23-04-2024 - OUT GOING SENIORS - EAPCET - GT-02 - Key & Sol's
23-04-2024 - OUT GOING SENIORS - EAPCET - GT-02 - Key & Sol's
23-04-2024 - OUT GOING SENIORS - EAPCET - GT-02 - Key & Sol's
11) 4 12) 3 13) 1 14) 1 15) 2 16) 3 17) 4 18) 2 19) 1 20) 2
21) 2 22) 4 23) 3 24) 3 25) 3 26) 3 27) 3 28) 2 29) 1 30) 1
31) 4 32) 4 33) 3 34) 2 35) 2 36) 1 37) 2 38) 2 39) 1 40) 3
41) 3 42) 3 43) 4 44) 3 45) 2 46) 2 47) 2 48) 2 49) 4 50) 1
51) 1 52) 2 53) 3 54) 3 55) 1 56) 2 57) 2 58) 3 59) 2 60) 3
61) 2 62) 3 63) 3 64) 2 65) 4 66) 2 67) 3 68) 1 69) 1 70) 2
71) 1 72) 2 73) 3 74) 2 75) 2 76) 4 77) 1 78) 2 79) 4 80) 4
PHYSICS
81) 1 82) 1 83) 2 84) 4 85) 4 86) 3 87) 3 88) 2 89) 1 90) 1
91) 4 92) 3 93) 4 94) 4 95) 1 96) 1 97) 1 98) 1 99) 1 100) 4
101) 4 102) 4 103) 3 104) 2 105) 1 106) 1 107) 4 108) 3 109) 4 110) 3
111) 3 112) 1 113) 3 114) 1 115) 2 116) 2 117) 2 118) 1 119) 1 120) 3
CHEMISTRY
121) 2 122) 3 123) 4 124) 3 125) 1 126) 4 127) 3 128) 3 129) 4 130) 2
131) 1 132) 4 133) 2 134) 1 135) 1 136) 4 137) 1 138) 3 139) 2 140) 2
141) 3 142) 3 143) 1 144) 1 145) 1 146) 3 147) 2 148) 2 149) 3 150) 1
151) 3 152) 4 153) 3 154) 4 155) 3 156) 1 157) 3 158) 2 159) 2 160) 4
Narayana IIT Academy 23-04-2024_ALL OUT GOING_SENIORS_EAPCET_GTM-02_Key & Sol
MATHS
1. rn
2 x 1 16 x
3 x 16 1
17
x 5.6
3
x 5.6
x {1, 2,3, 4,5}
Domain of g(x) = {1,2,3,4,5}
a b
A
2. c d
f ( A) det A ad bc
i) One-one – different matrix have same det
1 0
Ex : A A 0
2 0
0 0
B B 0
0 0
(II) onto - every codomain has pre
image in the domain
That is every real value a matrix
∴ f is onto but not one- one
1 1 1 27
.......... n terms
3. 1.5 5.9 9.13 109
1 1 1 1 27
..........
1.5 5.9 9.13 4n 3 4n 1 109
1 4 4 4 4 27
..........
41.5 5.9 9.13 4n3 4n1 109
1 1 1 1 1 1 1 1 27
1 ........
4 5 5 9 9 13 4n3 4n1 109
1 1 27
1
4 4n 1 109
1 4n 27 n 27
4 4n 1 109 4n 1 109
n 27
4. We have,
A and B are two square matrices
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Narayana IIT Academy 23-04-2024_ALL OUT GOING_SENIORS_EAPCET_GTM-02_Key & Sol
T T
AB BA AB BA 2 BA
T T T T
AB BA AB BA 2 BA
T
AB BA
AT BT BA
If A and B are symmetric matrices
then AB= BA which is not possible
If A and B are skew symmetric matrices then AB = BA which is not possible
A and B are neither symmetric nor skew symmetric.
