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3D Cell Design Capability User Guide 2310

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0% found this document useful (0 votes)
22 views51 pages

3D Cell Design Capability User Guide 2310

Uploaded by

phuoc74
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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SIEMENS DIGITAL INDUSTRIES SOFTWARE

Simcenter STAR-CCM+ 3D Cell Design


Capability 2310
User Guide
Unpublished work. © 2023 Siemens

This Documentation contains trade secrets or otherwise confidential information owned by Siemens Industry
Software Inc. or its affiliates (collectively, “Siemens”), or its licensors. Access to and use of this Documentation
is strictly limited as set forth in Customer’s applicable agreement(s) with Siemens. This Documentation may
not be copied, distributed, or otherwise disclosed by Customer without the express written permission of
Siemens, and may not be used in any way not expressly authorized by Siemens.

This Documentation is for information and instruction purposes. Siemens reserves the right to make changes
in specifications and other information contained in this Documentation without prior notice, and the reader
should, in all cases, consult Siemens to determine whether any changes have been made.

No representation or other affirmation of fact contained in this publication shall be deemed to be a warranty or
give rise to any liability of Siemens whatsoever.

If you have a signed license agreement with Siemens for the product with which this Documentation will be
used, your use of this Documentation is subject to the scope of license and the software protection and
security provisions of that agreement. If you do not have such a signed license agreement, your use is subject
to the Siemens Universal Customer Agreement, which may be viewed at www.sw.siemens.com/en-US/sw-
terms/base/uca/, as supplemented by the product specific terms which may be viewed at
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About Siemens Digital Industries Software


Siemens Digital Industries Software is a global leader in the growing field of product lifecycle management
(PLM), manufacturing operations management (MOM), and electronic design automation (EDA) software,
hardware, and services. Siemens works with more than 100,000 customers, leading the digitalization of their
planning and manufacturing processes. At Siemens Digital Industries Software, we blur the boundaries
between industry domains by integrating the virtual and physical, hardware and software, design and
manufacturing worlds. With the rapid pace of innovation, digitalization is no longer tomorrow’s idea. We take
what the future promises tomorrow and make it real for our customers today. Where today meets tomorrow.
Our culture encourages creativity, welcomes fresh thinking and focuses on growth, so our people, our
business, and our customers can achieve their full potential.

Support Center: support.sw.siemens.com


Send Feedback on Documentation: support.sw.siemens.com/doc_feedback_form
Simcenter STAR-CCM+ 3D Cell Design Capability 2310 | User Guide

Contents

Simcenter STAR-CCM+ 3D Cell Design Capability..................................................................2


Accessing the Simcenter STAR-CCM+ 3D Cell Design Capability ..............................................................3
Preparing the Geometry...................................................................................................................................4
Generating the Battery Cell Mesh.................................................................................................................. 8
Setting up the Physics.................................................................................................................................... 10
Defining the Battery Cell Electrodes.....................................................................................................12
Defining the Current Collectors and Tabs, the Separator, and the Electrolyte................................. 13
Specifying the SOC ............................................................................................................................... 14
Running the Simulation................................................................................................................................. 15
Analyzing the Results..................................................................................................................................... 16

Simcenter STAR-CCM+ 3D Cell Design Capability Reference.....................................18


Pouch Cell Template View Reference.......................................................................................................... 19
Geometry Reference....................................................................................................................................... 20
Mesh Reference............................................................................................................................................... 24
Physics Reference............................................................................................................................................26
Positive Electrode Formulation Reference........................................................................................... 27
Negative Electrode Formulation Reference......................................................................................... 32
Current Collectors and Tabs Reference................................................................................................ 37
Separator Reference.............................................................................................................................. 38
Electrolyte Reference.............................................................................................................................39
OCV and SOC Reference........................................................................................................................40
Solve Reference............................................................................................................................................... 41
Post Process Reference...................................................................................................................................44
Thermal Analysis Reference.................................................................................................................. 45
Electrochemical Analysis Reference..................................................................................................... 46
Analyze Duty Cycle Reference.............................................................................................................. 48

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Simcenter STAR-CCM+ 3D Cell Design Capability 2310 | User Guide

Simcenter STAR-CCM+ 3D Cell Design Capability

In rapidly changing technology for energy sources, electric vehicles, and portable electronics, batteries play an
important role due to their efficient energy storage and release capabilities. Engineers now face the challenge
of creating reliable, long-lasting, high-performance, and safe battery packs.

For effective analysis of a battery cell, it is essential to use multi-physics models that consider the three-
dimensional electrochemical processes and precise geometric representations of the battery cell.
The Simcenter STAR-CCM+ 3D Cell Design Capability is a simulation template that uses 3D physics-based
electrochemical models to simulate high-performance lithium-ion battery cells. These models account for the
movement of charged particles within porous electrodes, intercalation reactions, charge transfer reactions,
internal particle diffusion, and the influence of temperature on transport properties. The simulation template
uses a detailed 3D geometrical representation of electrode layers, separators, and tabs.

The Simcenter STAR-CCM+ 3D Cell Design Capability provides a customized tree structure that categorizes and
groups relevant pre-defined parameters for the battery cell geometry, meshing, physics, solution methods, and
post-processing. This structure streamlines the process of customizing the template for a new battery
simulations, where parameters are easily modified to align with any specific battery cell.

The simulations are conducted based on a duty cycle approach, allowing for charge and discharge processes
that are driven by either current or power. Example duty cycle tables for constant current charge/discharge are
provided with the template package.

The template provides extensive post-processing with pre-defined plots and scenes for analyzing the battery
simulation results. It offers a comprehensive solution for battery cell designers and enhances battery pack
thermal analysis, battery cooling, thermal runaway assessment, and battery system integration.

Contents:
Accessing the Simcenter STAR-CCM+ 3D Cell Design Capability
Preparing the Geometry
Generating the Battery Cell Mesh
Setting up the Physics
Running the Simulation
Analyzing the Results

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Simcenter STAR-CCM+ 3D Cell Design Capability 2310 | User Guide

Accessing the
Simcenter STAR-CCM+ 3D Cell Design Capability

The Simcenter STAR-CCM+ 3D Cell Design Capability is available from the Simcenter STAR-CCM+ Support
Center directory.

Note: Simcenter STAR-CCM+ 3D Cell Design Capability requires a batterysim license feature in addition
to the other license features.

Before you begin downloading your application, you must have:


• A login to the Siemens Digital Industries Software Support Center
• A double precision version of Simcenter STAR-CCM+ 2310 installed

To access the stack cell template simulation file:


1. Use your web browser to navigate to https://support.sw.siemens.com/en-US/product/226870983/
downloads and log in. If you do not have your account information, contact your
Siemens Digital Industries Software representative.
2. In the Major Releases panel, select the large Simcenter STAR-CCM+ 2310 tile.
a) On the Simcenter STAR-CCM+ 2310 page, select the Simcenter STAR-CCM+ Application Specific
Solutions tag from the column of tags on the lefthand side of the page.

b) In the middle selection column, click next to Simcenter STAR-CCM+ 2310 - 3D Cell
Design Capability Stack Template.zip and unpack to your chosen working folder.

