Sainik school, Amaravathinagar.

Diwali break Holiday Assignment 2023

Class: XI
Chemistry
Note: This assignment has Part 1 & 2. Scroll the sheet till the end.
Part – I
 Revise the half yearly portions thoroughly and solve the question paper given below.
SECTION-A

Sr. MCQs Marks

No.
1. Formation of CO and CO2 illustrates the law of ————–. 1
(a) Law of conservation of mass (b) Law of Reciprocal proportion
(c) Law of Constant Proportion (d) Law of Multiple Proportion
2. Which of the following pairs of gases contains the same number of molecules? 1
(a) 8 g of O2 and 7 g of N2 (b) 8 g of O2 and 4.4 g of CO2
(c) 28 g of N2 and 22 g of CO2 (d) 32 g of O2 and 14g of N2
3. Which of the Following Statements about a Compound is Incorrect One? 1
(a) A molecule of a compound has atoms of different elements.
(b) The ratio of atoms of different elements in a compound is fixed
(c) A compound retains physical properties of its associated constituent elements
(d) A compound cannot be separated into its constituent elements by physical
methods of separation

4. Molarity of a solution that prepared by dissolved 5.85 g of NaCl(s) in 100 mL is- 1

(a) 3.65 mol/L (b) 10 mol/L (c) 0.1 mol/L (d) 1 mol/L

5. One Gram Molecule of Benzene is Equal to_____? 1

(a) 10 g C6H6 (b) 70 g C6H6 (c) 72 g C6H6 (d) 78 g C6H6

6. Which of the following statements do not form a part of Bohr’s model of hydrogen 1
atom?
(a) Energy of the electrons in the orbits are quantized
(b) The electron in the orbit nearest the nucleus has the lowest energy
(c) Electrons revolve in different orbits around the nucleus
(d) The position and velocity of the electrons in the orbit cannot be determined
simultaneously.
7. How many unpaired electron present in Cu + ion 1
a) 1 b) 6 c) 0 d) 10
8. The last entering electron in an element has quantum number n = 3, l = 2, m = + 2 and s 1
= + 1 /2. The atomic number of the element will be
(a) 13 (b) 21 (c) 29 (d) 39
9. The group number, number of valence electrons, and valency of an element with the 1
atomic number 15, respectively, are:
(a) 16, 5 and 2 (b) 15, 5 and 3 (c) 16, 6 and 3 (d) 15, 6 and 2

10. The most polar bond is 1

(a) C – F (b) C – O (c) C – Br (d) C – S
11. Among the following the electron deficient compound is 1
(a) BCl3 (b) CCl4 (c) PCl5 (d) BeCl2
12. Which one of the following statement is false? 1
(a) Work is a state function
(b) Temperature is a state function
(c) Change in the state is completely defined when the initial and final states are
specified
(d) Work appears at the boundary of the system
13. One mole of which of the following has the highest entropy? 1
(a) Liquid Nitrogen (b) Hydrogen Gas (c) Mercury (d) Diamond

14. Based on the first law of thermodynamics, which one of the following is correct? 1
(a) For an isothermal irreversible change , q = +w
(b) For an isochoric process, ΔU = -q
(c) For an adiabatic process, ΔU = -w
(d) For isothermal irreversible change , q = -w
15. Given below are two statements labelled as Assertion (A) and Reason (R) 1
Assertion (A): The empirical mass of Ethene is half of its molecular mass.
Reason (R ) : The empirical formula represents the simplest whole number ratio of
various atoms present in a compound

Select the most appropriate answer from the options given below:
a) Both A and R are true and R is the correct explanation of A
b) Both A and R are true but R is not the correct explanation of A.
c) A is true but R is false.
d) A is false but R is true.
16. Assertion (A): the atomic mass of most of the elements are fractional 1
Reason (R): most of elements occurs as mixture of isotopes.
Select the most appropriate answer from the options given below:
a) Both A and R are true and R is the correct explanation of A
b) Both A and R are true but R is not the correct explanation of A.
c) A is true but R is false.
d) A is false but R is true.
17. Assertion (A): Each orbital is designated by three quantum numbers labelled as n, l and 1
ml.
Reason (R): ‘n’ is a positive integer with value of n = 1,2,3.