5. co factor -1 is = - (0-4) = 4=m
Co factor of 1 is = +(1-0) = 1 = n
m + n = 4+1=5
0 3
6. A
0 0
0 3 0 3 0 0
A2 0
0 0 0 0 0 0
Similarly A3=0, A4 = 0……. A2023 = 0
F ( A) A A2 A3 ... A2023
0 3
F ( A)
0 0
0 3 1 0 1 3
f ( A) I
0 0 0 1 0 1
7. z1 z2 k
Locus of z is an ellipse
z 1
8. Arg
z 1 4
z 1 x 1 iy x 1 iy
z 1 x 1 iy x 1 iy
2y
1
x y2 1
2
x2 y 2 2 y 1 0
Locusof zisacircle
n 2 3 3
i i i i i
9. 3 1 3 3 3 3 ....
n 0
1 1 3 3(3 i ) 3(3 i ) 9 3i
i 3i 3i (3 i ) (3 i ) 9 1 10
1
3 3
(1 i ) 2025
1 i 2022 3
10. Arg 2022
Arg (1 i )
(1 i ) 1 i
= Arg ( i ) 2022 .( 2 2i ) Arg 2 2i
Page 3
Narayana IIT Academy 23-04-2024_ALL OUT GOING_SENIORS_EAPCET_GTM-02_Key & Sol
4
2
11. x 2 px 2 p 8 0
b2 4ac 0
4 p2 4.1 (2 p 8) 0
p2 2 p 8 0
p( p 4) 2( p 4) 0
(p+4)(p-2) <0
p (4, 2)
12. sin 4 x cos3x
sin 3 x
2
sin 4 x sin 3 x 0
2
x 2 7x 2
2cos sin 0
2 2
x2
cos 0
2
x2
2n 1 2
2
x 2n 2 6 , 2
(or)
7x 2
n
2
2n
x
7 14
For n 0 & n=1
5
x , 6 , 2
4 14
13. put n = 4 r= 3 then f 431(h) 0
f 2 (h) 0
f (x) x x3 4x2 x 1 0
f ' x 4 x 3 3x 2 8 x
f " x 12 x 2 6 x 8
f '' h 0 12h 2 6h 8 0
6 h 2 3h 4 0
3 9 96 3 105
h
12 12
Page 4
Narayana IIT Academy 23-04-2024_ALL OUT GOING_SENIORS_EAPCET_GTM-02_Key & Sol
3 105 3 105
,
12 2
12( )2 35
2 2
sin x
14. 81 81cos x 30
2
81cos x a
81
a 30
a
a2 30 a 81 0
(a 27)(a 3) 0
a 27 or a 3
2 2
34cos x 33 or 34cos x
31
x
6
15. The number of diagonals of polygon with n-sides is n ( n 3)
2
n ( n 3)
35
2
n ( n 3) 70 10 7 n = 10
The number of triangles formed by joining three vertices of a polygon having AB as one of its side =
8C1 = 8
16. Total points = 10. Non collinear points = 6
Collinear points = 4
No of triangles formed one of at least vertex from the collinear and other from the non collinear
6c2 .4c1 6c1.4c2 60 36 96
17. (7 5 x ) 2
3
2
2 5x
3 5x3
7 1 7 -1< 7 1
7 5 x 7
7 7
x
5 5
7 7
x ,
5 5
7
c 5c+7 = 14
5
18. (1 x)(1 x)n (1 x)[1 nx nc2 x2 ....... (1)n xn ] x n cofficient ( 1) n ( 1) n 1.n
f (2 0 2 3) 1 ( 1) 2 0 2 2 .(2 0 2 3)
=-1 + 2023 = 2022
19. 3 x 2 A (2 x 2 3) ( Bx 1)( x 1)
put x 1
Page 5
Narayana IIT Academy 23-04-2024_ALL OUT GOING_SENIORS_EAPCET_GTM-02_Key & Sol
1
1 A(2 3) A
5
Comparing x2 coefficient on both sides
2
0 = 2A+ B B =
5
2
Comparing x coefficient on both sides
13
3 = B+C C
5
A-B+C = 2
, are roots of equation 3x2 16x 5 0
16 5
,
3 3
NOW,
20.