To start a simulation:

3. Start a double-precision version of Simcenter STAR-CCM+.


4. In the Simcenter STAR-CCM+ menu, select File > Load.
5. In the Load a File dialog:
a) In the Process Options box, select an appropriate parallel option and set the number of Compute
Processes.
b) Click Browse.
c) In the Open dialog, navigate to the folder where you have downloaded the template and select 3D
Cell Design Capability Stack Template 2310.simt.
d) Click Open, then OK.
The template file loads up displaying the Pouch Cell Template View.
6. Before making any modifications, you are advised to save the simulation with a different name.

The Simcenter STAR-CCM+ 3D Cell Design Capability stack cell template provides a simulation guide—an
embedded document with guidance information on how to use the template.

7. To view the simulation guide, select File > Simulation Guide.


The Simulation Guide opens in the graphics window.

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Preparing the Geometry

Preparing the battery cell geometry involves defining the physical dimensions, structure, and placement of the
components for the battery pouch (stack) cell simulation.

The Simcenter STAR-CCM+ 3D Cell Design Capability stack cell template provides pre-defined geometric
parameters that are set to default values.

The Geometry custom tree consists of the following components:


• Positive and negative electrodes
• Tabs
• Separator
• Cell assembly
• Stack package foil

The following images provide a description of the geometry and the available parameters that are defined in
the Simcenter STAR-CCM+ 3D Cell Design Capability stack cell template.

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Simcenter STAR-CCM+ 3D Cell Design Capability 2310 | User Guide

To prepare the battery cell geometry:


1. In the Pouch Cell Template view, right-click the Geometry custom tree and select Open.
2. In the Geometry custom tree, right-click the Cell Geometry Visualization layout view and select Open.
A selection of scenes displaying a preview of the battery cell geometry from different perspectives opens
in the Graphics window.

You configure a single plate, the total number of plates is defined when you configure the cell assembly. The
dimensions of the electrode are specified in relation to the separator dimensions. You define the positive
electrode and the negative electrode independently, but the procedure is the same for both.

3. Expand the Positive Electrode/Negative Electrode group and edit the following parameters:
◦ Positive_Coating_Thickness/Negative_Coating_Thickness
◦ PositiveCollector Thickness/Negative_Collector_Thickness
◦ Positive_Height_Margin/Negative_Height_Margin—the positive/negative electrode is centered
with respect to the separator and applies the same margin at the top and bottom of the positive/
negative electrode.

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◦ Positive_Width_Margin/Negative_Width_Margin—the positive/negative electrode is centered


with respect to the separator and applies the same margin at the left and right of the positive/
negative electrode.

The location of the tabs on each electrode is determined by an offset from the separator centerline. The
parameters are designed to prevent the tab dimensions from exceeding the dimensions of the electrodes.

4. To define the tabs geometry, expand the Tabs group and set the following parameters:
◦ Negative_Tab_Offset—set in +X direction. A value of zero suggests that the tab is centered with
the negative electrode.
◦ Negative_Tab_Width
◦ Positive_Tab_Offset—set in +X direction. A value of zero suggests that the tab is centered with the
positive electrode.
◦ Positive_Tab_Width
◦ Tabs_Height—is equally divided between the pinch and weld. The current design in the template
places the weld at the bottom of the battery cell.
◦ Tabs_Pinch_Height
Refer to the Simulation Guide for examples on tab offset settings.

As the separator layer is used as a reference for the electrode dimensions, it is always larger than the
electrodes.

5. To define the separator geometry, expand the Separator group and set the following parameters:
◦ Separator_Height
◦ Separator_Thickness
◦ Separator_Width

After you have set the geometrical dimensions, you select the total number of electrodes and set the sequence
for configuring the electrodes in the stack.

6. To configure the stack, expand the Cell Assembly group and set the following parameters:
◦ End_Electrodes_Pattern_A-B_or_A-B-A—for the A-B pattern, the stack starts and ends with
different polarities. For the A-B-A pattern, the stack starts and ends with the same polarity.

Refer to the Simulation Guide for examples on electrode patterns.


◦ Opposite_Tab_Design—the orientation for the electrode tabs. Set to 0 for the same side tabs
orientation or set to 1 for opposite side tabs orientation.

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◦ Starting_Electrode_Negative_or_Positive—the order that the electrodes with start in +Z direction.


Set to 0 to start the stack with a negative electrode or set to 1 to start with a positive electrode.

◦ Total Number of Double-Coated Electrodes—the number of layers for a given polarity. For
example, if you select 10 electrodes, the cell assembly with A-B pattern has 5 double-coated
positive and 5 double-coated negative electrodes. However, if you start with a negative electrode
and an A-B-A pattern, the battery cell will have 5 positive electrodes and 6 negative electrodes.
The number of separators in the cell is equal to the total number of electrodes + 1, that is, there is a
separator layer between adjacent electrodes and an additional separator at either end of the stack.
7. To define the stack package foil geometry that encloses the battery cell assembly, expand the Stack
Package Foilgroup and set the following parameters:
◦ Package_Foil_Radius
◦ Package_Foil_Thickness

When the battery cell configuration is modified, a caution symbol appears on the CAD Status node. To update
the battery stack cell geometry, you activate and run the Update CAD simulation operation sequence.

8. Right-click the Update CAD simulation operation and select Activate.


9. To run the operation sequence, right-click the Update CAD simulation operation and select Play/Resume
Simulation Operations.
After the simulation operation has finished, the geometry is updated.

For further information on the geometry parameters, see Geometry Reference.

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Simcenter STAR-CCM+ 3D Cell Design Capability 2310 | User Guide

Generating the Battery Cell Mesh

The Simcenter STAR-CCM+ 3D Cell Design Capability stack cell template provides pre-defined global and local
mesh refinement parameters for discretizing the battery cell.

The template uses directed meshing for discretizing the battery cell. Directed meshing sweeps the mesh from
the surface of the geometry through its volume based on a specified mesh base size and a number of mesh
layers for each component. A volume mesh pattern is then used to replicate the single plate mesh across the
entire cell assembly. This ensures consistent meshing throughout the cell.

You use the Mesh custom tree to specify the mesh settings and pattern for the battery stack cell components.

To generate the battery cell mesh:

1. In the Pouch Cell Template view, right-click the Mesh custom tree and select Open.
2. In the Mesh custom tree, right-click the Cell Mesh Visualization layout view and select Open.
A selection of scenes that display the mesh of the cell from different perspectives open in the Graphics
window.

