from E  0 to  . This, of course, is not
surprising, since E is the kinetic energy of a free particle. It also corresponds
to the classical result.
For a real value of k, 1( x ) and 2 ( x ) do not diverge at x   or as x   ,

but neither do they go to zero. For 1( x ) , you can see that :
  
 1 ( x )1 ( x )dx   e e dx   dx

ikx ikx
(9.13)
  
which is clearly NOT finite. The same is true for 2 ( x ) . So, as you have
studied in Sec. 7.3.3, the eigen functions 1( x ) and 2 ( x ) are non-
normalizable.
We can also write down the time dependent wave function for the free particle.
In Sec. 7.4 you have studied that for a stationary state (x ) , the time
dependent wave function has the explicit form (Eq. 7.48):
( x, t )  ( x )e iEt  (9.14)
So the time dependent wave function for the free particle with an energy E is

( x, t )  Aeikx  Beikx e iEt   (9.15)
If the quantum mechanical free particle is in a stationary state (x ) which

corresponds to the energy eigen value E (Eq. 9.1), while the wave function will
evolve with time as given by Eq. (9.15), the energy of the particle, E, will (x,t)
Aei (kx t )
not change with time.
x
Using E   , we get:
( x, t )  Aei kxt   Bei kxt  (9.16)
In order to interpret Eq. (9.16) physically, let us consider some special cases.
If we set B = 0, the resulting wave function is the plane wave:
( x, t )  Ae i kx  t  (9.17)
This function represents a travelling plane wave as shown in Fig. 9.1. This Fig. 9.1: A travelling wave
wave is associated with a free particle of mass m moving along the positive x-
 2k 2
axis with a definite momentum of magnitude ħk and an energy .
2m
The probability density corresponding to the wave function of Eq. (9.17) is:
2
P ( x, t )   * ( x, t )( x, t )  A (9.18)
which is independent of time t as well as position x. In other words, at any

instant of time t, the probability of finding the particle in an interval
2
between x and x  dx is the same ( A dx ) for any value of x. In other
words, the position of the particle is completely unknown.
This result can also be deduced from the uncertainty principle. Since the
momentum of the particle is precisely known, p  px  0 . Then, from the
11
uncertainty principle, the uncertainty in the position of the particle x   .
Further, since the energy of the particle is also known precisely, we also have
E  0 . Hence, according to the energy-time uncertainty principle, we have
an infinite time ( t   ) to make a measurement of the energy of the particle.
You can carry out a similar analysis by setting A = 0 in Eq. (9.16). In this case
the plane wave will be travelling in the negative x-direction.
It is possible to verify that 1( x ) and 2 ( x ) are also the eigen functions of
the momentum operator. However the eigen values of the momentum
operator are different for the two eigen functions. We work that out in the
following example.
XAMPLE 9.1: MOMENTUM EIGEN VALUES

Show that 1 ( x )  eikx and 2 ( x )  eikx are eigen functions of the
momentum operator and determine the corresponding eigen values.
SOLUTION  We have to show that the eigen value equation, Eq. (8.35),
is valid for the wave functions 1 ( x )  eikx and 2 ( x )  eikx with
d
Dˆ  pˆ x  i  .
dx
Using 1 ( x )  e ikx in Eq. (8.35) we get:
pˆ x 1x   i 
d
dx
1x   i   
d ikx
dx
e  
 i  ike ikx  ke ikx
So pˆ x 1x   k 1x  . So 1 ( x ) is an eigen function of the momentum

operator p̂x with the eigen value k .
Using  2 ( x )  e  ikx in Eq. (8.35) we get:
pˆ x  2 x   i 
d
dx
 2 x   i  
d ikx
dx
e   
 i   ike ikx  ke ikx
Since pˆ x 2 x    k 2 x , we can say that  2 ( x ) is also an eigen

function of the momentum operator p̂x with the eigen value  k .
The energy E [E(k)] and the momentum p [p(k)] of a quantum mechanical free
particle are both constants of motion and are defined in terms of k. k also
characterises the eigen function (x ) for the quantum mechanical free particle
and hence we call k a quantum number.
Let us now summarize what you have studied so far.
12
FREE PARTICLE
The time independent Schrödinger equation for a quantum mechanical free

particle of mass m is:
 2 d 2( x )
  E( x ) (9.4)
2m dx 2
The general solution of Eq. (9.4) is:
2mE
( x )  Aeikx  Beikx ; with k 2  (9.10)
2
The quantum number k is real and the free particle can have any non-
negative value of energy:
 2k 2
E 0 (9.12)
2m
The energy of the particle does not change with time.
The time dependent wave function for the free particle with an energy
E   is:
( x, t )  Aei kxt   Bei kxt  (9.16)
You may now like to answer an SAQ.
SAQ 2 - Solutions of the free particle Schrödinger equation
Show that (i) ( x )  sin kx and (ii) ( x )  cos kx are solutions of the Schrödinger
equation for the free particle (Eq. 9.7).
In the classical picture, a free particle has “unbounded motion” because it is

not subjected to a force. In the corresponding quantum mechanical picture,
the free particle can have any energy as defined by Eq. (9.6) and the energy
eigen values E vary continuously with the value of k . So the energy spectrum
is continuous and ranging between zero to infinity. Each energy state has a
two-fold degeneracy corresponding to particles moving either along the
positive x direction or along the negative x direction, except for the state
corresponding to k = 0.
However, in the classical picture when the value of the momentum (p) is
known exactly, you can locate the position of the particle at any instant of
time, if the initial position is known. You have seen that this is not possible for
a quantum mechanical free particle because of the uncertainty principle.
Let us now see what happens when we confine the free particle to a box.
13
9.3. PARTICLE IN A BOX
V  V 
Let us consider that a free particle is confined in a one-dimensional length
segment lying between x = 0 and x  L . You can imagine that there are rigid
barriers at x  0 and x  L that the particle cannot penetrate to move beyond
these points: so the particle cannot move to the left of x  0 or the right of
x  L . This is also called a rigid box. We describe this system by saying that
the potential V(x) is infinite for all values of x  0 and x  L . Between
0  x  L , the particle is free, and the potential is zero in this region. The
potential function is shown in Fig 9.2 and is described as:
0 for 0  x  L
V (x)   (9.19)
V=0  x  0 and x  L
The “particle in a box” problem is also called the “infinite potential well” or the
x=0 x=L “infinite square well potential” problem. A simple classical analogue of this
Fig. 9.2: Potential system could be a ball bouncing elastically between two rigid walls (Fig. 9.3).
function for a one- Inside the box, the particle is “free” because the potential, and hence, the
dimensional box force on the particle is zero. As the particle bounces back and forth, its speed
and kinetic energy remain constant. In the classical picture, the particle could
have any speed inside the box, and any kinetic energy. Let us now solve the
v
the Schrödinger equation for this potential and determine the eigen functions
and eigen values of the Hamiltonian operator for this system.
v
9.3.1 Solving the Schrödinger Equation
For the (free) particle inside the box, V  0 . The Schrödinger equation for the
x stationary state wave function (x ) is:
Fig. 9.3: A ball going
back and forth between  2 d 2( x )
  E( x ) for 0  x  L (9.20)
rigid walls. 2m dx 2
Since the walls of the box cannot be penetrated, the particle cannot be found
beyond the walls (that is in the regions x  0 and x  L ). So, the quantum
mechanical probability of finding the particle in the region beyond the box,
should be zero. Therefore ( x )  0 for x  0 and x  L . Further, the wave
functions for a physical system are always single-valued and continuous. To
satisfy this condition, (x ) should also be zero at the boundaries of the box,
i.e. at x  0 and x  L . So, we can write the boundary conditions for the
wave function (x ) as:
( x  0)  ( x  L)  0 (9.21)
With these boundary conditions, we now solve Eq. (9.20). We put

2mE
k 2  2 in Eq. (9.20) and get the following second order ODE:

d 2 ( x )
2
 k 2 ( x )  0 (9.22)
dx
You have solved this equation in Sec. 9.2 (Eq. 9.8). From SAQ 2 you know
that ( x )  sin kx and ( x )  cos kx are both solutions of this equation. So we
14 can write the general solution for Eq. (9.22) as:
( x )  A sin kx  B cos kx (9.23)
To represent the particle in the box, this wave function must satisfy the
boundary conditions given in Eq. (9.21). So, we now impose these conditions
on the wave function (x ) of Eq. (9.23).
( x  0)  0  A sin k (0)  B cos k(0)  0 or B  0 (9.24)
With B  0 , the expression for the wave function of Eq. (9.23) becomes
( x )  A sin kx (9.25)
Applying the boundary condition on the wave function at x  L , we get:

( x  L)  0  A sin k (L)  0 (9.26)
Clearly, A  0 , because if it were, the wave function (x ) would be zero at all
2
In general, for
values of x and the probability density ( P ( x, t )  ( x ) ) for finding the particle sin x  0  x  n
at any position x would also be zero. This is an unphysical solution and where n  0,1,2,3...
cannot be considered. In Eq. (9.26), since A  0 , we must have (read the However the wave
function for a negative
margin remark ):
value of n is not linearly
sin k (L)  0  kL  n , n  0,1,2,3.... (9.27) independent of the wave
function for the positive
For n  0 , k would be equal to zero and hence, (x ) would be zero at all value of n. For example
values of x, once again an unphysical solution. So we discard the value for n=1:
 x 
of n  0 in Eq. (9.27) and write the possible values of k, which satisfy the 1( x )  A sin 
 L 
boundary conditions as:
And for n=1
n  x 
k , with n  1,2,3.... (9.28)  1( x )  A sin  
L  L 
So,
Notice from Eq. (9.28) that the all values of k are not permitted. k can have  1( x )  1( x )
only the following discrete or “quantized” values: So we can consider only
one of these solutions,
 2 3 
k , , ........ either n=1 or n=1. And
L L L so on for all values of n.
Therefore, we write k with a subscript n to denote the value of n:
n
kn  , with n  1,2,3.... (9.29)
L
We can now write down the possible stationary state solutions for this system
(which are the eigen functions) and determine the corresponding energy eigen
values.
9.3.2 Eigen functions and Eigen values

On substituting the value of kn in Eq. (9.25) we can write the stationary state
wave function as:
 nx 
 n ( x )  A sin kn x  A sin  , 0  x  L and n  1,2,3.... (9.30)
 L 
15
n
The subscript n once again indicates the value of k  kn  in the wave
L
function. As you can see, for each value of n we get a different wave function.
Each of these functions 1( x ), 2( x ),... is an eigen function of the Hamiltonian
operator for the particle in a box. What are the corresponding eigen energies
En?
We determine the energy eigen value En from the Schrödinger equation for
the eigen function n (x ) :
 2 d 2 n ( x )
  En  n ( x ) (9.31)
2m dx 2
 nx 
Since  n ( x )  A sin , we get
 L 
d n ( x )  n   nx 
 A  cos 
dx  L   L 
and
2 2
d 2 n ( x )  n   nx   n 
  A  sin      n ( x )
dx 2  L   L   L 
On substituting the second order derivative in Eq. (9.31), we get:
 2   n  
2
n 2 2 2
     n ( x )  E n  n ( x )  E n  (9.32)
2m   L   2mL2
Fig. 9.4: The energy levels So the energy eigen values for the quantum mechanical particle in the box
for a particle in a one- are:
dimensional box. The
ground state energy is E1.  2k n 2 n 2 2 2
En   with n  1,2,3.... (9.33)
2mL2 2mL2
As you can see, the particle can have only certain discrete values of energy.
In general, if we have a
bounded system, or in The energy spectrum is no longer continuous.
the terms of classical
From Eq. (9.33) we can write for n=1:
mechanics, if the motion
is confined to a finite
 2k n 2 2 2
region of space, solving E1   (9.34)
the corresponding 2mL2 2mL2
Schrödinger equation will
give us a discrete energy And therefore
spectrum.
En  n2E1 (9.35)
It is important to note the following properties of the energy eigen values of a

particle in a box:
1. Now that when the particle has been confined to a box, you no longer
have a continuous energy spectrum. Its energy can take only the
discrete values given by Eq. (9.33) and shown in Fig. 9.4. This is in
16
contrast to the classical picture in which all finite values of the energy
( E  0 ) are allowed.
2. The quantization of energy follows from the boundary conditions

imposed on the wave function due to the confinement of the particle.
3. The minimum energy of the particle in the box is not zero but has a
2 2
finite value: E1  . So in the quantum mechanical system, the
2mL2
particle can never be at rest. This is in keeping with the uncertainty
principle and the concept of zero point energy that you have studied in
Unit 6. E1 is the zero point energy for this system.
Notice that the wave function defined by Eq. (9.30) is not normalized. Let us
now determine the normalization constant A in the following example.
XAMPLE 9.2 : NORMALIZING THE WAVE FUNCTION

Determine the normalization constant A for the following eigen function of a
2  nx 
L
particle confined in a box of length L:  sin   dx
0  L 
 nx  1 L 2nx 
 n ( x )  A sin k n x  A sin , 0 x L   1  cos dx
 L  2 0 L 
L
SOLUTION  We use the normalization condition given by Eq. (7.50) with 1 L 2nx 
  x sin
2 2n L  0
 nx 
 n * ( x )  A * sin  . We can write the normalization condition as: 
L
 L  2
L L
 nx   nx  2  nx 
 
2
A * sin  A sin  dx  1  A sin   dx  1
0
 L   L  0
 L 
On evaluating the integral we get (see the margin remark):
2 L  2
A    1 A 
2 L
Substituting the value of A from Example 9.2 into Eq. (9.30), we can write the
eigen function  n (x ) for a particle confined in a line segment of length L as:
2  nx 
n (x)  sin  with n  1,2,3.... (9.36)
L  L 
The corresponding energy eigen values are given by Eq. (9.33). Let us write
down the eigen functions and energy eigen values for the first three states of
the system (n = 1, 2 and 3 respectively):
2  x   2 2
1( x )  sin ; E1  (9.37a)
L  L  2mL2
2  2x  2 2 2
2 ( x )  sin ; E2   4E1 (9.37b)
L  L  mL2 17
2  3x  9  2 2
3 ( x )  sin  3
; E   9E1 (9.37c)
L  L  2mL2
These eigen functions are shown in Fig. 9.5.
3(x)
2(x)
1(x)
x
x=0 x=L
Fig: 9.5 : The first three eigen functions for a particle in a box.
You can see that each of the eigen functions has a node (a point where the
wave function goes to zero) at x  0 and x  L . The number of nodes in the
eigen function increases with the value of n. The eigen functions
corresponding to different eigen values are orthogonal, as you can check for
yourself in the next SAQ.
SAQ 3- Orthogonal eigen functions
Show that the eigen functions for the particle in a box are orthogonal.
So how do we reconcile the quantum mechanical picture with our experiences

in the macroscopic world? By working through the following Example you will
get an idea of value of the zero point energy of a typical macroscopic object.
XAMPLE 9.3 : MACROSCOPIC OBJECT AS PARTICLE

IN A BOX
A toy car of mass 0.2 kg is moving back and forth on a track 1.0 m long.
Treating the car as a particle in a box, what would be the minimum energy
of this car? Suppose it moves with a constant speed of 0.1ms-1, what is the
value of n, corresponding to this speed.
18
SOLUTION  Assuming the toy car to be a particle of mass m = 0.2 kg

confined to a region of length L = 1.0 m, can say that its energy is (Eq.
9.33):
n 2 2  2
En   2.5n222 J (i)
20.2 kg  1.0 m
2
The minimum energy is the zero point energy:

E1  2.52 2  2.5  ( ) 2  1.054  10 34 
2
J  2.7  10 67 J
The kinetic energy of the car is
K
1
2 2
2

mv 2   0.2 kg  0.1ms 1  1.0  103 J
1
 (ii)
We calculate the value of n for which the energy of the bound state would
be equal to the kinetic energy of the car. So using :
K  En  1.0  10 3 J  n 2E1 and substituting for E1 we get:
1.0  10 3 J
n2   n  6  1031
 67
2.7  10 J
So the minimum energy of the car is too small to be measured, and we can
take it to be zero. Also the energy of the classical particle is characterized by
an extremely large quantum number. As you have studied in Sec. (4.6.3), the
Correspondence principle tells us that we need not use the quantum
formalism for such large quantum numbers. We can use Newtonian
mechanics. If n is small, on the other hand, we cannot use classical
mechanics.
Unlike for the free
The integer n that is used to index the eigen functions  n (x ) and the energy particle, for the particle in
eigen values En is called the “energy quantum number” or the “principle a box, the eigen
quantum number”. As you can see in Fig. 9.4, corresponding to any allowed functions of the
value of n you have a discrete eigen energy (level) . The state 1( x ) is the Hamiltonian operator are
not the simultaneous
ground state eigenfunction and E1 , the ground state energy. The state
eigen functions of the
 2 ( x ) is the first excited state and E2 , the energy of the first excited state. momentum operator,
The state 3 ( x ) is the second excited state and E3 , the energy of the second which is why we call n
excited state. You can think that these energy states are like the energy the energy quantum
number. You will see
levels in an atom. Suppose a particle “occupies” the energy state (or energy
this for yourself in
level) E1 . On being given an energy ( E2  E1 ), it can move into the first
Terminal Question 8.
excited state E2 . On the other hand, if the particle occupies the first excited
state E2 , it can emit an energy ( E2  E1 ) and move to the ground state E1 .
Note from Eq. (9.33) that the eigen energy values depend upon the size of
the box, L and the mass of the particle m. The energy difference between the
corresponding energy levels also depends on L and m. The energy difference
between the nth and (n+1)th energy levels is:
19
E  E n 1  E n 
2 2
2mL2
( n 1) 2
 n 
2
 ( 2n  1)
2 2
2mL2
(9.38)
What does eq. (9.38) tell us? Smaller the region in which a particle is
confined (L), the larger is the difference in energy (E) between the
consecutive energy levels. Conversely, as L increases, the energy separation
decreases. When L is much larger than atomic dimensions, the energy
separation is so small that we approach the classical correspondence limit.
Note that for large L, the zero point energy also tends towards zero, as you
have seen in Example 9.3.
In fact in the limit when mL2 becomes much larger than h2 ( mL2   2 ), which
is typically true for everyday macroscopic objects, the spacing between the
energy levels keeps getting smaller. So the energy of a classical particle in a
box will vary continuously and quantum effects will not be visible.
Let us now try to model the electron in an atom like a particle in a box.
XAMPLE 9.4: ELECTRON IN AN ATOMIC BOX
Calculate the energy levels of an electron confined to an atomic box of size

1.0 Å.
SOLUTION  The energy levels for the electron are calculated using Eq.
(9.33) with L  1.0 Å  1.0  10 10 m . Now,
n 2 2 2 n 2h 2
En   , n = 1, 2, 3,…
2 meL2 8meL2
For n=1:
E1 
12 h2
 
6.626  10 Js
h2  34 2
8meL2 8meL2 89.109  10 kg  1.0  10 

 31 10 2
m
 0.602  10 17 J  38 eV
So the remaining energy levels are:
E n  n 2E1  38n 2 eV
9.3.3 Time Dependent Wave Function

The complete time dependent wave function  n ( x, t ) corresponding to  n (x )
is
2  nx  iEnt
 n ( x, t )  sin e

(9.39)
L  L 
Using Euler’s Formula, we can write:

20
sink n x  
2i
e 
1 ikn x
 e ik n x  (9.40)
n
where k n  , and En  n . Then we get:
L
 n ( x, t ) 
1
2i L
e
2 i kn x  nt 
 e  i kn x  nt   (9.41)
This is the superposition of two travelling waves having the same frequency
and amplitude. The first term in Eq. (9.40) represents the wave travelling
along the positive x-direction. The second term is for the wave travelling in the
negative x-direction, which is the second term. This is similar to the standing
wave solutions of a vibrating string fixed at both ends.
We next determine the probability density corresponding to these eigen

functions.
9.3.4 Probability Density

The probability density for a stationary state is time independent and we can
write for the nth eigen state:
2 2  nx 
Pn ( x, t )  Pn ( x )   n ( x )  sin2   (9.42)
L  L 
From Eq. (9.42), you can see that Pn (x ) depends on the position of the
particle in the box. In Fig. 9.6 below, we have plotted the values of Pn (x )
corresponding to first three eigen functions of the system (for n=1, 2, 3).
The probability of finding the particle is maximum around the maxima (humps)
of the probability distribution and is zero at the nodes. So the probability of
finding the particle in any finite region of the box also changes with the eigen
function.
P3 ( x )
P2 ( x )
P1( x )
x
x=0 x=L
2
Fig: 9.6: The probability density (  n (x ) ) as a function of position for the first
three eigen functions of a particle in a box.
21
To understand, let us work through the following example.
XAMPLE 9.5 : CALCULATING THE PROBABILITY
Calculate the probability of finding the particle between
(i) x  L / 4 and x  3L / 4 , and
(ii) x  0 and x  L / 4
when the particle is in the ground state.
SOLUTION  We use Eq. (7.15) to calculate the probability of finding the

particle between two points x1 and x2 .
x
(i) With x    * x  
2
sin for the ground state, x1  L 4 and
L L
x2  3L 4 in Eq.(7.15) we calculate the probability as:
3L / 4 2
 2 x   1
3L / 4
 2x 
P 

 L
sin
L  
dx    
 L  L/4 
1  cos
L 
 dx
L/4 
3L / 4
1 L 2x 
  x sin
L 2 L L / 4
1  3L L  L 2  3L  L 2  L  
    sin    sin  
L  4 4  2 L  4  2 L  4 
1 L L 3 L  L 1 2  1 1
  sin  sin      
L  2 2 2 2 2  L  2 2   2  
x
(ii) For x    * x  
2
sin , x1  0 and x2  L 4 the probability is:
L L
L/4 2
 2 x  1 L 2x 
L/4
P 
 L
sin  dx   x 
L  L 2
sin
L  0
0 
1 L L 2  L   1  L L  1 1 
   sin          
L  4 2 L  4   L  4 2   4 2 
You may now like to work out an SAQ on calculating the probability.
SAQ 4- Calculating Probability

Calculate the probability of finding the particle between x  L / 4 and x  3L / 4 ,
when the particle is in the first excited state.
22
Let us compare this with the classical picture. Classically, the particle bounces
back and forth between the walls. Since the kinetic energy of the particle is
constant, it moves at a constant speed between collisions with the walls.
Therefore, it spends the same amount of time in all intervals which have an
equal length. So the normalized probability per unit distance, of the particle
being found anywhere in the box is just 1/L which is independent of the
position of the particle. This is clearly not the case for the quantum mechanical
particle. However, when n is very large the wave function begins to have so
many nodes and humps that in the limit as n   each position of the particle
is equally probable. Then the quantum mechanical probability distribution
begins to look like the classical distribution.
For a large value of n, you would observe only the average value of the
probability density which is
2  nx  2  1 1
Pn ( x, t )  sin2      (9.43)
L  L  L 2 L
(This is because the average of the square of the sine function over one or
more cycles is always half.)
Let us now summarize what you have studied about the particle in a box.
PARTICLE IN A ONE-DIMENSIONAL BOX
 A particle is confined within a length segment lying between x = 0

and x = L by the following potential function(infinite potential well):
0 for 0  x  L
V (x)   (9.19)
 x  0 and x  L
 The time independent Schrödinger equation for the particle is:
 2 d 2( x )
  E( x ) for 0  x  L (9.20)
2m dx 2
 The boundary conditions to be satisfied by the wave function are:

( x  0)  ( x  L)  0 (9.21)
 The normalized eigen functions of the Hamiltonian are
2  nx 
n ( x )  sin  , 0  x  L for n  1,2,3.... (9.30)
L  L 
 The corresponding energy eigen values are:
n 2 2 2
En  with n  1,2,3.... (9.33)
2mL2
 n is called the energy quantum number.

23
PARTICLE IN A ONE-DIMENSIONAL BOX (Contd.)
 The energy of a particle bound inside an infinite potential well can

have only discrete values.
2 2
 The minimum energy of the particle is not zero, it is E1  .
2mL2
 The complete time dependent wave function  n ( x, t ) corresponding

to  n (x ) is
 n ( x, t )  sin e

(9.36)
L  L 
 The eigen functions of the system are orthogonal.
Our understanding of the way charge carriers behave in materials is also an

application of quantum mechanics. Solving the Schrödinger equation using
the exact potentials experienced by the charge carriers is very complicated.
However, it is often possible to understand the observed phenomena using
simple models of the potential which are easier to solve.
Some of you may have read( or you can read now) popular science articles
about “nano” sized materials like quantum wells, quantum wires and quantum
dots and how they have exciting applications, mainly because they exhibit
quantum effects. In the next section we study about quantum dots. We can
understand the special properties of a quantum dot by modelling a charge
carrier inside the quantum dot as a particle in a box.
9.4 Quantum Dot

Quantum dots (sometimes called artificial atoms) are typically semiconductor
(or metal) particles with sizes ranging from 1 to 100 nm. Their properties are
very different from the bulk properties of the materials of which they are made
and depend on the size of the particle.
You have all studied about conductors, insulators and semiconductors in your
school physics courses. As you have studied in Bohr’s atomic model, in an
isolated atom, the electrons occupy discrete energy levels. Whereas in bulk
materials made up of several atoms, we have continuous energy bands which
are collections of available energy states and energy gaps between these
bands.
The quantum dot is a very tiny object. Therefore, the charge carriers inside
the dot are confined within a very small region, very much like a particle in a
rigid box. The simplest approximation for a quantum dot is an infinite potential
24
well where all the charge carriers are confined. So like a particle in a box ( or
an electron in an atom) , the charge carriers in the quantum occupy discrete
energy levels.
While in a bulk semiconductor material you would have energy bands, in a

quantum dot made out of the same material, the energy bands are replaced
by discrete energy levels, as shown in Fig 9.7.
Conduction
Band
Energy
Band Gap
Levels
Valence
Band
(a) (b)
Fig. 9.7: Energy levels of (a) a bulk semiconductor and (b) a quantum dot of
the same semiconductor.
Absorption and emission of light by these quantum dots (as in any atom or
molecule) takes place by the transition of charge carriers between these
energy levels. Ideally you should
think of an electron in a
Suppose an electron occupying the energy state j in a quantum dot of size D quantum dot as an
make a transition to state i. Let us assume that the quantum dot is a one- electron confined in a
dimensional rigid box of size D (read the margin remark). Using Eq. (9.33) for three dimensional box.
the energy of the electron, we can write the expression for the energy emitted To understand the
in this transition as: physical properties,
here we assume it to
j 2 2 2 i 2 2 2  2 2
E ji  E j  Ei    ( j2  i2) (9.44) be a one-dimensional
2meD 2 2meD 2 2me * D 2 box.
This energy difference depends on the size of the dot D. If D increases, other
parameters remaining the same, the value of E ji decreases. This is
depicted in Fig. 9.8 below.
Eji
j
i Eji
L1 L2
(a) (b)
Fig. 9.8: Energy level variation with size. For a box of size (a) L1 and (b) L2 with
 25
L1  L2 , the difference between the energy levels E ji  E ji .
This energy difference is emitted from the dot as a photon of light. What is the
wavelength of this photon? If the frequency of the emitted photon is  and  its
wavelength (   c  ), then:
Notice that for the
electron in the
hc  2 2
semiconductor quantum E ji  h   ( j2  i2) 
(9.45)
dot we are writing the  2me D 2
mass of the electron as
me* and not me. This is So the wavelength of the emitted photon is directly proportional to the size of
because in a the dot D. As the size of the dot increases, the wavelength of the emitted
semiconductor, the photon also increases. As D increases, even though the material of the dot
electron has an effective may remain the same, the wavelength of the emitted lights changes from the

mass me (which is blue towards the red end of the visible spectrum! So by tuning the size of the
much less than the free quantum dot in the process of preparation, you can obtain a specific
electron mass me ) wavelength of the emitted light.
which decides to a large
extent how the electron A real quantum dot is definitely more complicated than what we have
behaves inside a described here. However as you can see it is possible to understand certain
semiconductor! It is salient features of light emission from QDs using the particle in a box model. A
because of this that the more realistic estimate of the numbers is obtained by considering the
de Broglie wavelength in
confinement of an “electron-hole” pair also called an “exciton” inside a
a semiconductor is
typically of the order of spherical quantum dot.
nanometers, and not
Several other applications of the quantum dot are also related to the fact that
angstroms as for a
conduction electron in a its energy levels can be tuned by its size. Quantum dots are used in single-
metal. electron transistors, solar cells, LEDs, lasers, single-photon sources, cell
biology research, microscopy, and medical imaging.
QUANTUM DOT
 Quantum dots (sometimes called artificial atoms) are typically

semiconductor (or metal) particles with sizes ranging from 1 to 100
nm with properties that are vastly different from the bulk material of
which they are made and depend on the size of the particle.
 The simplest approximation for a quantum dot is an infinite potential

well where all the charge carriers are confined to a region and
occupy discrete energy levels, like electrons in a atom.
 A change in the size of the dot changes the spacing between the
energy levels. This changes the energy released in the transition of
the electron between the energy levels. So the wavelength of the
light emitted by the quantum dot changes with the size of the dot.
Now we will summarize the concepts you have studied in this Unit.
9.5 SUMMARY
26
Concept Description
Free Particle  The time independent Schrödinger equation for a quantum mechanical
free particle of mass m is:
 2 d 2( x )
  E( x )
2m dx 2
The general solution of Eq. (9.4) is:
2mE
( x )  Aeikx  Beikx ; with k 2 
2
The quantum number k is real and the free particle can have any non-
negative value of energy:
 2k 2
E 0
2m
The energy of the particle does not change with time.
The time dependent wave function for the free particle with an energy
E   is:
( x, t )  Aei kxt   Bei kxt 
Particle in a one-  A particle is confined within a length segment lying between x = 0 and
dimensional box x = L by the following potential function(infinite potential well):
0 for 0  x  L
V (x)  
 x  0 and x  L
The time independent Schrödinger equation for the particle is:
 2 d 2 ( x )
  E( x ) for 0  x  L
2m dx 2
The boundary conditions to be satisfied by the wave function are:

( x  0)  ( x  L)  0
The normalized eigen functions of the Hamiltonian are
2  nx 
n ( x )  sin  , 0  x  L for n  1,2,3....
L  L 
The corresponding energy eigen values are:
n 2 2 2
En  with n  1,2,3....
2mL2
n is called the energy quantum number.
The energy of a particle bound inside an infinite potential well can

have only discrete values. 27
2 2
The minimum energy of the particle is not zero, it is E1  .
2mL2
The complete time dependent wave function  n ( x, t ) corresponding to

 n (x ) is
 n ( x, t )  sin e

L  L 
The eigen functions of the system are orthogonal.
Quantum dot  Quantum dots (sometimes called artificial atoms) are typically
semiconductor (or metal) particles with sizes ranging from 1 to 100 nm
with properties that are vastly different from the bulk material of which
they are made and depend on the size of the particle.
The simplest approximation for a quantum dot is an infinite potential

well where all the charge carriers are confined to a region and occupy
discrete energy levels, like electrons in an atom.
A change in the size of the dot changes the spacing between the
energy levels. This changes the energy released in the transition of the
electron between the energy levels. So the wavelength of the light
emitted by the quantum dot changes with the size of the dot.
9. 6 TERMINAL QUESTIONS
1. A free quantum mechanical particle has a wave function given by
( x, t )  Aei ( k0 x 0t ) , k0  4.0  1011 m-1 and 0  5.0  1015 s-1. Determine
its momentum and energy.

2. Determine the eigen value of the operator Hˆ  i for the free particle
t
wave function ( x, t )  Ae i kx  t  .
3. Let us model the proton in an atomic nucleus as a particle in a box.

Suppose the proton is confined to a box of size 2.0 10-14 m( size of a
nucleus). Calculate the frequency of the emitted photon if the proton
makes a transition from the first excited state to the ground state.
4. Suppose an electron confined to a box emits photons. The longest

wavelength that is registered is 400.0 nm. What is the width of the box?
5. The wave function of a particle of mass m inside an infinite square well of

width 2a (  a  x  a ) is given by:
 3x   3x 
( x )  A cos   B sin 
 2a   2a 
28
Obtain the values of A and B and the eigen energy corresponding to the
above eigen function.
6. A particle in a one-dimension box has an energy of 10 eV in its first

excited state. Calculate its ground state energy and the energy in the
second excited state.
7. Calculate the expectation value of p 2 for the wave function

( x, t )  Ae i kx  t  .
8. Show that the eigen functions  n (x ) are not the eigen functions of the
momentum operator.
2  nx 
9. For the stationary state  n ( x )  sin  show that
L  L 
i)  pˆ x  0
n 2 2  2
ii)  pˆ x 2 
L2
9.7 SOLUTIONS AND ANSWERS

Self-Assessment Questions
d 2
1. We use Eq. (9.4) with   Ae ikx  Be ikx . We first evaluate :
dx 2
d

dx dx
d

Aeikx  Beikx  ik Aeikx  Be  ikx  
d 2
dx 2

d
dx
   
ik Ae ikx  Be ikx  ik 2 Ae ikx  Be ikx  k 2( x )
d 2
Substituting  k 2( x ) in Eq.(9.4) we get,
2
dx
 d   2k 2
2 2
 2k 2
  x   Ex   E 
2m dx 2m 2m
2. (i) To show that x   sin kx is solution of Eq. (9.4), we have to show:
2 d 2 2 2
 sin kx   E sin kx with E   k (i)
2m dx 2m
We have
d2
sin kx   d  d sin kx   k d  cos kx   k 2 sin kx (ii)
dx 2 dx  dx  dx
d2
Substituting for sin kx  from Eq. (ii) into the LHS of Eq. (i) we see
dx
that:
29
   2k 2 

2 2 2
  sin kx  E   k
  k 2 sin kx  
2m  2m  2m
 
So Eq. (i) is true for x   sin kx .
ii) To show x   cos kx is a solution of Eq. (9.4), we have to

2 d 2 2 2
show:  cos kx   E cos kx where E   k (iii)
2m dx 2m
d2
Since cos kx   k 2 cos kx , we get:
dx 2
2
 
  2k 2  2 2
 .  k 2 cos kx    cos kx  E   k
2m  2m  2m
 
So Eq. (iii) is true for x   cos kx .
3. For any two eigen functions n x  and m (x ) to be orthogonal we must

show that
L
  n x   m ( x ) dx  0 when m  n
0
2 sin A sin B
Substituting for n x  and m (x ) in this integral we get:
 cos(A  B )  cos(A  B ) L
 2  nx   2  mx  2
L
 nx   mx 

 L
sin
 L
 
   L
sin
 L

 
dx 
L
sin 
 L
 sin 
 
 L
 dx

0   0
1 
L
n  m x  cos n  m x  dx

L 
cos
L L 

(see the margin remark)
0
1
 
L n  m  x  L sin n  m  x  L
sin 
L  n  m   L n  m   L 0
 0 ( because m and n are integers sinn  m  sinn  m   0 )
4. To calculate the probability for the first excited state we use Eq. (7.15) with
2x
 x    * ( x ) 
2
sin , x1  L 4 and x2  3L 4 . So the probability is:
L L
2
3L / 4
 2 2x  1 3L / 4  4x 
P   
 L

sin
L  
dx   1  cos
L L/4  L 
dX
L/4
1  3L L  L 4  3L  L 4  L 
       
L  4 
sin sin
L  4 4  4 L  4  4
1 L L L  1
   sin 3  sin  
L  2 4 4  2
30
Terminal Questions
1. Using Eq. (5.3) we can write
  
p  k  1.054  10  34 Js  4.0  1011 m 1  4.2  10 23 kg ms 1

E    1.054  10 34 Js 5.0  10 5

s 1  5.3  10 19 J

2. The eigenvalue of Hˆ  i  is determined using Eq. (8.35). With Dˆ  Hˆ
t
we can write:
Ĥ  E (i)
Calculating the derivative, we get:
i

t
 
Aei kx  t   i  i Aei kx  t     (ii)
Substituting for Ĥ in Eq. (i) we get
    E (iii)
So the eigenvalue of Ĥ is  .
3. The ground state of the proton in the nucleus is calculated with n = 1,

mass of the proton is m p  1.673  10 27 kg and L  2.0  10 14 m :
E1 
h2

6.626  10 Js
34 2
8 m p L2 8  1.673  10 kg  2.0  10 
27 14 2
m
 0.82  10 13 J  0.51MeV
The first excited state: E 2  n 2E1  4   0.51MeV  2.1MeV
When there is a transition from E2  E1, the emitted photon has an

energy: E ph  E 2  E1  2.1  0.51MeV  1.6 MeV
The frequency of the photon is,
E ph 1.6  1.6  10 J  0.39  1021Hz

13

h

6.626  10 Js
 34
4. The longest wavelength will correspond to the minimum energy

hc
difference, because E  h  . The energy difference, E , defined in

Eq. (9.38) will be minimum for the lowest value of n which is n=1.
Substituting n  1 in Eq. (9.38) we can write:
32 2 3h 2
Emin   (i)
2meL2 8meL2
hc
Using E  in Eq. (i) we get

31
hc 3h 2  3h 
 or L2    (ii)
 8me L2  8mec 
So the size of the box, L, with   400 nm  4.0 10 7 m is:
 
 3  6.626  10  34 Js  4.0  10  7 m   1/ 2
L
  
 8  9.109  10  31 kg  3.0  108 m s 1  
9
 0.60  10 m  0.60 nm .
5. We have the following boundary conditions to be satisfied at the

boundaries of the potential well: ( x  a)  ( x  a)  0 . Using
( x  a)  0 we get:
 3a   3a   3   3 
(a )  A cos   B sin   0  A cos   B sin   B  0
 2a   2a   2   2 
So the wave function is:
 3x 
( x )  A cos 
 2a 
a
2  3x 
 cos  2a  dx Using the normalization condition of Eq. (7.50) we can get:
a
a a
1 a  3x   3x   3x  2  3x 
 
2
  1  cos dx A * cos  A cos  dx  1  A cos   dx  1
2 a  a   2a   2a   2a 
a a
a
1 a 3x 
  x sin
a   a
2 3
On evaluating the integral we get (see the margin remark):
a
A
2
a   1  A  1
a
Since V(x) is zero inside the well, the Schrödinger equation is:
 2 d 2 ( x )
  E( x ) (i)
2m dx 2
 3x 
With ( x )  A cos  we get:
 2a 
2 d 2   3x   2 d   3   3x 
        A  sin 
2m dx   2a   2a 
A cos
2m dx 2   2a 
2
 2   3   3x   2  3  
2 2
 3x 
  A  cos      A cos 
2m   2a   2a  2m  2a    2a 

92 2
 ( x )
8ma2
On comparing with Eq. (i) we get the energy eigen value as:
9 2  2
E
8ma 2
32
6. From Eq. (9.35) we know that En  n 2 E1 . n = 2 corresponds to the first
excited state and E1 is the ground state. So,
 
E 2  10 eV  22 E1  E1  2.5 eV
 The second excited state is E3, with n = 3 in Eq. (9.35). So:
E3  3 3 E1  9  2.5 eV  22.5 eV
7. Using Eq.(8.26), we can write for an unnormalized wave function x  :