tan1 tan1 tan1
1
1
tan1 tan [ 1]
1 1
21. we have log 9 3 2 2 5 4 5
log 9 6 2 3 10 4 5
log 9 3 10 6 2 4 5
log 3 10 3 2 2
log 3 10 log 3 8
log 3 32 1 log 3 32 1
sin h 1 3 cos h1 3
2 2
22. 2 x y 4 x 4 y 0
x xh, y yk
2 x 2 y 2 X 4h 4 y 2k 4 2h 2 4 h k 2 4k 0
2 x2 y 2 8x 8 y 18 0
h 1 , k 2
x 2y 5 0
23.2x2+3xy–5y2+2x–23y-24=0
a=2, 2h=3, b=-5, 2g=2, 2f=-23, c =-24 h=3/2 g=1 & f =-23/2
hf bg hg af
p = 2
, 2
=
ab h ab h
Page 6
Narayana IIT Academy 23-04-2024_ALL OUT GOING_SENIORS_EAPCET_GTM-02_Key & Sol
3 23 3 23
2 ( 2 ) (5)(1) 2 (1) 2( 2 )
,
9 9
2(5) 2(5)
4 4
69 3 46 69 20 49
5 4
= 4 2 2 = , 2
40 9 , 40 9 49 49
4 4 4 4
(h , K) = (1,-2)
x= X + h = X + 1, y= Y + k = Y – 2
2(X + 1)2 +3(X +1)(Y - 2) - 5(Y - 2)2 + 2(X + 1) -23(Y -2) – 24 = 0
2(X2 + 2X + 1) + 3(XY – 2X + Y - 2) - 5(Y2 + 4 – 4Y) + 2X + 2 – 23Y + 46 - 24 = 0
2X2 + 4X + 2 + 3XY – 6X + 3Y – 6 – 5Y 2 – 20 + 20Y + 2X + 2 – 23Y + 22 = 0
2X2 + 3XY – 5Y2 = 0
24. 2 1 1 3 2 1 4 3
n 1 n
f n tan tan1 1
tan 13.2 tan 1 4.3 ....... tan 1 n 1 n
1 2
tantan1 2 tan11 tan1 3 tan1 2 tan1 4 tan1 3 .......tan1 n1 tan1 n
x y
tan tan 1 n 1 tan 1 1 tan 1 x tan 1 y tan 1
1 xy
n
f n
n2
2021
f 2021
2023
2
25. x = log ( y y 1)
y y2 1 ex .
y 2 1 ex y
2e x y e2 x 1
e2 x 1 e x e x
y y
2e x 2
Y = sinhx
26. Given that,
1
tanh 1 coth 1 x log e f x for
x
x 1
Page 7
Narayana IIT Academy 23-04-2024_ALL OUT GOING_SENIORS_EAPCET_GTM-02_Key & Sol
20 3 2 15
60 30
1800
2 900 30 2
28. Given that
In ABC
a 3b 3c
a 3c 3b
a 3 c b
abc 4 c b
sb b 2 c b
2 2
a bc 2 c b
s c c c b
2 2
sin
A
s b s c
2 bc
A 2 c b c b 2 a 2
sin c b
2 bc bc 3 bc
AB AC
29. AG
3
i 3 j 4k 5i j 2k
3
4
2i j 2k
3
2
AG 22
3
Page 8
Narayana IIT Academy 23-04-2024_ALL OUT GOING_SENIORS_EAPCET_GTM-02_Key & Sol
r 3i 5 j 3k
31. PQ i 5 j 3k
PR 4 i 3 j 3k
PS i 7 j 1 k
1 5 3
4 3 3 0
1 7 1
146
17
Page 9
Narayana IIT Academy 23-04-2024_ALL OUT GOING_SENIORS_EAPCET_GTM-02_Key & Sol
3 3
ACB , ACD and CAD
5 10 3
In AD b
ACD,cos AD acos 2AD 2acos 2cos
5 AC 5 5 a 5
AD CD
On adding eq. (i) and (ii), we get cot15 cot 75
BD
AC
2 32 3 4
BD
AC : BD 4 :1
36. Let, AB is tall building CQ is short building
AB = H, CQ = h
H H
In ABC, tan 60 AC
AC 3
Hh
In BPQ, tan 30 PQ (H h) 3
PQ
AC PQ
H
(H h) 3
3
h 2
H 3H 3h 2H 3h
H 3
h : H 2 :3
Page 10
Narayana IIT Academy 23-04-2024_ALL OUT GOING_SENIORS_EAPCET_GTM-02_Key & Sol
44.