You specify an overall mesh base size and the number of mesh layers for each component. Local mesh
refinement (applied in all directions) is available for the tabs mesh only.

3. Set the Mesh Base Size that applies to all battery cell components.
4. Expand the following groups in turn and specify the number of mesh layers for each of them:
◦ Positive Electrode
◦ Negative Electrode
◦ Separator
◦ Package Foil
5. Expand the Tabs group and specify Mesh_Refinement_For_Tabs and Number of volume cells in tab
height

When parameters of the battery cell mesh are modified, a caution symbol appears on the Mesh Status node
which indicates that the mesh is no longer up to date and requires re-execution. To update the battery stack
cell mesh, you activate and run the Update Mesh simulation operation sequence.
6. Right-click the Update Mesh simulation operation and select Activate.
7. To run the operation sequence, right-click the Update Mesh simulation operation and select Play/
Resume Simulation Operations.
After the simulation operation has finished, the mesh is updated. The Cell Mesh Visualization scenes
update to reflect the changes to the mesh. The following screenshot shows an example battery mesh
with tab refinement.

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Simcenter STAR-CCM+ 3D Cell Design Capability 2310 | User Guide

8. You can use the Representations > Volume Mesh node to assess the number of volume cells in the
mesh.

For further information on the mesh parameters, see Mesh Reference.

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Setting up the Physics

The Simcenter STAR-CCM+ 3D Cell Design Capability stack cell template provides the physics models for
advanced 3D modeling of the electrochemical processes occurring in a lithium ion battery cell.

The physics models in the template account for the movement of charged particles within porous electrodes,
intercalation reactions, charge transfer reactions, internal particle diffusion, and the influence of temperature
on transport properties.

The following image is an example representation of a 3D resolved electrode stack:

The template uses the Concentrated Electrolyte model for the electrolyte transport and the Sub-grid Particle
Intercalation model for the storage and transport of lithium atoms in the electrodes host solid phases. The
Concentrated Electrolyte model requires the Electrodynamic Potential model to determine the electric
potential and current in the electrolyte regions.

The Sub-grid Particle Intercalation model resolves electrochemical reactions on geometrically unresolved
surfaces. It assumes that the active material is composed of spherically shaped particles into which lithium
atoms can diffuse. The vacancies within the active electrode material are defined by using the Porous Media
model and the electrochemical reactions are defined by the Electrochemical Reactions model.
For more information on the physics models, see the Simcenter STAR-CCM+ User Guide:
• Home > Physics Simulation > Electrochemistry > Battery Cells > Battery Cells Reference.
• Home > Physics Simulation > Electrochemistry > Electrochemical Surface Reactions >
Electrochemical Surface Reactions Reference > Reacting Surface Model Reference.

The Physics custom tree consists of the following components:

• Positive Electrode Formulation


• Negative Electrode Formulation
• Current Collectors and Tabs
• Separator

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Simcenter STAR-CCM+ 3D Cell Design Capability 2310 | User Guide

• Electrolyte
• OCV and SOC

The following steps are followed for defining the parameters that are available within the Physics custom tree.

Contents:
Defining the Battery Cell Electrodes
Defining the Current Collectors and Tabs, the Separator, and the Electrolyte
Specifying the SOC

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Simcenter STAR-CCM+ 3D Cell Design Capability 2310 | User Guide

Defining the Battery Cell Electrodes

Defining the battery cell electrodes involves setting up the equilibrium potential curves, specifying the
electrode formulation (materials and weight fractions), and the electrode kinetics.

The Simcenter STAR-CCM+ 3D Cell Design Capability stack cell template provides pre-defined electrode
formulation parameters (materials and conditions) for the active materials, conductors, and binders.

You use the Physics custom tree to define the electrodes.

To define the electrodes:


1. In the Pouch Cell Template view, right-click the Physics custom tree and select Open.
2. Right-click the Positive Electrode Formulation custom tree and select Open.
3. Expand the Positive Electrode Parameters group and specify the formulation, kinetics, and initial
condition parameters for the positive electrode. For more information, see Positive Electrode Parameters.
4. Right-click the Negative Electrode Formulation custom tree and select Open.
5. Expand the Negative Electrode Parameters group and specify the formulation, kinetics, and initial
condition parameters for the positive electrode. For more information, see Negative Electrode
Parameters.

The Simcenter STAR-CCM+ 3D Cell Design Capability stack cell template uses half-cell equilibrium potential
curves for the electrode active material potential changes relative to their concentration in the cell. The tables
are specified in the following format:

<Number> <X> <E(V)> <dE/dX(V)> <d2E/dX2(V)>

6. To define the positive electrode equilibrium potential curves, select the Positive Electrode Formulation
> Equilibrium Potential Positive node and, using the (Custom Editor), navigate to the desired folder
and select your equilibrium potential positive curve.
7. To define the negative electrode equilibrium potential curves, select the Negative Electrode
Formulation > Equilibrium Potential Negative node and, using the (Custom Editor), navigate to
the desired folder and select your equilibrium potential negative curve.
8. You can use the Physics > Voltage Equilibrium Curves layout view to examine your electrode
equilibrium potential plots.
9. (Optional) To assess the physics models used to model the electrodes, or to define any of the parameters
as field functions or tables, use the following groups:
◦ Positive Electrode Conductor Definition
◦ Positive Electrode Binder Definition
◦ Positive Electrode Active Material Definition
◦ Negative Electrode Conductor Definition
◦ Negative Electrode Binder Definition
◦ Negative Electrode Active Material Definition

For further information on defining the electrodes, see Positive Electrode Formulation Reference and Negative
Electrode Formulation Reference.

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Simcenter STAR-CCM+ 3D Cell Design Capability 2310 | User Guide

Defining the Current Collectors and Tabs, the Separator, and


the Electrolyte

The Simcenter STAR-CCM+ 3D Cell Design Capability stack cell template provides pre-defined material
parameters with default values for the current collectors and tabs, the separator, and the electrolyte.

In the template, the electrolyte is a combination of lithium/salt and solvent, the separator is a porous solid
phase, and the current collectors and tabs are defined as solids.

You use the Physics custom tree to define the positive and negative collectors and tabs, the separator, and the
electrolyte.

Define the negative and positive collectors and tab:

1. Define the negative and positive collectors and tab.


a) In the Physics custom tree, right-click the Current Collectors and Tabs custom tree and select
Open.
b) In the Current Collectors and Tabs custom tree, set the densities for the negative and positive
current collectors. For more information, see Current Collectors and Tabs Reference.
2. Define the separator.
a) In the Physics custom tree, right-click the Separator custom tree and select Open.
b) In the Separator custom tree, select the Separator_Density parameter and specify the density of
the separator material.
c) In the Separator custom tree, expand the Separator Porosity Properties group and specify the
porosity and the tortuosity for the separator material. For more information, see Separator
Reference.
3. Define the electrolyte.
a) In the Physics custom tree, right-click the Electrolyte custom tree and select Open.
b) In the Electrolyte custom tree, expand the Electrolyte Parameters Properties group and specify
the electrolyte density and lithium ion molar concentration. For more information, see Electrolyte
Reference.
The template defines molecular diffusivity of each electrolyte component. When updating to a
different electrolyte, you are recommended to modify the salt diffusivities only, and maintain the
default values for the solvent. This is important for preserving mass conservation in the salt
transport equation.