Select the most appropriate answer from the options given below:
 a) Both A and R are true and R is the correct explanation of A
b) Both A and R are true but R is not the correct explanation of A.
c) A is true but R is false.
d) A is false but R is true.
18. Assertion (A): According to Mendeléev, the properties of elements are a periodic 1
function of their atomic masses.
Reason (R) : Atomic number is equal to the number of protons

Select the most appropriate answer from the options given below:
a) Both A and R are true and R is the correct explanation of A
b) Both A and R are true but R is not the correct explanation of A.
c) A is true but R is false.
d) A is false but R is true.

SEC :B

This section contains 7 questions with internal choice in two questions. The following
Questions are very short answer type and carry 2 marks each.

19. a) How many seconds are there in 2 days (Unit method calculation)? 1+
b) How are 0.50 mol Na2CO3 and 0.50 M Na2CO3 different? 1

20. i. Calculate the energy of each of the photons which 1+

(a) correspond to light of frequency 3 × 1015 Hz 1
(b) have wavelength of 0.50 0A.

ii. Yellow light emitted from a sodium lamp has a wavelength of 580 nm. Calculate the
frequency (v) and wave number (v-) of yellow light.
2
21. Consider the following species: 2
N3-, O2-, F–, Na+, Mg2+, Al3+
(a) What is common in them?
(b) Arrange them in order of increasing ionic radii?
22. Using the Periodic Table, predict the formulas of compounds which might be formed 2
by the following pairs of elements;
(a) silicon and bromine (b) aluminium and sulphur
23. i.Calculate the standard enthalpy of formation of CH3OH. from the following data: 2
(i) CH3OH(l) + 3/2 O2 (g) ———-> CO2 (g) + 2H2O (l); ∆rH0 = – 726kj mol-1
(ii) C(s) + O2(g) —————>CO2 (g); ∆cH0 = -393 kj mol-1
(iii) H2(g) + 1/2O2(g) —————->H2O (l); ∆fH0 = -286 kj mol-1

ii. The enthalpy of combustion of methane, graphite and di hydrogen at 298 K are -
890.3 KJ mol-1, – 393.5 KJ mol-1 and – 285.8 KJ mol-1 respectively. Calculate Enthalpy
of formation of CH4(g)
2
24. a) Explain why BeH2 molecule has a zero dipole moment although the 1+
Be—H bonds are polar. 1=
b) Which out of NH3 and NF3 has higher dipole moment and why? 2
25. (a) What is bond energy? Why is it called enthalpy of atomisation? 1+
(b) Write the Relationship between Cp and CV for an Ideal Gas. 1=
 2
SECTION : C
This section contains 5 questions with internal choice in two questions. The following
questions are short answer type and carry 3 marks each
26. i.50.0 kg of N2 (g) and 10.0 kg of H2 (g) are mixed to produce NH3 (g). Calculate the 2+
amount of NH3 (g) formed. Identify the limiting reagent in the production of NH3 in this 1
situation.
ii. A compound contains 4.07% hydrogen, 24.27% carbon and 71.65% chlorine. Its
molar mass is 98.96 g. What are its empirical and molecular formulas?
3
27. (a) Write designation of an orbital having n = 5,1 = 3. 1
(b) Name the spectral line series in the spectrum of H-atom obtained when an electron
jumps from n = 4 to n = 2. 1
(c ) Define Zeeman effect. 1
28. a) Show by a chemical reaction with water that Na2O is a basic oxide and Cl2O7 is 2
an acidic oxide.
b) Give the general electronic configuration of the transition elements. 1

29. a) Geometries of NH3 and H2O molecules are distorted tetrahedral but bond angle 1
in water is less than that of ammonia, why?
b) Draw the resonance structures of carbonate (CO32-) ion . 1
c) Both CO2 and H2O are triatomic molecules, the shape of H2O molecule is bent
while that of CO2 is linear, why? 1

30. (a) Out of 1 mole of H2O(g) and 1 mole of H2O(l) which one will have greater entropy? 3
(b) what will be the value of ΔG° for boiling water?
( c) What is meant by the term state function? Give one example.
(d)Define entropy. And prove that entropy is an extensive property.