2x 3 y 1 0
2
y 1 ( x 2)
3
O.P.V we get 3
45.
4 x y 1
3x 4 y 1 0
m1 m2 19
tan 0
1 m1m2 8
46. PA + PB = 4
PA = 4 – PB
PA2 = 16 + PB2 – 8PB
A (2,0) B (0, -2)
(x-2)2 + y2 = 16+ (x-0)2 +(y+2)2 – 8PB
x2+ 4 - 4x + y2 = 16 + x2 + y2 + 4+ 4y-8PB
-4x – 16 – 4y = -8PB
x + y+4=2PB (S.O.B.S)
x +y + 16 + 2xy + 8x+8y = 4(x2+y2+4+4y)
2 2
Page 12
Narayana IIT Academy 23-04-2024_ALL OUT GOING_SENIORS_EAPCET_GTM-02_Key & Sol
a 2 l 3, 2 h 2 l , h = l , b = -1
h 2 ab
l 2 (2l 3)(1)
l 2 2l 3
l2 2l 3 0
l 2 3l l 3 0
( l 3)( l 1) 0
l R 3,1
48. ax2 – xy - 3y2 -5x + 20y +c=0 ------------(i)
a = a , b= - 3 , c = c
2g= -5 g 5
2
2f = 20 f = 10
h = 1
2h= -1
2
abc + 2fgh - ab2 - bg2 - ch2 = 0
a( -3 ) + 2(10) (-5) ( - 1 ) –a (100) + 3( 25 ) -c( 1 ) = 0
2 4 4
-12ac - 400a + 175 – c = 0 -------(ii)
Eq (i) Passing through (2,3)
4a - 6 - 27 - 10 + 60 + c = 0
4a + c = - 17
C = - 17 - 4a -------- (iii)
Put c in (ii)
a2 4a 4 0
2
a 2 0
a 2 put in iii
c= - 25
a - c = 27
49. x2 y2 1
C (0, 0) r 1 x y 1 0 let (h, k ) be image
h 0 k 0 2 (1)
1
1 1 11
h 1, k 1 = x 2 y 2 2 x 2 y 1 0
50.
1 2 x 4 2 y
1, 2 ,
3 3
x, y 2,5
2 2
x 2 y 5 10
a 4 , b 10 , c 19
Page 13
Narayana IIT Academy 23-04-2024_ALL OUT GOING_SENIORS_EAPCET_GTM-02_Key & Sol
51.
AB 2
2 32 12 10
10
, ( 10,3)
52) A (3,4), B
(3,2), C (1,4)
Midpoint BC
3 1 2 4
,
2 2
0 (2, 3)
BC (1 3)2 (4 2)2
44 2 2
r 2
ba r a 32 ( 2)2 = 9 x 2 = 18
53. Common tangents which are parallel are 3 x 4 y 4 0 and 6 x 8 y 7 0
3
so, the radius =
4
7
k 4 k
2
1 3
For k distance from other line is
4 4
1
Locus if centers of the circles is 3 x 4 y 0
4
54) A y 2 4 x 2 y 3 0
Page 14
Narayana IIT Academy 23-04-2024_ALL OUT GOING_SENIORS_EAPCET_GTM-02_Key & Sol
x2 y2
57. Ellipse: x 2 3 y 2 6 2
2
1
6 2
1 3
Therefore, cos ,
2 4 4
58) Let P h, k be the pole of chord of the hyperbola
59)
Page 15
Narayana IIT Academy 23-04-2024_ALL OUT GOING_SENIORS_EAPCET_GTM-02_Key & Sol
mx2 nx1
x-coordinate: x
mn
2 m 4n
y-coordinate: 8
mn
m 2
z-coordinate :
n 3
60. Let A 1, 2,3 , B 3, 1,5 , C 4,0, 3 dr’s of AB 2, 3, 2
Dr’s of AC 3, 2, 6
Now AB. AC 0
The points from aright angled at A
for right angled triangle, circumcentre is mid point of hypotenuse
1
circumcentre = midpoint of BC 7, ,1 , ,
2
4 r
61. Given points are (4,3,-5) and
(-2,1,-8)
Direction ratios a, b, c 6, 2,3
P a,3b, 2c 6,6, 6
For x y 2 z 0 12 12 0 true
f x. f y f xy x.......(i)
62) f y. f x f xy y.......(ii)
f f x . f y f y. f x f x .......(iii)