If you have an electrolyte database available, you can replace the salt in the electrolyte mixture.

4. (Optional) To replace the salt from your database, right-click the Liquid ComponentsLiClO4 PC DME 1 1
node, select Replace with... and then select a replacement material from the list in the Replace Mixture
Component dialog and click OK.

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Specifying the SOC

The state of charge (SOC) indicates the current energy level or capacity of a battery as a percentage of its
maximum capacity.

You specify the maximum/minimum voltage limits (corresponding to 100% and 0% state of charge) and the
initial charge of the battery cell, represented on a scale from 0 (complete discharge) to 1 (full charge).

The template uses the initial electrode stoichiometry, voltage limits, initial state of charge, and electrode
masses to compute the open circuit voltages within the specified voltage limits.
You use the Physics custom tree to specify the SOC.

To specify the SOC:

1. In the Physics custom tree, right-click the OCV and SOC custom tree and select Open.
2. In the OCV and SOC custom tree, specify the SOC limits and the initial charge of your battery cell. For
further information, see OCV and SOC Reference.

To compute the open circuit voltages, you activate and run the Initialize SOC simulation operation sequence.

3. Right-click the Initialize SOC simulation operation and select Activate.


4. To run the operation sequence, right-click the Initialize SOC simulation operation and select Play/
Resume Simulation Operations.
The SOC initialization progress is displayed in the Output window.

The following screenshot shows the OCV vs Absolute Capacity template pre-defined plot. This displays
an example of the computed open circuit voltages relative to the lithium ion concentration after running
the Initialize SOC simulation operation.

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Simcenter STAR-CCM+ 3D Cell Design Capability 2310 | User Guide

Running the Simulation

To run battery stack cell simulations, an input duty cycle is required to specify the operating conditions and
parameters for the charge-discharge cycles.

The Simcenter STAR-CCM+ 3D Cell Design Capability stack cell template uses an Input Duty Cycle table that
defines the operational parameters for running the battery simulation. Within this table, you configure
stopping criteria, current, power, or voltage settings.

You use the Solve custom tree to specify the duty cycle and run the battery simulation.

To run the simulation:

1. In the Pouch Cell Template view, right-click the Solve custom tree and select Open.
2. In the Solve custom tree, select the Global Initial Temperature parameter and specify the initial
temperature of the battery cell.

The Simcenter STAR-CCM+ 2310 - 3D Cell Design Capability Stack Template.zip package
contains example input duty cycle tables to set up constant current charge/discharge simulations. Navigate to
the template download directory and copy the Input Duty Cycle file that you find relevant.

3. Select the Input Duty Cycle table and, using the (Custom Editor), navigate to the folder of your input
duty cycle table, select the input duty cycle file and click Open.
For details on the input duty cycle procedures, see Solve Reference.

After you have defined your operating conditions, the simulation can be run. You run the simulation by
activating and running the Duty Cycle Sim Op simulation operation sequence.

4. Right-click the Duty Cycle Sim Op simulation operation and select Activate.
5. To run the operation sequence, right-click the Duty Cycle Sim Op simulation operation and select Play/
Resume Simulation Operations.
The simulation continues until the criteria that are specified on Input Duty Cycle are met.

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Analyzing the Results

Once the simulation has finished running, you can analyze the results by using the available post-processing
functionalities.

The Post Process custom tree consists of the following components:


• Thermal Analysis
• Electrochemical Analysis
• Analyze Duty Cycle

To analyze the temperature distribution results:

1. In the Pouch Cell Template view, right-click the Post Process custom tree and select Open.
2. In the Post Process custom tree, right-click the Thermal Analysis custom tree and select Open.
A selection of scenes and plots that display the temperature distribution, or the total heat that is
generated by the battery cell are available. For further information on thermal analysis post-processing
parameters, see Thermal Analysis Reference.

To analyze the electrochemical behaviour of the battery cell:

3. In the Post Process custom tree, right-click the Electrochemical Analysis custom tree and select Open.
4. In the Electrochemical Analysis custom tree, right-click the Electric Current Densities layout view and
select Open.
The following screenshot shows an example of the electric current densities distribution scenes available
in the template.

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5. Select the following custom trees to review the battery cell electrochemical behaviour, for example,
lithium/salt concentration in the active materials, or the electric potential.
◦ Molar Concentration Negative Active Material
◦ Molar Concentration Positive Active Material
◦ line section Li+ concentration plots
◦ Electric Potential
For further information, see Electrochemical Analysis Reference.

To examine the voltage, current and cell capacity of the battery cell:

6. In the Post Process custom tree, right-click the Analyze Duty Cycle custom tree and select Open.
7. In the Analyze Duty Cycle custom tree open the plots for battery cell duty cycle, voltage, current and
capacity. For more information, see Analyze Duty Cycle Reference.

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Simcenter STAR-CCM+ 3D Cell Design Capability


Reference

This section provides descriptions for the parameters that are available within the
Simcenter STAR-CCM+ 3D Cell Design Capability.

Contents:
Pouch Cell Template View Reference
Geometry Reference
Mesh Reference
Physics Reference
Solve Reference
Post Process Reference

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Simcenter STAR-CCM+ 3D Cell Design Capability 2310 | User Guide

Pouch Cell Template View Reference

The Simcenter STAR-CCM+ 3D Cell Design Capability Pouch Cell Template provides the main workflow to guide
you through the setup of battery stack (pouch) cell simulations.

The Pouch Cell Template consists of the following aspects:


• Cell Design Geometry View
• Summary Report
• Geometry
• Mesh
• Physics
• Solve
• Post Process

Cell Design Geometry View


A scene showing the battery cell geometry.

Summary Report
When you right-click the Summary Report and select Open Summary, provides an overview of the battery cell
design results, stack general metrics, electrode formulation, and stack assembly information. A summary
report for some parts of the simulation that are of main interest. Use this node to output a simulation summary
report for the stack general metrics and layout results, and the electrodes formulation.

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Geometry Reference

The Geometry custom tree allows you to modify the physical dimensions of a battery stack (pouch) cell
geometry.

The stack cell geometry consists of the following components:


• Positive and negative electrodes
• Tabs
• Separator
• Cell assembly
• Stack package foil

Cell Geometry Visualization


Provides a selection of scenes that display the battery cell geometry from different perspectives.