*
pˆ  dx
2
x
pˆ x2    (i)

   dx
*

d d 2
` pˆ x  i   pˆ x2   2 (ii)
dx dx 2
And :
d 2 d  d
2
 
dx  dx

Aei kxt   
d

ik Aei kx  t   k 2 Aei kx t  
dx  dx
   (k )Ae  dx


 Ae
 i kx  t  * 2 2 i kx  t 
 p x2  

 Ae  Ae  dx

 i kx  t  * i kx  t 


*  i kx  t 
A e Aei kx  t dx
  2k 2 

 2k 2
*  i kx  t 
A e Aei kx  t dx

8. For n x  to be an eigen function of pˆ x , we have to show (Eq. 8.35) :
pˆ x n x   n x  (i)
2 nx
Using  n ( x )  sin in Eq. (i), we get :
L L
d  2 nx 
pˆ x  n x   i   n x   i 
d
sin
dx dx  L L 
2  n nx  2 nx
 i   cos   in 3 cos (ii)
L  L L  L L
Since we cannot write pˆ x  n x  as  n x  , n x  is not an eigen

function of the momentum operator.
33
9. Since n x  is the normalized wave function we use Eq. (8.26 ) and
nx
 n * x    n x  
2
sin to calculate the expectation values.
L L
L
 2 nx   2 nx 
(i) px   
 L

sin

pˆ x
L   L 
sin
L 
dx
0
As calculated in Eq. (ii) of Terminal Question 7,
nx
pˆ x  n x   in
2
cos
3 L
L
L L
2in nx nx in 2nx
 px  
L2 0
 sin
L
cos
L
dx  
L2 
sin
L
dx
0
L
i n  L   2nx 
   cos
2  2n    
i
cos 2n  cos 0  0
L L  0 2L
 px  0
L
L
2  nx  (ii) px2   *n x  pˆ x2  n x  dx

 sin   dx
 L  0
0
 2 n nx 

1 L
 1  cos
2nx 
dx pˆ x2 n x   pˆ x pˆ x  n x   pˆ x  i . cos 
2 0 L   L L L 
L (using the results of Terminal Question 7)
1 L nx 
  x sin 2
2n L  0 in 2  nx   n  nx
 i 2  
2 d 2
   i cos  sin
L L L dx L   L  L L

2 2 L
 n   2   nx 
So px2   2     sin2 
   0
L L  L  
 dx (see the margin remark)
2 2n 2 2  L   2n 2 2
  
L3 2 L2
34
Unit 10 Step Potential
E
p
n
UNIT 10
For a p-n junction in forward bias, the
electrons in the n-type region in the
conduction band diffuse across the
potential barrier and find themselves
STEP
at a higher energy than the holes in
the p-type material. Combination of
POTENTIAL
holes and electrons may occur which
creates a continuous flow of current
through the junction.
Structure
10.1 Introduction
10.4 Energy (E) of the Particle is greater than V0
Expected Learning Outcomes
Reflection and Transmission Coefficients
10.2 Step Potential and Schrödinger Equation
10.5 Summary
10.3 Energy (E) of the particle is less than V0
10.6 Terminal Questions
Reflection and Transmission Coefficients
10.7 Solutions and Answers
STUDY GUIDE
In the previous unit you have learnt how to solve the time independent Schrödinger equation for a
particle in a box and obtained the energy eigenvalues for the problem. You have seen that the energy
levels of the particle in the box are discrete. This is contrary to the results of classical physics where the
energy of a system is continuous. In this unit, you will study the time independent Schrödinger equation
for a step potential and learn how to solve it. The method of solving it is similar to what you have studied
in Unit 9. Therefore, we advise you to revise Unit 9 before studying this unit. The mathematics in this
unit is similar and we have used a great deal of algebra with which you are familiar since school. Work
out all steps yourself and practice the SAQs and Terminal Questions to get a good grip of this unit.
“What quantum physics teaches us is that everything we

Bruce H. Lipton
thought was physical is not physical.”
35
10.1 INTRODUCTION
In the previous units, you have studied the time independent Schrödinger
equation of a free particle and a particle in a box. You have learnt how to
solve it to obtain the eigenfunctions and energy eigenvalues for these
systems.You have also learnt that a free particle has a continuous energy
spectrum but a particle in a box has discrete energy levels.
In this unit, you will learn how to solve the time independent Schrödinger
equation for a step potential. You will obtain the eigenfunctions and energy
levels for such a potential. You are familiar with steps all around you. So, you
can think of a step as a flat surface, which changes abruptly after a certain
distance so that another flat surface is obtained at a higher level.
Similarly, the step potential changes abruptly, much like a single physical step.
So, a step potential has an abrupt increase or decrease in its value. In Sec.
10.2, we first define the step potential and write down the time independent
Schrödinger equation for a particle subjected to a step potential.
Then we take up two interesting cases: When the energy of the particle is less
than the height of the step potential (Sec. 10.2.1), and when it is greater
(Sec. 10.3). In both cases, we will get interesting results when we solve the
time independent Schrödinger equation for the step potential.
The step potential can be used to model a variety of physical systems and
some well known applications are seen in semiconductor devices, the physics
of normal-metal superconductor interfaces, and alpha decay in the nucleus.
Solving the step potential problem in this unit will also serve as a good
exercise for you to help you understand the next unit, where you will study
about the barrier potential.

After studying this unit, you should be able to:
 define a step potential;
 solve time independent Schrödinger equation for step potential under

given conditions;
 determine the reflection and transmission coefficients; and
 solve simple problems based on step potential.
10.2 STEP POTENTIAL AND SCHRÖDINGER

EQUATION
A step potential is shown in Fig. 10.1. You can see that we can define it
mathematically as:
 0, for x  0
V (x)   (10.1)
36  V0  0, for x  0
V(x)
V  V0
I II
V 0
0 x
Fig. 10.1: A step potential. Note that the potential is zero in Region I and it
has a non-zero value (V0 ) in Region II.
In Fig. 10.1, note that the step potential V (x ) is zero in the region x  0 and
non-zero (equal to V0 ) in the region x  0. Note also from Fig.10.1 that the
step potential is discontinuous at x  0.
You may like to ask: What does such a potential mean physically? To
understand this, and to get a physical picture of the potential, let us see what
happens to a particle subjected to the step potential.
Let us consider a particle of mass m having kinetic energy, E, and moving

from left to right along the x-axis as shown in Fig. 10.2.
(a) (b)
Fig. 10.2: Classical picture of a particle with energy (a) lower than the step
potential V0 and (b) higher than the step potential V0 .
Let us first ask: What would happen if the particle was a classical particle?
From classical mechanics, you know that if the energy (E) of the particle were
less than the step potential V0, that is, if E < V0, then the particle would not be
able to enter Region II from Region I (see Fig. 10.2a). A classical particle for
which E < V0, would be reflected at the step. However, if the energy of the
classical particle was greater than V0, it would be able to cross the step
potential and move into Region II (see Fig.10.2b).
Let us now ask: What would happen to a quantum particle subjected to this
potential? Refer to Fig. 10.3. Note that the particle is incident from Region I of
the step potential (V0 ). Note that in the Region I, the energy (E) of the particle
is purely kinetic energy, while in Region II, the energy is partly kinetic and
partly potential. Now recall from Unit 9, how quantum mechanics differs
fundamentally from classical physics. According to quantum mechanics, the
wave function of the particle has finite value in Region II, which means that
37
there is a finite probability of finding the particle in Region II even when the
particle has less energy than the potential! This is the result we get when we
solve the Schrödinger equation.
V (x )
V  V0
I II
(a)
E V 0
0 x
V (x )
V  V0
I II
(b)
E
V 0
0 x
Fig. 10.3: A particle with energy E is incident from Region I and subjected to a
step potential V0 at x  0. We consider two cases, a) when E < V0 ;
b) when E > V0 .
We now write the time independent Schrödinger equation for a particle in a

step potential defined by Eq. (10.1). Note that there are two regions, Region I
( x  0) in which the potential is zero and Region II ( x  0) in which it is V0.
So, we write the Schrödinger equation for a particle of mass m in the two
regions (see Fig. 10.3) as:
 2 d 21
  E 1 x 0 (10.2a)
2m dx 2
 2 d 2 2
  V0  2  E  2 x 0 (10.2b)
2m dx 2
We solve the Schrödinger equation for the two regions [Eqs. (10.2a and b)]
using the method you have learnt in Unit 9. We also have to apply the
boundary conditions to get acceptable wave functions. Note that we have
denoted the solutions of the Schrödinger equation in Regions I and II as 1
and 2 in Eqs. (102a and b). The boundary conditions for this problem are:
At x  0
1 ( x  0)  2 ( x  0) (10.3a)
 d1   d 
and     2 (10.3b)
 dx  x 0  dx  x 0
38
Now, there are two interesting possibilities regarding the energy of the particle
with respect to the step potential. The first case is when the energy of the
particles is less than the step potential V0 and the second, when it is greater.
Therefore, in Secs. 10.3 and 10.4, we will solve Eqs. (10.2a and b) for the
following two cases:
Case 1: The energy E of the particle is less that V0 (Fig. 10.3a)
Case 2: The energy E of the particle is greater than V0 (Fig. 10.3b)
10.3 ENERGY (E) OF THE PARTICLE IS LESS

THAN V0
Let us solve Eqs. (10.2a and b) for Regions I and II.
Region I:    x  0 for which V  0
Let 1( x ) be the solution of the Schrödinger equation for the particle in
Region I. Since the potential is zero in this region, the particle is free and the
corresponding time independent Schrödinger equation is:
  2 d 21
 E1 (10.4a)
2m dx 2
d 21 2mE
   1  0 (10.4b)
dx 2 2
d 21
  k121  0 (10.4c)
2
dx
2mE
where k1  (10.4d)
2
You know from Unit 9, [Eq. (9.10)], that the solution of Eq. (10.4c) is:
1 ( x )  A e ik1x  B e ik1x (10.5)
You know that, the term A e ik1x in Eq. (10.5) represents a wave of amplitude
A travelling in the positive x-direction while the term B e  ik1x represents a
wave with amplitude B travelling in the negative x-direction. The second term
in Eq. (10.5) is a wave reflected at the step potential (see Fig. 10.4).
Ae ik1x Be ik1x
I Ce x II V  V0
E
V 0
0
x
Fig. 10.4: The solutions [Eqs. (10.5 and 10.7)] of the Schrödinger equation for a
free particle in Regions I and II of the step potential. 39
So, the solution of Eq. (10.2a) is a linear combination of wave functions
representing an incident wave and a reflected wave.
Let us now solve Eq. (10.2b).
Region II:  0  x    for which V  V0
Let 2 ( x ) be the solution of the Schrödinger equation for the particle in

Region II. The time independent Schrödinger equation for Region II is given
as:
 2 d 2 2
  V0  2  E 2 (10.6a)
2m dx 2
d 2 2 2m
  (V0  E ) 2  0 (10.6b)
2
dx 2
2m(V0  E )
We put  (10.6c)
2
so that we can write Eq. (10.6b) as:
d 2 2
 2 2  0 (10.6d)
2
dx
The solution of Eq. (10.6d) is:
 2 ( x )  Ce x (10.7)
In Eq. (10.7), the term Cex represents an exponentially decreasing wave

function for positive values of x (Fig. 10.4). This means that the wave function
is finite in Region II of the step potential. Therefore, the probability of finding
the particle in Region II is finite. You know from Unit 4 of BPHCT 131 that the
general solution of Eq. (10.6d) is of the form  2 ( x )  Ce x  De x .
Can you say: Why have we not included the term Dex in Eq. (10.7)? Recall
what you have learnt in Units 7 and 9 about physically acceptable wave
functions.
You know that it is because the term Dex represents an exponentially

increasing wave function in the Region II. It is not physically meaningful since
an acceptable wave function must remain finite as x  . Thus, we must
have D  0.
Let us now put the solutions of the time independent Schrödinger equation for
the step potential defined by Eqs. (10.4c and Eq. 10.6d), at one place. The
solutions are:
1 ( x )  A e ik1x  B e ik1x for Region I: x < 0 (10.5)
40
 2 ( x )  Ce x for Region II: x > 0 (10.7)
The next step, as you know, is to apply the boundary conditions at x  0 to
determine the constants A, B and C. Applying the first boundary condition
[Eq. (10.3a)], we get:
AB C (10.8a)
Remember that A and B are the amplitudes of the incident wave and the
reflected wave in Region I and C represents the amplitude of a wave that
decreases exponentially in Region II. Applying the second boundary condition
[Eq. (10.3b)], we get:
 d1   d 2 
  
 dx   dx 
 Aik1  Bik1  C
i
 AB  C (10.8b)
k1
Let us now solve Eqs. (10.8a and b) to determine the constants A, B and C.
Adding Eqs. (10.8a and b), we get:
 i 
2 A  1  C
 k1 
 2k1 
 C    A (10.9a)
 k1  i 
Subtracting Eq. (10.8b) from Eq. (10.8a), we get:
 i   2k1 
2B  1  C  C   B
 k1   k1  i  (10.9b)
Equating the LHS of Eqs.(10.9a and 10.9b) we can write:
 k  i 
B   1  A (10.9c)
 k1  i 
Thus, we have obtained the constants B and C in terms of A. Let us now

interpret these results.
10.3.1 Reflection and Transmission Coefficients
Let us first ask: What is the incident probability density, i.e., the probability of
finding the particle in Region I? This is known as the incident probability
density.
From Unit 7, you know that the probability density in any region is defined as:
P ( x )   ( x ) ( x ) (10.10)
41
Note that from Eq. (10.5) that the wave function for the incident wave is
1 ( x )  A e ik1x . Therefore, the incident probability density is given as:
P1 ( x )  1 ( x ) 1 ( x )  ( Ae  ik1x )( Aeik1x )  A

2
We would now like you to calculate the reflected and transmitted probability
densities corresponding to the reflected and transmitted wave functions using
Eqs. (10.5 and 10.7). Try SAQ 1.
SAQ 1 - Reflected and transmitted probability densities
Determine the reflected and the transmitted probability densities for a step
potential.
Recall Eq. (7.31a) of Sec. 7.3.2 of Unit 7 from which the probability current
density is given by:
   d d  i   d d  
J     J     (10.11)
2mi  dx dx  2m  dx dx 
Substituting 1 ( x ) and 2 ( x ) in the Regions I and II, respectively, we obtain

the reflected and transmitted probability current densities, respectively. Let
J r be the probability current density of the reflected wave. Let us take up an
example to calculate it.
XAMPLE 10.1 : PROBABILITY CURRENT DENSITY Jr
What is the probability current density (Jr ) of the reflected wave?
SOLUTION  We use Eq. (10.11) to determine Jr .
i   d d  
Since J    
2m  dx dx 
Jr  

Be   
i   ik1x  d Be  ik1x  
 Be  ik1x 
d Be  ik1x  

2m  dx dx 
 
 Jr  
i 
2m
 k

B B( ik1)  BB(ik1)   1 BB
m
k1  k 2
Hence, Jr   B B 1B
m m
You can now calculate the incident probability current density corresponding
to the incident wave function using Eqs. (10.5 and 10.11). Try SAQ 2.
SAQ 2 - Incident probability current density
Determine the probability current density (Ji ) of the incident wave.

42
The reflection coefficient (R) is the probability that an incident particle is
reflected from the step potential at x=0. It is defined as the ratio of the
magnitudes of the probability current densities of the reflected wave and the
incident wave:
Jr
R (10.12)
Ji
The transmission coefficient (T) is the probability that the incident particle is
transmitted and is defined as the ratio o as the ratio of the magnitudes of the
probability current densities of the transmitted wave and the incident wave:
Jt
T  (10.13)
Ji
Using Eq. (10.12), we can determine the reflection coefficient for a step
potential for E  V0 :
2
B
R (10.14)
2
A
2  k  i  k1  i  2
From Eq. (10.9c), we can see that B   1   A which means
 k1  i  k1  i 
2 2
that B  A . Substituting this result in Eq. (10.14), we get R  1.
Since the incident wave is either reflected or transmitted without any

absorption, the sum of the reflection coefficient (R) and the transmission
coefficient (T) should be unity:
R T  1
Therefore, for R  1, we can see that the transmission coefficient is zero:
T  0
This result agrees with the predictions of classical physics that when a particle
possesses lower energy than the potential step, the particle cannot cross it!
However, from Eq. (10.7) you have learnt that there is a finite probability of
finding the particle in Region II since the wave function (2 ) in the region is
non-zero.
You have already encountered a similar problem when you were dealing with
bound state (particle in a box) where the wave function is non-zero in the
classically forbidden region. So, how do we reconcile the two seemingly
contradictory results?
In order to understand the result, it is important to remember how we have
defined the step potential. You are aware that the step potential is an idealized
potential and beyond x > 0, the potential (V0 ) may extend to infinite distance.
Hence, whatever is incident towards the barrier will eventually be reflected
and it is for this very reason that we got R  1. However, since the wave
function is non-zero in Region II [Eq. (10.7)], we can conclude that the particle
turns back eventually but before turning, it penetrates into classically forbidden
region. 43
Thus, from the above result we can conclude that:
1. The reflection of incident wave at the step potential is total when E  V0;
2. In the Region II, the wave function is non-zero. Therefore, there is a finite
probability (  2 ( x )  2 ( x )  C *Ce 2x ) of finding the particle in Region II;
3. The wave function penetrates into classically forbidden region, x > 0.

However, eventually it is completely reflected.
Let us explain the point 3 further.
Penetration in the Classically Forbidden Region
One of the most interesting outcomes of solving the Schrödinger equation for
the step potential is that the wave function in the Region II (x > 0) is non-zero.
This means that there is a finite probability of finding the particle in Region II
even if E  V0.
Note that according to classical mechanics, particles with energy

E  V0 cannot penetrate the step potential since it would lead to negative
kinetic energy.
According to classical physics, when the initial energy of the particle is less
than the height of the potential, the particle is reflected back with its original
speed. The quantum particle’s behaviour is in sharp contrast to the classical
result. There is a finite probability of finding the particle in Region II given by
Eq. (10.7). Let us now take up the case when the energy of the incident
particle is greater than the height of the step potential.
10.4 ENERGY (E) OF THE PARTICLE IS

GREATER THAN V0
The case when the energy of the particle is greater than the potential step
(E  V0 ) is shown in Fig. 10. 3b. Again, we solve Eqs. (10.2a and b) in
Regions I and II.
Region I:    x  0 for which V  0, the particle is free and the solutions

remain the same as in Sec. 10.2 and are given by Eqs. (10.4c and 10.5),
respectively.
Region II: For 0  x   , the time independent Schrödinger equation is

given as:
d 2 2 2m
 (E  V0 ) 2  0
2
dx 2
d 2 2
 k 2 2  0 (10.15)
dx 2
2m(E  V0 )
where k2 
44 2
The solution of Eq. (10.15) is:
 2 ( x )  F e ik2 x (10.16)
Aeik1x B e ik1x
V (x ) F e ik2 x
K  E  V0
E K V 0 V0
0 x
Fig. 10.5: The solutions of Schrödinger equation given by Eqs. (10.5 and 10.16).
The solution of Eq. (10.15) exhibits an oscillatory nature of the wave function
(Fig. 10.5). The general solution of Eq.(10.15) is  2 ( x )  F e ik2 x  G e ik2 x .
The term F e ik2 x represents a wave travelling along the positive x-axis in the
Region II, while a term like G e  ik2 x would mean a wave travelling along the
negative x-axis in Region II. However, since the particle is incident only from
the left we can assume that G  0.
Let us now apply the first boundary condition: At x  0, [Eq. (10.3a)], we have
1( x )  2 ( x ). Hence, from Eqs. (10. 5 and 10.16), we get:
AB F (10.17a)
Here, F represents the amplitude of the wave in Region II. Similarly, applying
the second boundary condition [Eq. (10.3b)], we get:
 d1   d 2 
  
 dx   dx 
 Aik1  Bik1  iFk2
k
 AB  2 F (10.17b)
k1
Adding Eqs. (10.17a and 10.17b), we get:
k k   2k1 
2A   1 2 F  F    A (10.18)
 k1   k1  k2 
Subtracting Eq. (10.17b) from Eq. (10.17a), we get:

45
k k  k k 
2B   1 2 F  B   1 2  A (10.19)
 k1   k1  k2 
Once again, let us understand the results we have obtained for Case II.
10.4.1 Reflection and Transmission Coefficients
Let us now determine the reflection and the transmission coefficients for the
case when the energy of the particle is greater than the potential: E  V0.
From Eq. (10.12), the reflection coefficient (R) is given by:
The wave function in 2 2

J B k k 
region II is: R r    1 2  (10.20)
 k1  k 2 
Ji 2
  2 ( x )  F eik2 x A
 *   2 * ( x )  F * e ik2 x
Similarly, we determine the transmission coefficient (T) using Eq. (10.13)(read
the margin remark):
And
k 2 2
d

dx dx
d

F e ik2 x  T 
Jt
Ji
 m
F
k1 2
(10.21a)
A
 ik2 e ik2 x F m
d *
dx

d *  ik2 x
dx
F e   Substituting Eq. (10.18) in Eq. (10.21a), we get:
2
 ik2 e ik2 x F * k  2k1  4k1k2
T  2    (10.21b)
Substituting in Eq. k1  k1  k2  k1  k2 2
(10.11) we get the
probability current You may like to attempt an SAQ on reflection and transmission coefficients.
density of the
transmitted wave as:
i  *
SAQ 3 - Reflection and transmission coefficients
Jt   ik2FF
2m 
 ik2FF *  Show that R  T  1 for E  V0.
k 2  k 2
 F F 2F Let us now write the wave function for Region I in terms of the incident
m m
amplitude (A).
Substituting Eq. (10.19) in Eq. (10.5), we get the wave function for Region I
when E  V0 as:
 k  k 2  ik1x 
1( x )  Ae ik1x  1 e  for x < 0 (10.22)
 k1  k 2 
Attempt SAQ 4 to write the wave function for Region II.
SAQ 4 - Wave function for Region II
Write the wave function for Region II in terms of the incident amplitude when
E  V0.
Let us consider an example to apply the results obtained so far.