substituting f x x in Eq(i) we have f x x x 1
1
now, lim
f x 3 1
13 2
1
x 0 12 3
f x 2 1
63. Graph of given function f is continuous on everywhere.
So 0
F is not differentiate at x 3 because f has sharp edge at these points
So 2
xx x x
64) f x cot 1
2
Let u x x log u x log x
dv
similarly, v x x gives x x 1 log x
dx
2 2
f ' 1 1 0 1 1 2 1
11 2 4
65) f x Max 3 x, 3 x, 6
Page 16
Narayana IIT Academy 23-04-2024_ALL OUT GOING_SENIORS_EAPCET_GTM-02_Key & Sol
We know that a function is not differentiable at the points where it has sharp-corner point
In the above graph, we can see that only two sharp corner points are present
Therefore, the above function is not differentiable at two points which are x 3 and x 3
a 3 and b 3
a b 3 3 6
1 x2 2x
66. f ( x) 2
g ( x)
1 x 1 x2
x Tan
f 1 ( x) 4
g1 ( x ) 3
A 5m
y B
O x
67.
x 2 y 2 25
dx
3 m / sec
dt
dy
4 m / sec
dt
Y=3
2
68. y ea bx
dy 2
e a bx .(2bx)
dx
dy
m 2 .e a b (2b) 2
dx
Sub (1,1) 1 eab a b 0, 2b 2
a 1 b 1
2 a 3b 2(1) 3( 1) 5
Page 17
Narayana IIT Academy 23-04-2024_ALL OUT GOING_SENIORS_EAPCET_GTM-02_Key & Sol
x
tan t
71. 2
2t
sin 2 x
1 t2
1 t2
cosx
1 t2
2dt
dx
1 t2
2dt
1 t2
2t 1 t 2
1 t2 1 t2
72. I x 2 x 3dx
Page 18
Narayana IIT Academy 23-04-2024_ALL OUT GOING_SENIORS_EAPCET_GTM-02_Key & Sol
x dx
0
x32 2
3 3
2
x
76. e .sin 6 x dx
0
w.k.t
I m e x .sin m x
0
Page 19
Narayana IIT Academy 23-04-2024_ALL OUT GOING_SENIORS_EAPCET_GTM-02_Key & Sol
m m 1
I m 2
1 m2
6 6 1
I6 I4
1 36
36
I4
37
144
629
77.
y x2 2x 1
dy
2x 2
dx
p 1, 4 4
1
1
A y dx Lb
0
2
1
x3 1
x2 x 2
3 0 3
dy
x 1 cos y sin x 1 cos y
78. dx
dy 1
79. e 2 x , y log 2
dx 16
dy e2x dx
Page 20
Narayana IIT Academy 23-04-2024_ALL OUT GOING_SENIORS_EAPCET_GTM-02_Key & Sol
dy dy
80. y log e 0.5 0 log 0.5dx
dx y
x
y 0.5
1
When x , y k 0
2
PHYSICS
81. Strong nuclear force 1038
Weak nuclear force 10 25
Fs 1038
25 1013
F 10
Page 21
Narayana IIT Academy 23-04-2024_ALL OUT GOING_SENIORS_EAPCET_GTM-02_Key & Sol
dx 1 1
V
dt 2 ax b 2 ax b
dx
2a
dv d 1 dt
a
dt dt 2 ax b (2 ax b ) 2
2
1
Acceleration (a)=-2av
2ax b
3
accetaration a=-2av
87. CONCEPT
88. x 2 cos t
Is comparing with x a cos t
A =2 =1
2 2
T 2
1
89. Total distance travelled = h 2h1 2h2 ......
h 2e 2 h 2e4 h....
V2 2 v
2
4 v
4
2e 2e .......