Positive Electrode
The Positive Electrode group allows you to specify the dimensions of an individual plate of the positive
electrode in a battery stack cell.

Positive_Coating_Thickness
Specifies the thickness for the positive electrode coating layer.

Positive_Collector_Thickness
Specifies the thickness for the positive electrode current collector layer.

Positive_Height_Margin
Specifies the height margin for the positive electrode in relation to the separator height. In the
Simcenter STAR-CCM+ 3D Cell Design Capability stack template the positive electrode is always centered
with respect to the separator and applies the same margin at the top and bottom of the positive electrode.

Positive_Width_Margin
Specifies the width margin for the positive electrode in relation to the separator height. In the
Simcenter STAR-CCM+ 3D Cell Design Capability stack template the positive electrode is always centered
with respect to the separator and applies the same margin at the left and right side of the positive
electrode.

Negative Electrode
The Negative Electrode group allows you to specify the dimensions of a single plate of the negative electrode
in a battery stack cell.

Negative_Coating_Thickness
Specifies the thickness for the negative electrode coating layer.

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Negative_Collector_Thickness
Specifies the thickness for the negative electrode current collector layer.

Negative_Height_Margin
Specifies the height margin for the negative electrode in relation to the separator height. In the
Simcenter STAR-CCM+ 3D Cell Design Capability stack template the negative electrode is always centered
with respect to the separator and applies the same margin at the top and bottom of the negative electrode.

Negative_Width_Margin
Specifies the width margin for the negative electrode in relation to the separator height. In the
Simcenter STAR-CCM+ 3D Cell Design Capability stack template the negative electrode is centered with
respect to the separator and applies the same margin at the left and right side of the negative electrode.

Tabs
The Tabs group allows you to specify the dimensions of the tabs for a single plate of the negative and positive
electrode in a battery stack cell.

Negative_Tab_Offset
Specifies the offset between the center of the tab to the center of the negative electrode, in +X direction. A
value of zero means that the tab is centered with the negative electrode.

Negative_Tab_Width
Specifies the width of the negative electrode tab.

Positive_Tab_Offset
Specifies the offset between the center of the tab to the center of the positive electrode, in +X direction. A
value of zero means that the tab is centered with the positive electrode.

Positive_Tab_Width
Specifies the width of the positive electrode tab.

Tabs_Height
Specifies the tab height for the negative and positive electrode tabs. The tabs height is equally divided
between the pinch and weld. The current design in the template places the weld at the bottom of the
battery cell.

Tabs_Pinch_Height
Specifies the height of the pinched tabs area.

Separator
The Separator group allows you to specify the dimensions of an individual plate of the separator in a battery
stack cell.

Separator_Height
Specifies the height of the separator, which is used as the reference for calculating the electrode heights.

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Separator_Thickness
Specifies the thickness of the separator.

Separator_Width
Specifies the width of the separator.

Cell Assembly
The Cell Assembly group allows you to configure the stacking of electrodes.

End_Electrodes_Pattern_A-B_or_A-B-A
Controls the sequence for configuring the negative and positive electrodes in the stack. You can specify a
value of 0 or 1 for this dimensionless parameter.
A value of 0 corresponds to the A-B pattern, which means that the stack is starting and ending with
different polarities. A value of 1 corresponds to the A-B-A pattern, which means that the stack is starting
and ending with the same polarity.

Opposite_Tab_Design
Specifies the orientation of the electrode tabs.
You can specify a value of 0 or 1 for this dimensionless parameter.
A value of 0 signifies that the tabs are oriented to be on the same side. A value of 1 signifies that the tabs
are on the opposite side of the battery cell.

Starting_Electrode_Negative_or_Positive
Specifies the order in which the electrodes start within the battery stack.
You can specify a value of 0 or 1 for this dimensionless parameter.
A value of 0 means that the stacking starts with a negative electrode under the positive z component. A
value of 1 means that the stacking starts with a positive electrode under the positive z component.

Total Number of Double-Coated Electrodes


Specifies the total number of double-coated electrodes, that is, the sum of all double-coated positive and
negative electrodes for a given polarity.
For example, for an A-B pattern, a value of 10 represents a configuration that has 5 double-coated positive
electrodes and 5 double-coated negative electrodes. If the assembly starts with a negative electrode and an
A-B-A pattern, the battery cell has 5 positive electrodes and 6 negative electrodes.

Stack Package Foil


The Stack Package Foil group allows you to specify the dimensions of the package foil in a battery stack cell.

Package_Foil_Radius
Specifies the radius of the battery cell package foil at the round corners.

Package_Foil_Thickness
Specifies the thickness for the battery cell assembly package foil.

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Update CAD
A simulation operation sequence that updates the simulation operations that interact with geometry control
features in Simcenter STAR-CCM+ 3D Cell Design Capability stack template. You activate and run the Update
Cad simulation operation sequence to update the geometry after any modifications are made.

CAD Status
Provides the geometry status for the battery cell. When the configuration of a battery cell element is modified,
a caution symbol appears on the CAD Status node to indicate the changes.

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Mesh Reference

The Mesh custom tree allows you to define and control the volumetric discretization of the battery stack
(pouch) cell domain.

The stack cell mesh consists of the following components:


• Positive and negative electrodes
• Tabs
• Separator
• Stack package foil

Cell Mesh Visualization


Provides a selection of scenes that display the battery cell mesh from different perspectives.

Mesh Base Size


Sets the overall mesh base size for the battery stack cell parts.

Positive Electrode
The Positive Electrode group allows you to specify the mesh settings of a single plate of the positive electrode
in a battery stack cell.

Number Of Mesh Layers in Positive Coating


Specifies the number of mesh layers to discretize the thickness of the positive electrode coating.

Number Of Mesh Layers in Positive Collector


Specifies the number of mesh layers to discretize the thickness of the positive electrode current collector.

Negative Electrode
The Negative Electrode group allows you to specify the mesh settings of a single plate of the negative
electrode in a battery stack cell.

Number Of Mesh Layers in Negative Coating


Specifies the number of mesh layers to discretize the thickness of the negative electrode coating.

Number Of Mesh Layers in Negative Collector


Specifies the number of mesh layers to discretize the thickness of the negative electrode current collector.

Tabs
The Tabs group allows you to specify the mesh refinement and settings of a single plate of the negative and
positive electrode tabs in a battery stack cell.

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Mesh_Refinement_For_Tabs
Specifies the mesh local refinement level near the tabs. The mesh refinement for the tabs is specified as a
percentage of the Mesh Base Size.

Number of volume cells in tab height


Specifies the number of mesh layers to discretize the height (+Y direction) of the tabs.

Separator
The Separator group allows you to specify the mesh settings of a single plate of the separator in a battery
stack cell.

Number Of Mesh Layers in Separator Coating


Specifies the number of mesh layers to discretize the thickness of the separator.

