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Syllabus : 2023-2024
Class – XI
Sub : Chemistry
(Theory)
Time : 3 hours, Max. marks : 70
Course Structure
Unit No. Chapters Title No. of periods Marks
Unit I Chapter-1 Some Basic Concept of Chemistry 12 07
Unit II Chapter-2 Structure of Atom 14 09
Unit III Chapter-3 Classification of Elements and 08 06
Periodicityin properties
Unit IV Chapter-4 Chemical Bonding and Molecular Structure 14 07
Unit V Chapter-6 Chemical Thermodynamics 16 09
Unit VI Chapter-7 Equilibrium 14 07
Unit VII Chapter-8 Redox Reactions 06 04
Unit VIII Chapter-12 Organic Chemistry: Some basic Principles 14 11
and Techniques
Unit IX Chapter-13 Hydrocarbons 12 10
Theory 70
TOTAL Practical 30
Grand Total 100
Class – XI
Chemistry (Theory)
Time : 3 hours, Max. marks : 70
Unit-I : Some Basic Concepts of Chemistry 12 Periods
General Introduction: Importance and scope of chemistry. Nature of matter, laws of chemical
combination,Dalton’s atomic theory: concept of elements, Atoms and molecules.
Atomic and molecular masses, mole concept and molar mass, percentage composition, empirical and
molecular formula, chemical reactions, stoichiometry and calculations based on stoichiometry.
Unit-II : Structure of Atom 14 Periods
Discovery of Electron, Proton and Neutron, atomic number, isotopes and isobars, Thomson’s model and its
limitations, Rutherford’s model and its limitation, Bohr’s model and its limitations concept of shells and sub-
shells, dual nature of matter and light, de-Broglie’s relationship, Heisenberg uncertainty principle, concept of
orbital’s, quantum numbers, shapes of s, p and d orbital’s, rules for filling electrons in orbital’s - Aufbau
principle, Pauli’s exclusion principle and Hund’s rule, electronic configuration of atoms, stability of half-
filled and completelyfilled orbital’s.
Unit-III : Classification of Elements and Periodicity in Properties 08 Periods
Significance of classification, brief history of the development of periodic table, Modern periodic law and
the
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present form of table, periodic trends improprieties of elements - atomic radii, ionic, radii, inert gas radii,
Ionization enthalpy, electron gain enthalpy, electro negativity, valency, Nomenclature of elements with atomic
number greater than 100.
Unit-IV : Chemical Bonding and Molecular Structure 14 Periods
Valence electrons, ionic bond, covalent bond, bond parameters, Lewis structure, polar character of covalent
bond, covalent character of ionic bond, valence bond theory, resonance, geometry of covalent molecules,
VSEPR theory, concept of hybridization, involving s, p and d orbitals and shapes of some simple molecules,
molecular orbital theory of homo nuclear diatomic molecules(qualitative idea only), hydrogen bond.
Unit-V: Chemical Thermodynamics 16 Periods
Concept of System and types of systems, surroundings, work, heat, energy, extensive and intensive properties,
state functions.
First law of thermodynamics-internal energy and enthalpy, heat capacity and specific heat, measurement of
U and H, Hess’s law of constant heat summation, enthalpy of bond dissociation, combustion, formation,
atomization, sublimation, phase transition, ionization, solution and dilution. Second law of Thermodynamics
(brief introduction).
Introduction of entropy as a state function, Gibb’s energy change for spontaneous and non-spontaneous
processes. Criteria for equilibrium. Third law of thermodynamic(brief introduction)
Unit-VI: Equilibrium 14 Periods
Equilibrium in physical and chemical processes, dynamic nature of equilibrium, law of mass action, equilibrium
constant, factors affecting equilibrium-LeChatelier’sprinciple.
ionic equilibrium – ionization of acids and bases, string and weak electrolytes, degree of ionization, ionization
of poly basic acids, acid strength, concept of pH, hydrolysis of salt (elementary idea) buffer solution, Henderson
Equation, solubility product, commonion effect (with illustrative examples).
Unit-VII : Redox Reactions 06 Periods
Concept of oxidation and reduction, redox reactions, oxidation number, balancing redox reactions, in terms
of loss and gain of electrons and change in oxidation number, application of redox reaction.
Unit-VIII : Organic Chemistry - Some Basic Principles and Techniques 14 Periods
General introduction, methods of purification, qualitative and quantitative analysis, classification and IUPAC
nomenclature of organic compounds. Electronic displacements in a covalent bond: inductive effect, electromeric
effect, resonance and hyper-conjugation, Homolytic and heterolytic fission of a covalent bond : free radicals,
carbocations, carbanions, electrophiles and nucleophiles, types of organic reactions.
Unit-IX : Hydrocarbons 12 Periods
Classification of Hydrocarbons
Aliphatic Hydrocarbons:
Alkanes – Nomenclature, isomerism, conformation (ethane only), physical properties, chemical
reactions including free radical mechanism of halogenations, combustion and pyrolysis.