3
SECTION : D
31. The spectrum of radiation emitted by a substance that has absorbed energy is
called an emission spectrum. Atoms, molecules or ions that have absorbed
radiation are said to be “excited”. To produce an emission spectrum, energy is
supplied to a sample by heating it or irradiating it and the wavelength (or
frequency) of the radiation emitted, as the sample gives up the absorbed energy,
is recorded. An absorption spectrum is like the photographic negative of an
emission spectrum. A continuum of radiation is passed through a sample which
absorbs radiation of certain wavelengths. The missing wavelength which
corresponds to the radiation absorbed by the matter, leave dark spaces in the
bright continuous spectrum. The study of emission or absorption spectra is
referred to as spectroscopy. The spectrum of the visible light, as discussed
above, was continuous as all wavelengths (red to violet) of the visible light are
represented in the spectra.

a) State dual nature of matter ( de Broglie equation and statement ) [1]

b) The Spectral Lines for Atomic Hydrogen shown in visible region are in [1]
--------------series
c) Distinguish between an Emission spectrum and an Absorption spectrum. [2]
32. In order to explain the characteristic geometrical shapes of polyatomic molecules like
CH4, NH3 and H2O etc., Pauling introduced the concept of hybridisation. According to
him the atomic orbitals combine to form new set of equivalent orbitals known as hybrid
orbitals. Unlike pure orbitals, the hybrid orbitals are used in bond formation. The
phenomenon is known as hybridisation which can be defined as the process of
intermixing of the orbitals of slightly different energies so as to redistribute their
energies, resulting in the formation of new set of orbitals of equivalent energies and
shape. For example when one 2s and three 2p-orbitals of carbon hybridise, there is the
formation of four new sp3 hybrid orbitals.

a) Why axial bonds are weaker than equatorial bonds in PCl5 [1]
b) What is the shape of compound undergoing sp3d hybridization? [1]
c) Explain conditions for Hybridisation (any two ) [2]

SECTION :E

33. (a) Explain Heisenberg’s Uncertainty Principle and its significance. 1

(b) What is the maximum number of emission lines when the excited electron of a +1
hydrogen atom in n = 6 drops to the ground state ? 1
( c) What are degenerate orbitals ?
(d) Arrange X-rays, cosmic rays and radio waves according to frequency. 1
1
(a) State and explain the following:
34. (i) Aufbau principle 1+
(ii) Pauli exclusion principle. 1+
(iii) Hund’s rule of maximum multiplicity. 1
(b) (i) How many sub-shells are associated with n = 4 ?
(ii) How many electrons will be present in the sub-shells having ms value of -1/2
for n = 4 ?
1+
1
35. a) On the basis of MOT, find the bond order of the following and Compare their 3
relative stability also indicate their magnetic properties.
O2, O2+ O2– (Superoxide),O22- (peroxide) 2
b) What is the total number of sigma and pi bonds in the following molecules?
(i) C2 H2 (ii) C2 H4

(a) Draw diagrams showing the formation of a double bond and a triple bond
36. between carbon atoms in C2 H4 and C2 H2 molecules.
(b) Is it possible for a non polar molecule to have polar bonds?, give one example. 2
( c) Use molecular orbital theory to explain why the Be2 molecule does not exist. 1
(d) Write the structure and hybridisation in case of PCl5. 1

1
37. Explain the following 1x
a) Chlorine have more negative electron gain enthalpy than fluorine 5=
b) Write the symbol and IUPAC name for atom with atomic no 102. 5
c) Write the electronic configuration of trivalent ion of element for Z= 26
 d) What Are the oxidation state and covalency of Al in [Al Cl (H2O)5 ] 2+ ?
e) State the Modern Periodic Law

Part – II
 Make a working model related to any topics of chemistry.
Few suggested topics are
1. https://youtu.be/SXJC9DRAdAU?feature=shared
2. https://youtu.be/KU2fVQnbbOc?feature=shared
3. https://youtu.be/QWn7HQZR3C8?feature=shared
4. https://youtu.be/zHNu7OycW7Q?feature=shared
5. https://youtu.be/msBnS55TMJY?feature=shared
6. https://youtu.be/AkXWH7GTu6E?feature=shared
7. https://youtu.be/ipMRalhJEaU?feature=shared
8. https://youtube.com/watch?v=pTksJeBFCcI&feature=shared
9. https://youtu.be/Sew6Of3B12A?feature=shared
10. https://youtu.be/3gel2r9EZkw?feature=shared
11. https://youtu.be/aD8ut50QMx8?feature=shared