Stack Package Foil


The Stack Package Foil group allows you to specify the mesh settings of the package foil of the battery stack
cell.

Number Of Mesh Layers in Package Foil


Specifies the number of mesh layers to discretize the thickness of the package foil.

Update Mesh
A simulation operation sequence that re-generates the volume mesh of the battery cell.

Mesh Status
Provides the status of the battery cell mesh. A caution icon appears on the Mesh Status node which indicates
that geometry or mesh parameters have been modified and the mesh must be re-generated.

Representations
Lists all the different representations of the model: geometry, surface mesh or volume mesh. Use the Volume
Mesh representation node to assess the number of cells in the mesh.

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Physics Reference

The Physics custom tree provides you with the models to simulate the three-dimensional electrochemical
processes within battery stack (pouch) cell.

The selected models and their pre-defined parameters account for the material properties and conditions of all
the relevant battery components. These include electrode equilibrium voltage curves, state of charge (SOC)
conditions, and electrochemical reactions and charge transfer processes at the electrode-electrolyte interface.

This section provides descriptions for the parameters that are available within the Physics custom tree.

Voltage Equilibrium Curves


Provides plots that display the voltage equilibrium curves in relation to the concentration within the active
material of each electrode.

Contents:
Positive Electrode Formulation Reference
Negative Electrode Formulation Reference
Current Collectors and Tabs Reference
Separator Reference
Electrolyte Reference
OCV and SOC Reference

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Positive Electrode Formulation Reference

The Physics > Positive Electrode Formulation custom tree allows you to modify the battery stack (pouch)
positive electrode formulation.

Positive Electrode Parameters

1-Formulation
bruggeman parameters Alpha pos electrode
to model tortuosity / The coefficient for the Bruggeman method, used to calculate the positive
porosity correlation electrode effective electrical conductivity.

a pos electrode
A pre-exponential factor for the Bruggeman method.

b pos electrode
The exponent factor for the Bruggeman method.

The tortuosity for the positive coating, computed as τ = aχ−b. Where a is the a
pos electrode parameter, χ is the positive coating porosity, and b is b pos
electrode.
Densities Positive Active Material Density
The density of the positive active material.

Positive Binder Density


Density of the positive binder.

Positive Conductor Density


The density of the positive conductor.

Output (read only) Output: Positive Solid Density


Outputs the resulting density of the positive electrode based on the volume
fractions and material densities of the active material, binder, and conductor.
Weight Fractions Positive Active Material Solid Weight Fraction
The solid weight fraction of the active material relative to the total mass of the
positive electrode.

Positive Binder Solid Weight Fraction


The solid weight fraction of the binder material relative to the total mass of the
positive electrode.

Positive Conductor Solid Weight Fraction


The solid weight fraction of the conductor material relative to the total mass of
the positive electrode.

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1-Formulation

Output (read only) Output: Positive Active Material Solid Volume Fraction
Outputs the volume fraction of the positive electrode solid active material
relative to the total volume of solids in the positive electrode.

Output: Positive Binder Solid Volume Fraction


Outputs the volume fraction of the positive electrode binder material relative
to the total volume of solids in the positive electrode.

Output: Positive Coating Solid Total Volume Fraction


Outputs the volume fraction of the positive electrode coating material relative
to the total volume of solids in the positive electrode.

Output: Positive Coating Solid Total Weight Fraction


Outputs the weight fraction of the positive electrode solid positive coating
material relative to the total mass of solids in the positive electrode.

Output: Positive Conductor Solid Volume Fraction


Outputs the volume fraction of the positive electrode conductor material
relative to the total volume of solids in the positive electrode.

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1-Formulation
Positive_Coating_Porosity
Bulk volume of the positive coating material divided by the volume of the
pores of the positive coating material. Linked directly to tortuosity.

Positive_Coating_Tortuosity
The shortest distance between two points for mass transfer. Linked directly to
porosity.

Positive Active Material Maximum Site Concentration in mAh/g


The maximum concentration of lithium ions in the positive electrode (in
mAh/g).

Positive Active Material Molecular Diffusivity


The molecular diffusivity of the positive electrode active material.

Positive Active Material Particle Radius


The particle radius of the positive electrode active material.

Positive Active Material Specific Heat


The specific heat of the positive electrode active material.

Positive Active Material Thermal Conductivity


The thermal conductivity of the positive electrode active material.

Output: Positive_Coating_Thickness - Formulation


Displays the thickness of the positive electrode coating geometry.

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2-Kinetics
ECH Li+RateExpPos (a)
Specifies the rate exponent for the positive electrode Li+ reactant in the
elctrochemical reactions.

ECH LiRateExpPos (b)


Specifies the rate exponent for the positive electrode Li+ product in the
elctrochemical reactions.

Positive_Anodic_Transfer_Coefficient_(Alpha a)
Specifies the anodic apparent transfer coefficient for the Butler-Volmer
reaction method.

Positive_Cathodic_Transfer_Coefficient_(Alpha c)
Specifies the cathodic apparent transfer coefficient for the Butler-Volmer
reaction method.

Positive_Specific_Exchange_Current
Specifies the positive electrode exchange current density.

Positive_Vacancy_Rate_Exponent_(c)
Specifies the positive electrode vacancy rate exponent for calculating the
equilibrium potential activity term.

3-Initial Conditions
Positive Coating Initial Stoichiometry
The fractional loading concentration of lithium ions in the positive
electrode, represented on a scale from 0 to 1.

Positive Conductor Electrical Conductivity


The positive electrode conductor electrical conductivity.

Equilibrium Potential Positive


Table that contains the half-cell equilibrium potentials for the positive electrode. You provide the table as a .csv
file in the following format:

<Number> <X> <E(V)> <dE/dX(V)> <d2E/dX2(V)>

Positive Electrode Conductor Definition


Contains the physics models including material properties, and initial conditions for the positive electrode
conductor.

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Positive Electrode Binder Definition


Contains the physics models including material properties for the positive electrode binder.

Positive Electrode Active Material Definition


Contains the physics models including material properties for the positive electrode active material.

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Negative Electrode Formulation Reference

The Physics > Negative Electrode Formulation custom tree allows you to modify the battery stack (pouch)
negative electrode formulation.

Negative Electrode Parameters

1-Formulation
Densities Negative_Active_Material_Density
The density of the negative active material.

Negative_Binder_Density
Density of the negative binder.

Negative_Conductor_Density
The density of the negative conductor.

Output (read only) Output: Negative_Solid_Density


Outputs the resulting density of the negative electrode based on the volume
fractions and material densities of the active material, binder, and conductor.
Weight Fractions Negative Active Material Solid Weight Fraction
The solid weight fraction of the negative electrode active material relative to
the total mass of the negative electrode.

Negative Binder Solid Weight Fraction


The solid weight fraction of the binder material relative to the total mass of the
negative electrode.

