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Structure of Atom DPP 10 SOLUTION

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39 views4 pages

Structure of Atom DPP 10 SOLUTION

Uploaded by

Vikas Kakkar
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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CLASS : XIth SUBJECT : CHEMISTRY

DATE : Solutions DPP No. : 10

Topic :- STRUCTURE OF ATOM


1 (d)
The values of quantum number will give idea about the last subshell of element. From that
value we can find the atomic number of element, 𝑛 = 3 means 3rd-shell
𝑙=0
𝑚 = 0}means subshell
It means it is 3𝑠-subshell which can have 1 or 2 electrons.
∴ Configuration of element is
1𝑠2,2𝑠2,2𝑝6,3𝑠1―2
∴ Atomic 𝑖.𝑒., number is 11 or 12.
2 (a)
ℎ𝑣 = work function +𝐾𝐸;
or ℎ𝑣 = ℎ𝑣0 + 𝐾𝐸;
ℎ𝑐
ℎ𝑣0 = work function = 𝜆0 ;
where 𝜆0 is threshold wavelength.
3 (a)
The Sc atom has 3𝑑1,4𝑠2 configuration.
4 (a)
Wave number of spectral line in emission spectrum of hydrogen,

(1
𝑣 = 𝑅𝐻 2 ― 2
𝑛1 𝑛2
1
) …(i)
8
Given, 𝑣 = 9𝑅𝐻
On putting the value of 𝑣 in Eq. (i), we get
8
9 (1
= 𝑅𝐻 2 ― 2
𝑛1 𝑛2
1
)
8 1 1
= 2
― 2
9 (1) 𝑛2
8 1
―1=― 2
9 𝑛2
1 1
=
3 𝑛2
∴ 𝑛2 = 3
Hence, electron jumps from 𝑛2 = 3 to 𝑛1 = 1
5 (b)
J.J. Thomson (1987) was first experimentally demonstrated particle nature of electron. It
was first of all proposed by Millikan’s oil drop experiment.
6 (b)
𝑛ℎ ℎ
Angular momentum for 𝑛 and (𝑛 + 1) shells are 2𝜋 and (𝑛 + 1)2𝜋.
7 (b)
4 4
The volume of nucleus : volume of atom, 3𝜋𝑟3𝑛:3𝜋𝑟3 atom.
8 (c)
O2― has 10 electrons but 8 neutrons ( 8O16).
10 (c)
Possible mol. wt. may be 18,20,19,20,22,21 respectively for H1H1O16,H2H2O16,H1H2O16,H1
H1O18,H2H2O18,H1H2O18 .
11 (c)
Magnetic moment = [𝑛(𝑛 + 2)] where 𝑛 is number of unpaired electrons .
12 (d)
Hertz for the first time noticed the effect.
13 (b)
Cr (24):[Ar]3𝑑54𝑠1
Cr3+:[Ar]3𝑑34𝑠0
14 (d)
A part of energy of photon (ℎ𝑣-work function) is used for kinetic energy of electrons.
15 (b)
𝑒 1.6 × 10―19
for electron (𝑒) =
𝑚 9.1 × 10―28
= 1.758 × 108
𝑒 1.6 × 10―19
for proton (𝑝) =
𝑚 1.672 × 10―24
= 9.56 × 104
𝑒 0
for neutron (𝑛) = =0
𝑚 1.675 × 10―24
𝑒 2
for α ― particle = = 0.5
𝑚 4
𝑒
Hence, the increasing order of 𝑚 is as
𝑛<𝛼<𝑝<𝑒
16 (d)
Ionisation energy of nitrogen =energy of photon
𝑐
= 𝑁ℎ
𝜆
where, 𝑁 = 6.02 × 1023
𝑐 = 3 × 108ms―1
𝜆 = 854 Å = 854 × 10―10m
6.02 × 1023 × 6.6 × 10―34 × 3 × 108
=
854 × 10―10
= 1.4 × 106 J mol―1
= 1.4 × 103 kJ mol―1
17 (a)
1 2
𝑒/𝑚 for proton = 1;𝑒/𝑚 for 𝛼 = 4
18 (a)
ℎ𝑐
𝐸=𝑛
𝜆
𝑛 × 6.6 × 10―34 × 3 × 108
ℎ = 6.6 × 10―34 Js or 1J =
4000 × 10―10
19 (c)
We know that the energy is emitted in the form of quanta and is given by,
ℎ𝑐
∆𝐸 = ℎ𝑣 =
𝜆
ℎ𝑐
or 𝜆 = ∆𝐸
6.62 × 10―27 × 3 × 1010
=
3 × 1.6 × 10―12
= 4.14 × 10―5 cm
= 4140 Å
ANSWER-KEY
Q. 1 2 3 4 5 6 7 8 9 10
A. D A A A B B B C D C

Q. 11 12 13 14 15 16 17 18 19 20
A. C D B D B D A A C B

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