46
XAMPLE 10.2 : REFLECTION AND TRANSMISSION

COEFFICIENTS
A particle encounters a step potential of height V0. What is the reflection

and transmission coefficient if E  2V0 ?
SOLUTION  We use Eqs. (10.20 and 10.21b).
2
 k  k2 
2  E  E  V0 
Since R   1    
 k1  k 2   E  E V 
 0 
2
 2V0  2V0  V0 
 R 
 2V  2V  V 
 0 0 0 
 R  0.029
This means that about 3% of the wave is reflected even when the energy
of the particle is greater than the height of the potential.
Similarly, from Eq. (10.21b), the transmission coefficient is given as:
4k1k 2
T 
k1  k 2 2
4 E E  V0
 T
 E E  V0 2
4 2V0 V0
 T 
 2V0  2V0  V0 2
T  0.971
Thus, you can see that R  T  1.
Let us now summarise the contents of the unit.
10.5 SUMMARY
Concept Description
Step potential  A one-dimensional step potential is an idealized potential function which is zero
for negative values of the independent variable and constant for positive values
of the independent variable. The step potential is defined mathematically as:
 47
0 for x  0
V (x)  
V0  0 for x  0
It is discontinuous at the point x  0 and constant on each side of the

discontinuity.
Schrödinger  The time independent Schrödinger equation for the step potential is:
equation for the
 2 d 21
step potential   E 1 x 0
2m dx 2
 2 d 2 2
  V0  2  E  2 x 0
2m dx 2
with the boundary conditions that at x  0,
 d1   d 2 
1 ( x )  2 ( x ) and   
 dx   dx 
The Schrödinger equation is solved for two cases: 1) When the energy, E, of
the particle is less than V0; 2) when the energy, E, of the particle is greater than
V0.
Solutions of the  When E  V0, the solutions of the Schrödinger equation are:
Schrödinger
equation for the 1 ( x )  A e ik1x  B e ik1x for    x  0
step potential for
E  V0  2 ( x )  Ce x for 0  x  
2mE 2m(V0  E )
where k1  and  
 2
2
 k  i   2k1 
and B   1  A, C    A
 k1  i   k1  i 
The reflection coefficient (R) is the ratio of J r and Ji , where J r and J i are the
probability current densities of the reflected and incident waves, respectively.
The transmission coefficient (T) is the ratio of Jt and Ji , where Jt and J i are
the probability current densities of the transmitted and incident waves,
respectively. The reflection and transmission coefficients are 1 and 0, in this
case. Thus, R  T  1. The particles with energy lower than the step potential
have finite probability of penetrating through the classically forbidden region.
Solutions of the  When E  V0, the solutions of the Schrödinger equation are:
Schrödinger
equation for the 1 ( x )  A e ik1x  B e ik1x for    x  0
step potential for
E  V0 and  2 ( x )  F e ik2 x for 0  x  
2m(E  V0 )
where k2  ,
2
k k   2k1 
and B   1 2  A, F    A
 k1  k2   k1  k 2 
48
In this case, the reflection and transmission coefficients are:
2
k k  4k1k 2
R   1 2  and T 
 k1  k 2  k1  k2 2
such that R  T  1. A particle with energy higher than the height of the step
potential can get reflected back at the point of discontinuity.
10.6 TERMINAL QUESTIONS

1. A 1.1 mA beam of electrons enters a sharply defined boundary with a
velocity 2.5 10 6 ms 1, and then its velocity reduces to 1.0 10 6 ms 1,
due to the difference in potential. Determine the transmitted and reflected
currents.
2. Determine the expression for the reflection coefficient when E  V0.
3. A beam of particles with energy 7eV is sent towards a step potential of

height 5eV. What fraction of the beam is reflected back?
4. A particle with energy 5 eV is incident on a potential with energy 7 eV.
Calculate the distance in which the probability of finding the particle goes
to 0.05 as it goes into the classically forbidden region.
5. A beam of free electrons are moving from left to right and suddenly
i)
encounters a step potential of height 8 eV. What should be the (8.19c)
approximate energy (E) of the electrons such that 20% get reflected?
ii) (8.19d)
An operator always commutes with its own power:
(8.19e)
1. The reflected (Pr) and the transmitted (Pt) probability density is given as:
The
2 commutator always commutes 2 with2a constant:
Pt ( x )  Cex  C e  2x
2
Pr ( x )  Be ik1x  B and
wherewave can
2. The probability current density of the incident ( abe
constant)
obtain from (8.19f)
Eq. (10.11): For the position and momentum operators we have:
 * d
i  d * 
J   
2m  dx dx 
The incident wave function is ( x )  Ae ik1x , then the conjugate wave

function is ( x )  Ae ik1x .
Ji  

i 

Aeik1x  
 d Aeik1x  
 Aeik1x
d Aeik1x
  

2m  dx dx 
 
Ji  
2m

i 
k k
A Aik1   A A( ik1)  1 A A  1 A
m m
2
3. From Eqs. (10.20 and 10.21b) we have:

2 2 2
Jr k k 
B k  2k1  4k1k2
R    1 2  and T  2   
Ji A
2
 k1  k 2  K1  k1  k2  k1  k2 2
49
or
k k 
R  T   1 2  
4k1k2
2
k  k 2 2  4k1k 2
 1
 k1  k2  k1  k2 2 k1  k 2 2
 R T 
k1  k2 2 1
k1  k2 2
4. Substituting Eq. (10.18) in Eq. (10.16), the wave function for Region II
for E  V0 :
 2k1  ik2 x
 2 ( x )  A   e for x > 0
 k1  k 2 
Terminal Questions
1. From Eq. (10.21b)
4k1k 2 4k1 / k 2
T  
k1  k 2  2
k1 / k 2  12
k1 v1 10
For the given condition,   2.5. Hence, T 
k2 v 2 12.25
The transmitted current is T  1.1 mA  0.816  1.1 mA  0.898 mA
and the reflected current is 0.102 mA.

2
 k1  k 2 
2  E  E  V0 

2. From Eq. (10.20), R      
  E  E V 
 k1  k 2   0 
Thus, R  1 as E  V0 .
2  2
 k1  k 2  E  E  V0 

3. From Eq. (10.20), R   
  
 k1  k 2   
 E  E  V0
Using

E  E  V0 2
 7 2
E  E  V0 or R     0.092. Thus, 9.2% is reflected back.
 7 2 
E  V0  
1
4. Here, E < V0. From Eq. (10.7),  2 ( x )  C e x
 E
E  V0
1
E
2m(V0  E ) (7  5) eV
And where   . So,    7.25 nm 1
2 3 2
 38  10 eV nm
E  V0
x
E If the probability of finding the particle at x  0 is P, then the probability of
We can write :
finding the particle at x  d is 0.05P. Thus,
1 x
 0.447  x  0.38
1 x
C e  2d  0.05P
2 2
P C or
E  V0
  0.38 Dividing the two relations, we get
E
E  V0 e2d  20 or 2d  ln 20 and d  0.21 nm
  0.146
E 2
 E  E  V0   
 E  9.35 5. R     0.2   E  E  V0   0.447
 E  E V   E  E V 
 0   0 
For (see the margin remark) V0  8 eV , E  9.35 eV  9 eV
50
Unit 11 Barrier Potential
UNIT 11
Silicon atoms observed at the
surface of a silicon carbide
crystal using a Scanning
Tunnelling Microscope.
[Guillaume Baffou, CC BY-SA 3.0
BARRIER
<https://creativecommons.org/lic
enses/by-sa/3.0>, via Wikimedia
Commons] POTENTIAL
Structure
11.1 Introduction 11.3 Applications of Quantum Tunnelling
Expected Learning Outcomes Alpha Decay
11.2 One-Dimensional Barrier Potential Scanning Tunnelling Microscope
Solving the Schrödinger equation 11.4 Summary
Reflection and Transmission Coefficient 11.5 Terminal Questions
for E<V0. 11.6 Solutions and Answers
Reflection and Transmission Coefficient
for E>V0
Discoveries in physics are made when the time for making them is ripe, and
STUDY GUIDE
In this unit you will solve the one-dimensional Schrödinger equation for another physical system,
which is the potential barrier. You will use the same techniques that you have learnt in the last two
units: differential and integral calculus and second order ODEs. You should also be comfortable with
complex numbers. You must work out all the steps of each derivation and work through all the SAQs
and TQS. We have added an Appendix on the derivation of the reflection and transmission
coefficients which you may like to go through.
“The simplicities of natural laws arise through the complexities

of the language we use for their expression.” Eugene Wigner
51
11.1 INTRODUCTION
In Unit 9 you have solved the time independent Schrödinger equation for a
free particle and for a particle confined to a certain region of space. You have
seen that for a free particle you can have a continuous spectrum of energies,
whereas when the particle is localized to a small region, you have a discrete
The idea of quantum energy spectrum. In general, whenever you solve the time independent
tunnelling was used by Schrödinger equation for a potential V(x), you will have either (i) “bound”
George Gamow in 1928 states with discrete energy values, or (ii) “unbound” states with continuous
to explain -decay and by energy values. In Unit 10 you solved the Schrödinger equation for a quantum
Cockcroft and Watson in
mechanical particle incident on a step potential.
1932, in their experiment
to split an atom at In this unit we solve the time independent Schrödinger equation for a particle
energies forbidden by
incident on a potential barrier. Just like a potential well tends to attract and
classical physics. Over
the years several Nobel localize a particle, a barrier, as the name suggests, has a tendency to deflect
Prizes have been particles. When a classical particle is incident on a barrier, it will cross the
awarded for research barrier if its energy is greater than the barrier potential. It will be reflected at
based on the idea of the barrier if its energy is less than the barrier potential. What about a
quantum tunnelling: to quantum particle? Will it be reflected or transmitted through the barrier? No
Cockcroft and Watson in
matter what the energy of a quantum particle is, because the matter wave
1954, to Esaki in 1973 for
discovering tunnelling in
associated with it is finite everywhere – there is no region of space that is
semiconductors, also in forbidden to a quantum particle. In Unit 10 also you have seen that there is a
the same year to Giaever finite probability of finding a quantum particle in a classically forbidden region.
and Josephson for The phenomenon in which a quantum particle is transmitted through a
tunnelling in potential barrier and penetrates into regions which are classically forbidden to
superconductors and to it is called “quantum tunnelling”. Quantum tunnelling was first noticed in
Binnig and Rohrer in 1986
1927 by Friedrich Hund and since then it has been used to explain many
for the scanning tunnelling
microscope. Since physical phenomena and has several important applications (read the margin
tunnelling across potential remark).
barriers is a purely
quantum mechanical In Sec. 11.2 we solve the Schrödinger equation for the barrier potential and
phenomenon, it is also calculate the reflection and transmission probabilities at the barrier. In Sec.
seen as an important 11.3 we study some important applications of the concept of quantum
success of quantum tunnelling in explaining -decay and in scanning tunnelling microscopy.
theory.
In the next unit we solve the Schrödinger equation for the one-dimensional
finite potential well.

 solve the time independent one-dimensional Schrödinger equation for a
quantum particle incident on a potential barrier;
 carry out calculations using the reflection and transmission coefficients;
 identify the factors on which the tunnelling probability depends;
 explain how tunnelling enables alpha decay; and
 describe the working of a scanning tunnelling microscope.
52
11.2 ONE-DIMENSIONAL BARRIER POTENTIAL

Let us first look at the classical version of a potential barrier. Recall Sec. 10.5
of BPHCT 131, where you have studied the principle of conservation of
energy. Consider a ball of mass 200 g (a cricket ball, for example) rolling
along a (frictionless surface) with a constant speed of 20 ms-1. So its kinetic
energy is 40 J. Now suppose it comes to a hump in the surface which has a
height of 15 m as shown in Fig.11.1a below. If the ball were to reach the top of
the hump, its potential energy at the top of the hump would be ~30 J. So you
expect that the ball will easily reach the top of the hump and roll over it to
come down the other side. This is an application of this principle of
conservation of energy (recall Terminal Question 6 of Unit 10 of BPHCT 131).
What if the height of the hump is 30 m (Fig. 11.1b)? Then the potential of the
ball at the top of the hump would be ~ 60 J. In this case, the ball would not be
able to cross over to the other side of the hump. It would roll back at some
point as is shown in the figure. Therefore, if the potential energy is greater
than the kinetic energy, the ball is not able to cross the hump. You can
imagine that the hump is the potential barrier which prevents the ball from
rolling over to the other side. This is the classical picture.
30 m V (x )
40 J 40 J
15 m
V0
(a) (b)
Fig. 11.1: A ball having a kinetic energy of 40 J trying to cross a hump of height a) I II III
15.0 m , and b) 30.0 m.
Let us now look at the quantum mechanical analogue of this. In quantum

mechanics the hump can be represented by a potential barrier. We define the
x
potential energy function for a one-dimensional potential barrier as follows: x=0 x=L
0 for x  0 Fig. 11.2: A Potential

V ( x )  V0 for 0  x  L (11.1) Barrier.
 0 for x  L
V(x) is shown in Fig. 11.2.
We divide the entire one-dimensional space into three regions as shown in the
figure. Region I extends from   to 0 ; region II from 0 to L and Region III from
L to  . The central region is known as the potential barrier. You can see that
the shape of the barrier is rectangular. In text books you may come across the
term “rectangular potential barrier” for this or “square potential barrier”
when the potential barrier has a square shape. They refer to the same
problem.
53
A classical particle incident on the barrier from the left cannot cross the barrier
if the energy (E) of the particle is less than the barrier potential V0 i.e. if
E  V0 . If E  V0 , the particle continues its motion over the barrier with a
kinetic energy E  V0 and crosses it. So Region II and Region III are
inaccessible to a particle which has an energy E  V0 .
We now solve the time independent Schrödinger equation for a quantum

mechanical particle incident on the barrier with (i) an energy E  V0 and (ii)
E  V0 .

Let us consider the motion of a particle of mass m and total constant energy E
in the above mentioned one-dimensional space. Let us first write down the
time independent Schrödinger equations for the particle in regions I and III.
Since the potential energy in these two regions is zero, we have (putting
V(x)=0 in Eq. 7.47):
Notice that we use either:  2 d 2( x )

  E( x ) (for Regions I and III) (11.2)
ikx  ikx
2m dx 2
( x )  Ae  Be
Recall that you have already solved this equation in Sec. 9.2. We therefore
or write down the solutions (as in Eq. 9.10) for Regions I and III, which are
( x )  A sin kx  B cos kx I (x ) and III (x ) , respectively(see also the margin remark):
as the general solution of I ( x )  Aeikx  Beikx (for Region I) (11.3)
of the Schrödinger
equation for V(x)=0. Both And
solutions are equivalent.
The choice of the form of III ( x )  Fe ikx  Ge  ikx (for Region III) (11.4)
the solution is made for
convenience. where
 2k 2
E (11.5)
2m
and:
2mE
k (11.6)
2
You have studied in Unit 9 that the function eikx represents a particle moving
along the positive x - direction. And the function e ikx represents a free
particle moving along the negative x - direction.
In the expression for I (x ) , Aeikx represents the plane wave that is incident
on the barrier at x  0 , which has an amplitude A and is travelling to the right.
Beikx represents the plane wave reflected at the barrier, which has an
amplitude B and is moving towards the left from x  0 . So in Eq. (11.4) both A
and B are non- zero. In Region III, since there is only the wave that is
transmitted through the barrier and moving towards the right, and no wave
travelling to the left, we can set G  0 . So, the wave function for Region III is:
54
III ( x )  Fe ikx (for Region III) (11.7)
We next write the time independent Schrödinger equation for the particle in
Region II ( 0  x  L ), where the function is denoted by II (x ) :
 2 d 2  II ( x )
  V0  II ( x )  E II ( x ) (for Region II) (11.8)
2m dx 2
Let us now define a parameter k  similar to k in Eq. (11.6):
2m(V0  E )
k  (11.9)
2 Note that unlike in Eq.(
10.7), in Eq. (11.11) we
Then we rewrite Eq. (11.8) as: retain both the
terms Ce k x and De k x in
d II ( x )
2
d II ( x )
2
2

2m
2
V0  E II ( x )  0 or 2
 k 2 II ( x )  0 (11.10) the solution for region II.
dx  dx That is because, in this
case this solution is valid
From your knowledge of homogeneous second order ODEs (Unit 4 of BPHCT only over the range
131) you know that the solution of Eq. (11.10) is (see the margin remark): 0  x  L and both terms
in Eq. (11.11) would
II ( x )  Cek x  Dek x (for Region II) (11.11) remain finite in this range.
Let us now summarize what you have studied so far.
ONE-DIMENSIONAL POTENTIAL BARRIER
The potential energy function for a one-dimensional potential barrier of

width L is:
0 for x  0
V ( x )  V0 for 0  x  L (11.1)
 0 for x  L
The time independent Schrödinger equation for a particle of mass m is:
 2 d 2( x )
  E( x ) (for x  0 and x  L ) (11.2)
2m dx 2
 2 d 2  II ( x )
  V0  II ( x )  E II ( x ) (for 0  x  L ) (11.8)
2m dx 2
The solutions of the Schrödinger equations are:
I ( x )  Aeikx  Beikx (for x  0 ) (11.3)
II ( x )  Cek x  Dek x (for 0  x  L ) (11.11)
III ( x )  Fe ikx (for x  L ) (11.7)

where
2mE 2m(V0  E )
k and k 
2 2
55
Now we consider the following two cases:
I. The energy of the particle: E  V0 .
 
In this case V0  E is positive and the solution is given by Eq. (11.11)
with a real value of the parameter k  .
II. The energy of the particle: E  V0 .
 