Negative Conductor Solid Weight Fraction


The solid weight fraction of the conductor material relative to the total mass of
the negative electrode.

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1-Formulation

Output (read only) Output: Negative Active Material Solid Volume Fraction
Outputs the volume fraction of the negative electrode solid active material
relative to the total volume of solids in the negative electrode.

Output: Negative Binder Solid Volume Fraction


Outputs the volume fraction of the negative electrode binder material relative
to the total volume of solids in the negative electrode.

Output: Negative Coating Solid Total Volume Fraction


Outputs the volume fraction of the negative electrode coating material relative
to the total volume of solids in the negative electrode.

Output: Negative Coating Solid Total Weight Fraction


Outputs the weight fraction of the negative electrode solid negative coating
material relative to the total mass of solids in the negative electrode.

Output: Negative Conductor Solid Volume Fraction


Outputs the volume fraction of the negative electrode conductor material
relative to the total volume of solids in the negative electrode.

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1-Formulation
Negative_Coating_Porosity
Bulk volume of the negative coating material divided by the volume of the
pores of the negative coating material. Linked directly to tortuosity.

Negative_Coating_Tortuosity
The shortest distance between two points for mass transfer. Linked directly to
porosity.

Negative Active Material Maximum Site Concentration in mAh/g


The maximum concentration of lithium ions in the negative electrode (in
mAh/g).

Negative Active Material Molecular Diffusivity


The molecular diffusivity of the negative electrode active material.

Negative Active Material Particle Radius


The particle radius of the negative electrode active material.

Negative Active Material Specific Heat


The specific heat of the negative electrode active material.

Negative Active Material Thermal Conductivity


The thermal conductivity of the negative electrode active material.

Output: Negative_Coating_Thickness - Formulation


Displays the thickness of the negative electrode coating geometry.

2-Kinetics
bruggeman parameters to Alpha neg electrode
model tortuosity / porosity The coefficient for the Bruggeman method, used to calculate the
correlation negative electrode effective electrical conductivity.

a neg electrode
A pre-exponential factor for the Bruggeman method.

b neg electrode
The exponent factor for the Bruggeman method.

The tortuosity for the negative coating, computed as τ = aχ−b. Where a is


the a neg electrode parameter, χ is the negative coating porosity, and b
is b neg electrode.

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2-Kinetics
ECH Li+RateExpNeg (a)
Specifies the rate exponent for the negative electrode Li+ reactant in the
elctrochemical reactions.

ECH LiRateExpNeg (b)


Specifies the rate exponent for the negative electrode Li+ product in the
elctrochemical reactions.

Negative_Cathodic_Transfer_Coefficient_(Alpha c)
Specifies the cathodic apparent transfer coefficient for the Butler-Volmer
reaction method.

Negative_Specific_Exchange_Current
Specifies the anodic apparent transfer coefficient for the Butler-Volmer
reaction method.

Negative Anodic Transfer Coefficient_(Alpha a)


Specifies the negative electrode exchange current density.

Negative Vacancy Rate Exponent_(c)


Specifies the negative electrode vacancy rate exponent for calculating
the equilibrium potential.

3-Initial Conditions
Negative Coating Initial Stoichiometry
The fractional loading concentration of lithium ions in the negative
electrode, represented on a scale from 0 to 1.

Negative Conductor Electrical Conductivity


The negative electrode conductor electrical conductivity.

Equilibrium Potential Negative


Table that contains the half-cell equilibrium potentials for the negative electrode. You provide the table as
a .csv file in the following format:

<Number> <X> <E(V)> <dE/dX(V)> <d2E/dX2(V)>

Negative Electrode Conductor Definition


Contains the material properties, physics models, and initial conditions for the negative electrode conductor.

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Negative Electrode Binder Definition


Contains the material properties and physics models for the negative electrode binder.

Negative Electrode Active Material Definition


Contains the material properties and physics models for the negative electrode active material.

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Current Collectors and Tabs Reference

The Physics > Current Collectors and Tabs custom tree allows you to modify the battery stack (pouch) current
collectors and tabs properties.

Solids
Positive Current Collector and Tabs
Allows you to specify the material properties for the positive electrode current collector and tabs.

Negative Current Collector and Tabs


Allows you to specify the material properties for the positive electrode current collector and tabs.

Negative_Collector_Density
The density of the negative electrode collector.

Positive_Collector_Density
The density of the positive electrode collector.

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Separator Reference

The Physics > Separator custom tree allows you to modify the battery stack (pouch) separator properties.

Solid
Separator Material Properties
Allows you to specify the material properties for the separator.

Separator Porosity Properties


Separator_Porosity
Bulk volume of the separator material divided by the volume of the pores of the separator. Directly linked to
tortuosity.

Separator_Tortuosity
The shortest distance between two points for mass transfer. Linked directly to porosity.

Separator_Density
The density of the separator.

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Electrolyte Reference

The Physics > Electrolyte custom tree allows you to modify the battery stack (pouch) electrolyte properties.

Electrolyte Parameters
Electrolyte Density
The density of the electrolyte mixture.

Electrolyte Molar Concentration Li+


The electrolyte lithium ion molar concentration.

Liquid Components
Solvent
The material properties for the electrolyte solvent. You are advised to not change these material properties.

LiClO4 PC DME 1 1
Allows you to specify the material properties for the electrolyte lithium ions.

Material Properties
Allows you to specify the electrolyte mixture material properties for the battery cell.

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OCV and SOC Reference

The OCV and SOC custom tree allows you to modify the initial state of charge (SOC) and voltage limits for a
battery stack cell.

State of charge (SOC) estimation is based on the specified voltage limits that are calculated analytically for a
single active phase electrode.

SOC_VoltageMax
Specifies the maximum voltage limit for the battery cell.

SOC_VoltageMin
Specifies the minimum voltage limit for the battery cell.

Initial SOC
Specifies the battery cell initial state of charge, represented on a scale from 0 (complete discharge) to 1 (full
charge).

Initialize SOC
A simulation operation that uses the voltage limits and the initial state of charge to compute the open circuit
voltage within the specified voltage limits for the initial conditions of the simulation.

OCV vs Absolute Capacity


A plot of the open circuit voltage (OCV) in relation to the absolute capacity of the battery cell.

OCV vs SOC
A plot of the OCV of the battery cell relative to the SOC, displayed on a scale from 0 to 1.

SOC Ranges
A plot of the SOC ranges for the battery cell.

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Solve Reference

The Solve custom tree allows you to modify the operating conditions and parameters for running the battery
stack (pouch) cell simulation.

The Simcenter STAR-CCM+ 3D Cell Design Capability simulates charge and discharge cycles using an input duty
cycle table.

Global Initial Temperature


The average battery cell temperature at the beginning of the simulation.

Initial SOC
The starting state of charge of the battery, ranging from a scale of 0 (complete discharge) to 1 (full charge).
This parameter is also available within the OCV and SOC custom tree.