2g 2g 2g
V 2 2e 2 v 2 1 1 e 2 2e 2 v 2
2g g 1 e 2 1 e 2 2 g
1 e2
2
h
1 e
90.
mg 3mg
T ma 1 ; T ma 2
2 2
From (1) and (2)
1 3mg mg 3 1
a g
2m 2 2 4
So, net acceleration on COM is
a1 a 2 2a a
an
2 2 2
3 1
a n g
4 2
91. CONCEPT
92.
Given,
Radius of earth,
Page 22
Narayana IIT Academy 23-04-2024_ALL OUT GOING_SENIORS_EAPCET_GTM-02_Key & Sol
Fl Fl
94. Y 2
Al r t
ll / r2 l / D2
L 100
l 2
2
10103
D (0.1)
L
l 5 103
D 2
L
l 3.33 103
D 2
L 2
l 2 4 20 10 3
D 10
95. Given A1 : A2 : A3 1:2:3
Y1 :Y2 : Y3 3:2:1
Page 23
Narayana IIT Academy 23-04-2024_ALL OUT GOING_SENIORS_EAPCET_GTM-02_Key & Sol
l1 : l2 : l3 1:1:1
F1 : F2 : F3 1:1:1
e1 : e2 : e3 ?
Fl Fl
w.r.t Y e
Ae AY
1 1 1
e1 : e2 : e3 : :
AY
1 1 A2Y2 A3Y3
1 1 1 1 1 1
: : : :
1 3 2 2 3 1 3 4 3
e1 : e2 : e3 4:3:4
96. Q mL mSt m L S.t
h
10 0.05
2 10
h 125 10 4 m
T
99. Young modules Y
r2
Tl
Then elongation l
r2 y
l
or l
r2
3KT
Vx 2 V12 m KT / m.........(i) V22 3KT .........(ii )
3 2m
V12 KT / m
V22 3 KT
2m
V12
2/3
V22
V1
2/3
V2
101. 7th harmonic, closed organ pipe
7v
f1
4l1
4th harmonic open organ pipe
4v
f2
2l2
f1 f 2
7v 4v
4l1 2l2
l1 7
l2 8
V V0
f1 f
102. V
v 6
v0 , s. f 1 f
5 5
f
100 20%
f
103. R.I is
i 2r
sin i sin 2r 2 sin r cos r
2 cos r
sin r sin r sin r
cos r
2
r cos 1
2
i 2 cos 1
2
104. Diagram based
Page 25
Narayana IIT Academy 23-04-2024_ALL OUT GOING_SENIORS_EAPCET_GTM-02_Key & Sol
105. z 24i 30 j 28 k N/C
A 20i
E.A
24 20
2
480 Nm C
106.
1 Q
VA VB V .
4 0 R
no change in potential
R1 l
107. R2 100 l
2 l
3 100 l
200 2l 3l
200 5l
200
l 40cm
5
1 2
108. V
2
y 4x
dv y2
E V 2x
dx 2
dv dv dv
E i j k
dx dy dz
1
( 2i . 2 y j )
2
2i y j
2i j
Page 26
Narayana IIT Academy 23-04-2024_ALL OUT GOING_SENIORS_EAPCET_GTM-02_Key & Sol
112. L n 2V n 2 Al
1 2
U Li
2
1 B2
U L
2 n 2
1 B2
U o n 2 Al 2 2
2 on
1 2
U B Al
2 o
117. A
Z X A 4 Z 2 Y 4 Z He
KE Q value m x m y mHe c 2
118.