In this case V0  E is negative and the parameter k  is complex. If we
write k   i , where  is real, then the solution is:
II ( x )  Ceix  Deix (11.12)
Where:
2m(E  V0 )
 (11.13)
2
Let us now study the two cases separately.
CASE I: E  V0
To determine the constants A, B , C, D and F we use the properties of an

acceptable wave function for a physical system.
Let us first write down the boundary conditions. You know that for (x ) to be
d ( x )
an acceptable wave function in a physical system, (x ) and must be
dx
continuous for all x. So, the wave functions in the three regions and their
derivatives must be equal at the boundaries of the potential barrier and satisfy
the following conditions:
I ( x  0)  II ( x  0) (11.14a)
II ( x  L)  III ( x  L) (11.14b)
And
d I ( x ) d II ( x )
 (11.14c)
dx ( x 0 ) dx ( x 0 )
d II ( x ) d III ( x )
 (11.14d)
dx ( x  L ) dx ( x  L )
We first apply the boundary condition given by Eq. (11.14a). From Eq. (11.3)
we can write I ( x  0)  A  B . From Eq.( 11.11) for II (x ) we get
II ( x  0)  C  D . Therefore, from Eq. (11.14a) we have:
AB C D (11.15a)
To apply Eq.(11.14b), we set x  L in Eqs. (11.11 and 11.7) for II (x ) and
56
III (x ) , respectively, and get:
CekL  DekL  FeikL (11.15b)
To apply Eqs. (11.14c and d), we first write down the derivatives of I (x ) ,
II (x ) and III (x ) .
d I
dx

d
dx
  
Aeikx  Be ikx  ik Aeikx  Be ikx  (11.16a)
d II
dx

d
dx
  
Cek x  De  k x  k  Cek x  De  k x  (11.16b)
d III
dx

d
dx
  
Fe ikx  ik Fe ikx  (11.16c)
From Eqs. (11.14c and d) we can write:
ik A  B  k C  D (11.17a)
and
 
k  Ce k L  De  k L  ikFeikL (11.17b)
Now we have four equations (11.15a and b, and 11.17a and b), but there are
five unknowns: A, B, C, D and F. However, as you will see in the next section,
we are interested in calculating the probability of reflection and transmission,
for which we need the ratios B / A and F / A . If we divide the equations
(11.15a and b, and 11.17a and b) by A, we will be left with just four unknowns
as you can see below:
C D B
  1 (11.18a)
A A A
C k L D  k L F ikL
e  e  e (11.18b)
A A A
C D   B
k     ik 1   (11.18c)
 A A  A
C D  F
k  e k L  e  k L   ik e ikL (11.18d)
A A  A
The four unknowns now are B / A , C / A , D / A and F / A . We can determine

these constants by solving Eqs. (11.18a – 11.18d).
However, even without calculating the constants, we can see that the wave
function has an oscillatory behaviour in Regions I and III, but in Region II the
wave function is exponential. The typical wave function in all the three regions
for E  V0 , is shown in the Fig. 11.3.
57
V (x )
V0
I (x )
II (x ) III (x )
I II III
x
x 0 x L
Fig. 11.3: The wave functionx=L x=L
for the one –dimensional potential barrier for a
particle with an energy less than the barrier height.
In region III, the wave function is purely a travelling wave. We can calculate
the probability density of the wave in this region as:
PIII ( x )  III  ( x )III ( x )  F

2
(which is a constant) (11.19)
In region I, the wave function is primarily a standing wave because we have a

wave travelling to the right as well as a wave travelling to the left. Note that
the amplitude of the reflected wave is necessarily less than that of the incident
wave. We can write the probability density probability density for Region I as:

PI ( x )   I ( x ) I ( x )  A  B  ABe 2ikx  ABe 2ikx
2 2
(11.20)
So, the probability density in Region I has an oscillatory component (last two
terms of Eq. 11.20) as well as a constant component (first two terms of Eq.
11.20). So the minimum probability density in Region I is always slightly
greater than zero as it is in Region III.
Within the barrier, although we have both the exponential terms, the
decreasing exponential term ( Dek x ) is dominant. Hence, the probability
density decreases exponentially as PII ( x )  D e 2k x . The probability density
2
for all three regions is shown in Fig.11.4 below:

P(x )
V0
I II III
x
x 0 x L
x=Ldensity asx=L
Fig. 11.4: The probability a function of position, for a quantum
mechanical particle with an energy less than the barrier height.
58
We next calculate the reflection and transmission coefficients which are a
measure of the probability of the particle being reflected or transmitted at the
barrier.
11.2.2 Reflection and Transmission Coefficient

for E < V0
For the wave function I (x ) , 0 ( x )  Aeikx is the part of the wave that is
incident on the barrier from the left, whereas  R ( x )  Be  ikx represents the part
xof the wave that is reflected back from the barrier as shown in Fig. 11.5.
Aeikx
incident
wave
Feikx
transmitted
wave
Be ikx
reflected
wave
x
x 0 x L
x=L x=L
Fig. 11.5: Incident, reflected and transmitted waves at the one-dimensional
potential barrier.
As you have studied in Unit 10, the reflection coefficient is given by the ratio of
the magnitude of the probability current density associated with the reflected
wave to the magnitude of probability current density associated with the
incident wave (Eq.10.12). So we write the reflection coefficient R as:
2
B
R (11.21)
2
A
You have studied that the intensity of a wave is proportional to its amplitude.
The reflection coefficient is, therefore, the fraction of the intensity of the
incident wave that is carried by the reflected wave. It also gives us the
probability that a particle having an energy E incident on a potential barrier V0
(such that E  V0 ) is reflected back by the barrier.
We next define the transmission coefficient which tell us the probability of a

particle being transmitted through the barrier. The transmission coefficient, T,
is the ratio of the magnitudes of the probability current densities associated
with the transmitted wave and the incident wave (Eq. 10.13), which is:
2
F
T  (11.22)
2
A
This is the ratio of the intensity of the transmitted wave to the intensity of the
incident wave.
59
Since the incident wave is either reflected or transmitted, we must also have
the sum of the reflection and transmission coefficient to be one:
R T  1 (11.23)
To calculate R and T for the system we have to calculate B / A and F / A

using Eqs. (11.18 a to d). The algebra is lengthy but straightforward and is
worked out for you in the Appendix to this unit (you will not be tested on this
derivation). We write down the results for T and R:
1
 V0
2

T  1  sinh 2 (k L ) (11.24a)
 4E (V0  E ) 
1
 4E (V0  E ) 
R  1   (11.24b)
 V0 2 sinh 2 (k L ) 
where
e k L  e  k L
sinh( k L )  (11.24c)
2
and
2mL2 (V0  E ) 2mV0L2  E

k L   1   (11.24d)
2 2  V0 
The transmission coefficient tells us about the extent of the penetration of the
barrier by the particle. It is also called the tunnelling probability.
Notice that Eq. (11.24a) tells us something that is totally at odds with classical
behaviour. For a classical particle, for E  V0 , the particle is always reflected
at the barrier. So R = 1 and T = 0. But, for a quantum mechanical particle
there is always a small but finite probability for the particle to penetrate the
barrier and appear on the other side. This phenomenon is called “barrier
penetration”. You can see that the transmission coefficient becomes
vanishingly small in the limit of large values of k L , because the factor e 2k L in
Eq. (11.24a) would be very small.
For large values of k L , sinh( k L)  ekL / 2 and we can write the expression for
the transmission coefficient as:
1
 V0
2
 e 2k L 
T    (11.25)
 
 4E (V0  E )  4 
or,
16E  E
T 1  e 2k L for k L  1 (11.26)
V0  V0 
Eq. (11.26) holds for wide barriers and large values of V0.
60
The transmission coefficient T decreases exponentially as e 2k L and T  1.

The factor k L in the exponent (refer to Eq. 11.24d) is very large because
Planck’s constant is a very small number.
We define a tunnelling length:
1 
T   (11.27)
k 2m(V0  E )
T is a measure of the opacity of the barrier. It is also known as the barrier

penetration depth. At a distance T into the barrier, the wave function has
fallen to 1/e of its value at the barrier edge; thus, the probability of finding the
particle is appreciable only within about T of the barrier edge. Notice that T
decreases exponentially with L, the barrier width (beyond the tunnelling
length) and the energy difference (V0  E ) .
In terms of the tunnelling length, Eq. (11.26) can be written as:

2L
16E  E  L
T  1  e T for  1 (11.28)
V0  V0  T
Let us estimate how the transmission coefficient changes with the barrier
width L for a fixed value of the tunnelling length T .
XAMPLE 11.1: TUNNELLING LENGTH AND TRANSMISSION

COEFFICIENT
Consider an electron bound inside a typical metal. Typically the effective

value of (V0  E ) that prevents the electron from escaping the metal is ~ 5.0
eV. Calculate the tunnelling length and the ratio of the transmission
coefficients for L=0.3 nm and 0.2 nm.
SOLUTION  We calculate the tunnelling length using Eq. (11.27) with

V0  E  5.0 eV  8.0  10 19 J :
 1.054  10 34 Js
T  
2mV0  E   
2  9.109  10 31 kg  8.0  10 19 J 
 .09  10 9 m  .09 nm
Notice that the transmission coefficient of Eq. (11.28) can be written as

2L

T  f E / V0  e 2k 'L  f E / V0 e T (i)
With T  .09 nm , the transmission coefficient for L  0.3 nm is
20.3 nm

T1  f E / V0  e 0.09 nm  f E / V0  e 6.7
61
For L  0.2 nm the transmission coefficient is:

20.2 nm

T2  f E / V0 e 0.09 nm  f E / V0  e 4.4
So the ratio of the transmission coefficients

T f E / V0 e 4.4
is: 2   e 2.3  10
T1 f E / V0 e  6.7
So the transmission through a barrier of width 0.2 nm is almost ten times

more probable than a barrier of width 0.3 nm.
Let us work out another example on calculating the transmission coefficient.
XAMPLE 11.2 : TRANSMISSION COEFFICIENT
Calculate the transmission coefficient for an electron of energy 1.5 eV

incident on a potential barrier of 2.0 eV, if the width of the barrier is 0.50
nm.
SOLUTION  We calculate first calculate T using Eq. (11.27) with

E  1.5 eV, V0  2.0 eV and then calculate the value of T from Eq. (11.26) ,
1
with using L = 0.50 nm and k   . So,
T
V0  E  0.5 0 eV  0.80  10 19 J .
T 
1.054  10 34
Js   0.28  10 9 m  0.28 nm

2  9.109  10 31

kg  0.80  10 19

J
2L 20.50 nm
 E   T  1.5 eV  1.5 eV   0.28 nm
 3e  3 . 6
E
T  16 1   e  16   1  e
V0  V0   2.0 eVV  2. 0 eV 
Let us now summarize what we have studied about the reflection and
transmission coefficient
RELECTION AND TRANSMISSION COEFFICIENT (E<V0)
The transmission coefficient T is the probability of a particle being

transmitted through the barrier and is given by:
1
 V0 2 
T  1  sinh 2 (k L ) (11.24a)
 4E (V0  E ) 
62
RELECTION AND TRANSMISSION COEFFICIENT

(E<V0)(Contd.)
Where
2mL2 (V0  E ) 2mV0L2  E

k L   1   (11.24d)
2 2  V0 
The reflection coefficient R is the probability of the particle being reflected
at the barrier edge and is given by:
1
 4E (V0  E ) 
R  1   (11.24b)
 V02 sinh2 (k L ) 
The sum of the reflection and transmission coefficients is 1.
For wide barriers and large values of V0 the transmission coefficient is:
1 2L
 V02  e2k L  16E  E 
T     1  e T (11.25)
 4E (V0  E ) 
 4 
 V0  V0 
Where the tunnelling length T is:
1 
T   (11.27)
k 2m(V0  E )
The probability of finding the particle is appreciable only within about T of
the barrier edge.
You may like to work through the following SAQ.
SAQ 1 - Transmission Coefficient
Calculate the transmission coefficient for an electron in a semiconductor (having

an energy of 1.5 eV incident on a potential barrier 2.0 eV if the width of the
barrier is 0.10 nm. The effective mass of the electron is 0.22 me.
You should not take the word ‘tunnelling’ literally. There is, of course, a finite
probability for the particle to be inside the classically forbidden barrier region
where its kinetic energy is negative. But the point is that nobody can "see" a
particle actually go through a classically forbidden region.
Particle detectors can detect only objects of kinetic energy greater than zero.
Suppose you are able to tunnel through a barrier to insert a detector inside it
to ‘see’ the particle. Then, you are not only making a hole in the potential but
also in your objective. Why so? Because the object will no Ionger belong to a
classically forbidden region, where you wanted to find it! Another way to say
this is that our effort to observe the object with any measuring instrument will
give it an uncontrollable amount of energy. This is how the uncertainty
principle works in such measurement situations!
63
Quantum tunnelling should be taken into consideration only in those systems
where wave particle duality is significant. In the Sec 11.3 we will take up
certain important applications of quantum tunnelling.
We now study the reflection and transmission coefficient for Case II in which
the energy of the particle E  V0
11.2.3 Reflection and Transmission Coefficient

for E > V0
Let us write down the wave function for the three regions for E  V0 (Eqs.
11.4, 11.12 and 11.5) once again:
I ( x )  Aeikx  Beikx (for Region I) (11.3)
II ( x )  Ceix  Deix (for Region II) (11.12)
III ( x )  Fe ikx (for Region III) (11.5)
2m(E  V0 ) 2mE
where   and k  .
2 2
You can see that the wave function is oscillatory in all three regions. Applying
the boundary conditions Eqs. (11.14a to d) at x  0 and x  L for the wave
function and its derivatives as stated in Sec. 11.2.2, we can derive the
expressions for the transmission and reflection coefficients as:
1
 V0 2 
T  1  sin2 (L ) (11.29a)
 4E (E  V0 ) 
1
 4E (E  V0 ) 
R  1   (11.29b)
 V0 2 sin2 (L ) 
From the expressions you can see that both R and T have an oscillatory
component. Notice here that even when E  V0 , there is a finite probability
for the particle to be reflected at the barrier.
Once again this behaviour is NOT what is predicted by classical mechanics. A

classical particle which has an energy E  V0 would be transmitted and not
reflected (T=1 and R=0).
The typical variation of the transmission coefficient with the ratio of the particle
energy E to the value of the potential at the barrier which is V0, is plotted in
Fig. 11.6. For E / V0  1, T is defined by Eq. (11.24a) and for E / V0  1 , T is
given by Eq. (11.29a). For E / V0  1, you can that while there is a finite
probability of tunnelling , R  T .
64
E /V0
Fig. 11.6: The typical variation of the reflection coefficient R and

2mV0 L2
transmission coefficient T with E /V0 , for  16 .
2
Notice that the value of T is close to 1 for E  V0 and actually equal to 1 at

some points. These are the points at which T=1 in Eq. (11.29a) and so we
must have:
sin2 (L)  0  L  n for n  1,2,3... (11.30)
These points of perfect transmission, or T=1 are called “transmission

resonances and the energies at which they occur can be calculated from Eq.
(11.30). At these energies, a quantum particle will cross the potential barrier
without any reflection.
RELECTION AND TRANSMISSION COEFFICIENT (E >V0)
The wave function for the three regions for E>V0 are:
I ( x )  Aeikx  Beikx (for x  0 ) (11.3)
II ( x )  Ceix  Deix (for 0  x  L ) (11.12)
III ( x )  Fe ikx (for x  L ) (11.5)
2m(E  V0 ) 2mE
where   and k  .
2 2
The transmission and reflection coefficients are:

1
 V0 2 
T  1  sin2 (L) (11.29a)
 4E (E  V0 ) 
1
 4E (E  V0 ) 
R  1   (11.29b)
 V0 2 sin2 (L) 
The points of perfect transmission at which T=1 and R=0, are called
“transmission resonances” and are given by the condition:
L  n , n  1,2,3...
65
Let us now look at some interesting applications of quantum tunnelling which
also point towards the success of quantum mechanics.
11.3 APPLICATIONS OF QUANTUM

TUNNELLING
We discuss two important applications which are alpha decay and scanning
tunnelling microscopy.
11.3.1 Alpha Decay

Alpha decay is the process in which the isotopes of certain radioactive
elements like uranium, radium and bismuth, decay by emitting alpha ()
particles. Alpha particles are helium nuclei with two neutrons and two protons.
After emitting the alpha particle, the original nucleus (parent nucleus) is
transformed into a different atomic nucleus (the daughter nucleus), with the
mass number reduced by four and the atomic number reduced by two. The
following two aspects of the alpha decay process were not explained for a
long time:
 All alpha particles emitted from the same source have almost the same
kinetic energy. If they are emitted from different sources, the kinetic
energies all lie within a narrow range of 4.0 to 9.0 MeV.
 The half- life of the radioactive element from which the alpha particle is
emitted, however varies over a very large range: for example the half-
life for polonium-214 is 160 s and the half life of uranium-238 is
around 4.5 billion years. Incidentally the kinetic energies of the emitted
alpha particles are ~7.7 MeV for polonium and 4.3 MeV for uranium.
This large variation in the half-lives of the parent element in the alpha decay
process was explained by George Gamow using the concept of quantum
tunnelling. He assumed that before the alpha decay takes place, an alpha
particle exists inside the parent nucleus and is bound by the attractive
potential of the strong nuclear force. You may consider the nucleus to be a
kind of rigid spherical box inside which the alpha particle is confined. The
alpha particle is free to move between the walls of the box. It does have a
finite kinetic energy but this kinetic energy is much less that what required to
escape from the nucleus, leaving behind the daughter nucleus. So classically,
the alpha particle should remain forever remain bound inside the parent
nucleus.
We consider a somewhat simplified picture as shown in Fig. 11.7, in which the

potential function is plotted as a function of the distance from the centre of the
nucleus. In this the nuclear potential which binds the alpha particle is
represented by a square well. The nuclear force itself is extremely short-
ranged (~10-15 m) and hence it is not significant outside the nucleus. Typically
the radius of the nucleus is about 1 fm (~10-14 m). Suppose the alpha particle
now tunnels out of the nucleus, leaving behind the daughter nucleus. Once
the alpha particle escapes the nucleus by tunnelling through the nuclear
potential barrier, the only force acting on it is the Coulomb repulsive force due
66 to the (daughter) nucleus. Therefore outside the radius of the nucleus ( r  R0
), the potential is modified by the Coulomb repulsion V(r) between the alpha
particle( which has a charge 2e) and the daughter nucleus( which has a
charge Ze). r is the distance between alpha particle and the nucleus. V(r) is
given by:
V (r ) 
Ze (2e)  Ze 2
(11.31)
4 0r 2 0r
The shaded region shows the forbidden region for the alpha – particle.
V (r )
Ze2
V (r ) 
20r
E
r
R
R0
Fig. 11.7: Potential barrier for alpha-particle decay.
The kinetic energy of the alpha particle is E. At the point R, at which the alpha
particle escapes the nucleus, the kinetic energy of the alpha particle is at least
equal to the electrostatic energy between it and the daughter nucleus. So,
at r  R ,
Ze 2
E  (11.32)
20R
It is possible to calculate the tunnelling probability for the alpha particle,

which is just the transmission coefficient T which you have studied in Sec.
11.2.2. Instead of the potential barrier of constant height which you have
studied earlier in this unit, here the potential barrier is described by the
function V (r ) defined in Eq. (11.31). The transmission coefficient (of Eq.
11.26) now looks like:
R
2 
2m
V ( r )E dr
 2 k L 2
T e e R0
(11.33)
This tunnelling probability, T, is the probability of emission of an alpha particle

from a nucleus. T is used to calculate the decay rate  for the nucleus, which
is the alpha particle emission probability per unit time. To calculate  , we
multiply T by the number of times the alpha particle approaches the barrier
v
per second. This number is just , where v is the speed of the alpha
2R0
particle inside the nucleus. v can be calculated from the kinetic energy E of
v
the alpha particle, when it escapes from the nucleus. Typically  10 21
2R0
collisions per second and the decay rate   1021T .
67
The decay rate is used to calculate the half -life of the parent nucleus using
the relation T1 2  .693 /  . From Eq. (11.33), you can see that for a very small
change in E, there will be a disproportionately large change in  and hence in
T1 2 . So the more energetic α -particles have a better chance to escape the
nucleus, and, for such nuclei, the nuclear disintegration half-life will be shorter.
We now describe in brief another important device based on the tunnelling

phenomena, which is extensively used in materials science research today.
11.3.2 Scanning Tunnelling Microscope
Electrons tunnelling
between the sample
tip surface and the tip
sample
surface
Fig. 11.7: Schematic Diagram of a Scanning Tunnelling Microscope
The Scanning Tunnelling Microscope (STM) is a type of microscope which is

used for imaging surfaces at the atomic level. It is based on the phenomenon
of field emission, in which electrons bound inside a metal are removed from its
surface by a very strong electric field. This happens by the quantum tunnelling
of electrons through the potential barrier.
The STM consists of
 a very sharp, conducting ( typically tungsten, gold, or platinum—

iridium) tip(probe), which scans the surface to be imaged;
 a piezoelectric device which can control the height of the tip above the
surface to be scanned( typically 0.4 to 0.7 nm); and
 a mechanism to move the tip over the surface being studied.
There is of course a complex instrumentation that converts the inputs into a

computer imagery of the surface. Here we shall discuss only the basic
principle of the microscope.
When the tip is brought very close to the surface and a voltage difference
exists between the tip and the surface, electrons tunnel through the gap
between the tip and the surface and set up a tunnelling current. The tunnelling
current (which is proportional to the tunnelling probability of the electron
through the barrier) will depend on the distance between the tip and the
surface(this is the width of the barrier). So as we scan the tip over the sample
68 at a fixed height, the distance and hence the tunnelling current will depend on
the corrugations on the surface of the material. The variations in current are
converted into an image of the topography of the surface of the material. The
sensitivity of the microscope is such that the resolution is of the order of
0.001nm, which is even less than the typical diameter of an atom.
APPLICATIONS OF QUANTUM TUNNELLING
Alpha Decay
The process of emission of alpha particles from a radioactive nucleus takes
place by the quantum tunnelling. The alpha particle is initially trapped in a
potential well by the nucleus. Classically, it cannot escape from the
nucleus. However quantum mechanics allows for a finite probability of
tunnelling of the alpha particle through the potential barrier created by the
nuclear potential. The lifetime of the radioactive nucleus is calculated from
tunnelling probability.
Scanning Tunnelling Microscope

