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Tutorial 5

This document contains a tutorial on physical chemistry equilibrium with 14 questions. It asks students to define equilibrium, differentiate between chemical and physical equilibrium, write equilibrium expressions, discuss Le Châtelier's principle, and calculate various equilibrium constants and concentrations.

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aisyahfadhilah12
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18 views

Tutorial 5

This document contains a tutorial on physical chemistry equilibrium with 14 questions. It asks students to define equilibrium, differentiate between chemical and physical equilibrium, write equilibrium expressions, discuss Le Châtelier's principle, and calculate various equilibrium constants and concentrations.

Uploaded by

aisyahfadhilah12
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
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TUTORIAL : PHYSICAL CHEMISTRY CLB 10703

October Semester 2023

Name :
Student ID : Group :

Tutorial 5

1. Define equilibrium. Differentiate between chemical equilibrium and physical


equilibrium. Give examples.

2. Describe homogeneous equilibrium and heterogeneous equilibrium.

3. Write equilibrium constants Kc expressions for the following reversible reactions.

a) CO (g) + 3H2 (g) ↔ CH4 (g) + H2O (g) b) 2TiCl3 (s) + 2HCl (g) ↔ 2TiCl 4(s) + H2 (g)

c) H2O (l) ↔ H⁺ (aq) + OH¯ (aq) d) CH4 (g) + Cl2 (g) ↔ CH3Cl (g) + HCl (g)

4. Write expressions for the equilibrium constants K p for the following reactions.
a) 2SO2 (g) + O2 (g) ↔ 2SO3 (g) b) PCl5 (g) ↔ PCl3 (g) + Cl2 (g)

c) NH3 (g) + HCl (g) ↔ NH4Cl (s)

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5. Discuss in details about Le Chaterlier’s Principle.

6. Heating solid sodium bicarbonate in a closed vessel establishes the following equilibrium:
2 NaHCO3 (s) ↔ Na2CO3 (s) + CO2 (g) + H2O (g)

Predict the equilibrium position of the reaction if

a. some of the CO2 were removed from the system.


b. some solid Na2CO3 were added to the equilibrium mixture.
c. some of the solid NaHCO3 were removed from the system.
d. some of catalyst were added to the system.

7. At a specified temperature T °C, the following equilibrium reaction was conducted in a 2.75 L
flask.
CO2 (g) + N2 (g) ↔ CO (g) + NO (g)
Calculate the equilibrium constant Kc if 0.94 mol of N2, 0.23 mol of CO2, 1.14 mol of CO and
0.85 mol of NO were found at equilibrium.

1 Universiti Kuala Lumpur |Malaysian Institute of Chemical and Bioengineering Technology


TUTORIAL: PHYSICAL CHEMISTRY CLB 10703

October Semester 2023

8. Determine the K c value for the reaction below at 298 K.


½N2 (g) + ½ O2 (g) + ½ Br2 (g) NOBr (g)

Given the following data:


2NO−(g) ½ N2 (g) + ½ O2 (g) 1
Kc = 2.6 x 1017
NO(g) + ½ Br2(g) NOBr (g) 2
K = 2.34

9. Consider the heterogeneous equilibrium below.


MO (s) + H2 (g) ↔ M (g) + H2O (g)

At 29°C, 1.6 mol of metal oxide, MO and 0.8 mol of H2 reacted to produce 0.014 mol of M and
0.014 mol of water at equilibrium. Calculate the Kp value at 29°C.

10. A sample of air is compressed with 0.76 mol dm-3 N2 and 0.15 mol dm-3 O2. It is then heated to
1500 K and is allowed to reach equilibrium.
N2 (g) + O2 (g) ↔ 2NO (g)
Calculate the concentrations of N2, O2 and NO that will present at equilibrium if given Kc =
1.63 x 10-1 at 1500 K?

11. In a 1.25 L vessel, 1.34 moles of phosgene gas, COCl2 were allowed to decompose into CO
and Cl2 at 180°C. At equilibrium, it is found that 26.6% of the phosgene had been decomposed.
Determine the equilibrium constant, Kp for the reaction at same temperature.

12. Consider the reaction: ½ A (g) + 2B (g) ↔ CD (g)


If 0.78 moles of gas A and 0.35 moles of gas B were placed in a 1.5 liter container at 150°C, the
equilibrium concentration of gas CD is found to be 0.102 M. What is the Kc value for this
reaction at 150°C?

13. The Kp value for reaction below at 700 °C is 167.5.


C(s) + CO2 (g) ↔ 2CO (g)
Calculate the equilibrium partial pressure for CO2 if the partial pressure given for CO is 0.50
atm.
14. What is the meaning of reaction quotient? Compare with equilibrium constant.

2 Universiti Kuala Lumpur |Malaysian Institute of Chemical and Bioengineering Technology

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