119. Logic gates : AND , OR, NOT, NAND & NOR
Truth table
A B Q
0 0 0
x y 0 1 1
x y p x y Q y.x R P Q
1 0 1
1 0 1 0 1 1 0
1 1 1
120. The loss of strength of a signal while propagating through a medium is called Attenuation.
CHEMISTRY
h h 6.625 1034 Js
121. The de-Broglie equation is, v v 4 103 m / s The kinetic
mv m 9.110 kg 182 10 m
31 9
1 1 2
KE mv 2 9.11031 kg 4 103 m / s 7.28 10 24 J
2 2
n2
122. The relation of the radius of orbit is given as rn r0
Z
n2
52.9 pm 52.9 pm
Z
n2 Z
2 4
The energy is given by, En E0 Z 2.18 1018 n 2.18 10 18 n2
2 2
n n
For n= 2, the energy is given by , E n 2.18 10 18 2 8.72 10
2 18
J
1s 2 , *1s 2 , 2 s 2 , * 2 s 2 , 2 p X2 2 p y2
Thus C2 has only pi bonds according to molecular orbital theory
126. In NH3, NH4, central atom Nitrogen Undergoes Sp3 hybridisation
2 KE
127. The kinetic energy is given by vrms
M
3RT 2 4 103
KE and 500m / s
2 32 103
2
129. The chemical reaction is as follows. 2 KMnO4 10 I 5I 2 2Mn
N – factor of KMnO4 5
Number of equivalent of KMnO4 Number of equivalent of I 0.02 V 5 60 0.01 2
v 6mL
1
1 mol MnO42 mol of MnO2
3
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Narayana IIT Academy 23-04-2024_ALL OUT GOING_SENIORS_EAPCET_GTM-02_Key & Sol
Moreover ,
2
1 mol MnO42 mol MnO4
3
131. The energy required by 12 g of graphite is 248 kJ/ mol. Therefore, the energy require by 6 g is 124 kJ / mol.
124kJ / mpl cv T2 T1 cv 31 25
The heat required is given by
20.6kJ / K
132. G 2.303RT log K
G 5.74KJ / mol
133. Because of common ion effect, the solubility of AgCl in 0.1M of KCl will be less.
HCOOH conc
. H 2 SO 4
CO H 2 O
138. CuI 2 is not stable does not exist due to Iodide ion I
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Narayana IIT Academy 23-04-2024_ALL OUT GOING_SENIORS_EAPCET_GTM-02_Key & Sol
R C N H3O R COOH
Ans is Nitrile
140. Conceptual
2.303 a
141. K log
t ax
2.303 100
t 2
log
6.93 10 100 90
2.303
t log
6.93 10 2
2.303
t 102
6.93
33
Z atomicweight
142. The density is given by
a3 N 4
0.2 500
143. The number of moles of NaOH 0.1mol
1000
0.1 200
The number of moles of H 2 SO4 0.01M
1000 2
6
The number of moles of urea 0.1M
60
w2 1000
144. Tb K b
M2 w1
x 1000
0.052 0.52
y 60
x
6 103
y
0
145. Ecell 0.34 0.76 1.1V
2.303RT
E E0 logQ
nF
2.303RT Zn 2
E E0 log 2
nF Cu
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Narayana IIT Academy 23-04-2024_ALL OUT GOING_SENIORS_EAPCET_GTM-02_Key & Sol
0.059 C
E 1.1 log 2
n C1
C2 H 5 I C2 H 4 HI
2.303 p 2.303 2
k log log 3103 min1
t p0 x 1000 0.1
147. Sodium rosinate is a filler, which increase the lathering property of soap.
148.
Kernite is B Na2 B4O7 .4 H 2O
Cryolite is Al Na3 AlF6
The S8 molecule has both monoclinic as well as rhombic.
149.
573k
150. Xe F Xe F
2 60 70atm 6
Xe F6 H 2O XeOF 4 2HF
Xe F6 3H20 XeO3 3HF
y XeOF4 square pyramidal
z XeO3 pyramidal
151. Secondary valency gives the intimation of co-ordination number.
152.
[ Co( NH 3 )6 ]3 Co 3 3d 6
t 2 g 6eg o
[CoF6 ]3 Co 3 3Cl 6 t 2 g 4 eg 2
[ Ni (Co) 4 ] Ni 3d 8 4 S 2 t 2 g 4eg 6
[ Fe(CN ) 6 ]3 Fe 3 3d 5 t 2 g 5eg o
A B C D
II V I III
154. Conceptual
157. Lucas reagent is anhydrous ZnCl 2 and HCl alcohol undergoes carbon oxygen fission to forms
stable carbocation. Benzyl, 3 0 carbocation and allylic cation. They react immediately to form
low soluble organic chlorides giving turbidity.
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Narayana IIT Academy 23-04-2024_ALL OUT GOING_SENIORS_EAPCET_GTM-02_Key & Sol
159. The hydrogen atom does not show hybridisation the compound (CH3 ) 4 C has 20 hybridised
orbital. Therefore, option (2) is correct.
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