The Scanning Tunnelling Microscope (STM) is a type of microscope which
is used for imaging surfaces at the atomic level and works on the principle
of quantum tunnelling. When the tip of the STM is very close to the surface,
the voltage difference between the tip and the surface causes electrons to
tunnel through the gap and set up a tunnelling current which depends on
the distance between the tip and the surface. This is used to create an
image of the surface.
11.4 SUMMARY
Concept Description
One-dimensional  The potential energy function for a one-dimensional potential barrier of

Potential Barrier width L is:
0 for x  0
V ( x )  V0 for 0  x  L
 0 for x  L
The time independent Schrödinger equation for a particle of mass m is:
 2 d 2( x )
  E( x ) (for x  0 and x  L )
2m dx 2
(for ) (11.8)
69
 2 d 2  II ( x )
  V0  II ( x )  E II ( x ) (for 0  x  L )
2m dx 2
The solutions of the Schrödinger equations are:
I ( x )  Aeikx  Beikx (for x  0 )
II ( x )  Cek x  Dek x (for 0  x  L )
III ( x )  Fe ikx (for x  L )

where
2mE 2m(V0  E )
k and k 
2 2
 The transmission coefficient T is the probability of a particle being

Reflection and
transmitted through the barrier and is given by:
transmission 1
coefficients for E<V0  V0 2 
T  1  sinh 2 (k L )
 4E (V0  E ) 
Where
2mL2 (V0  E ) 2mV0L2  E

k L   1  
2 2  V0 
The reflection coefficient R is the probability of the particle being
reflected at the barrier edge and is given by:
1
 4E (V0  E ) 
R  1  
 V02 sinh2 (k L ) 
The sum of the reflection and transmission coefficients is 1.
For wide barriers and large values of V0 the transmission coefficient
is:
1 2L
 V02  e2k L  16E  E 
T     1  e T
 4E (V0  E )  4  V0  V0 
where the tunnelling length T is:
1 
T  
k 2m(V0  E )
The probability of finding the particle is appreciable only within about T
of the barrier edge.
Reflection and  The wave function for the three regions for E>V0 are:
transmission
coefficients for E>V0 I ( x )  Aeikx  Beikx (for x  0 )
II ( x )  Ceix  Deix (for 0  x  L )
III ( x )  Fe ikx (for x  L )
70
2m(E  V0 ) 2mE
where  and k  .
2 2
The reflection and transmission coefficients are:

1
 V0 2 
T  1  sin2 (L)
 4E (E  V0 ) 
1
 4E (E  V0 ) 
R  1  
 V0 2 sin2 (L) 
The points of perfect transmission at which T=1 and R=0 are called
“transmission resonances and are given by the condition: L  n for
n  1,2,3...
Applications of quantum  Alpha Decay

tunnelling The process of emission of alpha particles from a radioactive nucleus
takes place by the quantum tunnelling. The alpha particle is initially
trapped in a potential well by the nucleus. Classically, it cannot escape
from the nucleus. However quantum mechanics allows for a finite
probability of tunnelling of the alpha particle through the potential barrier
created by the nuclear potential. The lifetime of the radioactive nucleus
is calculated from tunnelling probability.
Scanning Tunnelling Microscope

The Scanning Tunnelling Microscope (STM) is a type of microscope
which is used for imaging surfaces at the atomic level and works on the
principle of quantum tunnelling. When the tip of the STM is very close to
the surface, the voltage difference between the tip and the surface
causes electrons to tunnel through the gap and set up a tunnelling
current which depends on the distance between the tip and the surface.
This is used to create an image of the surface.
11.5 TERMINAL QUESTIONS

1. An electron with a kinetic energy 4.0 eV is incident on a potential barrier
of height 10.0 V and width 0.80 nm. Calculate the tunnelling length and
tunnelling probability of the electron to tunnel through the barrier (use Eq.
11.28).
2. For the electron of TQ1, calculate in which case the tunnelling probability
increases more:
(i) when the width of the barrier is reduced to 0.4 nm, other parameters
remaining the same.
71
(ii) when energy of the electron is increases to 8 eV, other parameters
remaining the same.
3. An electron and a proton with the same kinetic energy E are incident on a
potential barrier of height V0 and width L. Calculate the ratio of their
tunnelling probabilities.
4. An electron with a energy of 8.0 eV strikes a potential barrier of energy

10.0 eV. If the tunnelling probability is 2.0 percent, determine the width of
the barrier (use Eq. 11.28).
5. An electron has a kinetic energy of 8.0 eV. The electron is incident upon a
rectangular barrier of height 15.0 eV which has a thickness of 1.0 nm.
Calculate the increase in the tunnelling probability of the electron if it
absorbs all the energy of a photon of blue light (3.1eV).
6. Calculate the probability that an electron will tunnel through a 0.4nm gap
from a metal to the STM probe if the work function is 3.0eV. By what
factor does the tunnelling probability change if we increase the gap to
0.50 nm.

1. Following the steps of Example 11.2, we first calculate the tunnelling

length T using Eq.(11.27) with E  1.5 eV, V0  2.0 eV and m  0.22me .
So:
V0  E  0.50 eV  0.80  10 19 J
1.054  10 34 Js
T   0.58 nm
   
(i)
2  0.22  9.109  10  31 kg  0.80  10 19 J
E 1.5 eV 3
Using Eq. (11.28) with   , L  0.10 nm , and T as
V0 2.0 eV 4
calculated in Eq. (i) we calculate the transmission coefficient T :
20.10 nm
3  3 
T  16     1   e 0.58 nm
 3 e 0.34
4  4
Terminal Questions
1. We first calculate the tunnelling length T using Eq. (11.27) with

E  4.0 eV,V0  10.0 eV and m  me :
1.054  10 34 Js
 T   0.08 nm
   
(i)
2  9.109  10  31 kg  9.6  10 19 J
E 4.0 eV 2
With   , L  0.80 nm and T  0.8 nm in Eq. (11.28):
V0 10.0 eV 5
72
20.80 nm
2  2  96 
T  16     1  e 0.08 nm   e  20  3.84  e 20
5  5  25 
2. Let us denote the transmission coefficient calculated in TQ 1 by T0
So T0  3.84 e 20 (i)
E 2
i) With L = 0.40 nm, T  0.08 nm and  in Eq. (11.28) :
V0 5
20.40 nm
 2  2 
T1  16  1   e 0.08 nm  3.84 e 10 (ii)
 5  5 
ii) We first calculate T with E  8.0 eV, V0  10 eV and m  me
T 
1.054  10 34
Js   0.14 nm

2  9.109  10  31

kg  3.2  10 19 J 
E 8.0 eV 4
Then with E = 8 eV , L = 0.80nm,   and
V0 10.0 eV 5
T  0.14 nm , we get from Eq. (11.28):
20.80 nm
 4  4   64 
T2  16.  1   e 0.14 nm    e 11.4  (2.56 )e 11.4 (iii)
 5  5  25 
We now calculate the ratios of the transmission coefficients T1 and T2

with respect to T0:
T1 (3.84)e 10
  e10
T0 (3.84 )e 20
T2 (2.56) e 11.4
and   (0.67) e8.6
T0 20
(3.84) e
Since e10  0.67e8.6 we can say that the tunnelling probability

increases more in case (i) when width of the barrier is decreased.
3. Let us say that the tunnelling length for the electron is

TE 
2me V0  E 
And the tunnelling length for the proton( mP  1836me ) is

 TP 
2mP V0  E 
  Te
   (i)
21836me V0  E  2me V0  E  1836 43
The transmission coefficient for the electron is
73
2L
 E  E 
Te  16  1   e Te
 V0   V0 
and for the proton it is:

2L
 E  E   TP
TP  16  1   e
 V0   V0 
2L 2L
   2L 
Te 42
Te 
T e e  
 e   e  Te   Te  TP
TP 2L 2L
 
Tp
e Te 43 
e
4. We calculate the tunnelling length by using Eq.(11.27) with

V0  E  2 eV  3.2  10 19 J
So T 
1.054  10 34
Js   0.14 nm
  
(i)
31 19
2  9.109  10 kg  3.2  10 J
The tunnelling probability is calculated using Eq.(11.28) with

E 8 eV 4 1
  and T  0.14 nm . Given that T  2%  we can
V0 10 eV 5 50
write:
2L
1  4  4  
T   16   1  e 0.14 nm
50  5  5 
2L 2L
 25
e 0.14 nm  or e 0.14 nm  128
64  50
Taking the logarithm of both sides,
 ln128   L  0.07  4.85 nm  0.34 nm

2L
0.14 nm
5. We first calculate the tunnelling length using Eq. (11.27), with

V0  E  15.0  8.0  eV  11.2  10 19 J
1.054  10 34 Js
 T   0.074  109 m  0.074 nm

2  9.109  10 31

kg  11.2  10 19
J
(i)
The tunnelling probability T1is calculated using Eq. (11.28) with L = 1.0
8.0 eV 1
nm, E / V0  and T   0.074 nm
15.0 eV k
21.0 nm
 8  8 
T1  16    1   e 0.074 nm  ( 4.0)e 27 (ii)
 15   15 
When electron absorbs an photon of energy 3.1eV its kinetic energy

74 becomes
E  8.0  3.1 eV  11.1eV . So V0  E  3.9 eV  6.24  10 19 J
Now the tunnelling length is,
1.054  10 34 Js
T   0.098 nm
  
(iii)
2  9.109  1031 kg  6.24  1019 J
11.1
With E / V0  and T given by Equation (iii) the tunnelling probability
15.0
is:
21.0 nm
 11.1   11.1 
T2  16    1  e .098 nm
 3.1 e 20.4
 15.0   15.0 
So the increase in the tunnelling probability is:
T2

3.1e 20.4   3.1   e6.6  570
 
T1 4.0e  27.0  4.0 
So the tunnelling probability increases about 570 times.
6. Since the electron must overcome the work function, we can assume that
the value of V0  E is at least  3 eV  4.8  1019 J
So the typical tunnelling length can be calculated using Eq. (11.27)
1.054  10 34 Js
T   0.11nm
 
2  9.109  10 31 kg  4.8  10 19 J 
Given that E,V0 are fixed we can write that the tunnelling probability is a
function only of the gap between the tip of the STM probe and the surface
i.e. T  f E / V0 e 2L / T .
For L  0.40 nm , the transmission coefficient is

20.40 nm 

T1  f E / V0  e 0.11nm   f E / V0  e 7.3
For L  0.50 nm the transmission coefficient is
20.50 nm

T2  f E / V0  e 0.11nm  f E / V0  e 9.1
T2 f E / V0  e 9.1 1
   e 1.8 
T1 f t / V0  e 7.3 6
The tunnelling probability reduces by 1/ 6 when the distance between the

tip and the surface increases by 0.10 nm. The tunnelling current also
changes proportionally. This is why the STM can detect variations even of
the order of 0.10 nm on the surface of a material.
75
APPENDIX 11A: CALCULATING THE REFLECTION AND
TRANSMISSION COEFFICIENTS
After applying the boundary conditions on the wave functions and their
derivatives for E  V0 , we have derived the following equations for A, B, C, D
and F:
AB C D (11.15a)
ek LC  ek LD  eikLF (11.15b)
ikA  ikB  k C  k D (11.17a)
k ek LC  k ek LD  ikeikLF (11.17b)
Let us first calculate the value of B/A from these equations. For this we
eliminate the constants C and D from the Eqs. (11.15a,11.15b, 11.17a and
11.17b). Multiplying Eq. (11.15a) by k  we get:
k A  k B  k C  k D (i)
Adding Eqs.(11.17a) and (i) we get:
(k   ik )A  (k   ik )B  2k C (ii)
Subtracting Eq. (11.17a) from Eq. (i) we get
(k   ik )A  (k   ik )B  2k D (iii)
Multiplying Eq. (11.15b) by ik we get:
ikek LC  ikek LD  ikeikLF (iv)
Subtracting Eq. (iv) from Eq. (11.17b) we get
(k   ik )ek LC  (k   ik )e k LD  0 (v)
Which we can write as:
(k   ik )e k LC  (k   ik )e k LD
(k   ik )e k L
or C D (vi)
(k   ik )ek L
Eq. (vi) gives us the relation between C and D. Substituting for C from Eq. (vi)
into Eq. (ii) we get:
(k   ik )e k L
(k   ik )A  (k   ik )B  2k  D
(k   ik )ek L
Which is:
(k   ik )ek L
(k   ik )A  (k   ik )B  2k D (vii)
(k   ik )e k L
76
You can see that the RHS of Eqs. (iii) and (vii) are equal. Equating the LHS of
these two equations we get:
(k   ik )ek L
(k   ik )A  (k   ik )B  (k   ik )A  (k   ik )B (viii)
(k   ik )e k L
On simplifying, we can write Eq. (viii) as:
(k   ik )ek L (k   ik )A  (k   ik )B   (k   ik )e k L (k   ik )A  (k   ik )B 
Which is:
(k   ik )( k   ik )e k L A  (k   ik )2 e k LB  (k   ik )( k   ik )e k L A  (k   ik )2 e k LB
Using (k   ik )( k   ik )  k 2  k 2 we can write:
(k 2  k 2 )ek L A  (k   ik )2 ek LB  ( k 2  k 2 )e k L A  (k   ik )2 e k LB (ix)

Notice that B/A given in
Dividing Eq. (ix) by A we get Eq. (xii) is complex and
it has the general form:
B B
(k 2  k 2 )ek L  (k   ik )2 ek L  (k 2  k 2 )e k L  (k   ik )2 e k L (x) B u
A A 
A v  iw
Therefore we have u  v  iw 
  
v  iw  v  iw 
B


(k 2  k 2 ) e k L  ek L  (xi) 
uv  iuw
A (k   ik )2 ek L  (k   ik )2 e k L v2  w2
which is: B
2

uv 2  uw 2
(k  k ) e 2 e 2
 k L k L
 A v 2
 w2 
2
v 
B
 
A (k   k ) e  e
2 2 k L  k
L

 (2ik k ) ek L  e k L   (xii)

u2 2  w 2
v 2
 w2 
2
Or u2
B (k 2  k 2 ) sinh( k L )

v 2
 w2 
 (xii)
A (k 2  k 2 ) sinh( k L )  2ik k cosh(k L ) With :
B
2 u  (k 2  k 2 ) sinh( k L)
The reflection coefficient is R  (Eq. 11.21). Using the value of B/A
2
A v  (k 2  k 2 ) sinh( k L)
obtained in Eq. (xii) we can write (see the margin remark):
And
(k 2  k ) sinh (k L )
2 2 2
w  2k k cosh(k L)
R (xiii)
2 2 2
(k  k ) sinh (k L)  4k 2k 2 cosh2 (k L )
2
We get the result of Eq.
Using the identity sinh (k L )  cosh (k L )  1, we can simplify the denominator
2 2 (xiii).
of the RHS of Eq. (xiii) as
(k 2  k 2 )2 sinh 2 (k L )  4k 2k 2 cosh2 (k L )

 (k 2  k 2 )2 sinh 2 (k L )  4k 2k 2 sinh 2 (k L )  4k 2k 2 cosh2 (k L )  4k 2k 2 sinh 2 (k L )
 (k 2  k 2 )2 sinh 2 (k L )  4k 2k 2
77
Therefore
1
(k 2  k 2 )2 sinh2 (k L)  (k 2  k 2 )2 sinh2 (k L)  4k 2k 2 
R   (xiv)
(k 2  k 2 )2 sinh2 (k L )  4k 2k 2  (k 2  k 2 )2 sinh2 (k L) 
2mE
From Eqs.(11.6 and 11.9) we also know that k  and
2
2m(V0  E )
k  .
2
2mE 2m(V0  E )
So, k 2  ; and k 2 
2
 2
and
2m(V0  E ) 2mE 2mV0 2m(V0  E ) 2mE

k 2  k 2  2
 2
 2
; k 2k 2   2 (xv)
   2 
Substituting from Eq. (xv) into Eq. (xiv) we get the result of Eq. (11.24b):
1 1
 4k 2k 2   4E (V0  E ) 
R  1    1  
 (k 2  k 2 )2 sinh2 (k L )   V02 sinh2 (k L ) 
To calculate T we use Eq. (11.23). Hence T=1-R. Using the value of R from
Eq. (xiv) we get:
(k 2  k 2 )2 sinh 2 (k L ) 4k 2k 2
T  1 R  1 
(k 2  k 2 )2 sinh 2 (k L )  4k 2k 2 (k 2  k 2 )2 sinh 2 (k L )  4k 2k 2
1
 (k 2  k 2 )2 sinh 2 (k L ) 
 1  
 4k 2k 2 
(xvi)
Substituting from Eq. (xv) into Eq.(xvi) we get the following result of
Eq.(11.24a):
1
 V 2 sinh2 (k L ) 
T  1  0 
 4E (V0  E ) 
78
Unit 12 Finite Potential Well
UNIT 12
A quantum well system can be
constructed by inserting a thin
layer of one type of
semiconductor material between
two layers of another with a
FINITE
different band-gap. [PFMoses, CC
BY-SA 4.0
POTENTIAL
<https://creativecommons.org/licens
es/by-sa/4.0>, via Wikimedia
WELL
Commons]
Structure
12.1 Introduction 12.3 Summary
Expected Learning Outcomes 12.4 Terminal Questions
12.2 One-Dimensional Finite Potential Well 12.5 Solutions and Answers
Solving the Schrödinger Equation
Parity of the Eigen Functions
Energy Eigen Values
Symmetric Infinite Potential Well
STUDY GUIDE
In this unit you will solve the one-dimensional Schrödinger equation for a finite potential well. You
have already solved the Schrödinger equation for the infinite potential well in Unit 9. Here the
mathematical solution of the differential equation with the relevant boundary conditions are slightly
more difficult, so please study this carefully. You must also understand how the finite well is different
from the infinite well. You will use the concepts of differential and integral calculus, second order ODEs
and complex number. You must work out all the steps of each derivation and work through all the
SAQs and TQS.
“Once again I repeat : the aim of physics at its most