Input Duty Cycle


Allows you to select a table to define the step-by-step procedure of your battery cycle simulation. These
structured steps that can be repeated until a specified criterion is reached.

Depending on the cycle you want to model, set the following table:

The input duty cycle includes rows to specify control boundary conditions for current, power, or voltage, and
to define stopping criteria and limit conditions. The available conditions for the input duty cycle table are
shown below:

Step Condition
Type 1 2 3 =<0 >=10
Specifies the charge or Charges the cell Discharges the Allows the cell Increments the Specifies a
discharge cycles and according to cell according to rest until cycle counter, repeat type. The
optional rest periods the given to the given the specified also referred to number of
until the specified end control control end condition as advance. repeat steps is
condition is reached. condition condition is reached. specified by the
(typically (typically StopValue.
current). current).
Control 0 1 2 3
Specifies the quantity N/A Specifies Specifies a Specifies a
that is kept constant constant constant constant power.
during the step. current that is voltage.
applied to the
cell.

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Current (A) Specifies the value for the chosen Control quantity, in corresponding units for that
The control value. property.
StopCriteria 2 3
Specifies a criterion to Sets a voltage- Sets the run
end the step. The based stopping time of the
procedure then moves criterion. step. By
to next step. default, all
values are
specified in
seconds.
StopValue Specifies the limit value for the chosen StopCriteria.
LimitCondition 0 1 2 3 4
Defines a limit that (None) Clears Limits the Sets a limit to Sets a power- Sets the time
must not be exceeded the condition current that is the cell based limit. limit for the
during a step. This setting. applied to the voltage. step. By default,
condition overrides the cell. Can be Can be used all values are
StopValue step if used with with Type 1 specified in
necessary. Type 1 and 2, and 2, and seconds.
For example, consider and Control 2 Control 1 and
a discharge step where (voltage 2(current/
the Control condition charge/ power charge/
is a constant discharge discharge) discharge)
and the conditions. conditions.
LimitCondition is a
specified voltage. If the
LimitCondition is
reached, the discharge
current is reduced to
maintain the limit
condition until the end
condition is reached.
LimitValue Specifies the limit value for the chosen LimitCondition, in corresponding units for
that property.

Simcenter STAR-CCM+ 3D Cell Design Capability stack template package contains some example duty cycle
tables to use for constant current charge/discharge simulations.

Duty Cycle Sim Op


A simulation operation that allows you to apply parameter changes that you make in the Solve custom tree
and to execute the duty cycle.

PRG_Time Step
Sets the initial duty cycle time-step prior to running the simulation.

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Convective_HTC
The convective heat transfer coefficient between the cell package foil and the surrounding environment.

T_Ambient
Sets the ambient temperature.

Program Variables
Lists the program variables used in simulation operations for running the battery cell simulation.

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Post Process Reference

The Post Process custom tree provides you with pre-defined plots and scenes for thermal and electrochemical
analysis of battery cell simulation results.

This section provides description for the pre-defined post-processing functionalities in


Simcenter STAR-CCM+ 3D Cell Design Capability .

Contents:
Thermal Analysis Reference
Electrochemical Analysis Reference
Analyze Duty Cycle Reference

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Thermal Analysis Reference

The Post Process > Thermal Analysis custom tree provides you with pre-defined plots and scalar scenes for
analyzing temperature distributions within the battery stack.

3D Cell Temperature Visualization


Provides a selection of scenes that display the temperature of the cell different perspectives.

Temperature on crossection planes through pos. and neg. Tabs


Provides a selection of scenes that display the temperature distributions on cross-section planes through the
positive and negative tabs centerline.

T_Threshold
Sets a the threshold value for the temperature threshhold scene.

temperature threshhold
A scalar scene, which displays only temperature distribution values above the specified T_Threshold
parameter.

Minimum, Maximum and Volume Average Cell Temperature [°C]


A plot of the minimum, maximum, and volume average temperature for the battery cell.

Total Heat of Battery Cell


A plot of the total heat that is generated by the battery cell.

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Electrochemical Analysis Reference

The Post Process > Electrochemical Analysis custom tree provides you with pre-defined plots and scalar
scenes for the electrochemical analysis of the battery stack data.

Electric Current Densities


Provides a selection of scenes that display the electric current distribution for the negative and positive current
collectors and tabs.

Neg and Pos Li+ concentration Vs Cell SOC


A plot that displays the correlation between negative and positive lithium ion concentration and cell state of
charge (SOC).

Molar Concentration Negative Active Material


A custom tree that provides pre-defined Layout Views with organized scenes of molar concentration
distribution of the negative electrode active material.

3D visulation:Surface vs Average Molar Concentration of Li+ in Neg. Active Material crossectiont


through center of neg tab

3D visulation:Surface vs Average Molar Concentration of Li+ in Neg. Active Material crossectiont


through center of pos tab

Molar Concentration Positive Active Material


A custom tree that provides pre-defined Layout Views with organized scenes of molar concentration
distribution of the positive electrode active material.

3D visulation:Surface vs Average Molar Concentration of Li+ in Pos. Active Material crossectiont through
center of neg tab

3D visulation:Surface vs Average Molar Concentration of Li+ in Pos. Active Material crossectiont through
center of pos tab

line section Li+ concentration plots


A custom tree that provides pre-defined plots for analyzing the distribution of lithium ion concentration in solid
electrodes in relation to the thickness of the electrode layers.

XY Electrolyte line section concentration plot

XY Solid Electrodes line section concentration plot normalized and horizontal line removed NEW

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Electric Potential
A custom tree that provides pre-defined plots and scenes for analyzing the distribution of the electric potential
and equilibrium curve verification.

Electric Potential Crossection

Chose part for Electric Potential crossection view

Electric Potentials

Negative Active Material Equilibrium Potential

Positive Active Material Equilibrium Potential

Negative Voltage Equilibrium Curve

Positive Voltage Equilibrium Curve

OCV vs Absolute Capacity

SIEMENS DIGITAL INDUSTRIES SOFTWARE 47


Simcenter STAR-CCM+ 3D Cell Design Capability 2310 | User Guide

Analyze Duty Cycle Reference

The Post Process > Analyze Duty Cycle custom tree provides you with pre-defined plots and scalar scenes for
analyzing the battery stack duty cycle, including voltage, current and capacity.

Cumulative Capacity vs Time


A plot of the cumulative capacity of the battery cell over time.

Cell current and voltage


A plot displaying the current-voltage distribution for the battery cell.

Cell Voltage vs Cumulative Capacity


A plot the battery cell's voltage in relation to cumulative capacity.

SIEMENS DIGITAL INDUSTRIES SOFTWARE 48


SIEMENS DIGITAL INDUSTRIES SOFTWARE About SIEMENS DIGITAL INDUSTRIES SOFTWARE

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