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Alkenes – Nomenclature, structure of double bond (ethane), geometrical isomerism, physical properties,
methods of preparation, chemical reactions : addition of hydrogen, halogen, water,
hydrogen halides (Markownikov’s addition and peroxide effect), ozonolysis, oxidation, mechanism of
electrophilic addition.
Alkynes – Nomenclature, structure of triple bond (ethane), physical properties, methods of preparation,
chemical reactions : acidic character of alkynes, addition reaction of - hydrogen, halogens, hydrogen halides
and water.
Aromatic Hydrocarbons – Introduction, IUPAC nomenclature, benzene: resonance, aromaticity, chemical
properties: mechanism of electrophilic substitution. Nitration, sulphonation, halogenation, Friedel Craft’s
alkylation and acylation, directive influence of functional group in mono substituted benzene. Carcinogenicity
and toxicity.
Class – XI
Chemistry (Practical)
Total no. of periods : 60
Sl No. Evaluation scheme for Examination Marks
1 Volumetric Analysis 10
2 Salt Analysis 10
3 Lab. Note Book 03
4 Viva 02
5 Attendance 05
TOTAL 30
Quantitative Estimation
i) Using a chemical balance.
ii)) Preparation of standard solution of Oxalic acid.
ii)) Determination of strength of a given solution of Sodium Hydroxide by titrating it against standard
solution of Oxalic acid.
iv) Preparation of standard solution of Sodium Carbonate.
v) Determination of strength of a given solution of Hydrochloric acid by titrating it against standards
SodiumCarbonate solution.
Qualitative Analysis
a) Determination of one anion and one cation in a given salt
Cations – Pb2+, Cu2+, Al3+, Fe3+, Mn2+, Ni2+ Zn2+, Co2+, Ca2+, Sr2+, Ba2+, Mg2+, [NH4]+
Anions – [CO3]2–, S2–, [SO3]2–, [SO4]2–, [NO3]–, Cl–, Br–, I–, [PO4]3–, [C2O4]2–, CH3COO
(Note : Insoluble sants excluded)
Class – XI
Chemistry
Chapter wise marks distribution
Half-yearly Examination : 2023-24
Unit No. Chapters Title Marks
Unit-I Chapter-1 Some Basic Concept of Chemistry 13
Unit-II Chapter-2 Structure of Atom 14
Unit V Chapter-6 Chemical Thermodynamics 15
Unit-VII Chapter-8 Redox Reactions 08
Unit-VIII Chapter-12 Organic Chemistry: Some basic Principles and 20
Techniques
Total(Theory) 70
Total Practical 30
Grand Total 100
Annual Examination : 2023-24
Unit No. Chapters Title Marks
Unit-III Chapter-3 Classification of Elements and Periodicity in properties. 10
Unit-IV Chapter-4 Chemical bonding and molecular Structure. 20
Unit VI Chapter-7 Equilibrium 20
Unit-IX Chapter-13 Hydrocarbons 20
Total(Theory) 70
Total Practical 30
Grand Total 100
Class – XI
Chemistry
Half-yearly Examination : 2023-24
Blue Print of distribution of Marks
Unit Chapter MCQ VSA SA(I) SA(II) LA(I) LA(II) Total Marks/
1 mark 1 mark 2 marks 3 marks 4 marks 5 marks No. of
Questions
Chapter-1 Some Basic Concept 1x2 1x2 2x1 3x1 4x1 - 13
of Chemistry
Chapter-2 Structure of Atom 1x2 1x3 2x1 3x1 4x1 - 14
Chapter-6 Chemical1x2 1x2 1x3 2x1 3x1 - 5x1 15
Thermodynamics
Chapter-8 Redox Reactions 1x2 1x1 2x1 3x1 - - 08
Chapter-12 Organic Chemistry : 1x2 1x1 2x1 3x2 4x1 5x1 20
basic Principles and
Techniques
Total no. of questions 10 10 05 06 03 02 36
Total Marks 70
Annual Examination : 2023-24
Blue Print of distribution of Marks
Unit Chapter MCQ VSA SA(I) SA(II) LA(I) LA(II) Total Marks/
1 mark 1 mark 2 marks 3 marks 4 marks 5 marks No. of
Questions
Chapter-3 Classification of 1x4 1x2 2x2 - - - 10
Elements and
Periodicity in
properties.
Chapter-4 Chemical bonding and 1x2 1x3 2x1 3x3 4x1 - 20
molecular structure
Chapter-7 Equilibrium 1x2 1x4 2x1 3x1 4x1 5x1 20
Chapter-13 Hydrocarbon 1x2 1x1 2x1 3x2 4x1 5x1 20
Total no. of questions 10 10 05 06 03 02 36
Total Marks 70
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