Steven Weinberg
fundamental level is not just to describe the world but to explain
why it is the way it is.”
79
12.1 INTRODUCTION
In Unit 9 you have solved the time independent Schrödinger equation for
a particle confined to a one-dimensional box. That was modelled by a
one-dimensional infinite potential well, in which the probability of finding
the box outside the well was exactly zero. A particle rigidly confined by an
infinite potential well is an idealization which does not correspond to any
real physical situation. Given sufficient energy, it is always possible for a
particle to escape the confines of a well. Hence, it is important that we
study the behaviour of a quantum particle in a finite potential well. The
important difference between the two systems is that in this case, even if
the kinetic energy of the particle in the well is less that the potential
energy, there is a finite probability of finding the quantum particle outside
the well.
In Sec. 12.2 we solve the Schrödinger equation for the quantum particle in
the symmetric finite potential well. As you have studied, whenever a
particle is bound to a certain region of space, the energy spectrum is
discrete and not continuous. We learn how to calculate the energy eigen
values and the corresponding eigen functions. You will see that the eigen
functions have a definite parity which is a consequence of the symmetry
of the potential function. We also study the symmetric infinite potential
well.
With this unit we complete our study of quantum mechanics. In the next
block you will study the fundamental concepts of nuclear physics.

 solve the time independent one-dimensional Schrödinger equation

for the finite potential well;
 determine the eigen functions and eigenvalues for a particle in a

one-dimensional finite potential well;
 determine the zero-point energy;
 determine the eigen functions and eigenvalues for a particle in a

one-dimensional symmetric infinite potential well; and
 state the parity of the stationary state wave functions.
12.2 ONE-DIMENSIONAL FINITE POTENTIAL

WELL
Let us first define the potential function V (x ) for the one-dimensional finite
potential well:
80
V0 for x  a
V ( x )   0 for a  x  a (12.1)
V0 for x  a
Note that the well defined by Eq. (12.1) has the following features:
 The potential energy V0 is finite for x  a as well as for x  a .
 The potential energy is zero for  a  x  a .
 The potential function V (x ) is symmetric, i.e. V ( x )  V (x )
This potential is sometimes referred to as the square potential well in

text books. V(x) is shown in Fig. 12.1.
V (x )
V  V0
V0
I II III
V=0
x  a x
0 x a
Fig. 12.1: A one-dimensional finite potential well. The potential energy

is V0 for x  a (Region I) and for x  a (Region III). It is zero
for  a  x  a (Region II).
If the total energy (E) of a classical particle is greater than the barrier
height V0 , it can move freely in the entire region, including the region
x  a and x  a . Its kinetic energy would be E  V0 in the region
x  a and x  a and E in the region  a  x  a . However, if E is less
than V0 , the classical particle would remain bound forever in the
region  a  x  a . It would move back and forth in the region with a
constant speed (and a momentum of constant magnitude) and the total
energy of the particle could have any value E  0 . Quantum mechanically,
however, a bound particle can only have certain discrete values of the
energy. Further, as you have also seen in Units 10 and 11, there is a
finite probability for the quantum mechanical particle to penetrate the
classically forbidden region i.e., x  a as well as x  a even if its
energy E  V0 .
The square shape of the potential is an over-simplification. However we

study this simpler shape because it is relatively easier to solve and it does
capture the physics for a microscopic particle bound in a region by certain
forces. An example of such a system would be a conduction electron
bound inside a metal block or a charge carrier trapped in a thin layer of 81
semiconductor sandwiched between two layers of a different
semiconductor with larger band gap than its own.
We now solve the time independent Schrödinger equation for a quantum

mechanical particle in this potential well.

Let us consider the motion of a quantum particle of mass m and total
constant energy E in the one-dimensional potential well described by Eq.
(12.1). We solve the Schrödinger equation in the three regions shown in
Fig. 12.1. Region I extends from   to a ; Region II from  a to a and
Region III from a to  . The central region is the potential well.
Let us first write down the time independent Schrödinger equation for the
particle in region II. Since the potential energy in this region is zero, we
have (with V(x)=0 in Eq. 7.47):
 2 d 2( x )
  E( x ) (for Region II) (12.2)
2m dx 2
Inside the well we have a free particle. You already know the solution of
the Schrödinger equation for a free particle (Eq. 9.23). It is:
II ( x )  A sin kx  B cos kx (for Region II:  a  x  a ) (12.3)
The total energy is
 2k 2
E (12.4)
2m
and:
2mE
k (12.5)
2
We next write the time independent Schrödinger equation for the particle
in Regions I and III ( x  a and x  a , respectively) which is:
 2 d 2( x )
  V0( x )  E( x ) (12.6)
2m dx 2
You have learnt how to solve such an equation in Unit 10 and 11. We
define a parameter k  :
2m(V0  E )
k  (12.7)
2
We can rewrite Eq. (12.6) as:
d 2( x ) d 2( x )
2

2m
2
V0  E ( x )  0 or
2
 k 2 ( x )  0 (12.8)
dx  dx
Let us write the solution for this equation for Regions I and III separately
(recall Eq. 11.10) where the wave functions are I (x ) and II (x ) ,
82 respectively:
k x  k x
 I ( x )  Ce  De (for Region I : x  a ) (12.9)
And
III ( x )  Fek x  Gek x (for Region III : x  a ) (12.10)
Let us consider that the total energy of the particle E  V0 . Therefore,

V0 
 E is positive and the parameter k  is real. We know that an
acceptable wave function must be finite for all values of x. Since the term
Dek x in Eq. (12.8) diverges as x   and the term Gek x in Eq. (12.9)
diverges as x   , for the wave function be finite in all regions we must
have :
D G  0 (12.11)
So, we can write:
 I ( x )  Ce k x (for Region I ) (12.12)
and
 III ( x )  Fe k x (for Region III) (12.13)
Let us summarize what we have studied so far.
PARTICLE IN A FINITE POTENTIAL WELL

The potential function for the one-dimension finite potential well is
V0 for x  a Region I

V ( x )   0 for a  x  a Region II (12.1)
V0 for x  a Region III
The time independent Schrödinger equation for the particle of mass m in
the three regions is:
 2 d 2( x )
  V0( x )  E( x ) (for Region I and III) (12.6)
2m dx 2
 2 d 2( x )
  E( x ) (for Region II) (12.2)
2m dx 2
The solutions of the Schrödinger equation in the three regions are:
 I ( x )  Ce k x (for Region I: x  a ) (12.12)
II ( x )  A sin kx  B cos kx (for Region II:  a  x  a ) (12.3)
 III ( x )  Fe k x (for Region III: x  a ) (12.13)
2m(V0  E ) 2mE
with: k   and k 
2 2
Next we evaluate the constants A, B, C and F using the boundary

conditions on the wave function and its derivatives. Notice that the wave
functions are different in the three regions of the potential. In order that
the wave function and its derivatives are continuous in the entire region,
83
we must match the wave functions and their derivatives at the boundaries
of the potential well.
Before we do that, let us examine a special property of a symmetric

potential function. This will help us simplify the solution for Schrödinger
equation in Region II.
XAMPLE 12.1 : PARITY OPERATOR AND THE SYMMETRIC

POTENTIAL FUNCTION
Show that, for a symmetric potential function V ( x )  V ( x ) , the parity
operator commutes with the Hamiltonian.
SOLUTION  The commutator of P̂ and Ĥ can be written as follows:
Pˆ,Hˆ   PˆHˆ  Hˆ Pˆ (i)
To determine the value of this commutator, we operate it on the wave

function (x ) :
PˆHˆ  HˆPˆ (x)  Pˆ Hˆ(x) Hˆ Pˆ(x) (ii)
Now
 2 d 2( x )
Hˆ ( x )    V ( x )( x ) (iii)
2m dx 2
In Unit 8 you have studied that the parity operator is the space inversion
operator ( x  x ) and Pˆ( x )  ( x ) . So the first term on the RHS of Eq.
(ii) is:
 
Pˆ Hˆ ( x )  
 2 d 2(  x )
2m dx 2
 V (  x )(  x )
 2 d 2(  x )
  V ( x )(  x )since V ( x )  V (  x )
2m dx 2
 2 d 2 
   V ( x ) (  x )  Hˆ (  x ) (iv)
2
 2m dx 
For the second term on the RHS of Eq. (ii) we get
 
Hˆ Pˆ( x )  Hˆ (x ) (v)
So, using Eqs. (iv) and (v) in Eq. (ii) we get:
Pˆ , Hˆ   0
Let us now apply this property to the potential function in Eq. (12.1).
12.2.2 Parity of the Eigen Functions

Recall that the finite well potential function defined by defined by Eq.
84 (12.1) is symmetric, that is V ( x )  V (x ) . So, as you have learnt by
solving Example 12.1, the Hamiltonian Ĥ of the symmetric potential
well commutes with the parity operator P̂ .
Now recall another result from Example 8.9 of Unit 8: If an operator Â

commutes with the parity operator P̂ , then the non-degenerate eigen
functions of Â have a definite parity, i.e., they are either of odd parity or
of even parity. So the solutions of the Schrödinger equation for the
symmetric finite potential well, which are the eigen functions of Ĥ , will
have a definite parity. That is: the eigen functions will either be even or
odd.
Now this helps us to simplify the wave function for Region II given by
II ( x )  A sin kx  B cos kx .
Notice that this wave function does not have a definite parity because
sin kx is an odd function [ sin k (x )   sin kx ] and cos kx is an even
function [ cos k (x )   cos kx ]. We have already established that the
wave function must have a definite parity. Therefore, either A or B
should be zero.
If we take A = 0 we get even parity solutions:
II ( x )  B cos kx (even parity : (x )  ( x ) ) (12.14)
With B = 0 we get the odd parity solutions:
II ( x )  A sin kx (odd parity : (x )  ( x ) ) (12.15)
Both solutions are valid. Now let us apply the boundary conditions. The
wave functions must match at the boundaries of the potential well and so
the boundary conditions are:
I ( x  a)  II ( x  a) (12.16a)
and
II ( x  a)  III ( x  a) (12.16b)
Let us first work out the relation between the constants for the even parity
solution: II ( x )  B cos kx . Substituting x  a in Eqs. (12.12 and 12.14),
we get from Eq. (12.16a):
Cek a  B cos k (a)  B cos ka (12.17)
Substituting x  a in Eqs. (12.13 and 12.14), we get from Eq. (12.16b):
Fe k a  B coska (12.18)
The RHS of Eqs. (12.18 and 12.17) are the same, so we can write:
Cek a  Fe k a  C  F ek a  0 (12.19)
Since e k a  0 , the following must be true for the even parity solution:
C F (12.20)
85
For the odd parity solution, II ( x )  A sin kx using Eqs.(12.16a and b)
respectively we get:
C  F (12.21)
You can verify Eq. (12.21) for yourself by solving SAQ 1.
SAQ 1 - Odd parity solution for the finite potential well
Show that for the odd parity solution II ( x )  A sin kx , C  F .
Now we can write the complete set of solutions for the finite potential well.
The even parity solutions are (using C  F ):
 I ( x )  Ce k x (for x  a ) (12.22a)
II ( x )  B cos kx (for  a  x  a ) (12.22b)
III ( x )  Cek x (for x  a ) (12.22c)
The odd parity solutions are (using C  F ) :
 I ( x )  Ce k x (for x  a ) (12.23a)
II ( x )  B sin kx (for  a  x  a ) (12.23b)
III ( x )  Cek x (for x  a ) (12.23c)
SOLUTIONS OF THE SCHRÖDINGER EQUATION
 The potential function for the one-dimension finite potential well is

symmetric, hence the Hamiltonian commutes with the parity
operator.
 The eigen functions of the Hamiltonian have a definite parity.
 The even parity solutions for E  V0 are:
 I ( x )  Ce k x (for x  a ) (12.22a)
II ( x )  B cos kx (for  a  x  a ) (12.22b)
III ( x )  Cek x (for x  a ) (12.22c)

 The odd parity solutions for E  V0 are:
 I ( x )  Ce k x (for x  a ) (12.23a)
II ( x )  B sin kx (for  a  x  a ) (12.23b)
III ( x )  Cek x (for x  a ) (12.23c)
The purpose of solving the Schrödinger equation is to obtain the eigen

functions of the Hamiltonian and the corresponding energy eigen values.
We have written down the even and odd parity eigen functions for the
bound state of the particle ( E  V0 ). However we have yet to determine
86
the constants B and C and the energy eigen values which are values of E
corresponding to these bound state eigen functions. Let us now determine
E.
12.2.3 Energy Eigen Values

We determine the constants B and C using the boundary conditions for
the continuity of the derivatives of the wave function.
You know that for (x ) to be an acceptable wave function, (x ) and
d ( x )
should be continuous for all x. Therefore the derivative of the
dx
logarithm of (x ) which is
d
ln ( x )  1 d( x ) , should also be
dx ( x ) dx
continuous. We now write the condition of continuity for the derivatives of
ln ( x ) at the boundary of Regions I and II:
1 dI ( x ) 1 dII ( x )
 (12.24)
I ( x  a) dx x  a II ( x  a) dx x  a
Since
d I
dx

d
dx
 
Cek x  Ck e k x (12.25)
and for the even parity solution II ( x )  B cos kx :
d II

d
Bk cos kx   B sin kx (12.26)
dx dx
On imposing the condition given by Eq. (12.24) on the even parity

solution, we get for x  a :
Ce
1

 k a

Ck e  k a 
B
1
cos ka
Bk sin ka  k   k tan ka (12.27)
Multiplying both sides of Eq. (12.26) by a we get:
ak   ak tanka     tan  (12.28)
We have introduced the variables  and , which are defined as follows:
2m(V0  E )a 2 2mEa2
  k a  and   ka  (12.29)
2 2
Notice that  and  are dimensionless quantities, but both  and  are
functions of the energy of the particle E.
From Eq. (12.28) we get:
2m(V0  E )a 2 2mEa2 2mV0a 2

2   2  k a 2  ka 2     R 2 (12.30)
2 2 2
  
where R is a constant that depends on the depth of the well ( V0 ) and its
width 2a:
87
2mV0a 2
R (12.31)
2
The energy eigen values can now be obtained by solving Eqs. (12.28) and
(12.30) for  and  for a fixed value of R. Combining these equation we
can write:
2   2  R 2 ;    tan  ; ,   0 for even parity states (12.32a)
Before we solve these equations you can derive the conditions equivalent
to Eq. (12.32a) for the odd parity states
Eqs. (12.32a and

SAQ 2 - Energy eigen values for the odd parity solution
12.32b) are what are
Show that for the odd parity solutions given by Eqs. (12.23 a,b,c) the boundary
known as
conditions on the continuity of the derivatives of the wave function lead to the
transcendental
equations, where the following conditions:
variable appears both
as an argument to a 2   2  R 2 ;    cot ; ,   0 for odd parity states (12.32b)
transcendental function
and elsewhere in the Eq. (12.32 a and b) are solved graphically as shown in Fig. 12.2. For this,
equation. These we plot  along the x-axis and  along the y-axis. Since both  and  are
equations are not
greater than zero, we plot only the first quadrant. The equation
solvable in closed form.
So we have to solve 2   2  R 2 represents a circle with a radius R and is plotted in Fig. 12.2
them numerically or for four different values of R. For each value of R (corresponding to the
graphically value of the product V0a 2 ), we get a different circle.
 A
B
   tan     cot 
C
R  6.2
D
R  3 / 2
  R 2  2
R
R  / 2
Fig. 12.2: Graphical Solution of Eqs. 12.32a and b. The red, blue and
black curves represent the functions    tan  ,    cot  and
2  2  R 2 respectively.
The equation    tan  and    cot  are plotted by the red and blue
lines respectively in Fig. 12.2. The solutions of Eq. (12.32a) are the
points at which the plot of the function 2   2  R 2 and
   tan  intersect. In Fig 12.2, for R  6.2 , these points of intersection
are A and C. At any point of intersection we get a value of  , say   n .
This value of n can be used to calculate the energy eigen value
88
2 2
 n
En using the relation E n  (from Eq. 12.29). Remember that this is
2m
for a particular value of R.
The solutions of Eq. (12.32b) are the points at which the plot of the
function 2   2  R 2 and    cot  intersect, which are the points B
and D in Fig.12.2 for R  6.2 . Once again, at the point of intersection, we
can calculate the energy eigen value using Eq. (12.29).
Note from Fig. 12.2 that the allowed values of  and hence E are discrete
and the number of allowed values of E increases as R increases. The
solutions of Eq. (12.32a) give us the energy eigen values for the even
parity states and the solutions of Eq.(12.32b) give us the energy eigen
values for the odd parity states.
Therefore for E  V0 , the energy levels of a particle in a finite potential
well are discrete and depend upon the well parameters ( V0 ) and its width
a. From Fig. 2.2, note that:
 For a value of R lying between 0 and /2, there is just one
possible solution of the set of Eqs. (12.32a and b) and that
corresponds to a state of even parity (obtained from the
intersection of the curves 2   2  R 2 and    tan  ). We can
write:
 2  2 2
R  R2   V0a 2 
2 4 8m
 2 2
So for 0  V0a 2  you can have just one bound state of
8m
even parity. There are no odd parity states for a value of R
between 0 and /2.
 For a value of R in the range  / 2  R   , you have one solution
of even parity and one solution of odd parity, hence two bound
states.
 For a value of R in the range  / 2  R  3 / 2 , you have two
solutions of even parity and one solution of odd parity, hence
three bound states.
 The number of bound states depends on the value of R. The
greater the value of R ( larger the value of V0 ), the greater the
number of bound states. As the value R increases, more bound
states of even and odd parities get added to the eigen functions.
 For the value of R = 6.2, you can see that there are four bound
states. The first intersection is at A, corresponds to a value of
  1 and it gives us the ground state energy for R  6.2 . It is a
state of even parity. The next intersection is at B, which
corresponds to   2 and gives us the energy of the first excited
state, and so on.
 However small be the value of R, there will always be a solution
corresponding to an intersection of the curves 2   2  R 2 and
   tan  . This ensures there will always be at least one bound
state and that this state corresponds to an even parity state. 89
 For any value of value of R, the lowest energy state is always
an even parity state
Clearly, for E  V0 the particle is bound to the well and the energy
spectrum is discrete. What if the energy of the particle is greater than
V0 ?
In that case the particle is no longer confined to the well and the energy
of the particle varies continuously from V0 to .
In Fig. 12.3, you can see typical energy level diagram for a particle in a
finite potential well. For E  V0 , you have discrete energy levels. For
E  V0 , you have a continuum of energies.
Continuum
of Energies
V  V0 V  V0
E3
Discrete
E2 energy
levels
E1
x =  a x=a
Fig. 12.3: Typical energy eigen values for a finite potential well.
ENERGY EIGEN VALUES
 The energy eigen values can be obtained by solving the

transcendental equations:
2   2  R 2 ;    tan  ; ,   0 for even parity states (12.32a)
2  2  R 2;    cot ; ,   0 for odd parity states (12.32b)

for  and  for a fixed value of R, where
2m(V0  E )a 2 2mEa2 2mV0a 2
  k a  ;   ka  ;R 
2 2 2
 For E  V0 the particle is bound to the well and the energy
spectrum is discrete.
 The lowest energy state is always an even parity state and there is
always at least one bound state.
 The number of bound states depends on the radius of the circle, R.
The greater the value of R( larger the value of V0 ), the greater
the number of bound states.
Once the energy eigen values are known, the corresponding eigen
functions can be determined by matching the wave function and its
90 derivatives at one of the boundaries x=a or x=-a. The calculation is
however complex. But we can deduce the nature of the eigen functions by
looking at the corresponding symmetric infinite square well ( i.e. V0   ).
12.2.4 Symmetric Infinite Potential Well

The symmetric infinite potential well can be written as
 for x  a

V ( x )   0 for a  x  a (12.33)
 for x  a
where we have replaced V0 by  in Eq. (12.1). Recall that we have

solved the infinite potential well in Unit 9. However, the potential well we
studied in Unit 9 was not symmetric about x  0 .
Since there is an infinite potential for x  a and x  a , we can say that

the wave function will not extend beyond the boundaries of the well.
Therefore, for both the even and odd parity solutions:
I ( x ) III ( x )  0
And for  a  x  a , we can write for the infinite symmetric potential well:
Even Parity Solution : ( x )  A cos kx (for  a  x  a ) (12.34a)
Odd Parity Solution : ( x )  B sin kx (for  a  x  a ) (12.34b)
The constants A and B are determined by the normalization condition for

the wave function. We can also write the following boundary condition for
the wave function going to zero at the boundaries of the potential well:
( x  a)  ( x  a)  0 (12.35)
Using this condition for Eq. (12.34a), we get:

( x  a )  A cos ka  0  ka  n  with n  1,3,5,... (12.36)
2
So the eigen function for the even parity state is:
Even Parity Eigen function :
 nx 
 even ( x )  A cos  with n  1,3,5,.... (12.37a)
 2a 
The corresponding eigen energy for the even parity states is found using
 2k 2
E and the value of k as obtained in Eq. (12.36) :
2m
2
 2  n 
En,even  with n  1,3,5,.... (12.37b)
2m  2a 
91
You can obtain the corresponding odd parity eigen functions and the
eigen energies by applying Eq. (12.35) to Eq. (12.34b). You may like to
work this out for yourself.
SAQ 3 - Odd parity eigen functions and eigen energies.

Show that the odd parity eigen functions and eigen energies of the symmetric
infinite potential well are:
 nx 
 odd ( x )  B sin  with n  2,4,6.... (12.38a)
 2a 
and
2
 2  n 
En,odd  with n  2,4,6.... (12.38b)
2m  2a 
(12.39)
You can see for yourself that the lowest possible energy is for n  1 in Eq.
(12.37b) which is:
 2 2
E1  (12.39a)
8ma2
 x 
This corresponds to the even parity eigen function 1( x )  A cos  .
 2a 
This is the ground state and this energy is the zero point energy. Notice
that the minimum energy is not zero.
The next energy eigenvalue is found by substituting n  2 in Eq. (12.38b):
 2 2   2 2 
E2    
2ma2
4 8ma2   4E1 (12.39b)
 
 x 
This corresponds to the odd parity eigen function  2 ( x )  B sin  .
 a 
The next energy eigen value corresponds to a even parity state, so we
evaluate it from Eq. (12.37b) with n  3 and get:
9 2  2
E3   9E1 (12.39c)
8ma2
 3x 
And the corresponding even parity eigen function is  3 ( x )  A cos .
 2a 
So as you can see, the eigen functions are alternately of even and odd
parity.
Now that we know the form of the eigen functions for the infinite potential
well, we can deduce what the eigen functions of a finite potential well
would look like. Unlike in the infinite potential well, the wave function for a
finite potential well would not go to zero at the boundaries of the potential
well. Rather the wave function would decay exponentially on both sides of
the potential well and the form of the wave function is given by
I ( x ) andIII ( x ) as described in Eqs. (12.22a and 12.22c) or Eqs.(12.23a
and 12.23c) depending on the parity of the solution.
In Fig. 12. 4(a) and (b) we plot the first three eigen functions for the
92 infinite and finite symmetric potential well respectively.
V  V0 V (x ) V  V0
V  V (x ) V 
3(x) 3(x)
2(x) 2(x)
1(x) 1(x)
x x
x =  a 0 x=a x =  a 0 x=a
.(a) (b)
Fig. 12.4: The first three eigen functions for (a) a symmetric infinite potential
well, and (b) a symmetric finite potential well
Note that the wave function extends into the classically forbidden region
on either side of the boundary of the finite potential well.
We define what is known as the penetration depth, which is the distance

to which the wave function penetrates the region beyond the boundaries
of the potential as:
1 
  (12.40)
k 2m(V0  E )
At a distance  beyond the boundary of the well the amplitude of the wave
function falls to 1/e of its value at the boundary. At this distance, the wave
function in the exterior of the well is almost zero.
Also the eigen energies for a finite well are typically less than that for an
infinite square well of the same width. This is because when the wave
functions extend upto a distance of  beyond the boundaries of the well,
we can say that the effective size of the box increases. So the typical
energies are lower.
PARTICLE IN A SYMMETRIC INFINITE POTENTIAL WELL
The potential function for the symmetric one-dimensional infinite potential

well is
 for x  a Region I

V ( x )   0 for a  x  a Region II (12.1)
 for x  a Region III
The solutions of the Schrödinger equation for a particle of mass m in the

symmetric infinite well have a definite parity:
93
PARTICLE IN A SYMMETRIC INFINITE POTENTIAL WELL
 nx 
 even ( x )  A cos  with n  1,3,5,.... (12.37a)
 2a 
 nx 
 odd ( x )  B sin  with n  2,4,6.... (12.38a)
 2a 
The eigen energies are:
2
 2  n 
En,even  with n  1,3,5.... (12.37b)
2m  2a 
2
 2  n 
En,odd  with n  2,4,6,.... (12.38b)
2m  2a 
 2 2
The ground state energy is: E1 
8ma2
12.3 SUMMARY
Concept Description
 The potential function for the one-dimension finite potential well is
Particle in a finite
V0 for x  a Region I
potential well

V ( x )   0 for a  x  a Region II
V0 for x  a Region III
The time independent Schrödinger equation for the particle of mass m
in the three regions is:
 2 d 2II ( x )
  V0( x )  E( x ) (for Region I and III)
2m dx 2
 2 d 2( x )
  E( x ) (for Region II)
2m dx 2
The solutions of the Schrödinger equation in the three regions are:
 I ( x )  Ce k x (for Region I )
II ( x )  A sin kx  B cos kx (for Region II:  a  x  a )
 III ( x )  Fe k x (for Region III)
With:
2m(V0  E ) 2mE
k  and k 
2 2
94
 The potential function for the one-dimension finite potential well is
Solutions of the
symmetric, hence the Hamiltonian commutes with the parity
Schrödinger equation
operator.
The eigen functions of the Hamiltonian have a definite parity.
The even parity solutions for E  V0 are:
 I ( x )  Ce k x (for x  a )
II ( x )  B cos kx (for  a  x  a )
III ( x )  Cek x (for x  a )

The odd parity solutions for E  V0 are:
 I ( x )  Ce k x (for x  a )
II ( x )  B sin kx (for  a  x  a )
III ( x )  Cek x (for x  a )
Energy eigen values .  The energy eigen values can be obtained by solving the
transcendental equations:
2   2  R 2 ;    tan  ; ,   0 for even parity states
2  2  R 2;    cot ; ,   0 for odd parity states

for  and  for a fixed value of R, where
2m(V0  E )a 2 2mEa2 2mV0a 2
  k a  ;   ka  ;R 
2 2 2
For E  V0 the particle is bound to the well and the energy spectrum
is discrete.
The lowest energy state is always an even parity state and there is
always at least one bound state.
The number of bound states depends on the radius of the circle, R.
The greater the value of R ( larger the value of V0 ), the greater
the number of bound states.
Particle in a symmetric  The potential function for the symmetric one-dimensional infinite
infinite potential well
potential well is
 for x  a Region I

V ( x )   0 for a  x  a Region II
 for x  a Region III
The solutions of the Schrödinger equation for a particle of mass m in

the symmetric infinite well have a definite parity:
 nx 
 even ( x )  A cos  with n  1,3,5,....
 2a 
 nx 
 odd ( x )  B sin  with n  2,4,6....
 2a 
95
The eigen energies are:
2
 2  n 
En,even  with n  1,3,5....
2m  2a 
2
 2  n 
En,odd  with n  2,4,6,....
2m  2a 
 2 2
The ground state energy is: E1 
8ma2
12. 4 TERMINAL QUESTIONS

1. Explain whether the eigen functions of the following Hamiltonian
for a particle of mass m will have a definite parity:
p2 1
H  m2 x 2
2m 2
2. Calculate the normalization constants for the wave functions of

Eqs. 12.34 and b
(i) ( x )  A cos kx (for  a  x  a )
(ii) ( x )  B sin kx (for  a  x  a )
3. Calculate the penetration depth for an electron of energy 40 eV,

trapped by an electrostatic potential of 100 eV.
4. The penetration depth for an electron is 2.0 nm. How much energy
would be required to “free” the electron from the well?

1. We use the condition given in Eq. (12.16 a), with 11x   A sin kx to
get,
C e k a  A sin k  a    A sin ka  A sin ka  Ce k a (i)
and applying the condition of Eq. (12.16a) we get
A sin ka  Fe k a (ii)
Equating the LHS of Eqs. (i) and (ii) we get:

  
 Cek a  Fek a  C  F  e k a  0
 e k a  0 we must have C  F
2. Taking II x   A sin kx we impose the condition

96
d I dII
1
x  a   1
x  a  (i)
I x  a  dx II x  a  dX
d I
From Eq. (12.25) we know:  C k  e k x (ii)
dx
dII
And 
d
A sin kx   Ak cos kx (iii)
dx dx
So, using Eq. (i) and the results of Eqs. (ii) and (iii) we get:
1

C e k a
C ke    A sin1 ka Ak cos ka  k  k cot ka
k a (iv)
or k a  ka cot ka (v)
With   k a and   ka , we get
   cot 
And from Eq. (12.30) 2  2  R 2
So, we can write the conditions for odd parity states as:
2  2  R 2;    cot , ,   0
3. Using x   B sin kx and applying Eq. (12.35) we get,

B sin ka  0  sin ka  0 or ka  n , n  2,4,6,...
2
n
 k , n  2,4,6,...
2a
 nx 
So  n ( x )  B sin , n  2,4,6,...
 2a 
2
 2k 2  2  n 
And En   , n  2,4,6,...
2m 2m  2a 
Terminal Questions
1. Following the steps of Example 12.1 we can write,
Pˆ , Hˆ   Pˆ Hˆ .x   Hˆ Pˆx  (i)
where
d2 1
Hˆ   2  m2 x 2
2 2
dx
    2 d 2 1
So Pˆ Hˆ x   Pˆ 

 m2 x 2 x 
 dx 2 2 
97
d 2  x 
m2 x 2 x 
1
  2  (ii)
dx 2 2
and

Hˆ Pˆ x  
2m

  2 d 2 (  x ) 1
2
 m 2 x 2  x 
2
(iii)
dx
From Eq. (ii) and (iii) we can write
   
Pˆ Hˆ   Hˆ Pˆ 
or Pˆ, Hˆ   0
 the parity operator commutes with the Hamiltonian, the eigen
functions will have a definite parity
2. i) The normalization condition is
a a
 x  x  dx  1  A  cos
* 2 2
kx dx  1 where
a a
n
k (n  1,3,5...)
2a
2 a 2 a
A A  
 1  cos 2 kx dx  1 
1
  x sin 2kx   1
2 2  2k  a
a
2
A  2 
 2a  2k sin 2ka  1
2  
Given that
n  n 
k (n  1,3,5...)  sin 2ka  sin 2  a  sin( n)  0
2a  2a 
2
A
 2a 1 and A A 
1
2 a
(ii) The normalization condition is written as
2a 2 n
B  sin kx dx  1 where k  , n  2,4,6...
a 2a
2 a
B
  1  cos 2 kx dx  1
2 a
2 a
B  1 
or  x sin 2kx   1
2  2k  a
98
2
B  1 
or 2a  sin 2ka   1
2  2k 
2n
sin 2ka  sin a   sin n  0
2a
2
B
 2a  1 or B B
1
2 a
3. We calculate penetration depth  using Eq.(12.40)
With V0  100 eV and E  40 eV
1.054  10 34 Js

  
So
2  9.109  10  31 kg  60  1.6  10 19 J
 .025  10 9 m  .025 nm
4. The energy required to free the electron is V0  E  .
Using Eq. (12.40) for the penetration depth  ,we can write
V0  E 
 2 (i)
2me2
with   2.0 nm  2.0  10 9 m
we get,
V0  E 
1.054  10 34
Js 
2
 0.015  10 19 J
 
2  9.109  10 31 kg  2.0  10 9 m 
2
 0.01eV
FURTHER READINGS
1. Quantum Physics of Atoms, Molecules, Solids, Nuclei and Particles,

Robert Eisberg and Robert Resnick, Wiley Student Edition (2006).
2. Modern Physics, Raymond Serway, Clement Moses and Curt Moyer,

3rd Edition, Cengage Learning (2012).
99
TABLE OF PHYSICAL CONSTANTS
Symbol Quantity Value

c Speed of light in vacuum 2.998  108 ms1
0 Permeability of free space 1.257  10 6 N A 2
0 Permittivity of free space 8.854  10 12 C2 N1 m2
1/40 8.988  109 Nm2C2
e Charge of the proton 1.602  10 19 C
e Charge of the electron 1.602  10 19 C
h Planck’s constant 6.626  10 34 Js
 h / 2 1.054  10 34 Js
me Electron rest mass 9.109  10 31 kg
 e/me Electron charge to mass ratio 1.759  1019 C kg1
mp Proton rest mass 1.673  10 27 kg
mn Neutron rest mass 1.675  10 27 kg
a0 Bohr radius 5.292  1011 m

NA Avogadro constant 6.022  1023 mol1
R Universal gas constant 8.315 J mol 1K 1
kB Boltzmann constant 1.381 10 23 J K 1

G Universal gravitational constant 6.673  10 11 N m2kg 2
100
LIST OF BLOCKS AND UNITS: BPHET-141
BLOCK 1: THE SPECIAL THEORY OF RELATIVITY
Unit 1 Postulates of Special Relativity

Unit 2 Relativistic Kinematics
Unit 3 Relativistic Dynamics
BLOCK 2: INTRODUCTION TO QUANTUM MECHANICS
Unit 4 Birth of Quantum Physics

Unit 5 Wave-Particle Duality
Unit 6 The Uncertainty Principle and its Consequences
Unit 7 Schrödinger Equation
Unit 8 Observables and Operators
BLOCK 3: APPLICATIONS OF QUANTUM MECHANICS TO SIMPLE SYSTEMS

BLOCK 4: NUCLEAR PHYSICS
Unit 13 Radioactivity
Unit 14 The Atomic Nucleus
Unit 15 Applied Nuclear Science
101
SYLLABUS: ELEMENTS OF MODERN PHYSICS (BPHET-141) 4
Credits
Special Theory of Relativity: Constancy of Speed of Light, Postulates of Special

Theory of Relativity, Lorentz Transformation, Length Contraction, Time Dilation,
Examples, Velocity Addition Theorem, Doppler Effect, Variation of Mass with Velocity,
Energy-Mass Equivalence, Relativistic Energy and Momentum.
An Introduction to Quantum Mechanics: Birth of Quantum Physics, Blackbody

Radiation, Planck’s Quantum Hypothesis, Planck’s constant and light as a collection of
photons; Photo-electric effect and Compton scattering. Problems with Rutherford
model instability of atoms and observation of discrete atomic spectra; Bohr Model,
Bohr's quantization rule and atomic stability; calculation of energy levels for hydrogen
like atoms and their spectra.
de-Broglie hypothesis and matter waves; Davisson-Germer experiment, Wave-Particle

Duality, Matter waves and wave amplitude, Wave Packet, Group Velocity.
The Uncertainty Principle and its Consequences, Thought Experiments: Position

measurement  gamma ray microscope thought experiment; Two slit interference
experiment with photons, atoms and particles; Complementarity; Estimating minimum
energy of a confined particle using uncertainty principle; Energy-time uncertainty
principle.
Postulates of Quantum Mechanics, Time Dependent and Time Independent

Schrödinger Equation in One Dimension, Statistical Interpretation of Wave Function,
Probability Current Density and Continuity Equation, Normalization of Wave Functions,
Wave Function in Momentum Space; Observables and Operators, Linear Momentum
and Energy Operators; Parity Operator and its Eigenvalues; Commutation Relations,
Expectation Values.
Applications of Quantum Mechanics: One Dimensional Infinitely Rigid Box  energy

eigen values and eigen functions, normalization, quantum dot as an example, Particle
in a Box, Free Particle, Step Potential and Rectangular Potential Barrier, Quantum
mechanical scattering and Tunneling; One Dimensional Potential Well and barrier.
Nuclear Physics: Radioactivity: Stability of nucleus; Law of Radioactive Decay, Mean

life and half-life; Radioactive Equilibria, Natural Radioactive Series, Law of  decay, 
decay  energy released, spectrum and Pauli's prediction of neutrino; -ray emission.
General Properties of Nuclei: Size and structure of atomic nucleus and its relation with
atomic weight; Impossibility of an electron being in the nucleus as a consequence of
the uncertainty principle. Nature of nuclear force, NZ graph, semi-empirical mass
formula and binding energy; Stability of Nuclei: Binding Energy Curve. Fission and
fusion  mass defect, generation of energy; Fission  nature of fragments and emission
of neutrons. Nuclear reactor: slow neutrons and their interactions with Uranium 235;
Fusion and thermonuclear reactions.
102

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BPHET-141

Block Preparation Team

Course Coordinators: Dr. Subhalakshmi Lamba, Dr. M Boazbou Newmai

Block Production Team

Unit 9 Particle in a Box 7

9.2. A FREE PARTICLE

So, for a system on which no force is exerted, we will have:

where V0 is a constant potential.

Without loss of generality, we can take the constant V0 to be zero. So now we

Let us now solve Eq. (9.1). Rearranging the terms we get:

1 ( x )  ei ( i) x  eix ex (9.11)

So, k should be a real number and therefore k 2  0 . Therefore a quantum

Since any non-negative value of E is allowed, the energy spectrum of a free

For a real value of k, 1( x ) and 2 ( x ) do not diverge at x   or as x   ,

 1 ( x )1 ( x )dx   e e dx   dx

If the quantum mechanical free particle is in a stationary state (x ) which

( x, t )  Aei kxt   Bei kxt  (9.16)

which is independent of time t as well as position x. In other words, at any

XAMPLE 9.1: MOMENTUM EIGEN VALUES

Using 1 ( x )  e ikx in Eq. (8.35) we get:

So pˆ x 1x   k 1x  . So 1 ( x ) is an eigen function of the momentum

Using  2 ( x )  e  ikx in Eq. (8.35) we get:

Since pˆ x 2 x    k 2 x , we can say that  2 ( x ) is also an eigen

Let us now summarize what you have studied so far.

The time independent Schrödinger equation for a quantum mechanical free

The general solution of Eq. (9.4) is:

The energy of the particle does not change with time.

( x, t )  Aei kxt   Bei kxt  (9.16)

You may now like to answer an SAQ.

SAQ 2 - Solutions of the free particle Schrödinger equation

In the classical picture, a free particle has “unbounded motion” because it is

With these boundary conditions, we now solve Eq. (9.20). We put

( x  0)  0  A sin k (0)  B cos k(0)  0 or B  0 (9.24)

Applying the boundary condition on the wave function at x  L , we get:

Therefore, we write k with a subscript n to denote the value of n:

9.3.2 Eigen functions and Eigen values

On substituting the second order derivative in Eq. (9.31), we get:

It is important to note the following properties of the energy eigen values of a

2. The quantization of energy follows from the boundary conditions

XAMPLE 9.2 : NORMALIZING THE WAVE FUNCTION

On evaluating the integral we get (see the margin remark):

These eigen functions are shown in Fig. 9.5.

SAQ 3- Orthogonal eigen functions

So how do we reconcile the quantum mechanical picture with our experiences

XAMPLE 9.3 : MACROSCOPIC OBJECT AS PARTICLE

SOLUTION  Assuming the toy car to be a particle of mass m = 0.2 kg

The minimum energy is the zero point energy:

The kinetic energy of the car is

K  En  1.0  10 3 J  n 2E1 and substituting for E1 we get:

XAMPLE 9.4: ELECTRON IN AN ATOMIC BOX

Calculate the energy levels of an electron confined to an atomic box of size

8meL2 8meL2 89.109  10 kg  1.0  10 

So the remaining energy levels are:

9.3.3 Time Dependent Wave Function

Using Euler’s Formula, we can write:

We next determine the probability density corresponding to these eigen

9.3.4 Probability Density

XAMPLE 9.5 : CALCULATING THE PROBABILITY

Calculate the probability of finding the particle between